The influence of reducing conditions on the dissolution of a Mn-rich slag from pyrometallurgical recycling of alkaline batteries

The redox potential (Eh) is a key parameter for controlling the release of elements from solid materials. Nevertheless, this parameter is seldom taken into account during risk assessment studies within any regulatory framework. We studied the incidence of redox changes to the solid materials using two batch procedures: i) a gradient of redox conditions obtained using sodium ascorbate solutions at various concentrations; ii) N₂ bubbling in water. These experiments were performed on two Mn-rich slag samples coming from a pyrometallurgical plant that recycles alkaline batteries. Both samples differed slightly in their chemical composition and solid characterization (i.e. presence of Mn oxide) and presented different behaviours. The present study focused on the release of the main slag elements (i.e. Mn and Si) chosen as indicators of the dissolution of primary silicate phases. Solid phase analyses (SEM-EDS and XRD) were coupled with the monitoring of elements in leachates in order to understand their behaviour and the mechanisms involved. The results indicated that the solid composition plays an important role in the release mechanisms. The presence of Mn oxide enhanced the mobilization of Mn in the greatest reducing conditions (−320 ± 5 mV/SHE), to the extent that 42% of the total Mn was leached. This demonstrated the significance in studying the solid phases (using SEM-EDS and XRD) before and after any leaching experiment. From a laboratory practice point of view, it was easier to use sodium ascorbate and allowed, in our case, greater reducing conditions to be reached.     

Plastic pollution threat in Africa: current status and implications for aquatic ecosystem health

Environmental Science and Pollution Research - Rapid population growth and poor waste management practice are among the main drivers of plastic pollution in modern times, thus making Africa a...     

A decision framework for estimating the cost of marine plastic pollution interventions

Marine plastic pollution has emerged as one of the most pressing environmental challenges of our time. Although there has been a surge in global investment for implementing interventions to mitigate plastic pollution, there has been little attention given to the cost of these interventions. We developed a decision support framework to identify the economic, social, and ecological costs and benefits of plastic pollution interventions for different sectors and stakeholders. We calculated net cost as a function of six cost and benefit categories with the following equation: cost of implementing an intervention (direct, indirect, and nonmonetary costs) minus recovered costs and benefits (monetary and nonmonetary) produced by the interventions. We applied our framework to two quantitative case studies (a solid waste management plan and a trash interceptor) and four comparative case studies, evaluating the costs of beach cleanups and waste-to-energy plants in various contexts, to identify factors that influence the costs of plastic pollution interventions. The socioeconomic context of implementation, the spatial scale of implementation, and the time scale of evaluation all influence costs and the distribution of costs across stakeholders. Our framework provides an approach to estimate and compare the costs of a range of interventions across sociopolitical and economic contexts.     

Environmental fate of chlordecone in coastal habitats: recent studies conducted in Guadeloupe and Martinique (Lesser Antilles)

Environmental Science and Pollution Research - The organochlorine pollution by chlordecone, an insecticide spread in the past in banana plantations, is now recognized as a major ecological,...     

Preimplantation genetic diagnosis (PGD), a collaborative activity of clinical genetic departments and IVF centres

An Erratum has been published for this article in Prenatal Diagnosis 22 (5) 2002, 451. Preimplantation genetic diagnosis (PGD) requires the combined efforts of geneticists and workers in the field of reproductive medicine. This was studied on the basis of a questionnaire, sent to 35 members of the PGD Consortium of the European Society of Human Reproduction and Embryology (ESHRE). A reply was obtained from 20 centres. They represent the majority of activities in the field of PGD in the world. It is obvious that many of the activities (in vitro fertilisation, embryo culture and biopsy) take place in IVF units while others (counselling and diagnosis) are the responsibility of genetic diagnostic centres. The distances between both units vary considerably. In all but one centre sex determination is offered. Aneuploidy screening is offered in 13 out of 20 centres. PGD of translocations and other structural chromosome abnormalities is offered in all but one centre. The number of monogenic diseases offered varies considerably. In comparison to prenatal diagnosis PGD is more expensive. The majority of these costs are due to the IVF or ICSI procedure. The charges for PGD vary between about € 600 and € 4000. In 16 out of 20 centres the parents to be must sign an informed consent form. Copyright © 2001 John Wiley & Sons, Ltd.     

Participatory Model Calibration for Improving Resource Management Systems: Case Study of Rainwater Harvesting in an Indian Village

While planning resource management systems in rural areas, it is important to consider criteria that are specific to the local social conditions. Such criteria might change from one region to another and are hence best identified using a participatory approach. In this work, we propose a participatory framework to identify such criteria and derive their weights. These identified criteria and their weights are used as parameters to develop a quantitative model for evaluating efficiency of each system. Such a model can serve as a support tool for stakeholders to simulate and analyze “what‐if” scenarios, evaluate alternatives, and select one which best satisfies their requirements. We use existing systems to test the model by comparing efficiencies evaluated by the model to efficiencies perceived by the stakeholders. The model is calibrated by repeating the process until statistically significant correlation is achieved between evaluated and perceived efficiencies. The novelty of the proposed framework lies in treating efficiencies perceived by the stakeholders as the ground truth since they know these systems well and are their ultimate users. The framework is successfully demonstrated using case study of rainwater harvesting (RWH) systems in an Indian village. The resulting calibrated model can be used to plan new RWH systems in this region and similar regions elsewhere. The framework can be used to plan other resource management systems in various regions.     

Industrial ecosystems as technological niches

In this paper we consider industrial ecology as a novel and distinct state in the evolution of production systems trajectory. More specifically, adopting an evolutionary institutionalist's perspective at the socio-technical system level of analysis, we discuss the transition towards an industrial ecology-inspired industrial production system through the governance approach of strategic niche management (SNM). Towards this end, the paper first develops industrial ecology as a novel state of the industrial production socio-technical system paying particular attention at its technological component, then it discusses in detail the transition of this system through SNM, and examines whether existing implementations of the industrial ecology (industrial ecosystems and eco-industrial parks) are efforts embracing this philosophy and transition procedures. We conclude by stressing the importance of adopting the technology policy and strategic niche management perspectives in eco-industrial projects and we provide insights for accomplishing it in a more effective manner.