Pesticide occurrence in groundwater and the physical characteristics in association with these detections in Ireland

This study explores the associations of pesticide occurrence in groundwater to geological characteristics of the monitoring points (MPs) contributing area. Pesticide analyses were undertaken during a 2-year groundwater monitoring campaign which generated 845 samples. MCPA and mecoprop were the most frequently detected pesticides in groundwater. Each MP (n?=?158) had a specifically delineated zone of contribution (ZOC) and the dominant physical characteristics present from nine national datasets were recorded for each ZOC. Associations between detections in groundwater and the dominant physical characteristic in each MPs ZOC tested were then statistically analyzed using Fisher’s exact test, logistic regression, and multiple logistic regression. The original physical characteristic datasets used that were associated with detections in groundwater were the type of MP, aquifer type, and Quaternary deposit type. Logistic regression revealed that springs, regionally important aquifer types, aquifers with a karstic flow regime, and alkaline Quaternary deposits in existence above karst aquifers in a MP’s ZOC were more likely to have a pesticide detection in groundwater. Multiple regression from this exploratory work showed some mutual dependency between soil association, aquifer type, and the Geological Survey of Ireland groundwater vulnerability map. The combination of national monitoring data and physical attribute datasets can be used to explore key areas where groundwater is more vulnerable to pesticide contamination.     

Ownership property size,landscape structure,and spatial relationships in the Edwards Plateau of Texas (USA): landscape scale habitat management implications

The present research focused on using spatial analysis to determine relationships among land ownership property sizes and landscape structure, with a focus on conservation management implications. Indices and metrics of ownership property sizes and landscape structure were calculated for 20 km buffer areas around 31 North American Breeding Bird Survey transects, 12 located within the Edwards Plateau ecoregion and 18 in contiguous ecoregions. The number of bird species observed at each transect provided a measure of avian species richness associated with land cover classes for each respective transect (González in Urban influence on diversity of avifauna in the Edwards Plateau of Texas: effect of property sizes on rural landscape structure, Texas A&M University, 2005). Spatial correlations were calculated between each pair of the landscape indices. Spatial analysis identified a “threshold of habitat fragmentation” for the 500 acre (ac) ownership property size. Significant spatial correlations among variables showed that property sizes lower than 500 ac produced habitat fragmentation represented by a decrease in mean patch size (MN) and proximity among habitat patches (Index PROX). Spatial analysis also made possible the prioritization of ecological sub-regions of the Edwards Plateau for conservation or restoration. The Live Oak-Mesquite Savannah showed the highest average ownership property size (7305 ac) and the highest values of patch richness. Based on the results, management in the Live Oak-Mesquite Savannah sub-region should focus on the conservation of land mosaic diversity to assure native avian species turnover (Whittaker 1972). In Balcones Canyon Lands, 64 % of land was covered by farms smaller than 500 ac and the overall average ownership property size was above the threshold of fragmentation (1440 ac), implying that management policies there should focus both on habitat conservation and on restoration. In contrast, 71 % of land in the Lampasas Cut Plains was covered by farms smaller than 500 ac, and average ownership property size was very close to the fragmentation threshold (625 ac). Consequently, the results indicate that management in the Lampasas Cut Plains sub-region should focus on habitat restoration (e.g., corridors that connect isolated habitat patches). In general, the threshold of ownership property size, 500 ac, is important for conservation planning because below that threshold of property size, habitat patch size begins to decrease and the distance between equivalent patches of habitat increases. Isolated patches act as islands within a sea of less suitable habitat which produce negative effects on biodiversity. Identifying the spatial characteristics indicative of habitat fragmentation, or the likelihood thereof, is an important issue for conservation planning in places with urban sprawl influence.     

