The thermal degradation of acrylic pressure-sensitive adhesives based on butyl acrylate and acrylic acid

The thermal degradation of acrylic pressure-sensitive adhesives at 250 °C was investigated using pyrolysis-gas chromatography. Knowledge of the types and amounts of pyrolysis products will provide important information on the thermal degradation of acrylic adhesives and the mechanisms involved. Unsaturated monomers including butyl acrylate and butyl methacrylate were formed during thermal degradation of butyl acrylate–acrylic acid copolymers. As a result of side chain reactions in the thermal destruction of the butyl acrylate–acrylic acid-based self-adhesives, a remarkable amount of butyl alcohol was produced. The unsaturated monomers formed as a result of thermal degradation could potentially be used in a new polymerization process.     

Lower bound estimation of load-carrying capacity of thin-walled structures with intermediate stiffeners

The design of thin structures must take into account the overall instability and the instability of component plates in the form of local buckling. This investigation is concerned with the interactive buckling of thin-walled structures with central intermediate stiffeners under axial compression and/or a constant bending moment. The structures are assumed to be simply supported at the ends. The lower bound estimation of load-carrying capacity on the basis of the post-buckling behaviour of thin-walled structures with imperfections is studied when the distortional deformations are taken into account. The asymptotic expansion established by Byskov and Hutchinson (AIAA J. 15 (1977) 941) is employed in the numerical calculations performed using the transition matrix method. The present paper is a continuation of previous work by the authors (Int. J. Solids Struct. 32 (1995) 1501; 33 (1996) 315; 37 (2000) 3323), where the interactive buckling of thin-walled beam-columns with central intermediate stiffeners in the first- and the second-order approximation were considered. In the solution obtained, the transformation of buckling modes with an increase in the load up to the ultimate load, the effect of cross-sectional distortions and the shear lag phenomenon are included. The results obtained are compared with data reported by other authors.     

Symbiosis between systems engineering and hydrology

The system concepts of importance to hydrological sciences are reviewed. The epochs of the development of systems sciences are discussed and their links with hydrological and water resources research are illustrated. Potentials and limitations of the system approach are discussed and the perspectives of further applications are sketched.     

Photoacoustic inspection of thermal properties of layered structure with pulse excitations

This paper presents possibilities of analysis of thermal properties of layered structures basing on the results of photoacoustic investigations in pulse excitations mode. The influence of linear distortions on results of measurements is discussed and the method of its elimination is proposed. This method uses the concept of thermal contrasts for harmonic excitations.     

Stiffness alterations of single cells induced by UV in the presence of nanoTiO2

Nanocrystalline titanium dioxide (nanoTiO2) has been reported to generate reactive oxygen species (ROS) under UV illumination. In our studies, changes in mechanical properties of human skin fibroblasts, exposed to the oxidative stress induced in the presence of nanoTiO2 and UV light, were studied using atomic force microscopy (AFM). The exposure of cells to the action of ROS was performed at low TiO2 concentration (4 microg/mL) and under illumination with low-intensity UVA (8 and 20 mW/cm2) or UVC (0.1 mW/ cm2). AFM measurements of the cell stiffness were carried out immediately after exposure of cells to the oxidative stress. The data suggest that under illumination with low-intensity UVA nanoTiO2 generates ROS, which, in turn, damage cellular and subcellular structures. This process was detected by AFM as a marked drop in the cellular stiffness of ca. 30-75%, which occurred rapidly, in the time frame of 1 min. The photo-oxidative stress inducing the decrease of cell stiffness was cancelled in the presence of a well-established antioxidant, beta-carotene. The results highlight the sensitivity of AFM to detect early changes in mechanical properties of cells exposed to oxidative stress.     

Characterizing temporal development of biofilm porosity using artificial neural networks

We used artificial neural networks (ANN) to compute parameters characterising biofilm structure from biofilm images and to interpolate a limited number of experimental data characterising the effects of nutrient concentration and flow velocity on the areal porosity of biofilms. ANN were trained using a set of experimental data characterising structural parameters of biofilms of Pseudomonas aeruginosa (ATCC #700829), Pseudomonas fluorescens (ATCC #700830) and Klebsiella pneumoniae (ATCC #700831) for various flow velocities and glucose concentrations. We used 80% of the data to train ANN and 10% of the data to validate the results, which is routinely carried out as a countermeasure against overtraining. Trained ANN were used to interpolate into the data set and evaluate the missing 10% of the data. To compare ANN accuracy in evaluating the missing data with the accuracies achieved using other interpolation algorithms, we used spline, cubic, linear and nearest-neighbour interpolation algorithms to evaluate the missing data. ANN estimates were consistently closer to the experimental data than the estimates made using the other methods.     

EXISTENCE OF A GENERALIZED SOLUTION IN THERMOELASTICITY WITH TWO RELAXATION TIMES,PART II

The existence of a generalized solution to a natural stress-temperature initial-boundary value problem of linear thermoelasticity with two relaxation times is established in a functional space of the Sobolev type.     

Thermal stability of poly(2-ethylhexyl acrylates) used as plasticizers for medical application

This article discusses thermal analysis of different molecular weight poly(2-ethylhexyl acrylates) synthesized by radical polymerization of 2-ethylhexyl acrylate. The main aim of this work was to investigate the thermal properties and degradation process of synthesized acrylic homopolymers and forming of thermal degradation products during their pyrolysis. As investigated method pyrolysis combined with gas chromatography was used. Poly(2-ethylhexyl acrylates) are used as plasticizers for pressure-sensitive adhesives applied in medical area.