滇西北兰坪地区金顶超大型铅锌矿床架崖山-北厂矿段岩石地层特征

详细描述了滇西北兰坪金顶矿区架崖山-北厂主矿段露采剖面的岩石地层学特征。架崖山-北厂矿段出露正常沉积岩和非正常沉积岩两大岩石系列,分别由灰白色白云质灰岩、黑色泥晶灰岩、青灰色泥灰岩、杂色泥质粉砂岩、砖红色粉砂岩、红色膏溶角砾岩和浅灰色钙质砂岩、灰褐色灰岩角砾岩、杂色垮塌角砾岩组成。空间上以非正常沉积岩系列灰褐色灰岩角砾岩和浅灰色钙质砂岩为中心,正常沉积岩系列灰白色白云质灰岩、黑色泥晶灰岩、杂色泥质粉砂岩、青灰色泥灰岩和红色膏溶角砾岩分布于其周围。灰褐色灰岩角砾岩和浅灰色钙质砂岩构成了金顶矿区的2种主要矿石类型,二者空间上密切共生,近直立的灰岩角砾岩分布于近水平的钙质砂岩层的下部,构成似“蘑菇”状的几何形态。架崖山-北厂矿段岩石地层学的特征揭示了兰坪金顶铅锌矿泥底辟机制的成因特点,为矿区勘查和外围寻找金顶式矿床提供了新恩路。     

金顶超大型铅锌矿床角砾岩及含角砾砂岩分类、特征及成因

兰坪盆地金顶超大型铅锌矿床广泛发育特征特殊的角砾岩和含角砾砂岩,前人对其成因有不同的认识。本文在矿区岩相构造填图的基础上,根据岩石角砾、杂基、胶结物成分和结构特点,划分出以下8类岩石:(1)层状含灰岩角砾砂岩,(2)方解石胶结灰岩砾角砾岩,(3)石膏/硬石膏胶结灰岩砾角砾岩,(4)铁泥质胶结灰岩砾角砾岩,(5)混杂状砂质胶结灰岩砾角砾岩(或称含灰岩角砾砂岩),(6)膏砂泥胶结复成分砾角砾岩,(7)砂质胶结复成分砾角砾岩,(8)含矿石砾角砾岩。其中,含矿石角砾岩形成于矿后,而其它角砾岩形成于矿前且可能近同期形成。角砾岩均处于下部"原地"和上部"外来"地层系统之间。研究认为含矿石砾角砾岩为矿后垮塌成因,其它角砾岩为(含砂)膏盐底辟成因,或含砂膏盐底辟破碎围岩、携带角砾流动的产物。目前角砾岩砂质杂基间的方解石胶结物和灰岩角砾间的方解石胶结物,可能为后期含有机质流体与先存的、作为胶结物的膏盐反应形成。这一过程同时产生H2S,对后期成矿具有重要意义。角砾岩的矿化与膏盐底辟体有关,具"单中心"分带、"多中心"叠加的特点。矿化主要为闪锌矿、方铅矿、黄铁矿等热液矿物交代角砾岩间或砂质杂基间的方解石胶结物,角砾本身弱/无矿化。比较而言,层状含灰岩角砾砂岩为含矿最普遍,次为方解石胶结灰岩砾角砾岩、铁泥质胶结灰岩砾角砾岩、含矿石砾角砾岩,混杂状砂质胶结灰岩砾角砾岩局部含矿。     

兰坪砂岩氧化铅锌矿工艺矿物学研究

兰坪砂岩氧化铅锌矿工艺矿物学研究孟凡梅（昆明冶金研究院，昆明６５００３１）关键词铅锌矿石工艺矿物学兰坪铅锌矿兰坪铅锌矿是我国储量最大的铅锌矿。本次研究直接配合选矿工艺，研究矿区内北厂、架崖山两矿段的砂岩混合矿。１矿石特征矿石化学成分见表１。回收金属品...     

