热处理褐铁矿去除水中的Mn2+

本文利用褐铁矿中针铁矿经热脱水相变获得以纳米晶赤铁矿为主要物相的纳米-微米多级孔结构材料,并用于模拟净化富Mn~(2+)地下水。同时考察了热处理温度、初始pH值、初始Mn~(2+)浓度、吸附反应时间等对材料去除溶液中Mn~(2+)的影响。XRD、TEM、BET表征结果表明,300℃热处理产物中赤铁矿孔径最小为2.7 nm,比表面积最大达到107.4 m~2/g。吸附实验结果表明,在pH值5~10的范围内,p H值对煅烧褐铁矿颗粒对Mn~(2+)去除效果影响较小;材料在贫氧条件下对水中低浓度Mn~(2+)的最大吸附量为6.45 mg/g;吸附动力学符合准二级动力学模型;褐铁矿热处理形成的纳米晶赤铁矿对Mn~(2+)具有吸附和催化氧化作用,其中的杂质锰氧化物对Mn~(2+)的吸附和催化氧化具有增强作用。     

地物化方法在航磁异常查证中的应用

航磁异常查证是矿产勘查中的一个重要环节,其目的是通过地面查证,确定异常是否存在,追踪异常源,了解异常源所处的地质环境,对异常作出客观评价,提出进一步工作的建议,为后续资料解释提供依据.通过使用地物化综合方法对黑C-2011-02243号异常查证发现：地质剖面测量和土壤地球化学测量可在地表发现较好的找矿线索;高精度磁测及激电中梯测量则反映了深部地质体及矿化特征.依据查证结果认为,在进行航磁异常查证工作时,可优先进行剖面性的地质、高精度磁法及土壤地球化学测量工作;在分析上述测量结果的基础上安排剖面性的电法测量;如存在进一步找矿信息,可安排面积性物化探测量及工程验证工作.     

基于数值模拟的再生水对地下水质影响实例

为了探讨在再生水地表回灌条件下,再生水对地下水中氨素和主要盐分浓度变化的影响,选取现实存在的清河再生水湿地公园为例,以氨氮、Cl-离子为主要研究对象,利用Hydrus-1D溶质运移模型和Modflow、MT3DMSD耦合地下水模型,模拟了再生水长期利用后的地下水氨氮和Cl-指标变化情况。研究结果显示,再生水到达包气带底部时,水中氮氨、Cl-离子含量高于研究区潜水地下水中的相应指标含量,氨氮超出地下水质量Ⅲ类标准。预测5~20年后,潜水中氨氮超标面积不断扩展,20年后将达14km2,氨氮超标垂向延伸至第一层弱透水层;Cl-离子在潜水中不超标,但在湿地公园周边浓度有所增加。湿地公园再生水的长期地表回灌将给当地地下水质量带来负面影响。     

地质资料目录查询系统的设计与实现

地质资料目录查询系统主要针对地勘单位地质资料管理现状进行研究,采用VS2010开发环境,SQL Server2008、.NET4.0框架、B/S架构等关键技术.设计提供报告查询、报告录入、报告维护、服务器连接、用户管理五大功能模块,提高了地质资料整理与查询的效率,实现对地质资料进行科学化、信息化管理.     

大兴安岭伊勒呼里山早白垩世碱长花岗岩年龄、地球化学特征及其地质意义

对大兴安岭伊勒呼里山早白垩世碱长花岗岩进行了岩相学、地球化学、LA-ICP-MS锆石U-Pb定年研究。伊勒呼里山地区碱长花岗岩主量元素具有富Si、富碱,贫Mg、Ca的特征;微量元素亏损Sr、P、Eu、Ti,富集K、Rb、Th等不相容元素,元素地球化学特征表明,岩体为铝质A型花岗岩(A/CNK=0.88~1.21,A/NK=0.94~1.49)。测年结果显示,粗中粒碱长花岗岩的锆石年龄为140.3±1.0Ma,细中粒碱长花岗岩锆石年龄为137.9±0.8Ma,均形成于早白垩世。结合区域研究资料,伊勒呼里山地区碱长花岗岩岩体的形成与蒙古-鄂霍茨克洋闭合后的岩石圈伸展密切相关,其岩浆源区可能为地壳物质的部分熔融。     

