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91.
In batch cultures of Lake Taupo water, phosphorus was the nutrient limiting plant growth from January to June, and nitrogen took over this role from July to December. Chlorophyll production by algae was often stimulated by trace element additions, but it was uncertain whether total cytoplasmic production was also involved.  相似文献   
92.
Wind and tracer data from the Oklahoma City Joint Urban 2003 (JU2003) and the Manhattan Madison Square Garden 2005 (MSG05) urban field experiments are being analyzed to aid in understanding air flow and dispersion near street-level in built-up downtown areas. The mean winds are separately calculated for groups of anemometers having similar exposures such as “near street level” and “on building top”. Several general results are found, such as the scalar wind speed at street level is about 1/3 of that at building top. Turbulent standard deviations of wind speed components and temperature, and vertical fluxes of momentum and sensible heat, are calculated from sonic anemometers near street level at 20 locations in JU2003 and five locations in MSG05, and from two rooftop locations in MSG05. The turbulence observations are consistent with observations in the literature at other cities, although the JU2003 and MSG05 data are unique in that many data are available near street level. For example, it is found that the local (i.e., at the measuring height) averages about 1.5 and the local averages about 0.25 in the two cities, where is the standard deviation of vertical velocity fluctuations, is the friction velocity, and u is the wind speed. The ratio of temperature fluctuations to temperature scale, , averages about −3 in both cities, consistent with similarity theory for slightly unstable conditions, where is the standard deviation of temperature fluctuations, and is the temperature scale. The calculated Obukhov length, L, is also consistent with slightly unstable conditions near street level, even at night during JU2003. The SF6 tracer concentration observations from JU2003 are analyzed. Values of for the continuous releases are calculated for each release and arc distance, where is the 30-min average arc maximum concentration, Q is the continuous source emission rate, and u is the spatial-averaged wind speed in the downtown area. The basic characteristics of the JU2003 plot of averaged agree reasonably well with similar plots for other urban experiments in Salt Lake City and London (i.e., at . A is found to be about 3 during the day and about 10 during the night.  相似文献   
93.
In order to constrain better the distribution, age, geochemistry and origin of widespread Cenozoic intraplate volcanism on Zealandia, the New Zealand micro-continent, we report new 40Ar/39Ar and geochemical (major and trace element and Sr–Nd–Hf–Pb isotope) data from offshore (Chatham Rise, Campbell and Challenger Plateaus) and onland (North, South, Auckland, Campbell, Chatham and Antipodes Islands of New Zealand) volcanism on Zealandia. The samples include nephelinite, basanite through phonolite, alkali basalt through trachyte/rhyolite, and minor tholeiite and basaltic andesite, all of which have ocean island basalt (OIB)-type trace element signatures and which range in age from 64.8 to 0.17 Ma. Isotope ratios show a wide range in composition (87Sr/86Sr = 0.7027–0.7050, 143Nd/144Nd = 0.5128–0.5131, 177Hf/176Hf = 0.2829–0.2831, 206Pb/204Pb = 18.62–20.67, 207Pb/204Pb = 15.54–15.72 and 208Pb/204Pb = 38.27–40.34) with samples plotting between mid-ocean-ridge basalts (MORB) and Cretaceous New Zealand intraplate volcanic rocks.Major characteristics of Zealandia's Cenozoic volcanism include longevity, irregular distribution and lack of age progressions in the direction of plate motion, or indeed any systematic temporal or spatial geochemical variations. We believe that these characteristics can be best explained in the context of lithospheric detachment, which causes upwelling and melting of the upper asthenospheric mantle and portions of the removed lithosphere. We propose that a large-scale seismic low-velocity anomaly, that stretches from beneath West Antarctica to Zealandia at a depth of > 600 km may represent a geochemical reservoir that has been in existence since the Cretaceous, and has been supplying the upper mantle beneath Zealandia with HIMU-type plume material throughout the Cenozoic. In addition, the sources of the Cenozoic intraplate volcanism may be at least partially derived through melting of locally detached Zealandia lower lithosphere.  相似文献   
94.
