Simulation of global warming potential (GWP) from rice fields in the Tai-Lake region,China by coupling 1:50,000 soil database with DNDC model

Quantifying greenhouse gas (GHG) emissions from wetland ecosystems is a relatively new issue in global climate change studies. China has approximately 22% of the world's rice paddies and 38% of the world's rice production, which are crucial to accurately estimate the global warming potential (GWP) at regional scale. This paper reports an application of a biogeochemical model (DeNitrification and DeComposition or DNDC) for quantifying GWP from rice fields in the Tai-Lake region of China. For this application, DNDC is linked to a 1:50,000 soil database, which was derived from 1107 paddy soil profiles compiled during the Second National Soil Survey of China in the 1980–1990s. The simulated results show that the 2.34 Mha of paddy soil cultivated in rice–wheat rotation in the Tai-Lake region emitted about ?1.48 Tg C, 0.84 Tg N and 5.67 Tg C as CO₂, N₂O, and CH₄ respectively, with a cumulative GWP of 565 Tg CO₂ equivalent from 1982 to 2000. As for soil subgroups, the highest GWP (26,900 kg CO₂ equivalent ha^?1 yr^?1) was linked to gleyed paddy soils accounting for about 4.4% of the total area of paddy soils. The lowest GWP (5370 kg CO₂ equivalent ha^?1 yr^?1) was associated with submergenic paddy soils accounting for about 0.32% of the total area of paddy soils. The most common soil in the area was hydromorphic paddy soils, which accounted for about 53% of the total area of paddy soils with a GWP of 12,300 kg CO₂ equivalent ha^?1 yr^?1. On a regional basis, the annual averaged GWP in the polder, Tai-Lake plain, and alluvial plain soil regions was distinctly higher than that in the low mountainous and Hilly soil regions. As for administrative areas, the average annual GWP of counties in Shanghai city was high. Conversely, the average annual GWP of counties in Jiangsu province was low. The high variability in soil properties throughout the Tai-Lake region is important and affects the net greenhouse gas emissions. Therefore, the use of detailed soil data sets with high-resolution digital soil maps is essential to improve the accuracy of GWP estimates with process-based models at regional and national scales.     

可拓法评估煤矿瓦斯爆炸易发性

为了量化煤矿瓦斯爆炸的可能性,并为防治瓦斯爆炸提供量化指标,借鉴可拓学原理,对煤矿瓦斯爆炸易发性进行预评估。首先,详细阐述可拓学评估原理;接着,为了验证煤矿瓦斯爆炸易发性可拓评估的可行性,结合某一煤矿实例,比选煤矿瓦斯爆炸易发性的评价指标,并确定煤矿瓦斯爆炸易发性的分类标准,构建煤矿瓦斯爆炸易发性评估的经典域、节域和物元;然后,为了避免确定指标权重的人为主观因素的影响,提出用简单关联函数确定指标权重;最后,计算煤矿瓦斯爆炸易发性的关联函数值和关联度,确定瓦斯爆炸易发性的等级及其变量特征值。经计算,煤矿爆炸易发性的可拓评估结果为"很小"等级。同时,为了验证可拓评估结果的合理性,将其与模糊评估进行比较,两者所得评估结果相一致。从而表明:将可拓学应用于煤矿瓦斯爆炸易发性评估是合理可行的。     

离子色谱法测定大气中的甲磺酸

建立了以玻璃纤维膜-KB120气溶胶采样器采集大气中甲磺酸的采样方法;以0.1mmol·l-1H3BO3/0.1mmol·l-1 Na2B4O7为淋洗液的甲磺酸离子色谱分析方法.分析方法的精密度和准确度分别为5%和4%.并实测了青岛冬季大气气溶胶中MSA,SO2-4和NO-3的平均浓度分别为0.10μg·m-3,30.40μg·m -3和17.98μg·m-3.     

曝气浸没固定生物膜反应器处理化粪池出水

研究了以丝瓜络作为生物膜载体的曝气浸没固定生物膜反应器在处理化粪池出水时的可行性以及运行性能。结果表明,丝瓜络生物膜反应器可以在2周内成功启动;水力停留时间(HRT)对COD和氨氮的去除效果有显著影响,在水力停留时间为4 h的条件下,系统对COD和氨氮的去除率分别达到了78.5%和96.4%。另外,系统有较强抗有机污染物冲击负荷的能力,当COD和氨氮的进水浓度分别为59.3 mg/L和15.9 mg/L时,系统对有机污染物的去除效果较佳,去除率分别达到了80.0%和98.9%。     

Influence of Spartina alterniflora on the mobility of heavy metals in salt marsh sediments of the Yangtze River Estuary, China

Using bio-disturbed sulphide to trace the mobility and transformation of Cu, Pb, Ni and Zn in the sediments of the Spartina alterniflora-dominated salt marsh in the Yangtze River Estuary, measurements were made of the seasonal variations of acid-volatile sulphide (AVS) and of the simultaneously extracted metals (SEM) in the rhizosphere sediments. Microcosm incubation experiments recreating flooding conditions were conducted to evaluate the effect of AVS and other metal binding phases upon the dynamics of Cu, Pb, Ni and Zn in the salt marsh sediments. The results demonstrate that the ratio values of SEM/AVS have a significant seasonal variation in the rhizosphere sediments and that the anoxic conditions in the sediments were likely enhanced by S. alterniflora during the summer and autumn compared with the anoxic conditions resulting from the native species Phragmites australis and Scirpus mariqueter. The incubation experiments suggest that Fe(III) and Mn(IV/III) (hydr)oxides provide important binding sites for heavy metals under oxic conditions, and sulphide provides important binding sites for the Cu and Pb under anoxic conditions. Our observations indicate that the mobility of heavy metals in the salt marsh sediments is strongly influenced by biogeochemical redox processes and that the invasive S. alterniflora may increase the seasonal fluctuation in heavy metal bioavailability in the salt marsh ecosystem.     

