Ge-bearing coals of the Luzanovka Graben, Pavlovka brown coal deposit, southern Primorye

Results of the study of a new Ge-bearing area of the Pavlovka brown coal deposit are presented. Ge is accumulated in bed III₂ lying at the bottom of the Late Paleogene-Early Neogene coal-bearing sequence adjacent to the Middle Paleozoic granite basement. The Ge content in coals and coal-bearing rocks varies in different sections from 10 to 200–250 ppm, reaching up to 500–600 ppm in the highest-grade lower part of the bed. The metalliferous area reveals a geochemical zoning: complex Ge-Mo-W anomalies subsequently grades along the depth and strike into Mo-W and W anomalies. Orebodies, like those at many Ge-bearing coal deposits, are concentric in plan and dome-shaped in cross-section. Coals in their central parts, in addition to Ge, W, and Mo, are enriched in U, As, Be, Ag, and Au. Distribution of Ge and other trace elements in the metalliferous sequence and products of gravity separation of Ge-bearing coals is studied. These data indicate that most elements (W, Mo, U, As, Be) concentrated like Ge in the Ge-bearing bed relative to background values are restricted to the organic matter of coals. The electron microscopic study shows that Ge-bearing coals contain native metals and intermetallic compounds in association with carbonates, sulfides, and halogenides. Coal inclusions in the metalliferous and barren areas of the molasse section strongly differ in contents of Ge and associated trace elements. Ge was accumulated in the coals in the course of the interaction of ascending metalliferous solutions with organic matter of the buried peat bogs in Late Miocene. The solutions were presumably represented by N₂-bearing thermal waters (contaminated by volcanogenic CO₂) that are typical of granite terranes.     

Occurrence of salt water above fresh water in dynamic equilibrium in a coastal groundwater flow system near De Panne, Belgium

A salt water lens is found above fresh water under the shore between Dunkerque (France) and Nieuwpoort (Belgium). This inverse density distribution is in a dynamic equilibrium. It develops due to the infiltration of salt water on the back shore during high tide. Under this salt water lens, water infiltrated in the adjacent dune area flows towards the sea and discharges at the seabed. This water quality distribution differs from the classic salt water wedge under fresh water described in the literature. Here, the evolution to this water quality distribution is simulated with a density dependent numerical model. A large tidal range, shore morphology and a permeable groundwater reservoir are the main conditions for the observed water quality distribution. By altering these conditions, intermediate water quality distributions between the classic salt water wedge and the one discussed here develop. Based on these simulations, it is expected that similar kinds of inverse density distribution could be present in a number of coastal areas, which have tides, a gently sloping shore and a permeable substratum.     

The chemical composition of HR 1512, a peculiar helium-weak star

We have used high-resolution spectra to study the chemical composition of HR 1512, a star with effective temperature T _eff = 15 200 K, atmospheric gravity log g = 3.52, microturbulence parameter V _t = 1.5 km/s, and rotation rate v sin i = 17 km s^?1. We confirm the presence of a helium deficiency (?0.6 dex), indicating that HR 1512 is a helium-weak star. Its considerable phosphorus excess (1.6 dex) testifies that the star belongs to the PGa subtype. We suggest that the He and P abundances increase with height; i.e., that there is stratification of He and P in the star’s atmosphere. Among the CNO elements, nitrogen demonstrates an underabundance of ?0.4 dex, while the abundances of carbon and oxygen are solar. Deficits of about ?0.5 or ?0.6 dex were also found for Mg, Si, and S. A neon excess of 0.4 dex was derived from our non-LTE analysis of NeI lines. The largest excess among the iron-peak elements (Cr, Mn, Fe, and Ni) is 0.6 dex, for manganese; the abundances of chromium and nickel display excesses of 0.5 and 0.3 dex, respectively, while the iron abundance is almost normal. The chemical anomalies of HR 1512 generally agree with those for mercury-manganese stars. This supports the hypothesis that PGa stars represent an extension of HgMn stars to higher temperatures.     

Dissolved trace elements in river water: spatial distribution and the influencing factor, a study for the Pearl River Delta Economic Zone, China

Twenty-nine water samples were collected from different river channels of the Pearl River Delta Economic Zone, China. An inductively coupled plasma-mass spectromonitor (ICP-MS) was used to measure concentrations of the trace elements in these samples. The results suggest that the average concentrations of rare earth elements in river water show an increasing trend from the West River, the North River, the rivers of the Pearl River Delta, and the Shenzhen River to the East River. Relatively high concentrations of heavy metals appear in the East River, the rivers of the Pearl River Delta and the Shenzhen River, while the West River and the North River have relatively low heavy metal concentrations. Trace element concentrations in samples collected near urban or industrial areas are much higher than those of samples collected from distant areas, away from urban and industrial areas. After natural conditions, human activities have significant influence on the trace element concentrations in river water. This trace element concentration’s spatial distribution in the river water from the Pearl River Delta Economic Zone is actually an integrated effect of natural conditions and human activity.     

