气藏水平井非稳态产能预测新方法研究

针对高产气藏储层特征,建立起气藏水平井非稳态产能预测模型,对高产气藏的产能进行分析和预测.实例分析表明,通过该模型形成的基于气藏与井筒耦合作用的非稳态产能预测新方法,对于单井产能预测具有优越性、长远性和实用性.该方法可直接利用不稳定压力测试成果进行预测,还可通过生产动态资料拟合来确定地层参数和预测,也可用来研究不同工作制度、完井方式,以及增产措施改善情况下的产能变化,为衰竭式开采的气藏工程研究提供了先进的手段.     

镍基均相络合催化剂苯加氢反应动力学研究

采用工业上应用较成功的HC-402-2型镍基均相Z iegler型络合催化剂,在排除扩散影响的条件下,研究了苯均相催化加氢制环己烷的反应动力学。在反应温度150~210℃、总压1.0~2.4MPa的范围内,考察了反应温度、氢分压和苯浓度对反应速率的影响。实验结果表明,苯加氢均相催化反应对苯浓度的反应级数为零级,对氢分压的反应级数为一级,反应活化能为36 435.27 J/mol。经检验,该动力学模型的相关系数大于0.9,模型合理,能够描述实际反应过程。     

A 5 mW and 5% efficiency 210 GHz InP-based heterostructure barrier varactor quintupler

This letter reviews the design, construction, and measurement of a 210 GHz heterostructure barrier varactor frequency quintupler. The quintupler utilizes planar heterostructure barrier varactors (HBVs) based on the InGaAs/InAlAs/AlAs material system and has produced a measured output power of 5.2 mW with 5.2% conversion efficiency at 210 GHz. This performance is comparable to the state-of-the-art results reported in the literature for HBV frequency triplers operating at millimeter and submillimeter wavelengths.     

钢管机械扩径工艺研究

介绍了大口径直缝焊管机械扩径的优点，原理及扩径力的计算，找出影响扩径力及扩径头寿命的因素。     

光测遥测数据联合计算速度的方法

提出了利用遥测的过载、俯仰角信息和光测的坐标联合计算弹道关机段速度的方法，从遥测结果的系统误差、随机误差和数值积分的截断误差三万面对剩余误差的影响进行了精度分析，并给出了速度精度的算法。     

Morphology control of titanium oxides by tetramethylammonium cations in hydrothermal conditions

The effect of tetramethylammonium cations (TMA⁺) on TiO₂ crystal morphology in hydrothermal conditions has been studied. The as-synthesized samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM) methods. The morphologies including besom-like particle, nanosheet and nanotube have been observed. The different ways TMA⁺ cations in the hydrothermal bases affect the crystal growth manner are suggested to be responsible for the different morphologies of the as-synthesized samples.     

Effect of polymerization conditions on o‐phenylenediamine and o‐phenetidine oxidative copolymers

A series of new o‐phenylenediamine (OPD)/o‐phenetidine (PHT) copolymers with partly phenazine‐like structures has been successfully synthesized at three polymerization temperatures by chemically oxidative polymerization in four different polymerization media. The molecular structures and properties of the resulting OPD/PHT polymers were investigated by IR, UV–vis and high‐resolution ¹H NMR spectroscopies, and DSC, in order to ascertain the effect of reaction temperature, comonomer ratio and acid medium. The copolymerization mechanism of OPD with PHT monomers has been proposed. It is found that the statistical OPD/PHT copolymer obtained at a temperature of 118 °C has a higher degree of polymerization than that obtained at 12–17 °C. The OPD content in the copolymers calculated from NMR spectroscopic analysis is higher than that in the feed OPD content, whereas the OPD content calculated from element analysis is slightly lower than the feed OPD content. It can be predicted that denitrogenation takes place in the OPD units during the polymerization process at OPD/PHT molar ratios of 90/10 and 100/0. These OPD/PHT copolymers exhibit a much better solubility than the OPD homopolymer, hence suggesting an incorporation of PHT units into the phenazine structure of the homopolymer. The thermal behavior of the copolymers was also studied. Copyright © 2004 Society of Chemical Industry     

DCA-112催化裂化抑焦剂的工业应用

针对改善催化裂化反应微环境研制开发的DCA - 112催化裂化抑焦剂 ,具有抑制生焦、改善产品分布、应用流程简单、加注方便等特点 ,经中石化长炼分公司 1Mt/a重油催化装置工业应用表明 ,在相近的工艺条件下 ,掺渣比提高 4 13个质量百分点 ,总液收提高 1 0 2个质量百分点。     

变频器的选型及配置要点

本文针对应用广泛的通用变频器，提出了在变频器选型和外围配置中需要注意的一些问题。     

The Synthesis of 1,4-Diazabicyclo (2.2.2) Octane over a Pre-Treated Titanium Silicalite-1 Catalyst

Potassium chloride salt pre-treated titanium silicalite-1 (TS-1) zeolite (K-TS-1) was prepared via an ion-exchange method. XRD, EDX and BET were used to identify the structure of the zeolite. The BET surface area and the adsorption/desorption cumulative pore volume of the K-TS-1 catalyst were about 297 m²/g and 0.213 cm³/g, respectively. The average pore diameter of the K-TS-1 catalyst was 29.49 Å. The catalytic activity of K-TS-1 catalyst was studied in the fixed-bed catalytic reactor. 1,4-Diazabicyclo (2.2.2) octane (DABCO) was prepared from ethylenediamine (EDA) over the K-TS-1 zeolite catalyst. The influences of various reaction parameters such as reaction temperature, space velocity and concentration of EDA were discussed. The conversion of EDA was more than 96% and the selectivity of DABCO and PIP were up to 64 and 30%, respectively, in the temperature of 340 °C and weight hourly space velocity of 1.5 h^?1 in the presence of water.