Interaction study of clay-bearing amphibolite–crude oil–saline water: Molecular level implications for enhanced oil recovery during low saline water flooding

Low saline water flooding (LSWF) had proved to be an efficient method for enhanced oil recovery in clay-bearing hydrocarbon reservoirs, but the interaction mechanisms among in-situ rocks – fluids and injection fluids within the reservoir – are not yet known properly. Understanding the molecular level interaction among these components is critical for designing and field scale implementation of LSWF in clay-bearing crystalline reservoir rocks, which is very limited in the existing literature. A weathered amphibolite rock and one dead crude oil from the Bakrol field (Cambay basin, India) have been used in this study. The presence of clay minerals in the weathered amphibolite rock was observed using a polarising microscope and characterised by the X-ray diffraction (XRD) and Fourier transform infrared (FTIR) techniques. The crude oil and its fractionated SARA components have been extensively studied by spectroscopic techniques for their characterisation. The interaction study among the rock powder, hydrocarbon crude oil and saline water has been performed in the present work for gaining better insight for designing the injection fluid for LSWF. The weathered amphibolite rock powder was mixed with the dead crude oil and kept for 30 days in room temperature (T) and pressure (P) for proper interaction. The XRD, FTIR and cation exchange capacity results clearly demonstrated the incorporation of crude oil components in the interlayer surfaces of clay minerals. The oil removal efficiency, from the oil-treated rock powder of three saline water samples having NaCl concentration of 3000, 5000 and 8000 ppm, was investigated using the UV–Vis and fluorescence spectroscopies. The low saline NaCl water is capable of removing the maximum amount of polar components from the oil-treated rock powder. These molecular level insights are valuable for designing effective injection fluid for enhancing the oil recovery from the clay-rich crystalline reservoir rock.     

Clusters of Galaxies and the Cosmic Web with Square Kilometre Array

The intra-cluster and inter-galactic media that pervade the large scale structure of the Universe are known to be magnetized at sub-micro Gauss to micro Gauss levels and to contain cosmic rays. The acceleration of cosmic rays and their evolution along with that of magnetic fields in these media is still not well understood. Diffuse radio sources of synchrotron origin associated with the Intra-Cluster Medium (ICM) such as radio halos, relics and mini-halos are direct probes of the underlying mechanisms of cosmic ray acceleration. Observations with radio telescopes such as the Giant Metrewave Radio Telescope, the Very Large Array and the Westerbork Synthesis Radio Telescope have led to the discoveries of about 80 such sources and allowed detailed studies in the frequency range 0.15–1.4 GHz of a few. These studies have revealed scaling relations between the thermal and non-thermal properties of clusters and favour the role of shocks in the formation of radio relics and of turbulent re-acceleration in the formation of radio halos and mini-halos. The radio halos are known to occur in merging clusters and mini-halos are detected in about half of the cool-core clusters. Due to the limitations of current radio telescopes, low mass galaxy clusters and galaxy groups remain unexplored as they are expected to contain much weaker radio sources. Distinguishing between the primary and the secondary models of cosmic ray acceleration mechanisms requires spectral measurements over a wide range of radio frequencies and with high sensitivity. Simulations have also predicted weak diffuse radio sources associated with filaments connecting galaxy clusters. The Square Kilometre Array (SKA) is a next generation radio telescope that will operate in the frequency range of 0.05–20 GHz with unprecedented sensitivities and resolutions. The expected detection limits of SKA will reveal a few hundred to thousand new radio halos, relics and mini-halos providing the first large and comprehensive samples for their study. The wide frequency coverage along with sensitivity to extended structures will be able to constrain the cosmic ray acceleration mechanisms. The higher frequency (>5 GHz) observations will be able to use the Sunyaev–Zel’dovich effect to probe the ICM pressure in addition to tracers such as lobes of head–tail radio sources. The SKA also opens prospects to detect the ‘off-state’ or the lowest level of radio emission from the ICM predicted by the hadronic models and the turbulent re-acceleration models.     