飞机氮氧化物排放指数计算方法研究

飞机发动机的噪声和氮氧化物排放已成为日益严重的环境问题,对人类和生态环境的影响越来越严重。自国际民航组织颁布国际民航公约附件16《第Ⅰ卷航空器噪声》和《第Ⅱ卷航空发动机排放物》以来,为控制航空器发动机排放物污染,特别是氮氧化物污染,国际民航组织一直在研究更加严格的发动机排放物限制标准,以减少航空活动中飞机发动机对人类和环境的影响。以实例的形式列举了B787-800在4个阶段氮氧化物排放指数(EINOx)的计算过程,可为我国大飞机氮氧化物排放适航标准提供信息参考。     

Investigation of carbonyl compound sources at a rural site in the Yangtze River Delta region of China

Carbonyl compounds are important intermediates in atmospheric photochemistry, but their primary sources are still not understood well. In this work, carbonyls, hydrocarbons, and alkyl nitrates were continuously measured during November 2011 at a rural site in the Yangtze River Delta region of China. Mixing ratios of carbonyls and hydrocarbons showed large fluctuations during the entire measurement. The average level for total measured volatile organic compounds during the pollution episode from 25th to 27th November, 2011 was 91.6 ppb, about 7 times the value for the clean period of 7th-8th, November, 2011. To preliminarily identify toluene sources at this site, the emission ratio of toluene to benzene (T/B) during the pollution episode was determined based on photochemical ages derived from the relationship of alkyl nitrates to their parent alkanes. The calculated T/B was 5.8 ppb/ppb, significantly higher than the values of 0.2-1.7 ppb/ppb for vehicular exhaust and other combustion sources, indicating the dominant influence of industrial emissions on ambient toluene. The contributions of industrial sources to ambient carbonyls were then calculated using a multiple linear regression fit model that used toluene and alkyl nitrates as respective tracers for industrial emission and secondary production. During the pollution episode, 18.5%, 69.0%, and 52.9% of measured formaldehyde, acetaldehyde, and acetone were considered to be attributable to industrial emissions. The emission ratios relative to toluene for formaldehyde, acetaldehyde, and acetone were determined to be 0.10, 0.20 and 0.40 ppb/ppb, respectively. More research on industrial carbonyl emission characteristics is needed to understand carbonyl sources better.     

河流氧化亚氮产生和排放研究综述

氧化亚氮(N2O)是仅次于二氧化碳(CO2)和甲烷(CH4)的重要温室气体.由于人类活动对土地的影响导致河流系统中氮的可利用性增加,河流生态系统的N2O排放量正日益增长.本文对国内外河流水体N2O溶存浓度和饱和度、水-气界面排放通量及沉积物-水界面交换通量等数据进行了收集,并总结和分析了河流生态系统中N2O的产生机制及主要影响因子.     

模拟酶蛋白结合物替代HEMIN测定大气过氧化物

在选择最佳测定条件的基础上，对比了模拟酶蛋白结合物和ＨＥＭＩＮ对过氧化物的测定效果。结果表明，ＨＥＭＩＮ－ＢＳＡ效果最好，其对过氧化物的荧光响应信号约是ＨＥＭＩＮ的２倍，该物质在不改变激发和发射光谱的前提下可增强反应活性，提高反应灵敏度，使方法检测限降低至使用ＨＥＭＩＮ时的１／３左右，最低线性值降至原来的１／５左右，同时，精度亦有所提高。     

滇西北高原生态恢复过程中土壤侵蚀特征及其影响因子

滇西北高原由于地处生态脆弱的石灰岩区,水土流失严重,探讨该区生态恢复过程中土壤侵蚀的变化规律,为开展人工植被建设提供依据。以时空互代的方法,通过径流小区,对坡面的产沙产流特性及其影响因素进行研究。结果表明:天然次生林和人工混交林均有较好的调节径流和减少泥沙的作用,产沙量分别比坡耕地减少了51.46%、43.18%,产流量也相应降低了39.39%、24.24%。在最大次降雨条件下,荒草丛、坡耕地、次生林和混交林单次降雨的产沙量分别占试验期产沙总量的55.38%、55.58%、58.35%和58.05%,产流量相应占产流总量的64.72%、64.63%、73.85%和55.39%。而且,产流产沙量与土壤有机质质量分数均存在明显正相关,与乔、灌层植物多样性及均匀度指数等呈显著负相关性(P<0.05)。因此,乔灌草结合的群落结构配置模式是滇西北地区水土保持林营造的目标和方向。