Post-independence population planning and social development in Singapore

The unique and remarkable post-independence demographic transition of Singapore, from high to low growth, has been accompanied by an equally spectacular social transformation. Both population control and social change have a positive impact on the fertility trend. Singapore's population policy has been dictated much by the crisis consciousness of the leadership which has been able to create a high degree of awareness among its population with regard to fertility.Ironically, public response to the government's population control has been too successful, particularly so among the upper-income groups. This has recently prompted the government to examine the sustained low fertility rate which, if unchecked, will bear serious social, economic, political and defence consequences in 20 to 30 years time. The aim of the current fertility campaign is to reachieve the replacement level, first reached in 1975, through the correction of the lopsided procreation pattern. As such, some disincentives have remained or been removed, while several new incentives and measures have been introduced. Observations are made with regard to the future fertility trends.     

Accumulation of heavy metals by cultured oysters from Merbok Estuary, Malaysia

The Merbok Estuary in Malaysia has a good potential of developing into a rich bivalve culture area. However, there is some concern on the likelihood of bio-accumulation of heavy metals by the oysters cultured there, since Merbok River is classified as very polluted. The accumulation of Cu and Zn in oysters (Crassostrea iredalei and Crassostrea belcheri) cultured at two locations in the estuary was studied. The results indicated that the Cu levels in oysters reaching marketable size are within the limit of 40 ppm specified in the Malaysian Food Regulations 1985, whereas Zn levels exceeded the limit of 100 ppm. The metal concentration data were fitted to a first-order kinetic model, and good agreement was found between the predicted and observed Cu concentrations using the x² test. The Zn data, however, did not fit the model. The Cu bioconcentration factors (BCF) for C. belcheri cultured at the two locations were found to be about 4.5 × 10³, which is close to that for C. iredalei. The results suggests that BCF value is site-specific.     

An oil spill-food chain interaction model for coastal waters

An oil spill-food chain interaction model, composed of a multiphase oil spill model (MOSM) and a food chain model, has been developed to assess the probable impacts of oil spills on several key marine organisms (phytoplankton, zooplankton, small fish, large fish and benthic invertebrates). The MOSM predicts oil slick thickness on the water surface; dissolved, emulsified and particulate oil concentrations in the water column; and dissolved and particulate oil concentrations in bed sediments. This model is used to predict the fate of oil spills and transport with respect to specific organic compounds, while the food chain model addresses the uptake of toxicant by marine organisms. The oil spill-food chain interaction model can be used to assess the environmental impacts of oil spills in marine ecosystems. The model is applied to the recent Evoikos-Orapin Global oil spill that occurred in the Singapore Strait.     

ULYSSES observations of energetic particle acceleration and the superposed CME and CIR events of November 1992

During November 1992, a series of forward and reverse shocks passed the ULYSSES spacecraft. Spectral and anisotropy measurements are reported for protons and alpha particles between 0.28 and 6 MeV observed by the Energetic Particle Composition Experiment, data recorded by the Magnetometer Experiment and the high-energy (2.7-300 MeV) proton data from the Kiel Electron Telescope. An analysis of energetic particle, plasma and magnetometer data from ULYSSES has allowed a unique study of the corresponding arrival of fare particles, particles within a corotating interaction region and particles transported with a coronal mass ejection. We present an analysis of these data in terms of possible diffusive shock acceleration but conclude that this is likely to be incompatible with the short transit time of the particles. Shock drift acceleration of particles with energies 0.3 MeV/nucleon or solar acceleration followed by particle trapping behind the shock front are alternative possibilities.     

A mapping of the electron localization function for the silica polymorphs: evidence for domains of electron pairs and sites of potential electrophilic attack

The electron localization function, η, evaluated for first-principles geometry optimized model structures generated for quartz and coesite, reveals that the oxide anions are coordinated by two hemispherically shaped η-isosurfaces located along each of the SiO bond vectors comprising the SiOSi angles. With one exception, they are also coordinated by larger banana-shaped isosurfaces oriented perpendicular to the plane centered in the vicinity of the apex of each angle. The hemispherical isosurfaces, ascribed to domains of localized bond-pair electrons, are centered ～0.70 Å along the bond vectors from the oxide anions and the banana-shaped isosurfaces, ascribed to domains of localized nonbonding lone-pair electrons, are centered ～0.60 Å from the apex of the angle. The oxide anion comprising the straight SiOSi angle in coesite is the one exception in that the banana-shaped isosurface is missing; however, it is coordinated by two hemispherically shaped isosurfaces that lie along the bond vectors. In the case of a first-principles model structure generated for stishovite, the oxide anion is coordinated by five hemispherically shaped η-isosurfaces, one located along each of the three SiO bond vectors (ascribed to domains of bonding-electron pairs) that are linked to the anion with the remaining two (ascribed to domains of nonbonding-electron pairs) located on opposite sides of the plane defined by three vectors, each isosurface at a distance of ～0.5 Å from the anion. The distribution of the five isosurfaces is in a one-to-one correspondence with the distribution of the maxima displayed by experimental Δρ and theoretical ??²ρ maps. Isosurface η maps calculated for quartz and the (HO) ₃ SiOSi(OH) ₃ molecule also exhibit maxima that correspond with the (3,?3) maxima displayed by distributions of ??²ρ. Deformation maps observed for the SiOSi bridges for the silica polymorphs and a number of silicates are similar to that calculated for the molecule but, for the majority, the maxima ascribed to lone-pair features are absent. The domains of localized nonbonding-electron pair coordinating the oxide anions of quartz and coesite provide a basis for explaining the flexibility and the wide range of the SiOSi angles exhibited by the silica polymorphs with four-coordinate Si. They also provide a basis for explaining why the SiO bond length in coesite decreases with increasing angle. As found in studies of the interactions of solute molecules with a solvent, a mapping of η-isosurfaces for geometry-optimized silicates is expected to become a powerful tool for deducing potential sites of electrophilic attack and reactivity for Earth materials. The positions of the features ascribed to the lone pairs in coesite correspond with the positions of the H atoms recently reported for an H-doped coesite crystal.     

