兴蒙造山带中段北部晚古生代两期岩浆活动及其构造意义

兴蒙造山带位于中亚造山带东段,长期以来是地质学家研究的焦点区域。内蒙古巴彦乌拉地区位于兴蒙造山带中段北部苏尼特左旗以北,广泛出露晚古生代宝力格组火山—沉积地层和酸性侵入岩体。本文对阿尔善宝拉格附近的宝力格组中性火山岩和侵入其中的花岗斑岩岩墙,及巴彦乌拉苏木南部花岗闪长岩进行了锆石LA-ICP-MS U-Pb定年,定年结果显示,宝力格组火山岩年龄为310.5±0.78 Ma,与巴彦乌拉苏木北部地区火山岩年龄(307.1±6.3Ma,308.9±1.8Ma)一致,证明本区宝力格组地层形成于晚石炭世;花岗闪长岩和花岗斑岩岩墙年龄分别为312.5±0.75 Ma和286.6±0.75 Ma,形成时代分别为晚石炭世和早二叠世;通过区域对比分析认为,兴蒙造山带北部晚古生代存在晚石炭世和早二叠世两期重要的岩浆活动,统计获得峰值年龄分别为318Ma和281Ma。岩石地球化学特征显示,本区晚石炭世宝力格组火山岩具有由低钾拉斑向钙碱性、碱性系列过渡的特征,并以钙碱性和碱性系列为主;早二叠世花岗斑岩为A型花岗岩,具有与邻区锡林浩特及巴彦乌拉—东乌珠穆沁旗带内A型花岗岩类似的地球化学特征;在花岗岩构造判别图中,花岗斑岩落入后造山区域,晚石炭世到早二叠世期间岩浆的形成环境向后造山环境逐渐演化,同时在SiO2和Na2O对K2O相关图解中,K2O含量具有增高变化的趋势,暗示构造环境有向更加稳定的板内环境演变的特征。因此,结合前人地质资料,兴蒙造山带北部晚古生代大量火山岩浆活动可能与二连—贺根山蛇绿混杂带形成有关,晚石炭世时期研究区处于后造山阶段,随着早二叠世大量A型花岗岩、碱性岩浆和双峰式火山岩的形成,该区进入造山后期更广泛的伸展环境。     

新疆西准噶尔庙尔沟岩体的地球化学及年代学研究

新疆西准噶尔庙尔沟岩体侵入于早中石炭世海相火山-沉积建造中,主体由碱长花岗岩组成,局部分布有紫苏花岗岩和碱长花岗岩脉。碱长花岗岩及岩脉高硅、富碱、贫钙,里特曼指数(δ)=2.17~2.98,A/CNK=0.96~1.03,A/NK=1.08~1.13,为准铝质-弱过铝质高钾钙碱性花岗岩,其富集LILEs(Rb、U、K、Th),相对亏损HFSEs(Nb、Ta、P、Ti)和Ba、Sr等,以及强烈Eu负异常,过渡族地幔相容元素Cr、Ni含量低,U、Th、Pb等地壳富集元素含量较高。Sr、Nd同位素组成:(87Sr/86Sr)i=0.70370~0.70541,εNd(t)=+4.10~+6.79,tDM=0.57~0.99Ga。锆石LA-ICP-MS U-Pb定年研究获得锆石U-Pb年龄为309±1.4Ma,表明岩体碱长花岗岩的形成时代为晚石炭世。紫苏花岗岩的SiO 2含量为60.88%~62.06%,Al2O3含量为15.50%~15.72%,里特曼指数(δ)=2.59~2.77,A/CNK=0.86~0.88,A/NK=1.50~1.53,为准铝质钙碱性-高钾钙碱性过渡的花岗岩,相对富集LREE(Rb、U、K、Th),而亏损HREE(Nb、Ta、P、Ti)和Sr,以及较显著的Eu负异常,过渡族地幔相容元素Cr、Ni含量低,U、Th、Pb等地壳富集元素含量较高。Sr、Nd同位素组成:(87Sr/86Sr)i=0.70382~0.70388,εNd(t)=+6.67~+6.98,tDM=0.59~0.62Ga。锆石LA-ICP-MS U-Pb定年研究获得锆石U-Pb年龄为302.1±2.1Ma,表明岩体紫苏花岗岩的形成时代为晚石炭世。综合庙尔沟岩体的地质特征、地球化学特征、年代学和区域地质背景,认为庙尔沟岩体碱长花岗岩及岩脉为A2型花岗岩,紫苏花岗岩具有A型花岗岩的地球化学性质,且它们是可能来自同一个岩浆源区,属于西准噶尔后碰撞阶段的岩浆活动产物。     