This paper appraises and compares the Middle-Upper Pleistocene sedimentary sequences preserved in the fluvial systems draining into the Fenland Basin and the Wash estuary. Of the main Fenland rivers the longest records, which extend back to the initial Anglian (glacial) formation of the basin, are found in the Great Ouse and its tributaries, particularly the Cam and the Nar. These sequences preserve sediments representing all four post-Anglian interglacials. The Nene also has an extensive post-Anglian history, with evidence for a Hoxnian estuary that is presumed to have been the precursor of the Wash. North of the Nene, however, the Welland and Witham (proto-Trent) have relatively short sequences, which are thought to commence with a later (post-Anglian-pre-Devensian) glaciation that affected Lincolnshire and fed the previously-recognized Tottenhill outwash delta south of Kings Lynn. Prior to Devensian deglaciation the Witham valley was occupied by the Trent, which was the trunk river of the late Middle Pleistocene Wash system. During periods of low sea level the river would have extended north-eastwards across what is now the floor of the North Sea, possibly via the Inner Silver Pit. Several of the central Fenland sequences show evidence of infrequent terrace formation during the late Quaternary, although this might in part be due to poor vertical separation between terraces, so that differentiating them has been difficult; this has been exacerbated by mixed biostratigraphical signals due to the preservation of sediments representing more than one interglacial beneath a single terrace surface. In several of the systems there is evidence for valley rejuvenation to the lowest terrace or valley-floor level during the MIS 4-3 transition. The observed differences within what, during the predominant periods of lower sea level, would have been a single Wash river system are difficult to explain.  相似文献   
95.
The late Middle Pleistocene fluvial terrace sequence of the lower Trent system, Lincolnshire (eastern England), provides an excellent record of environmental change, including evidence for the last two interglacial episodes. It also provides important stratigraphical evidence for the timing and extent of three separate glaciations. Two of these, the Anglian and Devensian, are well-established correlatives of Marine Isotope Stages (MIS) 12 and 2 respectively; the third is a hitherto un-named post-Anglian-pre-Devensian glaciation in eastern England that has been the subject of much previous speculation, but can now be attributed with some confidence to MIS 8. Crucially, the recognition of MIS 7 interglacial deposits within the Balderton-Southrey terrace of the proto-Trent indicates that the underlying Wragby Till, which is ascribed to this additional glaciation, was emplaced no later than MIS 8. The oldest terrace preserved within the lower Trent staircase, the Eagle Moor-Martin Terrace, is considered to be a complex glacial outwash terrace related to the Wragby Till glaciation. It is suggested that deposits representing MIS 11-9, which are conspicuously absent throughout the Trent system, were removed by this glaciation. This is a departure from previous interpretations, which have suggested MIS 10 or MIS 6 as the most likely stages in which an extensive post-Anglian-pre-Devensian lowland glaciation might have occurred in Britain. However, the widespread preservation of undisrupted post-MIS 8 fluvial sequences throughout the Trent valley and in neighbouring systems, within which MIS 7 interglacial deposits have now been recognized at a number of localities, indicates that ice sheets are unlikely to have advanced further into this catchment during MIS 6 than during the Devensian (MIS 2). Recognition of a British glaciation during MIS 8 corresponds with widespread evidence in Europe, which suggests that glacial deposits classified as ‘Saalian’ represent both MIS 8 and MIS 6; in many areas, distinguishing these remains controversial, as confident correlation with either stage is often only possible where glacial sediments interdigitate with well-constrained fluvial records.  相似文献   
96.
Jarosite phases are common minerals in acidic, sulfate-rich environments. Here, we report heat capacities (C p) and standard entropies (S°) for a number of jarosite samples. Most samples are close to the nominal composition AFe3(SO4)2(OH)6, where A = K, Na, Rb, and NH4. One of the samples has a significant number of defects on the Fe sites and is called the defect jarosite; others are referred to as A-jarosite. The samples, their compositions, and the entropies at T = 298.15 K are:
Sample Chemical composition S o/(J mol−1 K−1)
K-jarosite K0.92(H3O)0.08Fe2.97(SO4)2(OH)5.90(H2O)0.10 427.4 ± 0.7
Na-jarosite Na0.95(H3O)0.05Fe3.00(SO4)2(OH)6.00 436.4 ± 4.4
Rb-jarosite RbFe2.98(SO4)2(OH)5.95(H2O)0.05 411.9 ± 4.1
NH4-jarosite (NH4)0.87(H3O)0.13Fe3.00(SO4)2(OH)6.00 447.2 ± 4.5
Defect jarosite K0.94(H3O)0.06Fe2.34(SO4)2(OH)4.01(H2O)1.99 412.7 ± 4.1
There are additional configurational entropies of 13.14 and 8.23 J mol−1 K−1 in defect and NH4-jarosite, respectively. A detailed analysis of the synchrotron X-ray diffraction patterns showed a large anisotropic peak broadening for defect and NH4-jarosite. The fits to the low-temperature (approx. <12 K) C p data showed that our samples can be divided into two groups. The first group is populated by the K-, Na-, Rb-, and NH4-jarosite samples, antiferromagnetic at low temperatures. The second group contains the H3O-jarosite (studied previously) and the defect jarosite. H3O- and defect jarosite are spin glasses and their low-T C p was fit with the expression C p = γT + ΣB j T j , where j = (3, 5, 7, 9). The linear term is typical for spin glasses and the sum represents the lattice contribution to C p. Surprisingly, the C p of the K-, Na-, Rb-, and NH4-jarosite samples, which are usually considered to be antiferromagnetic at low temperatures, also contains a large linear term. This finding suggests that even these phases do not order completely, but have a partial spin-glass character below their Néel transition temperature.  相似文献   
97.
