An archetype hydrogen atmosphere problem

Populations for the first three bound states and the continuum of hydrogen are determined for an isothermal, hydrostatic atmosphere at 20 000 K. The atmosphere is treated as being optically thin in the Balmer and Paschen continua and illuminated by continuum radiation at these wavelengths with prescribed radiation temperatures. The atmosphere is optically thick in the 2-1, 3-1, 3-2 and c-1 transitions. Three stages of approximation are treated:

1. radiative detailed balance in the 2-1, 3-1 and 3-2 transitions,
2. radiative detailed balance in the 3-1 and 3-2 transitions, and
3. all transitions out of detailed balance.

The solution of this problem is non-trivial, and presents sufficient difficulty to have caused failure of at least one rather standard technique. The problem is thus a good archetype against which new methods, or new implementations of old methods may be tested.     

Spatio-temporal changes in totally and enzymatically hydrolyzable amino acids of superficial sediments from three contrasted areas

Spatio-temporal changes in totally and enzymatically hydrolyzable amino acids (THAA and EHHA) and EHAA/THAA ratios of superficial sediments were assessed during 1997-1999 in three areas (i.e., the Gulf of Lions, the Bay of Biscay, and Central Chile) differing in their primary productivity. In all three areas, and even off Central Chile where a strong El Niño event took place during 1997-1998, spatial changes were always much greater than temporal ones. The factors affecting the spatial distributions of amino acid concentrations differed among areas. In the Gulf of Lions, sediment granulometry was apparently the most important driving force of THAA, EHAA, and EHAA/THAA, and there was no marked difference between stations located on the open slope and those in submarine canyons. Conversely, in the Bay of Biscay, there were clear differences between the stations located off Cap-Breton, on the open slope, and those in the Cap-Ferret canyon; the latter two featuring lower EHAA and THAA but higher EHAA/THAA. This pattern is likely to result from the predominance of different sources of organic matter and especially from the importance of continental inputs to the Cap-Breton canyon. Off Central Chile, amino acid concentrations and ratios were both maximal around 100 m depth, probably reflecting the interaction between the primary productivity gradient and the presence of an oxygen minimum zone (OMZ) reducing the degradation of sedimentary organics. When comparing the average values collected in the three areas studied, THAA and EHAA were highest in Central Chile, intermediate in the Bay of Biscay and lowest in the Gulf of Lions. EHAA/THAA ratios were also highest in Central Chile but were lowest in the Bay of Biscay. Differences between the Gulf of Lions and the Bay of Biscay could have been affected by sampling design. In Central Chile, the use of labile organic carbon to total organic carbon (C-LOM/TOC) and EHAA/THAA as indices of organic matter lability led to very similar results. This was not the case in the Bay of Biscay. It is therefore argued that the use of C-LOM/TOC should be restricted to highly productive areas.     

Evidence for enhanced bioavailability of trace elements in the marine ecosystem of Deception Island, a volcano in Antarctica

This study assessed whether trace elements present at Deception Island, an active submarine volcano in the Antarctic Peninsula, show enhanced biological availability to the local marine community. Using a weak acid extraction method to dissolve organic material and leach associated but not constitutive trace elements of sediments, fifteen elements were measured from seafloor sediment, seawater particulates, and tissues of benthic (bivalves, brittlestars, sea urchins) and pelagic (demersal and pelagic fishes, krill) organisms collected in the flooded caldera. The highest element concentrations were associated with seafloor sediment, the lowest with seawater particulates and organism tissues. In the case of Ag and Se, concentrations were highest in organism tissue, indicating contamination through the food chain and biomagnification of those elements. The elements Al, Fe, Mn, Sr, Ti, and to a lesser extent Zn, were the most concentrated of the trace elements for all sample types. This indicates that the whole ecosystem of Deception Island is contaminated with trace elements from local geothermal activity, which is also reflected in the pattern of element contamination in organisms. Accordingly, element concentrations were higher in organisms collected at Deception Island compared to those from the neighboring non-active volcanic King George Island, suggesting that volcanic activity enhances bioavailability of trace elements to marine organisms. Trace element concentrations were highest in digestive tissue of organisms, suggesting that elements at Deception Island are incorporated into the marine food web mainly through a dietary route.     

