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1.
史文全  代文军 《甘肃地质》2008,17(1):13-16,22
四顶黑山岩体主要由超镁铁质岩和镁铁质岩组成。超镁铁质岩由橄榄岩、角闪橄榄岩、辉橄岩、辉石岩等组成;镁铁质岩由辉长岩、角闪辉长岩、橄榄辉长岩等组成。本次对辉长岩进行了全岩Sm-Nd同位素分析,得到的等时线年龄为327±9.0Ma,初始εNd(t)=+3.97,表明镁铁质—超镁铁质岩中辉长岩形成于早石炭世末。属于富集地幔向亏损地幔过渡类型。这一年龄的确定,为探讨北山—天山结合部晚古生代镁铁质—超镁铁质岩的成因机制和该区的区域地质演化提供了有效的年代学依据。  相似文献   

2.
对新疆西准噶尔达尔布特蛇绿岩套柳树沟镁铁质杂岩中橄榄辉长岩、蛇纹石化橄榄辉长岩、辉长岩和蚀变辉长岩地球化学分析表明:辉长岩和蚀变辉长岩具有钙碱性和拉斑玄武岩的双重特征,橄榄辉长岩和蛇纹石化橄榄辉长岩属镁铁质堆积岩,为蛇绿岩组成单元;稀土总量较高,具微弱正Eu异常,稀土元素配分模式为略左倾平坦型,与SSZ型镁铁质堆晶岩稀土配分模式相同;微量元素蛛网图上,富集大离子亲石元素Cs、K、Th、U,相对亏损高场强元素Nb、Ta,可能代表俯冲板片的流体交代上覆地幔楔使地幔岩石发生部分熔融。地球化学构造环境判别柳树沟镁铁质岩石岩浆源区为亏损型地幔向富集型地幔过渡的适度富集型地幔,其形成的最佳模型是在成熟岛弧基础上裂谷化形成的一个不成熟的类似边缘海性质弧后盆地,不具成熟大洋或盆地那样的洋壳-上地幔结构,在盆地扩张初期岩浆具岛弧特征,随着盆地被进一步打开,镁铁质岩石具N-MORB特征。对辉长岩采用SHRIMP锆石U-Pb同位素年龄测试,获得特柳树沟镁铁质岩石的结晶时间为314.9±1.7 Ma。  相似文献   

3.
浪木日镁铁质-超镁铁质岩体位于东昆仑造山带东段,临近昆中断裂,主要由橄榄岩、橄榄辉石岩、辉石岩和辉长岩组成,且局部发育星点状和浸染状硫化物矿化。辉石岩和橄榄辉石岩获得的锆石U-Pb年龄分别为(421.2±1.2)Ma和(421.10±0.96)Ma,表明岩体侵位于晚志留世。岩石地球化学特征显,浪木日镁铁质-超镁铁质岩具有较高的Mg#(Mg#>80),富集LILE(Rb、Th、U等),亏损HFSE(Nb、Ta、Ti等),轻、重稀土元素分馏程度较强((La/Yb)N=6.28~50.91,(La/Sm)N=1.45~4.15,(Gd/Yb)N=1.43~9.71),具有弱的负Eu异常(δEu=0.226~0.824)。锆石Lu-Hf(εHf(t)=-2.9~-10)和全岩Sr-Nd(εNd(t)=-10.3~-8.9)同位素特征显示,其岩浆源区主要来自富集地幔,与俯冲洋壳脱水交代上覆地幔楔活动有关。综合研究表明,浪木日镁铁质-超镁铁...  相似文献   

