The distribution of carbon monoxide in the lower atmosphere of Venus

We have obtained spatially resolved near-infrared spectroscopy of the Venus nightside on 15 nights over three observing seasons. We use the depth of the CO absorption band at 2.3 μm to map the two-dimensional distribution of CO across both hemispheres. Radiative transfer models are used to relate the measured CO band depth to the volume mixing ratio of CO. The results confirm previous investigations in showing a general trend of increased CO abundances at around 60° latitude north and south as compared with the equatorial regions. Observations taken over a few nights generally show very similar CO distributions, but significant changes are apparent over longer periods. In past studies it has been assumed that the CO latitudinal variation occurs near 35 km altitude, at which K-band sensitivity to CO is greatest. By modeling the detailed spectrum of the excess CO at high latitudes we show that it occurs at altitudes around 45 km, much higher than has previously been assumed, and that there cannot be significant contribution from levels of 36 km or lower. We suggest that this is most likely due to downwelling of CO-rich gas from the upper atmosphere at these latitudes, with the CO being removed by around 40 km through chemical processes such as the reaction with SO₃.     

Extending the Capture Map Concept to Estimate Discrete and Risk-Based Streamflow Depletion Potential

A popular and contemporary use of numerical groundwater models is to estimate the discrete relation between groundwater extraction and surface-water/groundwater exchange. Previously, the concept of a “capture map” has been put forward as a means to effectively summarize this relation for decision-making consumption. While capture maps have enjoyed success in the environmental simulation industry, they are deterministic, ignoring uncertainty in the underlying model. Furthermore, capture maps are not typically calculated in a manner that facilitates analysis of varying combinations of extraction locations and/or reaches. That is, they are typically constructed with focus on a single reach or group of reaches. The former of these limitations is important for conveying risk to decision makers and stakeholders, while the latter is important for decision-making support related to surface-water management, where future foci may include reaches that were not the focus of the original capture analysis. Herein, we use the concept of a response matrix to generalize the theory of the capture-map approach to estimate spatially discrete streamflow depletion potential. We also use first-order, second-moment uncertainty estimation techniques with the concept of “risk shifting” to place capture maps and streamflow depletion potential in a stochastic, risk-based framework. Our approach is demonstrated for an integrated groundwater/surface-water model of the lower San Antonio River, Texas, USA.     

Burial and exhumation of the Hoh Xil Basin,northern Tibetan Plateau: Constraints from detrital (U-Th)/He ages

The uplift and associated exhumation of the Tibetan Plateau has been widely considered a key control of Cenozoic global cooling. The south-central parts of this plateau experienced rapid exhumation during the Cretaceous–Palaeocene periods. When and how the northern part was exhumed, however, remains controversial. The Hoh Xil Basin (HXB) is the largest late Cretaceous–Cenozoic sedimentary basin in the northern part, and it preserves the archives of the exhumation history. We present detrital apatite and zircon (U-Th)/He data from late Cretaceous–Cenozoic sedimentary rocks of the western and eastern HXB. These data, combined with regional geological constraints and interpreted with inverse and forward model of sediment deposition and burial reheating, suggest that the occurrence of ca. 4–2.7 km and ca. 4–2.3 km of vertical exhumation initiated at ca. 30–25 Ma and 40–35 Ma in the eastern and western HXB respectively. The initial differential exhumation of the eastern HXB and the western HXB might be controlled by the oblique subduction of the Qaidam block beneath the HXB. The initial exhumation timing in the northern Tibetan Plateau is younger than that in the south-central parts. This reveals an episodic exhumation of the Tibetan Plateau compared to models of synchronous Miocene exhumation of the entire plateau and the early Eocene exhumation of the northern Tibetan Plateau shortly after the India–Asia collision. One possible mechanism to account for outward growth is crustal shortening. A simple model of uplift and exhumation would predict a maximum of 0.8 km of surface uplift after upper crustal shortening during 30–27 Ma, which is insufficient to explain the high elevations currently observed. One way to increase elevation without changing exhumation rates and to decouple uplift from upper crustal shortening is through the combined effects of continental subduction, mantle lithosphere removal and magmatic inflation.     

Evaluation of a simple,inexpensive, in situ sampler for measuring time‐weighted average concentrations of suspended sediment in rivers and streams

The accurate measurement of suspended sediment (<200 μm) in aquatic environments is essential to understand and effectively manage changes to sediment, nutrient, and contaminant concentrations on both temporal and spatial scales. Commonly used sampling techniques for suspended sediment either lack the ability to accurately measure sediment concentration (e.g., passive sediment samplers) or are too expensive to deploy in sufficient number to provide landscape‐scale information (e.g., automated discrete samplers). Here, we evaluate a time‐integrated suspended sediment sampling technique, the pumped active suspended sediment (PASS) sampler, which collects a sample that can be used for the accurate measurement of time‐weighted average (TWA) suspended sediment concentration and sediment particle size distribution. The sampler was evaluated against an established passive time‐integrated suspended sediment sampling technique (i.e., Phillips sampler) and the standard discrete sampling method (i.e., manual discrete sampling). The PASS sampler collected a sample representative of TWA suspended sediment concentration and particle size distribution of a control sediment under laboratory conditions. Field application of the PASS sampler showed that it collected a representative TWA suspended sediment concentration and particle size distribution during high flow events in an urban stream. The particle size distribution of sediment collected by the PASS and Phillips samplers were comparable and the TWA suspended sediment concentration of the samples collected using the PASS and discrete sampling techniques agreed well, differing by only 4% and 6% for two different high flow events. We should note that the current configuration of the PASS sampler does not provide a flow‐weighted measurement and, therefore, is not suitable for the determination of sediment loads. The PASS sampler is a simple, inexpensive, and robust in situ sampling technique for the accurate measurement of TWA suspended sediment concentration and particle size distribution.     

