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11.
Assessment of the effects of soil PAH accumulation by a battery of ecotoxicological tests 总被引:2,自引:0,他引:2
Surface soils were collected at remote, urban and industrial sites in the Southern of Italy in order to evaluate PAH concentrations and assess the toxic effects by a battery of ecotoxicological tests. The tests were performed on whole soils and on both organic and aqueous extracts. Further goal of this study was to integrate the results coming from each test and matrix in a synthetic toxicity index. The highest summation sigmaPAH concentrations were measured at the industrial soil, although this one did not show an high ecotoxicological risk. Among the performed tests, the phytotoxicity tests showed the highest sensitivity. For whole soil, the worst case always has been represented by test through bacteria. Our results could represent the first step toward the selection of a proper battery to characterize the soil ecotoxicological risk. 相似文献
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Bordeleau G Savard MM Martel R Ampleman G Thiboutot S 《Journal of contaminant hydrology》2008,98(3-4):97-105
Nitrate is one of the most common contaminants in shallow groundwater, and many sources may contribute to the nitrate load within an aquifer. Groundwater nitrate plumes have been detected at several ammunition production sites. However, the presence of multiple potential sources and the lack of existing isotopic data concerning explosive degradation-induced nitrate constitute a limitation when it comes to linking both types of contaminants. On military training ranges, high nitrate concentrations in groundwater were reported for the first time as part of the hydrogeological characterization of the Cold Lake Air Weapons Range (CLAWR), Alberta, Canada. Explosives degradation is thought to be the main source of nitrate contamination at CLAWR, as no other major source is present. Isotopic analyses of N and O in nitrate were performed on groundwater samples from the unconfined and confined aquifers; the dual isotopic analysis approach was used in order to increase the chances of identifying the source of nitrate. The isotopic ratios for the groundwater samples with low nitrate concentration suggested a natural origin with a strong contribution of anthropogenic atmospheric NOx. For the samples with nitrate concentration above the expected background level the isotopic ratios did not correspond to any source documented in the literature. Dissolved RDX samples were degraded in the laboratory and results showed that all reproduced degradation processes released nitrate with a strong fractionation. Laboratory isotopic values for RDX-derived NO(3)(-) produced a trend of high delta(18)O-low delta(15)N to low delta(18)O-high delta(15)N, and groundwater samples with nitrate concentrations above the expected background level appeared along this trend. Our results thus point toward a characteristic field of isotopic ratios for nitrate being derived from the degradation of RDX. 相似文献
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Joke Muys Bettina Blaumeiser Yves Jacquemyn Claude Bandelier Nathalie Brison Saskia Bulk Patrizia Chiarappa Winnie Courtens Anne De Leener Marjan De Rademaeker Julie Désir Anne Destrée Koenraad Devriendt Annelies Dheedene Annelies Fieuw Erik Fransen Jean-Stéphane Gatot Philip Holmgren Mauricette Jamar Sandra Janssens Kathelijn Keymolen Damien Lederer Björn Menten Marije Meuwissen Benoit Parmentier Bruno Pichon Sonia Rombout Yves Sznajer Ann Van Den Bogaert Kris Van Den Bogaert Olivier Vanakker Joris Vermeesch Katrien Janssens 《黑龙江环境通报》2018,38(13):1120-1128
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Abstract: In central Africa, where governments and funding agencies cover only a fraction of the recurrent expenditures needed to effectively manage the protected-areas network, it is essential to invest in the people who will be called on to participate in conservation efforts over the long term. In the Gamba Protected Areas Complex in southwestern Gabon, we analyzed the perseverance of all those who participated in training sessions, held since 1996, in ecological survey techniques and in participatory rural appraisal (socioeconomic studies). Of government agents who attended the respective training sessions, 7.7% continued ecological surveys and 0% continued participatory rural appraisal 2 years after training. However, 76.2% and 60.0% of the members of local communities who received training were still active in ecological surveys and participatory rural appraisal respectively after 2 years. Definitive conclusions regarding the participation of nongovernmental organization members cannot be drawn because of the low number of initial participants in the training programs. Based on our results, village collaborators seem to be a more "sustainable" human resource than government agents or of nongovernmental organizations members. Even though local communities cannot be solely responsible for managing protected areas, today's conservation professionals must acknowledge the strengths and limitations of village collaborators. Implementing a process involving the participation and the emulation of community members is a demanding task because protected-area managers must be based in the field to identify key individuals and to organize intensive training sessions. Also, constant support must be provided during the first years, and then the most capable and motivated collaborators will be able to pursue further training and work their way up through the ranks of the protected area's organizational structure. 相似文献
