Chemistry of Aerosols over Chukchi Sea and Bering Sea

The contents of elements in aerosols sampled during the First Chinese Arctic Research Expedition (CHINARE-1) show great differences from one element to another. Na, K,Ca, Mg, A1, F, and Cl are the major components in the aerosols, whose contents are larger than 30 ng/m^3. The chemical elements whose contents vary between 0.1 - 30 ng/m^3 are Br,Sr, Cr, Ni, and Zn. The chemical elements whose contents are close to or slightly higher than 0.1 ng/m^3 are Rb, Ba, Zr, Th, and Pb. The contents of As, Sb, W, Mo, Au, La, Ce, Nd,Sin, Eu, Tb, Yb, Lu, Sc, Co, Hf, Ta, and Cd are less than 0.1 ng/m^3. The mass concentration data for the same element, as observed during CHINARE-1, are almost accordant, but much lower than what is observed in the China‘ s seas or the coasts of China. The enrichment factor and electron microscopic analyses and lead isotope tracing were used to distinguish their sources.Four groups of sources can be classified as follows: anthropogenic: As, Sb, W, F, Mo, Au,Cu, Pb, Cd, V; crustal: La, Ce, Nd, Sm, Eu, Tb, Yb, Lu, Fe, Sc, Cr, Co, Ba, Zr, Hf,Ta, Cs, Mn, Th, U; oceanic:Na, K, Ca, and Mg; and mixing: Rb, Sr, Ca, and Mg.     

中国近海平均海面变化研究

本文在分析了中国沿海各长期验潮站年平均海面具有同升同降特点的基础上,应用方差分析方法求得年平均海面变化周期为5年、11年和19年.采用11年比较法,精选13个基本验潮站,和选择接近11年平均海面差值中数的时间段,求得中国近海近期(30余年)年平均海面上升速度为1.6±0.3mm/年.该结果与国内外大多数学者研究结果相一致,但方法简单易行.     

基于IceBridge数据的南极别林斯高晋海的海冰厚度研究

海冰变化与全球气候、 生态系统和人类活动密切相关， 海冰厚度是海冰变化研究的重要参数之一。全面立体高精度观测海冰厚度的最有效手段是航空遥感， 而冰桥计划（IceBridge）是当前南北极最大的航空遥感工程。基于2009 - 2014年冰桥计划的激光雷达高程数据和数字测图系统相机光学影像对南极别林斯高晋海的海冰厚度进行研究， 并结合降雪量等气象数据探讨该区域海冰厚度变化的原因。研究发现该海域的海冰厚度在2009 - 2014年间整体呈微弱增长趋势（0.07 m·a^-1）， 但是在95%置信水平下不具有显著性。2009 - 2011年呈现先增加后减少的大幅度变化， 其中2010年达到极大值2.42 m， 之后开始缓慢增加。海冰厚度的年际变化与降雪和近地表温度等气象要素相关， 二者相比较而言降雪为主要影响因素。     

2012年夏季挪威海和格陵兰海水文特征分析

利用2012年夏季在北欧海(挪威海和格陵兰海)的水文考察数据,对调查区域内海洋水团性质和分布进行了分析,并对北欧海冷却对流的发展加深过程进行了研究。在上层,从东侧暖而咸的大西洋水跨越锋区至西侧低温低盐的格陵兰海盆上层水体,温度和盐度的变化分别可以达到8℃和0.4 psu。中层与深层水体的性质则相对均匀和稳定,3个海盆内从浅至深依次分布着北极中层水、海盆深层水、北极深层水以及海盆底层水。格陵兰海盆中深层水体在3 500 m深度上位温约为-0.97℃,相比较1970s观测到的-1.30℃,升温幅度超过了0.3℃,表明海盆深层存储的热量显著增加。在只考虑局地表面冷却的简化条件下,当前格陵兰海内部通过冷却对流混合至季节性跃层下界需要向大气释放0.9×109~1.2×109J的热量,这一过程至少需要2个月的时间而不利于对流向深层的发展。大量的热量被存储于北欧海深海盆中使得北欧海已经成为北半球高纬海域的热量存储器,对当前北极气候变化的影响有待深入研究。     

