First direct age determination from the Jurassic radiolarian-bearing siliceous series (Jédidi Formation) of northwestern Tunisia

Our study presents preliminary biostratigraphic results from the Jurassic siliceous series of northwestern Tunisia. For the first time, radiolarians are extracted from the Jédidi formation and provide a direct age determination. They are the first radiolarian fauna documented from Tunisia. Two age assignments are comprised within the following intervals: (1) Late Bathonian–Early Callovian, (2) Late Bathonian–Early Oxfordian. These ages are compatible with recent stratigraphic synthesis proposed for the Jurassic series of Tunisia. The data suggest the correlation of the Jédidi formation with siliceous series of Middle–Late Jurassic age from the external zone of the Maghrebides belt rather than with true oceanic units from the Maghrebian flyschs or the internal zones of western Tethys. To cite this article: F. Cordey et al., C. R. Geoscience 337 (2005).     

SIMS analyses of oxygen isotopes: Matrix effects in Fe-Mg-Ca garnets

Large instrumental mass fractionation (IMF) may occur during measurements of oxygen isotope ratios by SIMS. Part of this fractionation depends on crystal structure and mineral composition. In order to improve the accuracy of SIMS measurements, we gathered 6 commonly used garnet standards and prepared 6 others to adequately cover the composition range Alm_0-73, Prp_0-99, Grs_0-20. Electron microprobe analyses were performed at UBP-Clermont to check the chemical homogeneity of these standards. Oxygen isotope compositions were determined by laser fluorination and mass spectrometry at UW-Madison. Ten SIMS sessions and 336 δ¹⁸O measurements at CRPG-Nancy, on a Cameca IMS1270 instrument, demonstrate that the standards are homogeneous with external reproducibility of 0.3‰ (1σ). In terms of δ¹⁸O, SIMS measurements indicate that, during a single session, IMF can vary up to 6.3‰ from one garnet standard to another. In most of the sessions, IMF can be correlated with the grossular content. However, for a satisfactory correction scheme, we suggest the combination of the 3 main components (Ca, Fe, Mg). This is done using a simple least square calculation routine. The correction coefficients determined for each session can be used to calculate the IMF and correct the measured isotopic ratio of a garnet of known chemical composition. This way, we were able to reproduce the δ¹⁸O values of most of the Fe-Mg-Ca garnet standards within ± 0.6‰. Interestingly, the use of only 3 end-member standards (AlmCMG, PrpMM, GrsSE) plus a standard of intermediate composition (e.g. UWG-2) is sufficient to reproduce δ¹⁸O within the same precision. Thus, linear interpolation among end-member standards is satisfactory in the case of the garnet solid-solutions. Two studies carried out on zoned garnets from the Alps and the Pyrenees indicate that matrix effects become significant when variations in grossular contents are important (> 10%). In order to obtain reliable isotope ratio measurements on Fe-Mg-Ca garnets using a SIMS, we suggest a correction scheme using at least 3 reliable end-member standards plus a standard of intermediate composition (a garnet standard closest to the average composition of the analysed garnet). This allows cross-checking and incorporates a correction based on the variations in composition of zoned crystals.     

Denudation rates of the Quadrilátero Ferrífero (Minas Gerais, Brazil): Preliminary results from measurements of solute fluxes in rivers and in situ-produced cosmogenic Be

This paper investigates the denudation rates in the Quadrilátero Ferrífero, Minas Gerais State (Brazil). The aim is to compare chemical weathering rates from measurements of solute fluxes in rivers and long-term mean erosion rates deduced from in situ-produced cosmogenic ¹⁰Be concentrations measured in fluvial sediments. Both water samples and sediments were collected in fifteen stations (checkpoints) located in four hydrographic basins with low anthropogenic perturbations.Depending of the type of substratum, three degrees of chemical denudation rates from water samples are observed: (i) high rates in marbles; (ii) medium rates in schists, phyllites, granites, gneisses and migmatites; (iii) low rates in quartzites and itabirites. Preliminary results of long-term erosion rates deduced from in situ-produced ¹⁰Be are comparable with those of chemical rates.     

