Effect of temperature on contents of essential highly unsaturated fatty acids in freshwater zooplankton

In 11 lakes from cold and warm regions we studied the content of highly unsaturated fatty acids (HUFA) in seston (<130 μm) and crustacean zooplankton using gas chromatography–mass spectrometry. An increase of temperature correlated with a decrease of HUFA content in zooplankton. A multivariate canonical correlation analyses revealed, that the decrease of HUFA content was related with a decrease of per cent of copepods in zooplankton communities, which are known to have higher HUFA levels in their biomass, than cladocerans. This means that temperature primarily affected the HUFA levels indirectly, via changing of taxonomic structure of zooplankton community, while the homeoviscous adaptation of zooplankton individuals had comparatively lower importance. As found, water temperature was better predictor of HUFA contents of zooplankton, than the fatty acid composition of seston. Thus, it can be predicted, that a probable climate warming will decrease the content of the essential HUFA in freshwater zooplankton with possible negative consequences for animals of higher trophic levels.     

The history of the Cretaceous environments of the northeastern Asian continental margin, Russia

Abstract The Cretaceous geodynamic and paleogeographic evolution of the northeastern Asian continental margin is summarized in five maps for time-intervals of 115-110, 100-90, 90-85, 85-74 and 70-50 Ma. Four major evolutionary stages are recognized: (i) the moderate extensional tectonic regime and origination of a system of island arcs in the Jurassic-Neocomian stage; (ii) Middle Cretaceous strong collisional and accretional processes resulting in the Asian continent formation in the Barremian-Early Albian stage; (iii) the origination of the subduction-related Okhotsk-Chukotka continental marginal volcanic belt in relation to the newly formed convergent plate boundary in the Late Albian-Senonian stage; and (iv) the next collision accompanied by the extinction of the subduction-related volcanism in the Late Cretaceous-Early Paleocene stage (Laramian orogeny) and displayed rift-related processes with the intraplate-type volcanism on the Asian continental margin. Those stages had been established through the whole Pacific ring and had close genetic relationships with mid-ocean ridges tectonic activity.     

Transpiration in Quercus suber trees under shallow water table conditions: the role of soil and groundwater

Water is one of the major environmental factors limiting plant growth and survival in the Mediterranean region. Quercus suber L. woodlands occupy vast areas in the Iberian Peninsula, frequently under shallow water table conditions. The relative magnitude of soil and groundwater uptake to supply transpiration is not easy to evaluate under these circumstances. We recently developed a conceptual framework for the functioning of the root system in Q. suber that simulates well tree transpiration, based on two types of root behaviour: shallow connected and deep connected. Although this significantly improved knowledge on the functional traits of Mediterranean Q. suber, the approach has the limitation of requiring root sap flow data, which are seldom available. In this work, we present alternative methodologies to assess if trees are connected to groundwater and to estimate the soil and groundwater contributions to tree transpiration. We provide evidence on the tree unrestricted access to groundwater solely based on meteorological, stem sap flow and leaf water potential data. Using a soil mass balance approach, we estimated the yearly soil and groundwater contributions to tree transpiration: 69.7% and 30.3%, respectively. Groundwater uptake became dominant in the dry summer: 73.2% of tree transpiration. Results reproduce extremely well those derived from root modelling. Because of its simplicity both in formulation and data requirements, our approach is potentially liable to be adapted to other groundwater‐dependent Mediterranean oak sites, where interactions between land use and water resources may be relevant. Copyright © 2013 John Wiley & Sons, Ltd.     

Comparative molecular analysis of bacterial communities inhabiting pristine and polluted with polycyclic aromatic hydrocarbons Black Sea coastal sediments

Molecular analysis was applied to characterize bacterial community structure in sediment samples collected from pristine site and oil-polluted Black Sea harbor. Amplified Ribosomal DNA Restriction Analysis (ARDRA) revealed a high similarity in the restriction patterns of both samples thus not demonstrating the effect of the pollutant on the structure of the bacterial communities. Constructed 16S rRNA gene libraries gave more detailed assessment of members. Results showed that α- and γ-Proteobacteria were dominant in the oil polluted site, whereas the pristine site was characterized by prevalence of Actinobacteria. The biodegradative potential of the adapted bacterial community in the oil-polluted sediments was demonstrated by the presence of the aromatic ring hydroxylating dioxygenase genes.     