4.
刘懿馨  沙鑫  马蓁  王金荣 《岩石学报》2018,34(2):383-397
北祁连西段双龙一带出露的镁铁质-超镁铁质岩主要由蛇纹石化二辉橄榄岩、辉长岩、辉绿岩及玄武岩组成,这些岩石单元与构造卷入的前寒武纪变质岩系和深海沉积的硅质岩一起构成蛇绿混杂岩带。辉长岩LA-ICP-MS锆石U-Pb年龄为464±2 Ma(MSWD=1.3)。Zr/TiO_2-Nb/Y图解显示辉绿岩为拉斑玄武岩系列,玄武岩为碱性系列,两者均具有低的MgO和相容元素Cr、Ni含量,指示在岩浆作用过程中发生过橄榄石、辉石的分离结晶作用。球粒陨石标准化稀土元素配分模式图显示,辉绿岩呈平坦型,(La/Yb)_N=1.35~1.45,无Eu异常(δEu=1.0~1.1),以及Lu/Yb(~0.15)、Zr/Y(~2.5)、Y/Tb(~39)比值等均类似于N-MORB;但它们又相对富集Ba、Sr,亏损Nb、Ta、Pb,以及Nb/U(~21)、Zr/Nb(~16)、Th/Ta(~5.7)比值则显示了岛弧玄武岩或弧后盆地玄武岩的特征,推测辉绿岩应源于受俯冲流体交代的尖晶石二辉橄榄岩部分熔融的产物。玄武岩地球化学特征明显不同于辉绿岩,表现为相对富集LREE,~8.48,轻微负Eu异常(δEu=0.91),以及Zr/Y(~8)、Y/Tb(~30)、Ta/Yb(~0.6)、Th/Yb(~2.5)比值等类似于OIB,指示玄武岩应源于富集地幔部分熔融的产物,但岩石又表现出富集Rb、Ba、Th、U、Pb、Sr、Zr、Hf,亏损Nb、Ta、Ti、P,以及Th/Ta(~4.8)、Zr/Nb(~14)、Nb/Yb(~10)、Nb/U(~11)比值又具有岛弧或弧后盆地玄武岩的亲缘性,显示了玄武岩应源于地幔深部流体交代的石榴石二辉橄榄岩或尖晶石+石榴石二辉橄榄岩部分熔融的产物,表明早古生代北祁连古大洋在俯冲闭合过程中具有洋岛或海底高原的增生作用。结合区域地质背景,利用全球大数据建立的构造判别图解综合研究认为,北祁连西段熬油沟-玉石沟-双龙-小龙孔-卡瓦-东沟等镁铁质-超镁铁质岩共同构成一条重要的SSZ型蛇绿岩带,为北祁连古大洋向南俯冲形成的弧后盆地的残留体。  相似文献   

5.
代文军 《甘肃地质》2010,19(2):8-17
四顶黑山镁铁、超镁铁质岩分布于黄山东—镜儿泉铜镍硫化物矿床北偏东约100km处,位于甘、新交界处。主要由橄榄岩、角闪橄榄岩、辉橄岩、辉石岩、辉长岩、角闪辉长岩、橄榄辉长岩等组成。研究认为该区镁铁、超镁铁质岩是同一岩浆源在不同阶段分异的产物。超镁铁质岩属玄武质科马提岩,镁铁质岩为拉斑玄武岩;镁铁质岩的TiO2含量1.2%,Nb含量2.0×10-6,Nb/Lapm=0.25~0.50,Th/Lapm=0.25~0.46,Ti/Ti*=0.37~0.88。镁铁质岩的εNd(t)值普遍大于+3,说明其起源于软流圈地幔,为富集地幔向亏损地幔过渡类型。在原始地幔标准化曲线上镁铁质岩、超镁铁质岩均相对富集大离子亲石元素Rb、Ba、K、U,且出现Nb、Ti的负异常。表明华力西中期哈萨克斯坦板块出现俯冲—增生的岛弧体制,在该体制下岩浆沿断裂多期次脱离地幔而上侵,为古亚洲洋闭合之前俯冲增生的产物,并非形成于碰撞后伸展环境。  相似文献   

6.
安江地区镁铁质-超镁铁质岩包括呈岩流、岩筒状的喷出岩和呈岩床、岩脉、岩墙状的侵入岩共10个岩体。岩体喷出及侵入的最新地层为新元古代高涧群砖墙湾组,西北侧古丈盘草处见被早震旦世长安组砂岩沉积覆盖。全岩钐-钕等时线同位素年龄值,喷出岩(868±30)Ma,侵入岩(855±6)  相似文献   