内蒙古达来庙地区晚石炭世花岗岩成因及其对兴蒙造山带北部构造体制转变的指示

达来庙岩体出露于内蒙古苏左旗北部中蒙边境一带,是二连-东乌旗晚古生代岛弧岩浆岩带的重要组成部分,对其开展研究可有效丰富对兴蒙造山带北缘构造演化的认识.野外观察、锆石U-Pb年代学、岩石地球化学及同位素地球化学研究结果表明,岩体由中部的中细粒黑云二长花岗岩和边部的中粒黑云二长花岗岩组成,岩石侵位年龄为301.2±2.1 Ma（MSWD=1.2,2σ）.岩体总体上具有富硅、贫铁、弱过铝质的特征,但中细粒花岗岩相对富钠,中粒花岗岩钾含量则明显升高.两类花岗岩均富Rb、Th、U、Pb,亏损Ba、Sr、P以及Nb、Ta等高场强元素,不过中粒花岗岩重稀土更加富集,Eu负异常也更显著.岩体具有亏损的Sr-Nd-Hf同位素组成,（87Sr/86Sr）_i=0.703 6~0.707 5,ε_Nd（t）=0.08~2.77,ε_Hf（t）=4.70~11.50.岩石学及地球化学分析显示,达来庙岩体为幔源物质底侵形成的新生地壳部分熔融的产物,岩石成因类型为I型,但具有向A型花岗岩过渡的特征,岩体产出于造山晚期挤压隆升向陆内拉张的过渡阶段,其侵位指示了晚石炭世兴蒙造山带北缘构造应力场从挤压向拉张转变的具体时限.      

内蒙古东乌珠穆沁旗查干敖包花岗岩体时代、成因及地质意义

内蒙古东乌珠穆沁旗北部的查干敖包岩体可分解为灰黄色细粒花岗岩单元和灰黄色中细粒似斑状含二云母花岗岩单元。前者锆石U-Pb加权平均年龄为(306.4±2)Ma,为晚石炭世岩浆活动产物,后者锆石U-Pb加权平均年龄为(278.3±2)Ma,为早二叠世岩浆活动产物。两期花岗岩具有相似的地球化学特征,主量元素均具有富Si,贫Ti、Mg、Ca,且有较高的碱/铝(NK/A)比值等特征;均表现出明显的负Eu异常;微量元素富集Rb、Th、U、K,弱富集P、Zr及Hf,强烈亏损Ba、Sr及Ti。通过分析讨论,认为晚石炭世晚期细粒花岗岩单元和早二叠世中细粒似斑状花岗岩单元的成因类型均为I-S过渡型钙碱性花岗岩。岩石化学、岩体产状、分布特点和源岩特征都表明,查干敖包岩体晚石炭世晚期和早二叠世花岗岩构造背景环境一致,均为晚古生代中亚造山大地构造背景下碰撞后转换期构造—岩浆事件产物。     

大兴安岭中南段甘珠尔庙地区晚中生代两期花岗岩的时代、成因、物源及其构造背景

大兴安岭晚中生代岩浆活动在东北亚晚中生代构造岩浆演化研究中具有重要意义。本文首次报道了大兴安岭中南段甘珠尔庙地区5个晚中生代花岗岩体的锆石U-Pb年龄和地球化学研究结果。这些岩体形成于晚侏罗世(154Ma)和早白垩世(139~125Ma),显示高硅富碱特征,属高钾钙碱性系列,为高分异钙碱性I-A过渡型花岗岩,其中,早白垩世花岗岩分异程度高于晚侏罗世花岗岩。锆石Hf同位素特征显示,这些花岗岩源区以年轻物质为主,其中,晚侏罗世花岗岩εHf(t)值(+9.9~+15.9)高于该区底侵的新生下地壳,源区可能有更年轻的新底侵物质参与。早白垩世花岗岩εHf(t)值略低(+3.4~+13.9),其物源主要为底侵的新生下地壳和古生代俯冲增生杂岩混源,可能还混有少量更年轻的新底侵物质。结合区域资料分析,甘珠尔庙地区晚中生代花岗岩形成于后造山伸展背景,这种背景可能与蒙古-鄂霍茨克洋闭合碰撞后伸展有关。     