Fertiliser management effects on dissolved inorganic nitrogen in runoff from Australian sugarcane farms

Dissolved inorganic nitrogen (DIN) movement from Australian sugarcane farms is believed to be a major cause of crown-of-thorns starfish outbreaks which have reduced the Great Barrier Reef coral cover by ~21% (1985–2012). We develop a daily model of DIN concentration in runoff based on >200 field monitored runoff events. Runoff DIN concentrations were related to nitrogen fertiliser application rates and decreased after application with time and cumulative rainfall. Runoff after liquid fertiliser applications had higher initial DIN concentrations, though these concentrations diminished more rapidly in comparison to granular fertiliser applications. The model was validated using an independent field dataset and provided reasonable estimates of runoff DIN concentrations based on a number of modelling efficiency score results. The runoff DIN concentration model was combined with a water balance cropping model to investigate temporal aspects of sugarcane fertiliser management. Nitrogen fertiliser application in December (start of wet season) had the highest risk of DIN movement, and this was further exacerbated in years with a climate forecast for ‘wet’ seasonal conditions. The potential utility of a climate forecasting system to predict forthcoming wet months and hence DIN loss risk is demonstrated. Earlier fertiliser application or reducing fertiliser application rates in seasons with a wet climate forecast may markedly reduce runoff DIN loads; however, it is recommended that these findings be tested at a broader scale.     

Identification of Conservation-Worthy Areas in Northern Zululand, South Africa

Abstract: We used spatial and statistical analyses to identify and prioritize broad areas for conservation attention in the northern Zululand region of KwaZulu-Natal, South Africa. We attempted to identify conservation-worthy areas based on species, vegetation types, ecological processes, and threats to biodiversity. Information on species was limited and so could not form the basis of the analysis. Priority vegetation types were identified by degree of endemicity, extent of protection and transformation, and degree of fragmentation. These priority vegetation types and threats to biodiversity were used to define broad linkages between existing protected areas. We set a goal of 10% protection for each vegetation type and 25% for each species. We identified several important (endemic or threatened) animal species and predicted their ranges using a simple model. Species ranges and their hotspots were compared with the distribution of protected areas and the suggested linkages to evaluate increased species representation. Generally, the eastern part of the study area was well protected. Unprotected conservation-worthy areas under greatest threat lay in the west, and protecting these areas is a priority. Furthermore, several vegetation types were not protected by provincial authorities, a situation that also needs to be addressed. The findings of our study need to be reassessed at a finer land-parcel scale, and implementation of a range of land-use options considered.     

Effects of Sulfur Dioxide and Nitric Oxide on Mercury Oxidation and Reduction under Homogeneous Conditions

Abstract

This paper is particularly related to elemental mercury (Hg⁰) oxidation and divalent mercury (Hg²⁺) reduction under simulated flue gas conditions in the presence of nitric oxide (NO) and sulfur dioxide (SO₂). As a powerful oxidant and chlorinating reagent, Cl₂ has the potential for Hg oxidation. However, the detailed mechanism for the interactions, especially among chlorine (Cl)-containing species, SO₂, NO, as well as H₂O, remains ambiguous. Research described in this paper therefore focused on the impacts of SO₂ and NO on Hg⁰ oxidation and Hg²⁺ reduction with the intent of unraveling unrecognized interactions among Cl species, SO₂, and NO most importantly in the presence of H₂O. The experimental results demonstrated that SO₂ and NO had pronounced inhibitory effects on Hg⁰ oxidation at high temperatures when H₂O was also present in the gas blend. Such a demonstration was further confirmed by the reduction of Hg²⁺ back into its elemental form. Data revealed that SO₂ and NO were capable of promoting homogeneous reduction of Hg²⁺ to Hg⁰ with H₂O being present. However, the above inhibition or promotion disappeared under homogeneous conditions when H₂O was removed from the gas blend.     

Evaluating Post-wildfire Vegetation Regeneration as a Response to Multiple Environmental Determinants

Vegetation regeneration in post-fire environments varies across the landscape of a burned area. Variations are caused by interacting factors, including soil properties, vegetation characteristics, hydrology, land management history, and burn severity. While many of these factors have been explored previously, few studies have investigated the combination of multiple factors. A time-series of the remotely sensed enhanced vegetation index data has been analyzed to estimate rates of regeneration across a burn in central Arizona. We used regression trees to evaluate post-fire vegetation response as a function of multiple factors. Regeneration was a function of elevation (likely a proxy for moisture availability), burn severity, pre-burn vegetation, and post-burn management activities. Both time-series vegetation data and regression trees were valuable tools for determining dominant interacting factors responsible for variations in post-fire regeneration. Evaluation of the time-series data and modeled post-fire vegetation permitted the interpretation of management actions across the burned area.     