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Polybromodiphenyl ethers (PBDEs) are one of the many toxic chemicals present in the environment and in the food we eat every day, being fish one of the main sources of persistent organic pollutants in our diet; like other lipid-related contaminants, they are of concern since they can bioaccumulate and biomagnify through the trophic chain. We published a study focused on the dietary uptake of dioxins and furans (PCDD/Fs) and dioxin-like polychlorobiphenyls (dl-PCBs) in a set of samples of Spanish farmed turbot (Blanco et al., 2007). In the present paper, we extend the study to PBDEs to provide more information about the uptake and transfer from feed to fish of halogenated contaminants. PBDEs in the feeds (2.35-4.76 ng g(-1)) were reflected in turbot fillets (0.54-2.05 ng g(-1)): predominant congeners were tetra-BDE 47, penta-BDEs 99 and 100. It is remarkable that tetra-BDE 49, accounting for only 2% in the feed, contributed to 15% of total PBDEs in turbot fillets. Dietary net accumulation values, 30-45%, showed that tri-, tetra-, penta- and hexa-BDEs were as efficiently transferred into turbot as dl-PCBs and tetra- and penta-chlorinated PCDD/Fs. Lipid-normalized biomagnification factors relating concentration in fish and in feed, BMFs>1 were obtained, except for BDE 209. BDE 49 accumulation, 90%, was possibly contributed by metabolism of higher brominated BDEs. Implication in aquaculture management is a need for uncontaminated fish feed to offer safe products. 相似文献
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Sonia Rombout Daniel Sartenaer Benoît Parmentier Christian Dugauquier Yves Gillerot 《黑龙江环境通报》2004,24(10):822-827
We present a case of de novo trisomy of distal 19q diagnosed prenatally by cytogenetics and FISH analysis. The autopsy performed after termination of the pregnancy showed major internal and external malformations that are associated with this chromosome abnormality. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
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Lina Vitali Fabio Monforti Roberto Bellasio Roberto Bianconi Valentina Sachero Sonia Mosca Gabriele Zanini 《Atmospheric environment (Oxford, England : 1994)》2006,40(40):8020-8033
In this paper the inert version of a Lagrangian particle model named photochemical Lagrangian particle model (PLPM) is described and validated. PLPM implements four density reconstruction algorithms based on the kernel density estimator. All these methods are fully grid-free but they differ each other in considering local or global features of the particles distribution, in treating the Cartesian directions separately or together and in being based on receptors or particles positions in space. Each kernel has been shown to have both advantages and disadvantages, but the overall good performances of the model when compared with the well known Copenhagen and Kincaid data sets are very encouraging in view of its extension to fully chemically active simulations, currently under development. 相似文献
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Trine Lund Hansen Thomas H?jlund Christensen Sonia Schmidt 《Waste management & research》2006,24(2):141-152
Modelling of environmental impacts from the application of treated organic municipal solid waste (MSW) in agriculture differs widely between different models for environmental assessment of waste systems. In this comparative study five models were examined concerning quantification and impact assessment of environmental effects from land application of treated organic MSW: DST (Decision Support Tool, USA), IWM (Integrated Waste Management, U.K.), THE IFEU PROJECT (Germany), ORWARE (ORganic WAste REsearch, Sweden) and EASEWASTE (Environmental Assessment of Solid Waste Systems and Technologies, Denmark). DST and IWM are life cycle inventory (LCI) models, thus not performing actual impact assessment. The DST model includes only one water emission (biological oxygen demand) from compost leaching in the results and IWM considers only air emissions from avoided production of commercial fertilizers. THE IFEU PROJECT, ORWARE and EASEWASTE are life cycle assessment (LCA) models containing more detailed land application modules. A case study estimating the environmental impacts from land application of 1 ton of composted source sorted organic household waste was performed to compare the results from the different models and investigate the origin of any difference in type or magnitude of the results. The contributions from the LCI models were limited and did not depend on waste composition or local agricultural conditions. The three LCA models use the same overall approach for quantifying the impacts of the system. However, due to slightly different assumptions, quantification methods and environmental impact assessment, the obtained results varied clearly between the models. Furthermore, local conditions (e.g. soil type, farm type, climate and legal regulation) and waste composition strongly influenced the results of the environmental assessment. 相似文献
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Pollution historical trends as recorded by sediments at selected sites of the Venice Lagoon 总被引:1,自引:0,他引:1
Polychlorinated biphenyls (PCBs), dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs) and hexaclorobenzene (HCB) were determined in three sediment cores of the Venice Lagoon: I1, from the San Giuliano Canal that is likely the main source of pollutants for the study area; E, representing the lagoon sediment of the zone of Campalto; and M3, typical of a salt marsh environment and mostly subject to atmospheric inputs. Maximum concentrations were found in core I1: 25-1858 ngI-TE kg(-1) (PCDD/Fs), 1.7-13 microg kg(-1) (HCB), and 107-717 microg kg(-1) (PCBs) are surficial and peak values, respectively. The lagoon sediment (E), is much less contaminated: 24-47 ngI-TE kg(-1) for PCDD/Fs, 2.3-3.6 microg kg(-1) for HCB, and 56-203 microg kg(-1) for PCBs, whereas M3 shows the lowest values: 1.6-6.0 ngI-TE kg(-1) for PCDD/Fs, 0.3-0.6 microg kg(-1) for HCB, and 7.1-39 microg kg(-1) for PCBs. In any case, the recent trend is toward a decrease of pollutant concentration. The chronology of cores E and M3 is based on both 210Pb and 137Cs activity-depth profiles. The maximum concentrations of PCDD/Fs, HCB, and PCBs correspond to the years 1949, 1980, and 1968, respectively. The homologue profiles of PCDD/Fs confirm that I1 has been subject to an industrial source while the other sites also recorded significant contributions, changing over time, of octachlorinated dioxin from combustion. A comparison of the pollutant inventories, all normalised to 210Pb inventories, suggests that the atmospheric contribution to the contamination of the area of Campalto is low: the upper limits range from 6% (PCDD/Fs) to 17% (HCB). 相似文献