Field Survey and Geological Effects of the 15 November 2006 Kuril Tsunami in the Middle Kuril Islands

The near-field expression of the tsunami produced by the 15 November 2006 Kuril earthquake (M_w 8.1–8.4) in the middle Kuril Islands, Russia, including runup of up to 20 m, remained unknown until we conducted a post-tsunami survey in the summer of 2007. Because the earthquake occurred between summer field expeditions in 2006 and 2007, we have observations, topographic profiles, and photographs from three months before and nine months after the tsunami. We thoroughly surveyed portions of the islands of Simushir and Matua, and also did surveys on parts of Ketoi, Yankicha, Ryponkicha, and Rasshua. Tsunami runup in the near-field of the middle Kuril Islands, over a distance of about 200 km, averaged 10 m over 130 locations surveyed and was typically between 5 and 15 m. Local topography strongly affected inundation and somewhat affected runup. Higher runup generally occurred along steep, protruding headlands, whereas longer inundation distances occurred on lower, flatter coastal plains. Sediment transport was ubiquitous where sediment was available—deposit grain size was typically sand, but ranged from mud to large boulders. Wherever there were sandy beaches, a more or less continuous sand sheet was present on the coastal plain. Erosion was extensive, often more extensive than deposition in both space and volume, especially in areas with runup of more than 10 m. The tsunami eroded the beach landward, stripped vegetation, created scours and trim lines, cut through ridges, and plucked rocks out of the coastal plain.     

A simple method to model the reduced environment of lake bottom sapropel formation

The Kambala and Barchin brackish lakes(Baraba steppe,southern West Siberia) contain an organic-rich sapropel layer that was formed in oxygen-depleted waters.We measured the bulk sediment elemental composition,the water chemistry and determined the mineralogical composition and predominant biota species(Diatoms and Cyanobacteria in phytoplankton community respectively) in the lakes.The result indicates that the first lake has a siliceous type of sapropel and the second a carbonaceous one.A computer thermodynamic model was developed for chemical interaction in water-bottom sediment systems of the Kambala and Barchin Lakes.The surface sodium bicarbonate waters are supersaturated with respect to calcite,magnesite(or low Mg-calcite),quartz and chlorite with minor strontianite,apatite and goethite(pH8.9-9.3,Eh 0.3 V).Nevertheless,it is shown that during sapropel deposition,deep silt waters should be anoxic(Eh0 V).The virtual component CH_2O has been used to create an anoxic environment suitable for pyrite formation due to the biotic community impact and abiotic reduction.Thermodynamic calculation has shown that silt water is not necessarily euxinic(anoxic and sulfidic).Depending on Eh,sulfate sulfur can dominate in solution,causing the formation of gypsum together with pyrite.An attempt was made to find a reason for solution supersaturation with respect to Ca and Mg ions due to their complexation with humic acids.     

Arsenic mobility in two mine tailings drainage systems and its removal from solution by natural geochemical barriers

Sulfide-mineral-bearing mill wastes are sources of high concentrations of acid, soluble metals, and As. These are serious problems for ore mining areas such as the Kemerovo and Cheljabinsk regions in Russia. This study evaluated the distribution of the mill wastes, the mobility of As from the wastes, and the potential of natural materials to attenuate As dispersion in the broader environment. Arsenic contents in wastes of the Belovo Zn-processing (Kemerovo) and the Karabash Cu-smelting plants (Cheljabinsk) are 2–3 orders of magnitude higher than the content of continental crust. Main mineral forms of As in these wastes are arsenopyrite (FeAsS) and scorodite (FeAsO₄·2H₂O). High dissolved As concentrations are found in water draining the wastes and in rivers adjacent to the mill sites. The water concentrations commonly exceed drinking water standards. High As concentrations in bottom sediments of the affected rivers extend a 100 m downstream of the waste drainage input. These sediments are also a source of river water contamination. Experiments were conducted to evaluate the ability of natural water to mobilize As from the wastes. The Belovo tailings released 86% of their contained As to the infiltrating water, whereas the less reactive Karabash tailings released only 22% of total As. The experimental leachates were used as influent to columns that tested the ability of limestone and natural clay to reduce the concentration of dissolved As and associated metals. Some dissolved As was precipitated with Fe, Pb and Sb initially in the limestone column. The decrease in dissolved As is consistent with the accumulation of As in yellow ferriferous sediments in the Belovo settling pond. In the pond and wetland sediments, As mobility is also decreased by the formation of sulfides and arsenides. Cubanite (CuFe₂S₃), klaprothite (Cu₃BiS₃)_, rammelsbergite (NiAs₂), maucherite (Ni₁₁As₈), semseyite (Cu₉Sb₈S₂₁), and skutterudite (CoAs₃) were found in the chemically reducing lower sediments of the Belovo settling pond.     