Competition among penguins and cetaceans reveals trophic cascades in the western Ross Sea, Antarctica

An apparent trophic cascade that appears during summer in the western Ross Sea, Antarctica, explains why the Antarctic silverfish (Pleuragramma antarcticum) there becomes cannibalistic; its principal prey, crystal krill (Euphausia crystallorophias) becomes scarce; and the diatom community is minimally grazed compared to adjacent areas. The krill is the major grazer of diatoms. On the basis of fieldwork at Ross Island, we suggest that the cascade results from foraging by unusually numerous Adélie Penguins (Pygoscelis adeliae), minke whales (Balaenoptera bonaerensis), and fish-eating killer whales (Orcinus orca). These species and other top predators apparently deplete the krill and silverfish. In drawing our conclusions, we were aided by two "natural experiments." In one "experiment," large, grounded icebergs altered the seasonal pattern of change in regional sea-ice cover, but not the seasonal change in penguin diet and foraging behavior that was also detected during the pre-iceberg era. In the other "experiment," a short-term polynya (opening in the ice) brought penguins and whales together in a confined area, this time altering both penguin diet and foraging behavior. We conclude that the foraging of penguins and whales, and not a formerly hypothesized seasonal decrease in sea-ice cover, explains (1) the annual switch in the penguins' prey from krill to silverfish, (2) the subsequent lengthening of penguin foraging trips, and (3) a marked decline of cetaceans in the area later in the season. Reduction in the middle-trophic-level prey is expressed in the relaxed grazing pressure on phytoplankton.     

Potential Mortality Effects of Off-Highway Vehicles on the Flat-Tailed Horned Lizard (<Emphasis Type="Italic">Phrynosoma mcallii</Emphasis>): A Manipulative Experiment

Southern California desert public lands receive especially high levels of off-highway recreation due to large population centers nearby and popular riding environments such as sand dunes. Controversy has developed over the flat-tailed horned lizard (Phrynosoma mcallii), previously a candidate for listing under the Endangered Species Act. Some evidence suggests lower lizard abundance in areas of higher recreational use than in areas with low or no use. We designed a manipulative experiment to ensure maximum inference in evaluating the direct impact of recreational riding of off-highway vehicles on lizards. Thirty-six lizards, in situ, were treated with an off-highway vehicle treatment during hibernation season in three treatment groups: high impact, low impact, and control. Treatments consisted of timed riding by off-highway vehicles. In all treatment groups survival was 100%, despite hibernation of lizards at very shallow depths. Consequently, indirect effects of off-highway vehicles deserve increased attention. The relative importance of direct versus indirect (i.e., degradation of lizard habitat) impacts caused by off-highway vehicles remains unknown. These indirect effects may include the altering of vegetation, substrate, and prey. We recommend that a manipulative approach be adopted to investigate these possibilities.     

Laboratory-scale measurement of trace gas fluxes from landfarm soils

Trace gas emissions from refinery and bioremediation landfarms were investigated in a mesocosm-scale simulator facility. Five simulators were constructed and integrated with a data acquisition system and trace gas analyzers, allowing automated real-time sampling and calculation of total hydrocarbon (THC), CO2, and water vapor fluxes. Experiments evaluating the influence of simulated cultivation and rainfall on trace gas fluxes from the soil surfaces were conducted. Results were compared with published field results. Results showed that cultivating dry or moderately wet soil resulted in brief enhancements of THC fluxes, up to a factor of 10, followed by a sharp decline. Cultivating dry soil did not enhance respiration. Cultivating wet soil did result in sustained elevated levels of respiration. Total hydrocarbon emissions were also briefly enhanced in wet soils, but to a lesser magnitude than in dry soil. Hydrocarbon fluxes from refinery landfarm soil were very low for the duration of the experiments. This lead to the conclusion that elevated THC fluxes would only be expected during waste application. An evaluation of the influence of simultaneous water vapor fluxes on other trace gas fluxes highlighted the importance in lab-scale experiments of correcting trace gas fluxes from soils. The results from this research can be used to guide management practices at landfarms and to provide data to aid in assessing the effect of landfarms.