北山辉铜山泥盆纪钾长花岗岩锆石U-Pb年龄、 成因及构造意义

LA-ICP-MS锆石U-Pb定年结果表明,北山柳园地区辉铜山钾长花岗岩的形成年龄为397±3Ma (MSWD=1.1).地球化学特征显示为高钾钙碱性的高分异Ⅰ型花岗岩到A型花岗岩过渡的特征.其全岩εNd(t)值为-1.3～ +1.2,Nd模式年龄(tDM)为960 ～ 1530Ma;锆石εHf(t)值为-1.0～ +5.8,两阶段Hf模式年龄(tDM2)为1024～1455Ma.地质背景、地球化学和同位素综合分析显示,辉铜山岩体为造山后伸展拉张背景下,幔源岩浆底侵导致上覆年轻地壳(可能为洋壳、岛弧建造或增生楔物质)部分熔融形成的钙碱性花岗闪长质岩浆经进一步演化及结晶分异形成.北山南带地区早-中泥盆世花岗岩显示出高分异钙碱性Ⅰ型花岗岩、I-A型花岗岩和A型花岗岩的组合特征.因此,在397Ma左右,北山地区古生代岩浆已经从Ⅰ型或S型转化为I-A型特征,构造环境转化为后造山或同造山晚期的伸展环境.     

小兴安岭西北部晚石炭世造山后达音河岩体的 特征及其地质意义

小兴安岭西北部达音河岩体主要由碱长花岗岩、正长花岗岩组成。碱长花岗岩的锆石LA-ICP-MS U-Pb定年结果为304.4±1.3 Ma,时代属于晚石炭世,而不是过去认为的晚侏罗世。该岩体化学组成以高硅、钾、钠,低钙为特征,富集Rb、La、Th等大离子亲石元素,亏损Ba、Sr、Eu等大离子亲石元素和Nb、Ta、Zr高场强元素,反映斜长石作为源区残留相对岩浆地球化学特征的控制。该岩体同区域上十二站、新开岭、龙镇、扎兰屯等岩体构成晚石炭世造山后伸展背景下形成的I型和A型花岗岩带,反映了兴安、松嫩块体在晚石炭世结束块体碰撞造山,转入造山后伸展环境。     

内蒙古京格斯台晚石炭世碱性花岗岩年代学及地球化学特征——岩石成因及对构造演化的约束

京格斯台碱性花岗岩出露于内蒙古东乌旗西北部的中蒙边境一带,是准噶尔-南蒙古-内蒙古碱性花岗岩带的一部分,为一套含钠铁闪石碱性花岗岩类。锆石LA-MC-ICPMS U-Pb测年获得了301.3±1.5Ma(n=21,MSWD=1.3)的年龄,表明侵位时代为晚石炭世。全岩地球化学分析显示样品具有高SiO2(75.16%~76.96%)、高碱(K2O=4.61%~5.04%,Na2O=3.98%~4.24%)、贫CaO(0.08%~0.25%)、MgO(0.07%~0.1%),低FeOt(1.05%~2.05%),高的FeOt/MgO比值(12.85~29.66),属于弱过铝质系列;富集Rb、Th、U、K等大离子亲石元素及Zr、Hf等高场强元素,弱亏损Nb、Ta,强烈亏损Ba、Sr、P、Ti等;稀土元素总量较低[ΣREE范围为(70.19~193.93)×10~(-6),平均值为126.82×10~(-6)],轻稀土略富集,具有明显的Eu负异常(δEu=0.03~0.07),呈类似"海鸥"型稀土配分模式。岩石学及地球化学特征表明京格斯台碱性花岗岩属于碱质A型花岗岩。锆石原位Hf同位素和全岩Nd同位素分析显示其具有亏损的Hf-Nd同位素组成εHf(t)和εNd(t)均为正值,Hf地壳存留模式年龄范围为385~1605Ma,并且多数集中于600~900Ma,二阶段Nd模式年龄范围为582~650Ma,这表明源岩为幔源新生地壳物质,代表了新元古代一次地壳增生。综合岩石学、岩石地球化学和同位素地球化学数据,我们认为京格斯台碱性花岗岩是由新生地壳,在晚石炭世贺根山洋闭合后的后造山伸展阶段,在上涌软流圈的加热及减压作用下部分熔融形成的,形成于后造山构造环境。     