Mineralogy, geochemistry and stratigraphy of the Maslovsky Pt–Cu–Ni sulfide deposit, Noril’sk Region, Russia

We report new data on the stratigraphy, mineralogy and geochemistry of the rocks and ores of the Maslovsky Pt–Cu–Ni sulfide deposit which is thought to be the southwestern extension of the Noril’sk 1 intrusion. Variations in the Ta/Nb ratio of the gabbro-dolerites hosting the sulfide mineralization and the compositions of their pyroxene and olivine indicate that these rocks were produced by two discrete magmatic pulses, which gave rise to the Northern and Southern Maslovsky intrusions that together host the Maslovsky deposit. The Northern intrusion is located inside the Tungusska sandstones and basalt of the Ivakinsky Formation. The Southern intrusion cuts through all of the lower units of the Siberian Trap tuff-lavas, including the Lower Nadezhdinsky Formation; demonstrating that the ore-bearing intrusions of the Noril’sk Complex post-date that unit. Rocks in both intrusions have low TiO₂ and elevated MgO contents (average mean TiO₂ <1 and MgO?=?12?wt.%) that are more primitive than the lavas of the Upper Formations of the Siberian Traps which suggests that the ore-bearing intrusions result from a separate magmatic event. Unusually high concentrations of both HREE (Dy+Yb+Er+Lu) and Y (up to 1.2 and 2.1?ppm, respectively) occur in olivines (Fo_79.5 and 0.25% NiO) from picritic and taxitic gabbro-dolerites with disseminated sulfide mineralization. Thus accumulation of HREE, Y and Ni in the melts is correlated with the mineral potential of the intrusions. The TiO₂ concentration in pyroxene has a strong negative correlation with the Mg# of both host mineral and Mg# of host rock. Sulfides from the Northern Maslovsky intrusion are predominantly chalcopyrite–pyrrhotite–pentlandite with subordinate and minor amounts of cubanite, bornite and millerite and a diverse assemblage of rare precious metal minerals including native metals (Au, Ag and Pd), Sn–Pd–Pt–Bi–Pb compounds and Fe–Pt alloys. Sulfides from the Southern Maslovsky intrusion have δ ³⁴S?=?5–6‰ up to 10.8‰ in two samples whereas the country rock basalt have δ ³⁴S?=?3–4‰, implying there was no in situ assimilation of surrounding rocks by magmas.     

Observations on New Approaches for the Determination of Platinum-Group Elements, Gold and Silver in Different Geochemical Samples from Siberia and the Far East

Some recent experiments on the determination of Au and the platinum-group elements (PGE) in geochemical samples are reviewed. Emphasis is given to the determination of ultra-low levels of PGE concentrations in resistant matrices, including chromites, molybdenites and ultrabasic ores. The problems and features of PGE determination in samples of various chemical composition are considered. For each sample type studied, a series of sample preparation techniques are proposed. These techniques included acid digestion, fusion with sodium peroxide, cold sintering with an oxidizing mixture of Na₂O₂+ Na₂CO₃ and also oxidizing fluorination with bromine trifluoride. A new approach for preparing geochemical material prior to digestion, based on mechano-chemical activation with simultaneous hyperfine grinding, is proposed and studied. The instrumental determination of PGE contents was carried out directly by AAS from extracted organic phases. It was found that a combination of digestion processes was required to achieve geochemical background levels of Au and PGE concentrations with the following detection limits: Pd, Rh - 1 ng g⁻¹, Pt, Ru - 10 ng g⁻¹, Au - 0.2 ng g⁻¹, Ag - 0.1 ng g^−1. The uncertainty in PGE and Au determination in geochemical samples is dependent on metal concentration, and also on their distribution in samples. The total analytical uncertainty of the proposed method is between 15-30%.