7.
为探讨内蒙古中部地区镁铁质-超镁铁质岩形成时代及地球化学特征,完善区域成岩成矿年代学格架,本文对克布、黄花滩和小南山岩体进行了锆石U-Pb年代学及全岩地球化学分析。LA-ICP-MS锆石U-Pb测年获得克布和黄花滩镁铁质-超镁铁质岩结晶年龄分别为258±2 Ma(MSWD=2.3)和262±1 Ma(MSWD=0.51),属于中-晚二叠世,小南山辉长岩应形成于中-晚二叠世(~273 Ma)。全岩地球化学分析表明,三个岩体样品m/f值介于0.96~3.54之间,主要为镁铁质-超镁铁质岩,其稀土和微量元素曲线基本表现为轻稀土元素(LREE)和大离子亲石元素(LILE)相对富集,高场强元素(HFSE)相对亏损的相似性特征,但也有明显的区别,显示各岩体岩浆演化或分异程度可能不尽相同。综合区域研究资料表明,内蒙古中部地区晚古生代镁铁质-超镁铁质岩浆活动可能至少始于早二叠世(294Ma),持续至中-晚二叠世(273~258Ma),且二叠纪时期中亚造山带南缘较大范围内均发育较为活跃的幔源岩浆活动。克布、黄花滩和小南山岩体应形成于后碰撞伸展环境,其岩浆源区可能混染了俯冲流体交代改造的地幔楔物质,使3个岩体的岩石样品均显示具有富含大离子亲石元素和轻稀土元素,贫高场强元素等部分岛弧岩浆特征的信号。  相似文献   

8.
内蒙古乌拉特中旗地处华北陆块北缘西段,大地构造分区属于狼山-白云鄂博陆缘裂谷。区域上,镁铁质-超镁铁质岩呈东西向带状分布,断续出露长约300km,宽约30km。该镁铁质-超镁铁质岩带内铜镍矿床(点)较为发育,克布为该带内一个中-小型铜镍硫化物矿床。克布镁铁质-超镁铁岩体出露面积约45km2,主要由辉长岩相和橄榄岩相组成,辉长岩相为岩体的主要岩相,橄榄岩相为主要的赋矿岩石,两个相带相伴产出,呈渐变过渡关系。本文采用LA-ICP-MS锆石U-Pb法测年,获得克布斜长方辉橄榄岩年龄为258.1±1.8Ma(MSWD=2.3),属于晚二叠世。岩石主、微量及稀土元素分析结果表明,岩石样品属铁质镁铁质-超镁铁质岩,具有拉斑玄武岩系列演化趋势,并相对富集大离子亲石元素(Rb、Sr、Ba),亏损高场强元素(Nb、Ta、Zr、Hf、Ti),以及具有轻稀土富集[(La/Yb)N=2.47~11.29]的右倾型稀土配分模式。以橄榄石-熔体平衡原理估算克布镁铁质-超镁铁质岩体母岩浆的MgO含量为10.1%,FeO为12.1%,应为高镁的拉斑玄武质岩浆。综合分析认为,克布镁铁质-超镁铁质岩体应形成于后碰撞伸展阶段,岩浆源区由被消减板片交代的地幔楔物质和软流圈物质组成。橄榄石和辉石等富镁铁矿物的分离结晶和富硅地壳物质的混染可能对硫化物熔离富集成矿起到了关键性作用。  相似文献   