新疆西准噶尔北部布尔津县木斯塔巴岩体年代学、地球化学特征及地质意义

准噶尔是新疆北部古生代造山带的重要组成部分,以广泛发育晚古生代花岗岩为特征,是中亚造山带总显生宙陆壳生长作用非常显著的地区之一。根据最新获得的LA-ICP-MSU-Pb锆石年龄,木斯塔巴岩体锆石年龄为(303±2.0) Ma(晚石炭世),岩石地球化学分析,岩石具高硅(66.04%~70.4%),高碱(2.26~2.87),高铝(13.25%~15.46%),高钾(3.4%~4.58%),低镁,A/CNK=1.06~1.22,低固结(6.34~12.87),高分异(78.35~84.5),富轻稀土(LREE/HREE=3.57~12.97)和大离子亲石元素K,Rb,Ba,Sr,亏损高场强元素Nb,Ta,Ti,P,为过铝质高钾钙碱性系列花岗岩,具碰撞花岗岩特征,属额尔齐斯构造带的重要组成部分,其形成与板块俯冲作用关系密切。本区石炭纪花岗岩的数据与北准噶尔地区对比,显示晚石炭世额尔齐斯构造带闭合,进入后碰撞阶段。     

东准噶尔北缘早石炭世构造体制转变:来自碱性花岗岩年代学和地球化学制约

新疆东准噶尔北缘位于西伯利亚板块和哈萨克斯坦-准噶尔板块的结合部位,是中亚造山带的重要组成部分,也是新疆北部最重要的成矿带之一。老山口碱性花岗岩和乔夏哈拉碱性花岗岩即位于该区域,LA-ICP-MS锆石U-Pb年龄显示其结晶年龄分别为330.5±3.5 Ma和331.1±3.1 Ma。结合区域内存在的多处近同时期的碱性花岗岩(布尔根碱性花岗岩、哈腊苏碱性花岗斑岩、乌图布拉克碱性花岗岩),指示东准噶尔北缘存在一期重要的早石炭世碱性花岗岩岩浆活动,并大致可分为东、中、西三段。这些早石炭世碱性花岗岩具有高硅(SiO_2=67.14%~83.02%)、富碱(Na_2O+K_2O=5.37%~10.73%)、低钛(TiO_2=0.04%~0.23%)、贫钙(CaO=0.04%~1.19%)的特征,与典型A型花岗岩特征相类似,成因类型上属A1型花岗岩,个别具有A2-A1型花岗岩过渡性质。微量元素组成具有富集大离子亲石元素K、Rb及高场强元素Nb、Zr、Hf、Th,亏损Ba、Sr、P、Eu、Ti的特征。轻稀土元素明显富集(LREE/HREE=3.42~8.11),具强烈的负Eu异常(δEu=0.03~0.74),稀土元素配分模式呈右倾海鸥型。岩石具有较高的ε_(Hf)(t)(7.6~12.4)和ε_(Nd)(t)值(5.4~6.9)。上述特征表明,这些碱性岩的母岩浆具有复杂的成因,推测为幔源岩浆底侵到下地壳,促使下地壳先存的富Nb玄武岩部分熔融,并发生岩浆混合,经过一定程度的分离结晶形成。综合本文数据及地质事实,我们认为东准噶尔北缘在358 Ma部分地区开始进入板内后造山伸展环境,即板内早期环境,但早石炭世(360~327 Ma)整体处于由后碰撞向板内后造山环境转化的过渡阶段。东准噶尔北缘东、中、西段进入板内环境的时间不尽相同,可能与其多俯冲岛弧系统拼贴增生时代的不均一性有关。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.