Psychohistory revisited: fundamental issues in forecasting climate futures

Uncertainty in the trajectories of the global energy and economic systems vexes the climate science community. While it is tempting to reduce uncertainty by searching for deterministic rules governing the link between energy consumption and economic output, this article discusses some of the problems that follow from such an approach. We argue that the theoretical and empirical evidence supports the view that energy and economic systems are dynamic, and unlikely to be predictable via the application of simple rules. Encouraging more research seeking to reduce uncertainty in forecasting would likely be valuable, but any results should reflect the tentative and exploratory nature of the subject matter.     

Comparison of a simple logarithmic and equivalent neutral wind approaches for converting buoy-measured wind speed to the standard height: special emphasis to North Indian Ocean

The difference between the transferred wind speed to 10-m height based on the equivalent neutral wind approach (U _n) and the logarithmic approach (U _log) is studied using in situ observations from the Indian, Pacific, and Atlantic Oceans, with special emphasis given to the North Indian Ocean. The study included U _n ? U _log variations with pressure, relative humidity, wind speed, air temperature, and sea surface temperature (SST). U _n ? U _log variation with respect to air temperature (T _a) reveals that U _n ? U _log is out of phase with air temperature. Further analysis found that U _n ? U _log is in phase with SST (T _s) ? T _a and varies between ?1.0 and 1.0 m/s over the North Indian Ocean, while for the rest of the Oceans, it is between ?0.3 and 0.8 m/s. This higher magnitude of U _n ? U _log over the North Indian Ocean is due to the higher range of T _s ? T _a (?4 to 6 °C) in the North Indian Ocean. Associated physical processes suggested that the roughness length and friction velocity dependence on the air–sea temperature difference contributes to the U _n ? U _log difference. The study is further extended to evaluate the behavior of U _n ? U _log under cyclonic conditions (winds between 15 and 30 m/s), and it was found that the magnitude of U_n ? U _log varies 0.5–1.5 m/s under the cyclonic wind conditions. The increasing difference with the wind speed is due to the increase in the momentum transfer coefficient with wind speed, which modifies the friction velocity significantly, resulting in U _n higher than U _log. Thus, under higher wind conditions, U _n ? U _log can contribute up to half the retrieval error (5 % of the wind speed magnitude) to the satellite validation exercise.     

Biopolymer-biocement composite treatment for stabilisation of soil against both current and wave erosion

Acta Geotechnica - Increased frequency of extreme weather events has made the conservation of riverbanks and coastlines a global concern. Soil stabilisation via microbially induced calcite...     

Iodine in karst-type phosphorites from the Lahn region,Germany

The concentration of iodine in 31 Tertiary continental phosphorites from the Lahn region in Germany ranges from about 0.01% to 0.18%, the mean value of 0.044% being quite compatible with that of typical commercial-grade iodine deposits. Microscopic and X-ray diffractometric studies manifested three main mineral phases in these phosphorites viz. francolite, clay minerals (kaolinite, illite), and ferric oxides (goethite, hematite). These mineral phases were investigated for iodine distribution, mode of its fixation and possible source. Sample heating at 600°C evinced no appreciable organic matter in the sample and further showed that the iodine was non-volatile in character. Regression analysis revealed a good correlation between I and Al (Ti), practically no correlation with Fe and negative correlation with P₂O₅. It was thus deduced that the iodine content is inorganic in nature and bound principally and probably internally to Al-bearing minerals. An iodine content of about 150 ppm is believed to be associated with the apatite phase of the phosphorite.Devonian volcanic rocks are assumed to be the ultimate source of both phosphorus and iodine. Those elements were released during a Tertiary weathering period, their accumulation being controlled by chemical environment and karst topography of a Devonian reef limestone.     

The application of finite elements to heat conduction problems involving latent heat

SummaryThe Application of Finite Elements to Heat Conduction Problems Involving Latent Heat A finite element method is developed for the solution of heat conduction problems which involve latent heat. The method is superior to other wellknown approaches to these problems in that it allows a wider range of material properties and boundary conditions to be dealt with, such as are encountered in complex engineering operations like ground freezing. The method is applied to simple triangular finite elements in this paper, although it could be extended to other types of element including three-dimensional ones. Several example problems are discussed and illustrated, and comparisons are made with other approaches where these can also be used.