云南金顶超大型铅锌矿区的构造格架与控矿构造问题讨论

金顶铅锌矿床是一个以沉积岩(灰岩与砂岩)为寄主岩石的超大型铅锌矿床。本文在对矿区构造和矿床基本特点研究的基础上,重点阐述了两种不同类型矿体(砂岩型和灰岩型)的构造类型、矿石显微构造及矿石组构的特点。本文研究表明,极其发育的断裂构造系统是兰坪盆地地质构造发育的基本特点,在盆地边缘、盆地内部普遍发育了具有薄皮式逆冲断层和推覆构造组合特点的成矿前断裂,它们造成矿区内大规模地层倒转与堆叠现象;盆地中发育了由构造角砾岩与透镜体带构成、宽度达近3km的NE-NNE向成矿期中轴断裂,它控制着矿体或矿床的发育与分布;近SN方向的成矿后地堑构造对于矿床具有破坏作用,并使之剥露于地表。金顶铅锌矿床主要有两种重要的矿床类型,即板状或层状砂岩型矿床和角砾状灰岩型矿床,它们分别位于白垩系钙质长石石英砂岩与三叠系沥青质灰岩构成的两个逆冲席体内。以凤凰山矿区为典型,金顶铅锌矿床具有3层结构:上部的三叠系白云质灰岩岩盖,中部的砂岩型矿体和下部的灰岩型矿体,三者之间被两条作为圈闭存在的重要逆冲断层带间隔。砂岩型矿体与灰岩型矿体之间由几个角砾岩筒连接,作为成矿时期的矿液运移通道存在。破裂与微破裂构造、块状构造、对生脉状构造及假晶构造等是最常见的显微构造型式,它们的存在揭示出破裂与碎裂、充填和交代作用过程在铅锌矿化过程中均起着重要的作用。金顶铅锌矿床的形成与就位,直接受构造作用控制。成矿前的逆冲推覆作用为高压成矿流体的形成以及成矿圈闭的发育创造了条件,成矿期中轴断裂的活动性促使成矿流体向上运移,而灰岩与砂岩的物理性质(包括孔隙度/渗透率以及力学属性)则制约了两种不同类型矿体的出现。致密的灰岩渗透率较低,含矿流体加热了灰岩并使之软化,同时高流体压力使得围岩易碎,形成由早期到晚期的细角砾岩、粗角砾岩和破裂,成矿物质同时沉淀结晶,胶结围岩角砾形成角砾型灰岩矿体。高压流体通过流体通道进入低孔隙度的砂岩后,便迅速弥散于其中,沿着颗粒边界或裂隙充填,并交代岩石中的钾长石碎屑及方解石胶结物,形成块状的砂岩型矿体。     

兰坪金顶超大型铅锌矿床含矿岩石沉积特征

云南兰坪金顶超大型铅锌矿含矿岩石的成因一直存在正常沉积和非正常沉积两种对立的观点。为了查明其成因,从矿区开采露头和岩芯观察描述出发,以矿区填图为基础,通过对含矿岩石的岩石学特征、粒度和沉积构造等相标志分析,确定了金顶超大型铅锌矿含矿岩石属于湖底扇深水重力流沉积,并识别出非沟道体系的液化流和沟道体系的砂质碎屑流、浊流等类型,进一步划分出内扇、中扇和外扇三个亚相。该湖底扇平面展布为自矿区东部至西部粒度明显由粗变细,岩性由厚层—块状灰岩岩块构成的角砾岩相逐渐过渡到交错层理发育的中细粒砂岩相,其中砂质碎屑流沉积体具有良好的储集层物性特征,亦是重要的含矿岩石,具有广阔的勘探前景。     

西藏林周县乌鲁龙上石炭统“冰筏”沉积岩的地质地球化学特点

上石炭统“冰筏”沉积岩地质剖面位于拉萨北70km的林周县乌鲁龙—马驹拉。剖面底部为黑色含砾粉砂质泥岩和黑色粉砂质泥岩,厚200m。中部为黑色粉砂质泥岩,厚200m。上部为深灰色泥灰岩,厚50m。上石炭统与上覆二叠系浅灰色灰岩呈整合接触。“冰筏”沉积岩具有如下地质地球化学特点: 1.岩石组合“冰筏”沉积岩主要由黑色粉砂质泥岩、含砾砂岩、砂砾岩等组成。砾石粒径一般为1—2cm,最大可达10—20cm。砾石成分比较复杂,有花岗岩、     