Genetic differentiation ofNiphargus rhenorhodanensis (Amphipoda) from interstitial and karst environments

Electrophoretic variation in proteins encoded by seven presumptive gene loci was analyzed in four populations of the stygobiont amphipodNiphargus rhenorhodanensis. The four populations occur in different habitats, including one in drainage canals, another from sediments of the Ain River, a tributary of the Rhône River, and the remaining two occur in a karstic massif (Dorvan, Ain, France) in the epikarstic and at the base level of the massif, respectively. Six of the seven loci were polymorphic within or among populations, with as many as three electromorphs segregating at the most variable loci. Significant deficiencies in the frequency of heterozygotes were common. Genetic divergence between the two populations of the Dorvan Massif and between the two of the Ain River (forest and sediment habitats) was large. This was highly unexpected, particularly in the case of the two hydrologically connected populations of the Dorvan Massif. It is suggested that either low migration rates or the presence of ecological barriers to gene flow may result in strong genetic differention among local populations ofNiphargus.     

Simulation des changements climatiques au cours du XXIe siècle incluant l'ozone stratosphériqueSimulation of climate changes during the 21st century including stratospheric ozone

Two climate simulations of 150 years, performed with a coupled ocean/sea-ice/atmosphere model including stratospheric ozone, respectively with and without heterogeneous chemistry, simulate the tropospheric warming associated with an increase of the greenhouse effect of carbon dioxide and other trace gases since 1950 and their impact on sea–ice extent, as well as the stratospheric cooling and its impact on ozone concentration. The scenario with heterogeneous chemistry reproduces the formation of the ozone hole over the South Pole from the 1970s and its deepening until the present time, and shows that the ozone hole should progressively fill during the coming decades. To cite this article: J.-F. Royer et al., C. R. Geoscience 334 (2002) 147–154.     

Significance of a combined approach for replacement stones in the heritage buildings’ conservation frame

Stone substitution is a conventional operation during heritage buildings’ restoration, but becomes problematic for architects and restorers when the quarry is mined out. The compatibility of the substitution stones with the original ones has been for long mainly based on the aesthetical aspect, this resulting too often in a patchwork of original and substitution stones with different patina after several years because of differences of properties. In this study, the objective is to show how substitution stones can be selected by combining aesthetic criteria and stones properties that are relevant for analyzing their compatibility. A couple of French limestones with their potential substitution stones were selected for the study. Our results showed that potential substitution stones selected on their aesthetic criteria require to be rejected because of their differences of physical properties. On the other hand, our results showed also the possibility to select substitution stones with satisfactory aesthetic aspect and properties that enable to expect a satisfactory compatibility with the original stone.     

Tracking past mining activity using trace metals,lead isotopes and compositional data analysis of a sediment core from Longemer Lake,Vosges Mountains,France

A 157-cm-long sediment core from Longemer Lake in the Vosges Mountains of France spans the past two millennia and was analyzed for trace metal content and lead isotope composition. Trace metal accumulation rates highlight three main input phases: Roman Times (cal. 100 BC–AD 400), the Middle Ages (cal. AD 1000–1500), and the twentieth century. Atmospheric contamination displays a pattern that is similar to that seen in peat bogs from the region, at least until the eighteenth century. Thereafter, the lake sediment record is more precise than peat records. Some regional mining activity, such as that in archaeologically identified eighteenth-century mining districts, was detected from the lead isotope composition of sediment samples. Compositional data analysis, using six trace metals (silver, arsenic, cadmium, copper, lead and zinc), enabled us to distinguish between background conditions, periods of mining, and of other anthropogenic trace metal emissions, such as the recent use of leaded gasoline.     