Management of freshwater lenses on small Pacific islands   总被引:3,自引:0,他引:3  
The nature of shallow aquifers and the impacts of seawater intrusion in small islands within the Pacific Ocean are reviewed. Many Pacific islands rely on shallow fresh groundwater lenses in highly permeable aquifers, underlain and surrounded by seawater, as their principal freshwater source. It is argued here that, in small islands, the nature of fresh groundwater lenses and their host aquifers coupled with frequent natural and ever-present anthropogenic threats make them some of the most vulnerable aquifer systems in the world. A simple steady-state approximation is used to provide insight into the key climatic, hydrogeological, physiographic, and management factors that influence the quantity of, and saline intrusion into freshwater lenses. Examples of the dynamic nature of freshwater lenses as they respond to these drivers are given. Natural and human-related threats to freshwater lenses are discussed. Long dry periods strongly coupled to sea surface temperatures impact on the quantity and salinity of fresh groundwater. The vulnerability of small island freshwater lenses dictates careful assessment, vigilant monitoring, appropriate development, and astute management. Strategies to aid future groundwater sustainability in small islands are presented and suggested improvements to donor and aid programs in water are also advanced.  相似文献   
98.
The simulation and prediction of extreme heat over Australia on intraseasonal timescales in association with the El Niño–Southern Oscillation (ENSO) and the Indian Ocean Dipole (IOD) is assessed using the Bureau of Meteorology’s Predictive Ocean Atmosphere Model for Australia (POAMA). The analysis is based on hindcasts over 1981–2010 and focuses on weeks 2 and 3 of the forecasts, i.e. beyond a typical weather forecast. POAMA simulates the observed increased probabilities of extreme heat during El Niño events, focussed over south eastern and southern Australia in SON and over northern Australia in DJF, and the decreased probabilities of extreme heat during La Niña events, although the magnitude of these relationships is smaller than observed. POAMA also captures the signal of increased probabilities of extreme heat during positive phases of the IOD across southern Australia in SON and over Western Australia in JJA, but again underestimates the strength of the relationship. Shortcomings in the simulation of extreme heat in association with ENSO and the IOD over southern Australia may be linked to deficiencies in the teleconnection with Indian Ocean SSTs. Forecast skill for intraseasonal episodes of extreme heat is assessed using the Symmetric Extremal Dependence Index. Skill is highest over northern Australia in MAM and JJA and over south-eastern and eastern Australia in JJA and SON, whereas skill is generally poor over south-west Western Australia. Results show there are windows of forecast opportunity related to the state of ENSO and the IOD, where the skill in predicting extreme temperatures over certain regions is increased.  相似文献   
99.
A recent airborne geophysical survey has provided high resolution estimates of the electrical resistivity of the near-surface and deeper (bedrock) formations found across Anglesey and a portion of the coastal area of North Wales. This single small survey provides new geophysical information on both the complex configuration of the Neoproterozoic and Cambrian bedrock units and the shallow near-surface geology and glacial features.  相似文献   
100.
Rainfall weakens an earth slope and triggers mass movement. Relevant triggering mechanisms are complex and include reduction of capillary pressure due to increased saturation and frictional drag on the sediment induced by fluid flow. Physics‐based continuum models utilizing modern computational tools are useful for understanding the mechanisms of deformation in partially saturated slopes; however, they do not provide a scalar indicator called ‘factor of safety’ that measures the potential of a given slope for mass movement. In the present work, we employ sequential calculations consisting of a physics‐based finite element model that couples solid deformation with fluid flow to quantify the stress and deformation fields in a steep hillside slope subjected to rainfall infiltration. This is followed by a limit‐equilibrium calculation based on the method of slices that evaluates the desired factor of safety. The field condition investigated is similar to the steep experimental catchment CB1 near Coos Bay, Oregon, which failed as a large debris flow from heavy rainfall. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
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