Discriminating characters of ore-forming intrusions in the super-large Chalukou porphyry Mo deposit,NE China

The Chalukou porphyry Mo deposit, located in the Great Hinggan Range, is the largest Mo deposit in northeast China, although the age and genesis of the associated magmatic intrusions remain debated.Here we report zircon U-Pb ages and trace elements, whole rock geochemistry and Sre Nd isotope data with a view to understand the relationship between the magmatism and molybdenum mineralization.Zircon U-Pb analysis yield an age of 475 Ma for rhyolite in the older strata, 168 Ma for the premineralization monzogranite, and 154 Ma for the syn-mineralization granite porphyry. The granite porphyry and quartz porphyry are considered as the ore-forming intrusions. These rocks are peraluminous, alkali-calcic, and belong to high-K to shoshonitic series with a strong depletion of Eu. They also display characteristics of I-type granites. The rocks exhibit wide variations of(87 Sr/86 Sr)iin the range of 0.705426 -0.707363, and ε_(Nd)(t) of -3.7 to 0.93. Zircon REE distribution patterns show characteristics between crust and the mantle, implying magma genesis through crust-mantle interaction. The Fe_2O_3/FeO values(average 1) for the whole rock and EuN/Eu*Nvalues(average 0.45), Ce~(4+)/Ce~(3+) values(average 301)for zircon grains from the granite porphyry are higher than those from other lithologies. These features suggest that the ore-forming intrusions(syn-mineralization porphyry) had higher oxygen fugacity conditions than those of the pre-mineralization and post-mineralization rocks. The Chalukou Mo deposit formed in relation to the southward subduction of the Mongol-Okhotsk Ocean. Our study suggests that the subduction-related setting, crust-mantle interaction, and the large-scale magmatic intrusion were favorable factors to generate the super-large Mo deposits in this area.     

Redkinian Biota of Macroscopic Fossils from the Northwestern East European Platform (South Ladoga Region)

The stratigraphic distribution of microfossils and macroscopic fossil biota in Vendian deposits of the South Ladoga region (northwestern East European Platform) is analyzed. In the sequence of the Shotkusa- 1 well, three taxonomically heterogeneous microfossil assemblages are distinguished: two of them refer to the Redkinian age (Starorusskaya Fm.) and one to the Kotlinian age (Vasileostrovskaya Fm.). Deposits of the Starorusskaya Fm. contain Redkinian biota of macroscopic fossils, of which the most characteristic representatives are Chuaria circularis, Doushantuophyton lineare, Morania zinkovi, Orbisiana simplex, and Redkinia spinosa. These new findings expand the paleontological characteristics of Upper Vendian deposits, also providing additional criteria for distinguishing the Redkinian horizon in the northwestern East European Platform.     

Shear Tectonic Fabric in the Atlantic Ocean and Its Relation to the Geodynamic Condition of the Upper Mantle and Intraplate Deformations

The tectogenesis of the Atlantic Ocean segments is complicated by the axial difference in spreading half-velocities, which causes additional shear displacements between the lithospheric blocks along the transform faults. The intensity of these processes and density of the fault zones iis related to the presence of “cold” sublithospheric lenses along the MAR at a depth of 500 km.     

First Data about Mercury in Modern Hydrothermal Process in the Ocean,Juan de Fuca Ridge

The results of studying Hg in an underwater hydrothermal system in the ocean using the Middle Valley of the Juan de Fuca ridge as an example are presented. A significant part of Hg is accumulated in the basalt fundament (Holes 858F, G), forming anomalously high concentrations (up to 29.30 ppm) in certain parts. The high Hg contents were established in metalliferous sediments (323 ppm) of the sedimentary cover (Hole 858D) and in sulfide deposits (up to 10.30 ppm). In other parts of the section, Hg content is 0.02–0.76 ppm (Holes 858B, D, F), background Hg contents in sediments—0.08–0.28 ppm and in basalts—0.17–0.31 ppm (Holes 855A, C, D).