9.
镁铁-超镁铁质层状杂岩体被认为是岩石圈伸展的重要标志之一,携带有丰富的地幔信息,是研究地幔物质组成、深部地质作用的绝佳对象。西南天山乌什县北巴勒的尔喀克沟地区新发现的镁铁-超镁铁质岩体具有层状杂岩特征,获得辉长岩锆石U-Pb年龄为224±4 Ma,属于晚三叠世。岩石地球化学分析显示富水、富碱、轻稀土富集、重稀土亏损以及明显富集Th、U、Nb、Ta、La、Ce不相容元素等特征,指示其源自于含水的富集型地幔源区,是石榴石二辉橄榄岩较低程度部分熔融的产物。其原生岩浆可能为富铁、钛的高镁玄武质岩浆,岩石系列主要受分离结晶作用控制,同化混染作用影响小。该期岩浆活动于南天山洋盆闭合、板块的碰撞造山活动之后的陆内造山阶段,代表了板块拉伸背景下幔源岩浆演化的产物,指示西南天山地区在三叠纪末可能存在一期岩石圈伸展事件。   相似文献   

10.
在东天山四顶黑山地区元古代深变质地层中发现层状镁铁质-超镁铁质岩体,研究了它的产状、岩石类型、结构构造、矿物组成、稀土微量元素地球化学、年代学等特征及其发现的地质意义。层状镁铁质-超镁铁质岩为后侵位的镁铁质杂岩体和花岗岩所穿切与破坏,其正堆晶结构发育,并可划分出两个结晶与演化旋回。四顶黑山层状钱铁质-超镁铁质岩的稀土微量元素含量和配分结构与该地区镁铁质杂岩、及图拉尔根镁铁质-超镁铁质岩体明显不同,具低∑REE、正δEu 异常、高 Sr 低Rh、高 Nb/U 值、及 Nb、Zr 和 Hf 亏损等地球化学特征,该特征与裂谷成因的攀枝花层状辉长岩和曹家村层状岩体非常相似,这意味着四顶黑山层状镁铁质-超镁铁质岩可能也形成于裂谷构造环境。选择层状镁铁质-超镁铁质岩体下部韵律层顶部辉石角闪石岩、镁铁质杂岩体闪长岩和角闪花岗岩中的角闪石开展~(39)Ar/~(40)Ar 定年,结果显示3种岩体分别形成于545±5Ma、263.8±2.6Ma 和200.8±0.91Ma。四顶黑山545Ma 裂谷成因层状镁铁质-超镁铁质岩体的发育,意味着早寒武世是天山地区镁铁质-超镁铁质岩型 Cu-Ni 矿的成矿期之一,天山地区在元古宙变质岩为基底的古大陆在早寒武世出现了雏形裂谷构造,545Ma可能是古天山洋形成的初始期。  相似文献   

11.
Police, politics, and the right to the city   总被引:1,自引:0,他引:1  
Mustafa Dikeç 《GeoJournal》2002,58(2-3):91-98
Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ18O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.  相似文献   

14.
Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N2 in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.  相似文献   

15.
马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。  相似文献   

16.
The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.  相似文献   

17.
18.
在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明:玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。  相似文献   

19.
The mineral composition of the Talatui gold deposit has been studied with modern methods. Previously unknown minerals (ilmenite, siegenite, glaucodot, wittichenite, matildite, hessite, pilsenite, zircon, tremolite, cummingtonite, hercynite, and goethite) have been identified in the ore. A high Re content has been detected in molybdenite. The spatiotemporal separation of Au and Ag is caused by different mineral species of these elements and their diachronous precipitation during the ore-forming process. Gold crystallized along with early mineral assemblages, beginning from virtually pure gold (the fineness is 996). Silver precipitated largely at the end of the process as hessite (Ag2Te) and matildite (AgBiS2). The temperature of ore deposition varied from 610 to 145°C, the pressure was 3370–110 bar, and the salt concentration ranged from 56.3 to 0.4 wt % NaCl equiv. The heterogeneous state (boiling) of fluid at the early stages has been documented. The chemical and isotopic compositions of the fluid testify to its magmatic nature and the participation of meteoric water at late stages in the ore-forming process. Thermodynamic modeling reproduces the main specific features of ore formation, including separation of Au and Ag. A physicochemical model of the gold mineralization in the Darasun ore district has been proposed. On the basis of several attributes, the Talatui deposit has been referred to the prophyry gold-copper economic type.  相似文献   

20.
岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...  相似文献   

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