论云南兰坪金顶超大型铅锌矿床的成因

在前人大量工作和资料积累的基础上,从成矿构造地质背景、容矿系统、容矿岩石的归属与成因、成矿时代和成矿物质来源方面论述了云南兰坪金顶超大型铅锌矿的成因,指出金顶超大型铅锌矿床是新生代陆陆碰撞造山背景下,在晚始新世至渐新世（大约33Ma）区域挤压推覆转变为区域拉张伸展构造环境转换时期,幔源岩浆和热流驱动盆山转换前被封闭在裂谷或前陆盆地深部富含油气、膏盐和金属的流体,沿着造山带两组伸展构造交汇部位上升,在构造圈闭环境下,通过角砾岩侵位—流砂底辟—流体排泄—金属淀积的产物。     

新疆伽师砂岩型铜矿地质特征及找矿标志

新疆伽师砂岩型铜矿区位于塔里木盆地西北缘柯坪古生代前陆盆地西南，北部以哈拉峻-阿合奇断裂为界，与南天山晚古生代陆缘盆地相邻，是塔里木北缘的一个陆内海盆。砂岩铜矿赋存于一套主要由褐红色-红色砂岩、粉砂岩、砂质泥岩及泥岩组成的红色砂岩建造中，其中夹有浅灰色砂岩层，铜矿化即发育于浅灰色砂岩中。含矿层长3km，厚4-6m，共发现有3条矿体。其中Ⅰ号矿体长650m，厚2．21～5．13m，平均厚度3．93m，Ⅱ号矿体长190m，厚2-4m；Ⅲ号矿体长100m，平均厚度3．37m。通过对矿区的地层、构造，铜矿体的规模、形态、产状的分析认为，古近系的浅灰色钙质砂岩为找矿的最有利层位；孔雀石化的含岩屑钙质细砂岩转石是找矿的直接标志；膏岩建造一般位于含矿层的底部，石膏层为明显的找矿标志。     

新疆伽师砂岩型铜矿地质特征及找矿标志

新疆伽师砂岩型铜矿区位于塔里木盆地西北缘柯坪古生代前陆盆地西南,北部以哈拉峻—阿合奇断裂为界,与南天山晚古生代陆缘盆地相邻,是塔里木北缘的一个陆内海盆。砂岩铜矿赋存于一套主要由褐红色—红色砂岩、粉砂岩、砂质泥岩及泥岩组成的红色砂岩建造中,其中夹有浅灰色砂岩层,铜矿化即发育于浅灰色砂岩中。含矿层长3km,厚4~6m,共发现有3条矿体。其中Ⅰ号矿体长650m,厚2.21~5.13m,平均厚度3.93m,Ⅱ号矿体长190m,厚2~4m;Ⅲ号矿体长100m,平均厚度3.37m。通过对矿区的地层、构造,铜矿体的规模、形态、产状的分析认为,古近系的浅灰色钙质砂岩为找矿的最有利层位;孔雀石化的含岩屑钙质细砂岩转石是找矿的直接标志;膏岩建造一般位于含矿层的底部,石膏层为明显的找矿标志。     

