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81.
G.D. Wignall R.W. Hendricks W.C. Koehler J.S. Lin M.P. Wai E.L. Thomas R.S. Stein 《Polymer》1981,22(7):886-889
A series of small angle neutron scattering measurements on blends of normal polystyrene (PSH) and labelled (deuterated) polystyrene (PSD) have been made with concentrations of PSD from 5 to 50 mol %. It is shown that the single chain form factor of the polymer in bulk can be obtained from a single concentration measurement for any concentration of labelled molecules, providing the molecular weights of the parent and labelled molecules are the same and the molecular weight distributions are narrow. 相似文献
82.
83.
Certain new sulfide-smelting processes and coal-gasification processes generate high-strength sulfur dioxide streams, for
which a new process for converting sulfur dioxide to elemental sulfur needs to be developed because no process exists that
is generally and economically applicable to the treatment of such streams. A thermodynamic and experimental investigation
to develop a new process for converting sulfur dioxide to elemental sulfur by a cyclic process involving calcium sulfide and
calcium sulfate without generating secondary pollutants was carried out. In this process, the starting raw material, calcium
sulfate, is reduced by a suitable reducing agent, such as hydrogen, to produce calcium sulfide, which is used to reduce sulfur
dioxide to elemental sulfur vapor and calcium sulfate. The latter is, in turn, reduced to regenerate calcium sulfide. In this
Part I, detailed experimental results are presented on the kinetics of the reaction between sulfur dioxide and calcium-sulfide
pellets, which produces elemental sulfur and calcium sulfate. The experiments were carried out at temperatures between 1023
and 1088 K and sulfur-dioxide partial pressures between 9 and 60 kPa by the use of a thermogravimetric analysis (TGA) technique.
The rate of this reaction was demonstrated by the conversion of 40 pct calcium-sulfide pellets obtained from the hydrogen
reduction of fresh calcium sulfate in 10 minutes at 1073 K under a sulfur-dioxide partial pressure of 43 kPa. The reactivity
decreased somewhat during the first three cycles but remained largely unchanged thereafter up to the tenth cycle. This characteristic
of the pellets is important because the solids must be reusable for repeated cycles to avoid generating secondary pollutants.
A pore-blocking model was found to fit the reaction rate. The reaction is first order with respect to sulfur-dioxide partial
pressure and has an activation energy of 101 to 134 kJ/mol (24 to 32 kcal/mol) for calcium-sulfide pellets reacted and regenerated
several different times. Sulfur dioxide-containing streams from certain sources, such as the regenerator off-gas from an integrated-gasification,
combined-cycle, desulfurization unit and new sulfide-smelting plants, contain much higher partial pressures of SO2. In these cases, the rate of the first reaction is expected to be proportionally higher than in the test conditions reported
in this article. The reduction kinetics of calcium-sulfate pellets with hydrogen gas is reported in the accompanying Part
II. 相似文献
84.
Mass transport in pulsating flow devices using either moving boundaries or oscillating imposed pressure drops are compared with each other by means of a calculation using a simple model. We conclude that there is no difference between the two configurations as long as one is interested only in the power required to move the fluid for the convective mass transport achieved. However, the boundary driven configuration is more efficient if the power is divided by the total mass transport where both the diffusive and convective parts are taken into account, the boundary driven configuration is more efficient. The amplitude of the piston stroke in the pressure driven configuration and the amplitude in the boundary driven case are assumed to be the same, and the inertia of the moving devices themselves are ignored in this calculation. 相似文献
85.
Microbiological denitrification of red beet juice 总被引:1,自引:0,他引:1
Dorota Walkowiak-Tomczak 《European Food Research and Technology》2002,215(5):401-406
The purpose of study was the determination of optimal conditions for red beet juice denitrification by Paracoccus denitrificans bacteria as well as the evaluation of the usefulness of microbiologically treated juice for the production of a natural colouring preparation for foods. Total reduction of nitrates was found during bacterial culturing at 25 and 30 °C, at an initial pH of 7.0-8.0 and juice osmotic pressure of 900-1100 mOsm/kg. Microbiological denitrification procedure affected colour, taste and aroma of the juice. However, the use of juice as food colouring and component was made feasible by acidification and partial evaporation of water together with volatile substances. 相似文献
86.
87.
88.
George Ter-Stepanian 《Bulletin of Engineering Geology and the Environment》2002,61(3):197-205
The paper discusses the postulated suspension force, by which it is possible to explain some enigmatic phenomena observed
in different types of mass movements. This force is generated in thick suspensions as a result of friction between sinking
solid particles and static water. The suspension force is related to the seepage force but they have opposite directions.
Both forces form flow networks. Having explained the suspension force, the paper describes how this influences the movement
of material, particularly in debris flows. Enigmatic features and the mechanism of debris flows and lahars are explained by
virtue of the suspension force.
Electronic Publication 相似文献
89.
We consider the problem of rescheduling trains in the case where one track of a railway section consisting of two tracks
in opposing directions is closed due to construction activities. After presenting an appropriate model for this situation
we derive a polynomial algorithm for the subproblem of finding an optimal schedule with minimal latenesss if the subsequences
of trains for both directions outside the construction site are fixed. Based on this algorithm we propose a local search procedure
for the general problem of finding good schedules and report test results for some real world instances.
Received: December 8, 1999 / Accepted: May 2, 2001 相似文献
90.
Kazdin Alan E.; Bass Debra; Siegel Todd; Thomas Christopher 《Canadian Metallurgical Quarterly》1989,57(4):522
112 children (aged 7-13 yrs) were randomly assigned to one of three treatments: problem-solving skills training (PSST), problem-solving skills training with in vivo practice (PSST-P), which included therapeutically planned activities to extend training to settings outside of treatment, or client-centered relationship therapy (RT). PSST and PSST-P children showed significantly greater reductions in antisocial behavior and overall behavior problems, and greater increases in prosocial behavior than RT children. These effects were evident on measures obtained immediately after treatment and at a 1-year follow-up, and on measures of child performance at home and at school. PSST-P children showed greater changes than PSST children on measures of functioning at school at posttreatment, but these differences were no longer evident at follow-up. Children in both PSST conditions showed significant reductions in deviant behavior and improvements in prosocial behavior from pretreatment to follow-up, whereas RT children tended to remain at their pretreatment level of functioning. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献