A predictive model (ETLM) for As(III) adsorption and surface speciation on oxides consistent with spectroscopic data

Arsenic(III) adsorption reactions are thought to play a critical role in the mobility of arsenic in the environment. It is the nature of the As(III) surface species that must be known on a wide variety of minerals and over a range of pH, ionic strength and surface coverage in order to be able to predict adsorption behavior. EXAFS and XANES spectroscopic studies have identified bidentate, binuclear inner-sphere surface species and/or an outer-sphere species, but only a few oxides have been examined. These results need to be integrated with a predictive surface complexation model in order to ascertain the environmental conditions under which the different surface species may be important on a wide range of solids. In the present study, the surface species information from XAFS and XANES studies has been built into a recent extension of the triple-layer model (ETLM) for the formation of inner-sphere complexes of anions that takes into account the electrostatics of water dipole desorption during ligand exchange reactions. The ETLM has been applied to regress surface titration, proton coadsorption, and As(III) adsorption data over extensive ranges of pH, ionic strength, electrolyte type and surface coverage for magnetite, goethite, gibbsite, amorphous hydrous alumina, hydrous ferric oxide (HFO), ferrihydrite, and amorphous iron oxide. Two principal reactions forming inner- and outer-sphere As(III) surface species,

     

Changing hillslope and fluvial Holocene sediment dynamics in a Belgian loess catchment

Floodplain deposition is an essential part of the Holocene sediment dynamics of many catchments and a thorough dating control of these floodplain deposits is therefore essential to understand the driving forces of these sediment dynamics. In this paper we date floodplain and colluvial deposition in the Belgian Dijle catchment using accelerator mass spectrometric radiocarbon and optical stimulated luminescence dating. Relative mass accumulation curves for the Holocene were constructed for three colluvial sites and 12 alluvial sites. A database was constructed of all available radiocarbon ages of the catchment and this database was analysed using relative sediment mass accumulation rates and cumulative probability functions of ages and site‐specific sedimentation curves. Cumulative probability functions of ages were split into different depositional environments representing stable phases and phases of accelerated clastic deposition. The results indicate that there is an important variation between the different dated sites. After an initial stable early and middle Holocene phase with mainly peat growth in the floodplains, clastic sedimentation rates increased from 4000 BC on. This first phase was more pronounced and started somewhat earlier for colluvial deposits then for alluvial deposits. The main part of the Holocene deposits, both in colluvial and alluvial valleys, was deposited during the last 1 ka. The sedimentation pattern of the individual dated sites and the catchment‐wide pattern indicate that land use changes are responsible for the main variations in the Holocene sediment dynamics of this catchment, while the field data do not provide indications for a climatological influence on the sediment dynamics. Copyright © 2011 John Wiley & Sons, Ltd.     

Stochastic micromechanical model of the deterioration of asphalt mixtures subject to moisture diffusion processes

The deleterious effect of moisture in the microstructure of asphalt mixtures, usually referred to as moisture damage, has been recognized as a main cause of early deterioration of asphalt pavements. The initiation and evolution of moisture‐related deterioration is strongly influenced by the internal air void structure of asphalt mixtures. Despite its importance, the majority of works conducted on the micromechanical modeling of asphalt mixtures overlook the role of the air void structure, mainly because of its high complexity and variability. This paper explores the influence of air void variability on the performance of asphalt mixtures subjected to moisture diffusion processes. A stochastic modeling technique based on random field theory was used to generate internal distributions of physical and mechanical properties of the asphalt matrix of the mixture that depend on probable air voids distributions. The analysis was conducted by means of a coupled numerical micromechanical model of moisture damage. The results showed that the variability and distribution of air voids are decisive in determining the moisture‐dependent performance of asphalt mixtures. Furthermore, it was also shown that a stochastic characterization of the diverse air void configurations is a feasible and useful approach to better represent and understand mechanically related deterioration processes in asphalt mixtures. Copyright © 2010 John Wiley & Sons, Ltd.