酸性矿山排水影响的水库沉积物微量元素地球化学特征

为了解酸性矿山排水（AMD）影响下水库沉积物中微量元素的质量分数水平及其分布特征,对常年受酸性废水影响的贵州兴仁猫石头水库沉积物中26种微量元素的质量分数、相关性及控制因素进行了分析。结果表明：猫石头水库沉积物柱中Sr、Ba、Zr、V、Cr和As质量分数平均值超过了100 μg/g,其中As质量分数最高,平均值超过800 μg/g;Be、Ta、Co、Ag、Cd、Sn和Se质量分数的平均值都在5 μg/g以下;其他元素质量分数平均值则在10~60 μg/g之间。相较未受AMD影响的水系沉积物,研究区水库沉积物具有明显的As和Sb富集特征。水库沉积物中Li、Be、Rb、Sr、Cs、Ba、Sc、Y、Zr、Hf、Nb、Ta、Th之间存在显著正相关关系,而As与这些元素之间存在显著负相关关系。元素相关分析、因子分析及微量元素图解表明,Li、Be、Rb、Sr、Cs、Ba、Sc、Y、Zr、Hf、Nb、Ta、Th、Cr、Sb等元素受控于流域岩石化学风化和土壤物理侵蚀,这也是控制研究区元素分布最重要的因素,而Cu、Cd等重金属元素则与AMD对地层中元素的溶蚀析出和有机质等细颗粒物的吸附有关。另外,研究区重金属元素中,Cd、Cu、Pb、Cr、Zn的生态风险轻微,而As和Sb则具有很强的潜在生态风险。     

大别造山带南坡晚白垩世玄武岩源区地幔特征

大别造山带南坡中生代断陷盆地中出露大量晚白垩世碱性玄武岩类。因岩浆受结晶分异和陆壳混染影响微弱,其成分基本可代表本区原生玄武岩浆。在微量元素原始地幔标准化蛛网图上,本区玄武岩具有地壳富集组分Pb、K、Rb、Ba等的正异常和Nb、P、Hf等高场强元素的负异常。同位素和微量元素特征显示,玄武岩浆来自亏损地幔(DM)和富集地幔(EM+EM)混合源区。玄武岩源区地幔中Pb的富集和Nb、P、Hf等的亏损基本可由中国东部亏损地幔与榴辉岩的混合获得,由此揭示富集地幔端元组成特征可能与晚白垩世前造山带根部榴辉岩拆沉并参与地幔再循环有关。     

Research progress and prospects of digital restructuring of global-local interactions北大核心CSCD

Global-local interaction is an important research topic in economic geography. In recent years, the rapid development of digitalization in various countries and regions has profoundly affected the global production and trade networks. However, there is a lack of systematic theoretical discussion on digitalization and global-local interaction studies. The objective of this study is to conceptually rethink the role of digitalization in reshaping global-local interactions from a dynamic and relational perspective. To do this, the study first systematically reviewed the digital turn in economic geography and discussed the rethinking of digitalization. It is found that the understanding of digitalization is gradually moving beyond the limits of isolated, static, and passive technocentric approaches and towards a more dynamic, relational, and open perspective. Second, the study combined the "digital turn" with the "relational turn" in relational economic geography, which constructs theoretical bridges between digitalization and global-local studies. Third, this study provided a basic understanding for sorting out the evolution of the research frameworks, that is, from the global value chain (GVC) to the global production network (GPN) and then to the digital ecosystem (DE). We argued that digitalization has been deeply involved in shaping the global economic landscape, restructuring global-local production relations, and reconstructing regional development. Based on this recognition, we discussed the primary performance of digitalization on the restructuring of global-local interaction from three aspects: enterprise relationship, spatial effect and interaction mechanism. Finally, grounded in the practice of China's urban and regional digital economy development, the possible theoretical innovations and prospects for future research on digitalization and global-local interaction in the Chinese context were proposed. The study pointed out that we can integrate the regional practices of China's digital development with more in-depth research from the perspectives of the platform ecosystems, spatial effects, location analysis, local development models, and so on in future research. © 2023, Editorial office of PROGRESS IN GEOGRAPHY. All rights reserved.     

Cs2NaMF6(M＝Al,Ga):Cr3+ 络合分子体系局域结构和基态分裂的理论研究

采用双自旋轨道耦合系数模型并结合完全能量矩阵的方法对Cs₂NaMF₆(M=Al, Ga):Cr³⁺ 体系中Cr³⁺ 离子的基态分裂和局域结构进行了研究.通过模拟光谱和EPR谱确定了Cr³⁺ 取代 M³⁺ 形成的两种占位结构的畸变角,发现用双自旋轨道耦合系数模型与单自旋轨道耦合系数模型计算出的畸变角Δθ存在较大的差异.这表     

开放边界条件下平面环行交叉路口交通流的相图研究

运用具有内、外环车道的平面环形交叉路口元胞自动机模型,对开放边界条件下平面环行交叉路口的交通流进行研究.计算机模拟结果表明:边界条件和道路瓶颈影响着平面环形交叉路口交通流的性质,产生概率和消失概率均只在一定范围内影响系统流量的变化.根据系统流量与产生概率和消失概率的关系,将系统分为三个相区,并对相图进行研究,为实际交通控制提供参考.     

锰掺杂对Ba(Zr,Ti)O3陶瓷压电与介电性能的影响

采用氧化物固相反应法制备了锰掺杂改性的Ba(Zr_0.06Ti_0.94)O₃陶瓷.研究了锰的掺杂量对Ba(Zr_0.06Ti_0.94)Mn_xO₃ (BZTM)陶瓷的结构、介电和压电性能的影响.实验发现,当锰含量x<0.5 mol%时进入晶格,使材料压电性能提高,损耗减小,表现出受主掺杂的特性;当锰含量x>0.5 mo     

三维椭球隐身条件的严格推导及其隐身特性验证

基于坐标变换理论,提出并推导了任意轴比下三维椭球的隐身条件,得到了相应隐身罩材料本构参数张量的通解表达式.根据导出的本构参数张量,利用电磁仿真软件分别对不同轴比的三个典型算例进行仿真验证.仿真结果证实了所导出的本构参数张量的正确性.这些分析结果为隐身物理机理的进一步理解,以及三维隐身罩的设计奠定了更充分的理论基础.     

1986—2021年国家自然科学基金资助大气科学研究35年

中国基础科学全面发展的一个重要标志,是1986年国家自然科学基金委员会的建立。从该年开始,基金委地学部开始资助大气科学基础研究项目。截至2021年,35年来,基金委以研究项目的遴选、资助和评估等过程为推动,不仅促成了我国大气科学研究的持续进步,更形成了一支核心研究机构和队伍。自然科学基金大气科学类项目立项呈现持续增加态势立项数量的增加出现两个快速增加的台阶:一是2000年开始。