Alkaline magmatism and enriched mantle reservoirs: Mechanisms, time, and depth of formation

Alkaline magmatism has occurred since 2.5–2.7 Ga and its abundance has continuously increased throughout the Earth’s history. Alkaline rocks appeared on the Earth with changes in the geodynamic regime of our planet, i.e., when plume tectonics was supplemented by plate tectonics. Global-scale development of plate tectonics at the Archean—Proterozoic boundary initiated subduction of already significantly oxidized oceanic crust enriched in volatiles and large-scale mantle metasomatism caused the formation of enriched reservoirs as sources of alkaline and carbonatite magmatism. Study of metasomatized mantle material showed the occurrence of traces of primary carbonatite melts, which are strongly enriched in rare elements, according to ion-microprobe analyses. The results obtained allowed us to propose a new two-stage genetic model for Ca-rich carbonatites including (1) metasomatic wehrlitization and carbonatization of mantle material and (2) partial melting of wehrlitized mantle with formation of carbonate-rich melts or three immiscible liquids (at high alkali contents), i.e., silicate, carbonatitic, and sulfide (at high sulfur activity). Original Russian Text L.N. Kogarko, 2006, published in Geokhimiya, 2006, No. 1, pp. 5–13.     

On global forces of nature driving the Earth’s climate. Are humans involved?

The authors identify and describe the following global forces of nature driving the Earth’s climate: (1) solar radiation as a dominant external energy supplier to the Earth, (2) outgassing as a major supplier of gases to the World Ocean and the atmosphere, and, possibly, (3) microbial activities generating and consuming atmospheric gases at the interface of lithosphere and atmosphere. The writers provide quantitative estimates of the scope and extent of their corresponding effects on the Earth’s climate. Quantitative comparison of the scope and extent of the forces of nature and anthropogenic influences on the Earth’s climate is especially important at the time of broad-scale public debates on current global warming. The writers show that the human-induced climatic changes are negligible.     

Construction Problems on the Karstified Limestone Tuffs of Condeixa, Central Portugal: A Case Study

During the excavations for the foundations of a three storey building on the limestone tuffs of Condeixa, Central Portugal, a large dissolution fissure and smaller dissolution voids were found. Since the area has never been the subject of engineering geology investigation, it was decided to evaluate the risk associated with the construction of the building. These limestone tuffs were formed in a continental environment by the precipitation of calcite carried by the water coming from the large limestone body in the east. The precipitated calcite mixed with the terrigenous materials and around trunks and leaves of plants, originating a very heterogeneous and porous ground, which is characteristic of limestone tuffs. The study started with a detailed geological survey followed by a large number of destructive drillings, located essentially under the pad foundations. The results revealed several karstic cavities with serious problems for the building foundations and the structure, and many smaller dissolution cavities, often filled with clayey soils. The ground treatment solutions used included, dental cleaning, filling with concrete or granular material the dissolution structures accessible at the level of the foundation, reinforcement of the footing and the structure of the building and adding a continuous foundation beam to hold the foundations together. The cost of the engineering geology study, site investigation, ground treatment, and the reinforcement of the foundation and building, increased the total construction cost from 2%, at the design stage, to 4.8%.     

Three-dimensional hydrodynamical modeling of mass transfer in the close binary system β Lyr with an accretor wind

We present three-dimensional hydrodynamical modeling of mass transfer in the close binary system β Lyr taking into account explicitly radiative cooling and the stellar wind of the accretor. Our computations show that flow forces wind out from the orbital plane, where an accretion disk with a radius of 0.4–0.5 and a height of about 0.15–0.17 (in units of orbital separation) is formed. Gas motions directed upward from the orbital plane are initiated in the region of interaction of the flow from L₁ and the accretor wind (x = 0.91, y = ?0.17); i.e., a jetlike structure forms. This structure has the shape of a gas pillar above the orbital plane, where gas moves with the velocity of stellar wind. The number density of the gas in this structure is about 10¹⁴ cm^?3, and its temperature is 20 000–45 000 K. At heights of about 0.15–0.20 above the orbital plane, in the region between the jetlike structure and the disk, two spiral shocks form. It is possible that the emission lines observed in the spectrum of β Lyr binary originate in this region.     

Geochronological constraints on the Legs Lake shear zone with implications for regional exhumation of lower continental crust, western Churchill Province, Canadian Shield

The Legs Lake shear zone marks the southeastern boundary of an extensive region (>20,000 km²) of high-pressure (0.8–1.5+ GPa) granulite-facies rocks in the western Churchill Province, Canada. The shear zone is one of the largest exhumation-related structures in the Canadian Shield and coincides with the central segment of the ∼2,800 km long Snowbird tectonic zone. The movement history of this shear zone is critical for the development of models for the exhumation history of the high-pressure region. We used electron microprobe U–Th–Pb dating of monazite with supplemental ID-TIMS U–Pb geochronology to place constraints on the timing of shear zone activity. Combining these and other data, we suggest that regional exhumation occurred during at least three distinct phases over an ∼150 million year period. The first phase involved high temperature decompression from ∼1.0 to 0.8–0.7 GPa shortly following 1.9 Ga peak metamorphism, possibly under an extensional regime. The second phase involved rock uplift and decompression of the hanging wall to 0.5–0.4 GPa during east-vergent thrusting across the Legs Lake shear zone at ca. 1.85 Ga. This phase was likely driven by early collision-related convergence in the Trans-Hudson orogen. The final phase of regional exhumation, involving the removal of 15–20 km of overburden from both footwall and hanging wall, likely occurred after ∼1.78 Ga and may have been related to regional extensional faulting.Electronic Supplementary Material Supplementary material is available to authorised users in the online version of this article at .