On the energy integral for first post-Newtonian approximation

The post-Newtonian approximation for general relativity is widely adopted by the geodesy and astronomy communities. It has been successfully exploited for the inclusion of relativistic effects in practically all geodetic applications and techniques such as satellite/lunar laser ranging and very long baseline interferometry. Presently, the levels of accuracy required in geodetic techniques require that reference frames, planetary and satellite orbits and signal propagation be treated within the post-Newtonian regime. For arbitrary scalar W and vector gravitational potentials \(W^j (j=1,2,3)\), we present a novel derivation of the energy associated with a test particle in the post-Newtonian regime. The integral so obtained appears not to have been given previously in the literature and is deduced through algebraic manipulation on seeking a Jacobi-like integral associated with the standard post-Newtonian equations of motion. The new integral is independently verified through a variational formulation using the post-Newtonian metric components and is subsequently verified by numerical integration of the post-Newtonian equations of motion.     

The Influence of Place on the Willingness to Pay for Ecosystem Services

Sense of place, including an individual’s attitudes toward specific geographic settings, is generally predicted to influence willingness to engage in place-protective behaviors. Relatively little research, however, has empirically examined the influence of people’s attitudes toward a place on their willingness to pay for environmental protection. Using the example of a payment for ecosystem services (PES) initiative in the McKenzie River watershed, Oregon, USA, we found that place attitudes were a significant predictor of respondents’ willingness to pay for a program designed to benefit drinking water quality. These results suggest that connecting conservation actions to landscapes that are meaningful to people may increase their financial support for PES and other conservation programs. While program managers have little or no influence over stakeholders’ political ideology, gender, or income, managers may be able to influence prospective PES buyers’ awareness and attitudes through targeted communications, thereby potentially increasing support for place-based conservation efforts.     

Constraining basin thermal history and petroleum generation using palaeoclimate data in the Piceance Basin,Colorado

Careful assessment of basin thermal history is critical to modelling petroleum generation in sedimentary basins. In this paper, we propose a novel approach to constraining basin thermal history using palaeoclimate temperature reconstructions and study its impact on estimating source rock maturation and hydrocarbon generation in a terrestrial sedimentary basin. We compile mean annual temperature (MAT) estimates from macroflora assemblage data to capture past surface temperature variation for the Piceance Basin, a high‐elevation, intermontane, sedimentary basin in Colorado, USA. We use macroflora assemblage data to constrain the temporal evolution of the upper thermal boundary condition and to capture the temperature change with basin uplift. We compare these results with the case where the upper thermal boundary condition is based solely upon a simplified latitudinal temperature estimate with no elevation effect. For illustrative purposes, 2 one‐dimensional (1‐D) basin models are constructed using these two different upper thermal boundary condition scenarios and additional geological and geochemical input data in order to investigate the impact of the upper thermal boundary condition on petroleum source rock maturation and kerogen transformation processes. The basin model predictions indicate that the source rock maturation is very sensitive to the upper thermal boundary condition for terrestrial basins with variable elevation histories. The models show substantial differences in source rock maturation histories and kerogen transformation ratio over geologic time. Vitrinite reflectance decreases by 0.21%Ro, source rock transformation ratio decreases 10.5% and hydrocarbon mass generation decreases by 16% using the macroflora assemblage data. In addition, we find that by using the macroflora assemblage data, the modelled depth profiles of vitrinite reflectance better matches present‐day measurements. These differences demonstrate the importance of constraining thermal boundary conditions, which can be addressed by palaeotemperature reconstructions from palaeoclimate and palaeo‐elevation data for many terrestrial basins. Although the palaeotemperature reconstruction compiled for this study is region specific, the approach presented here is generally applicable for other terrestrial basin settings, particularly basins which have undergone substantial subaerial elevation change over time.     

Geochemistry and petrography of basalt grindstones from the Karak Plateau,central Jordan

Seventeen basalt grindstone fragments from central Jordan's Karak Plateau were studied. Most of these artifacts are vesicular or amygdaloidal with calcite as the dominant mineral filling the voids. The major minerals are olivine (with iddingsite rims), plagioclase, clinopyroxene, magnetite, and apatite. Glass is present in some samples. One basalt fragment is quite different in appearance and composition and may have come from flows closer to the Dead Sea. Grindstone fragment compositions plot in the tephrite‐basanite and basalt fields. A plot of the concentrations of niobium, zirconium, and yttrium reveal that the sample compositions plot in the “within‐plate alkali basalt” and “within‐plate tholeiite” fields. The acquisition of basalts for preparing such implements appears to have been random. Some may have been introduced through trade and migration. Archaeological and environmental studies on the Karak Plateau are urgently needed because Jordan's population growth and economic development are destroying many sites and their environmental contexts. © 2004 Wiley Periodicals, Inc.     

A GPS-Supported Gravity Survey in the Amazon of Ecuador

The growing importance and effectiveness of the Global Positioning System (GPS) in positioning geophysical surveys is now well established. In Ecuador's Amazon basin the use of GPS was the determining factor in the successful completion of a gravity survey carried out in 1994. Over 500 gravity stations, spaced from 1 to 5 km apart and positioned by GPS, were collected in the jungle environment in the country's southeast, where the preexisting data, of variable and unknown quality, were mostly confined to areas along the major rivers. This station densification, which includes the reoccupation of selected points, contributed to increase the gravity coverage; it also allowed us to evaluate and correct 1100 preexisting data points in the area, so that the different surveys can be merged. The composite data set is used for a geologic analysis of the study area, where previously unknown structures are discovered. ? 1999 John Wiley & Sons, Inc.