Vertebrate burrows in late Pleistocene paleosols at Korean Palaeolithic sites and their significance as a stratigraphic marker

A vertebrate burrow-bearing layer of late Pleistocene age is commonly found at many Paleolithic archaeological sites in Korea. The burrows are straight to slightly curved in horizontal (plan) view and gently inclined in lateral (sectional) view. They are interpreted as having been produced by rodent-like mammals based on their size and architecture. The significance of such burrow-bearing layers as a characteristic stratigraphic marker unit is demonstrated by high burrow abundance, consistent stratigraphic position, lack of stratigraphic recurrence at these sites, and widespread geographic extent. Three dating methods, tephrochronology, radiocarbon, and OSL dating, were used to infer the age of these burrow-bearing layers. The dating results indicate that they were formed between ca. 40,000 and 25,000 yr (MIS 3−2), and this suggests that this layer can be used as a stratigraphic time-marker in late Pleistocene paleosol sequences for this region.     

Characteristics of tephra in Holocene lake sediments on King George Island, West Antarctica: implications for deglaciation and paleoenvironment

Several reworked tephra layers in gravity-flow deposits are present in lacustrine core sediments collected from Hotel and Rudy Lakes on King George Island, South Shetland Islands, maritime sub-Antarctica. This study tests the values of tephra for establishing regional tephrochronologies for lakes in ice-covered landscapes in the vicinity of volcanoes. The tephra record is more abundant in a long Hotel Lake core (515 cm long). This study uses volcanic glass samples from five tephra layers of Hotel Lake and from one tephra layer of Rudy Lake. Morphologically, tephras are mixtures of basaltic and pumice shards, both having various degrees of vesicularity. Major element analyses of glass shards reveal that the majority of the glass fragments belong to basic glass (<60 wt% SiO₂), compositionally ranging from basalt to low-silica andesite and subalkaline series medium-K tholeiites, probably sourced from Deception Island located 130 km southwest of King George Island. Less than 20% of tephra belongs to silicic glass and occurs in three tephra horizons E of Hotel Lake. However, source volcano(es) for about 10% of basic tephra and silicic tephra are not readily identified from nearby volcanic centers. Except for the studied tephra in Rudy Lake, all tephra samples in Hotel Lake are not ashfall deposits but reworked and redeposited pyroclasts derived from retreating ice sheet, resulting in the occurrence of geochemically equivalent tephra samples in different tephra horizons. The dating of the studied tephra horizons represents the timing of deglaciation rather than that of volcanic eruptions. The result of this study implies that combined with sedimentological information more chemical criterion is necessary to study tephrochronology and regional correlation and to understand paleoenvironmental changes using tephra.     

Estimating evapotranspiration from small watersheds using a water and energy balance approach

Meteorological and environmental data measured in semiarid watersheds during the summer monsoon and winter periods were used to study the interrelationships among flux, meteorological and soil water variables, and to evaluate the effects of these variables on the daily estimation of actual evapotranspiration (AET). The relationship between AET and potential evapotranspiration (PET) as a function of soil water content, as suggested by Thornthwaite–Mather and by Morton, was studied to determine its applicability to the study area. Furthermore, multiple linear regression (MLR) analysis was employed to evaluate the order of importance of the meteorological and soil water factors involved. The results of MLR analysis showed that the combined effects of available energy, soil water content and wind speed were responsible for more than 70% of the observed variations in AET during the summer monsoon period. The analyses also indicate that the combined effects of available energy, vapour pressure deficit and wind speed were responsible for more than 70% of the observed variations in AET during the winter period. However, the test results of two different approaches, using the relationships between AET and PET as a function of soil water content, indicated some inadequacy. Copyright © 2007 John Wiley & Sons, Ltd.     

Rare earth elements in bottom sediments of major rivers around the Yellow Sea: implications for sediment provenance

Rare earth elements (REEs) of 91 fine-grained bottom sediment samples from five major rivers in Korea (the Han, Keum, and Yeongsan) and China (the Changjiang and Huanghe) were studied to investigate their potential as source indicator for Yellow Sea shelf sediments, this being the first synthetic report on REE trends for bottom sediments of these rivers. The results show distinct differences in REE contents and their upper continental crust (UCC)-normalized patterns: compared to heavy rare earth elements (HREEs), light rare earth elements (LREEs) are highly enriched in Korean river sediments, in contrast to Chinese river sediments that have a characteristic positive Eu anomaly. This phenomenon is observed also in primary source rocks within the river catchments. This suggests that source rock composition is the primary control on the REE signatures of these river sediments, due largely to variations in the levels of chlorite and monazite, which are more abundant in Korean bottom river sediments. Systematic variations in ΣLREE/ΣHREE ratios, and in (La/Yb)–(Gd/Yb)_UCC but also (La/Lu)–(La/Y)_UCC and (La/Y)–(Gd/Lu)_UCC relations have the greatest discriminatory power. These findings are consistent with, but considerably expand on the limited datasets available to date for suspended sediments. Evidently, the REE fingerprints of these river sediments can serve as a useful diagnostic tool for tracing the provenance of sediments in the Yellow Sea, and for reconstructing their dispersal patterns and the circulation system of the modern shelf, as well as the paleoenvironmental record of this and adjoining marginal seas.