西藏北部班戈地层分区下白垩统郎山组、康曲组和余穷组地层层序研究

在西藏自治区北部区域地质调查过程中 ,在班戈地层分区的下白垩统郎山组之上发现一套厚约 180 0 m的滨海—浅海相碳酸盐岩、陆源细碎屑岩岩石组合 ,该套组合不属于郎山组定义之内 ,且出露良好、层序稳定、标志清楚、厚度巨大、化石丰富 ,并具有很强的可填图性。因此 ,我们将整合于郎山组之上 ,岩性以杂色微—薄层状钙质泥岩、钙质 (粉 )砂岩与泥质生物灰岩的韵律产出为特征 ,产圆笠虫、腹足类、双壳类等化石的地层命名为康曲组 ;将整合于康曲组之上 ,下部以灰—深灰色中薄层状泥质生物灰岩、圆笠虫泥晶灰岩、钙质泥岩等韵律出现为特征 ,上部以灰色中—厚层状含硅质结核圆笠虫泥晶灰岩、圆笠虫泥晶灰岩夹灰绿色薄层状钙质砂岩为特征 ,富含圆笠虫、腕足类、腹足类、双壳类及海胆等化石的地层定名为余穷组。时代均置于早白垩世晚期     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

山西五台山区滹沱群变质玄武岩岩石学、地球化学特征及其成因意义

在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明：玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

深港西部通道填海区地下水铜、钒、铊、镉、钨迁移的实验研究

填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。     

Pressure Increases, the Formation of Chromite Seams, and the Development of the Ultramafic Series in the Stillwater Complex, Montana

This paper explores the hypothesis that chromite seams in theStillwater Complex formed in response to periodic increasesin total pressure in the chamber. Total pressure increased becauseof the positive V of nucleation of CO₂ bubbles in the melt andtheir subsequent rise through the magma chamber, during whichthe bubbles increased in volume by a factor of 4–6. Byanalogy with the pressure changes in the summit chambers ofKilauea and Krafla volcanoes, the maximum variation was 0•2–0•25kbar, or 5–10% of the total pressure in the Stillwaterchamber. An evaluation of the likelihood of fountaining andmixing of a new, primitive liquid that entered the chamber withthe somewhat more evolved liquid already in the chamber is basedupon calculations using observed and inferred velocities andflow rates of basaltic magmas moving through volcanic fissures.The calculations indicate that hot, dense magma would have oozed,rather than fountained into the chamber, and early mixing ofthe new and residual magmas that could have resulted in chromitecrystallizing alone did not take place. Mixing was an important process in the Stillwater magma chamber,however. After the new magma in the chamber underwent {smalltilde}5% fractional crystallization, its composition, temperature,and density approached those of the overlying liquid in thechamber and the liquids then mixed. If this process occurredmany times over the course of the development of the Ultramaficseries, a thick column of magma with orthopyroxene on its liquiduswould have been the result. Thus, the sequence of multiple injections,fractionation, and mixing with previously fractionated magmacould have been the mechanism that produced the thick bronzitecumulate layer (the Bronzitite zone) above the cyclic units.     

Composition,formation conditions,and genesis of the Talatui gold deposit,the Eastern Transbaikal Region,Russia

The mineral composition of the Talatui gold deposit has been studied with modern methods. Previously unknown minerals (ilmenite, siegenite, glaucodot, wittichenite, matildite, hessite, pilsenite, zircon, tremolite, cummingtonite, hercynite, and goethite) have been identified in the ore. A high Re content has been detected in molybdenite. The spatiotemporal separation of Au and Ag is caused by different mineral species of these elements and their diachronous precipitation during the ore-forming process. Gold crystallized along with early mineral assemblages, beginning from virtually pure gold (the fineness is 996). Silver precipitated largely at the end of the process as hessite (Ag₂Te) and matildite (AgBiS₂). The temperature of ore deposition varied from 610 to 145°C, the pressure was 3370–110 bar, and the salt concentration ranged from 56.3 to 0.4 wt % NaCl equiv. The heterogeneous state (boiling) of fluid at the early stages has been documented. The chemical and isotopic compositions of the fluid testify to its magmatic nature and the participation of meteoric water at late stages in the ore-forming process. Thermodynamic modeling reproduces the main specific features of ore formation, including separation of Au and Ag. A physicochemical model of the gold mineralization in the Darasun ore district has been proposed. On the basis of several attributes, the Talatui deposit has been referred to the prophyry gold-copper economic type.