Shear zones in porous sand: Insights from ring-shear experiments and naturally deformed sandstones

In a high-resolution small-scale seismic experiment we investigated the shallow structure of the Wadi Araba fault (WAF), the principal fault strand of the Dead Sea Transform System between the Gulf of Aqaba/Eilat and the Dead Sea. The experiment consisted of 8 sub-parallel 1 km long seismic lines crossing the WAF. The recording station spacing was 5 m and the source point distance was 20 m. The first break tomography yields insight into the fault structure down to a depth of about 200 m. The velocity structure varies from one section to the other which were 1 to 2 km apart, but destinct velocity variations along the fault are visible between several profiles. The reflection seismic images show positive flower structures and indications for different sedimentary layers at the two sides of the main fault. Often the superficial sedimentary layers are bent upward close to the WAF. Our results indicate that this section of the fault (at shallow depths) is characterized by a transpressional regime. We detected a 100 to 300 m wide heterogeneous zone of deformed and displaced material which, however, is not characterized by low seismic velocities at a larger scale. At greater depth the geophysical images indicate a blocked cross-fault structure. The structure revealed, fault cores not wider than 10 m, are consistent with scaling from wear mechanics and with the low loading to healing ratio anticipated for the fault.     

Interannual variability and predictability of African easterly waves in a GCM

The interannual variability of African Easterly Waves (AEWs) is assessed with the help of spatio-temporal spectral analysis (STSA) and complex empirical orthogonal functions methods applied to the results of ten-member multiyear ensemble simulations. Two sets of experiments were conducted with the Météo-France ARPEGE-Climat GCM, one with interactive soil moisture (control), and the other with soil moisture relaxed towards climatological monthly means calculated from the control. Composites of Soudano–Sahelian AEWs were constructed and associated physical processes and dynamics were studied in the frame of the waves. It is shown that the model is able to simulate realistically some interannual variability in the AEWs, and that this dynamical aspect of the West African climate is potentially predictable (i.e. signal can be extracted from boundary conditions relatively to internal error of the GCM), especially along the moist Guinean coast. Compared with ECMWF 15-year reanalysis (ERA15), the maximum activity of AEWs is located too far to the South and is somewhat too zonal, but the main characteristics of the waves are well represented. The major impact of soil moisture relaxation in the GCM experiments is to reduce the seasonal potential predictability of AEWs over land by enhancing their internal variability.     

Electrical conductivity of polycrystalline Mg(OH)<Subscript>2</Subscript> at 2 GPa: effect of grain boundary hydration–dehydration

The effect of intergranular water on the conductivity of polycrystalline brucite, Mg(OH)₂, was investigated using impedance spectroscopy at 2 GPa, during consecutive heating–cooling cycles in the 298–980 K range. The grain boundary hydration levels tested here span water activities from around unity (wet conditions) down to 10⁻⁴ (dry conditions) depending on temperature. Four orders of magnitude in water activity result in electrical conductivity variations for about 6–7 orders of magnitude at 2 GPa and room temperature. Wet brucite samples containing, initially, about 18 wt% of evaporable water (i.e. totally removed at temperatures below 393 K in air), display electrical conductivity values above 10⁻²–10⁻³ S/m. A.C. electrical conductivity as a function of temperature follows an Arrhenius behaviour with an activation energy of 0.11 eV. The electrical conductivity of the same polycrystalline brucite material dried beforehand at 393 K (dry conditions) is lower by about 5–6 orders of magnitude at room temperature and possesses an activation energy of 0.8–0.9 eV which is close to that of protonic diffusion in (001) brucitic planes. Above ca. 873 K, a non-reversible conductivity jump is observed which is interpreted as a water transfer from mineral bulk to grain boundaries (i.e. partial dehydration). Cooling of such partially dehydrated sample shows electrical conductivities much higher than those of the initially dry sample by 4 orders of magnitude at 500 K. Furthermore, the corresponding activation energy is decreased by a factor of about four (i.e. 0.21 eV). Buffering of the sample at low water activity has been achieved by adding CaO or MgO, two hygroscopic compounds, to the starting material. Then, sample conductivities reached the lowest values encountered in this study with the activation energy of 1.1 eV. The strong dependency of the electrical conductivity with water activity highlights the importance of the latter parameter as a controlling factor of diffusion rates in natural processes where water availability and activity may vary grandly. Water exchange between mineral bulk and mineral boundary suggests that grain boundary can be treated as an independent phase in dehydroxylation reactions.