Biomarkers in upper Holocene Eastern North Sea and Wadden Sea sediments

Total extracts of sediment cores from five different stations in the North Sea and Wadden Sea were analysed for their biomarker composition. Only sediments of the Skagerrak contained significant amounts of marine biomarkers (mainly alkenones), other sites contained predominantly terrestrial biomarkers. Bioturbation in the Skagerrak is, however, far too high to determine sea surface temperature (SST) changes within short time intervals. These results indicate that biomarkers contained in these sediments are not useful to reconstruct climate fluctuations during the upper Holocene. High amounts of α-, β- and ω-hydroxy fatty acids as well as small amounts of α, β-dihydroxy fatty acids were released from the insoluble organic material of the sediments from the Wadden Sea station, indicating a significant input of the eelgrass Zostera marina. This was confirmed by microscopic observations. This is the first time the α,β-dihydroxy fatty acids have been found in a sediment core and they have proven to be potential biomarkers for these seagrass species.     

Mean Sea Level studies in the Aegean Sea

A study of Mean Sea Level (MSL) determination in the Aegean Sea is carried out. First, MSL values have been computed at a number of tide gauge stations. Then, Sea Surface Heights (SSHs) have been determined based on GEOSAT altimeter data of Geodetic Mission (GM). The computed SSHs were fitted to the tide gauge MSL values using a 4-parameters model. The best fitting agreement reached the level of 5cm, when GPM98A geopotential model was used as a reference surface.     

冰对海洋结构的临界力

将海冰作为浮在海水上的半无限大的平板,将海水的浮力作为弹性地基,把海冰与桩柱的作用力看作为集中力,海冰的破坏看作为集中力作用下的平板失稳问题,给出了冰排在集中力作用下的压曲微分方程,数值计算结果给出了海冰在桩柱作用下的临界载荷的表达式,为海洋结构的设计提供了依据.     

Atmospheric circulation and storm events in the Black Sea and Caspian Sea

Extreme sea storms are dangerous and a potential source of damage. In this study, we examine storm events in the Black Sea and Caspian Sea, the atmosphere circulation patterns associated with the sea storm events, and their changes in the present (1961–2000) and future (2046–2065) climates. A calendar of storms for the present climate is derived from results of wave model SWAN (Simulating WAves Nearshore) experiments. On the basis of this calendar, a catalog of atmospheric sea level pressure (SLP) fields was prepared from the NCEP/NCAR reanalysis dataset for 1961–2000. The SLP fields were subjected to a pattern recognition algorithm which employed empirical orthogonal decomposition followed by cluster analysis. The NCEP/NCAR reanalysis data is used to evaluate the occurring circulation types (CTs) within the ECHAM5-MPI/OM Atmosphere and Ocean Global Circulation Model (AOGCM) for the period 1961–2000. Our analysis shows that the ECHAM5-MPI/OM model is capable of reproducing circulation patterns for the storm events. The occurrence of present and future ECHAM5-MPI/OM CTs is investigated. It is shown that storm CTs are expected to occur noticeably less frequently in the middle of the 21^st century.     

Modern diversity of the macroalgae of the Sea of Azov,the Black Sea,and the Caspian Sea

Currently, the species list of the macroalgae (excluding Charales) inhabiting the southern seas of Russia includes 388 species, specifically, 362 species in the Black Sea, 46 species in the Sea of Azov, and 70 species in the Caspian Sea. The species list has been increased by approximately 30% (96 species, most of them are registered in the Black Sea), compared to the data obtained 30 years ago. The green and red macroalgae of warm-water Mediterranean and tropical origin (Ceramium, Polysiphonia, Laurencia, Ulva, and Chaetomorpha) and brown algae (Sargassum and Cytoseira) were the key invaders. Nowadays the maximal species diversity is found on the Crimean coast and the Turkish coast of the Black Sea; and the species list of the Turkish coast differs significantly from all the other studied sites of the Black Sea. The number of the algae of the warm-water complex increased the most in 1990s–2000s in the Black Sea; species of boreal-tropical and subtropical origin dominate. However, such a tendency was not observed in the Sea of Azov and in the Caspian Sea, but expansion of the habitats of the brackish green algae has been registered.     

南海后扩张期大陆边缘闭合过程及成因机制

南海是西太平洋海域最大的边缘海,然而南海扩张终结后动力学过程研究仍较为薄弱.通过构造变革界面识别、褶皱冲断带沉积记录等方面的系统研究,揭示南海南部和东部陆缘在南海后扩张期的演化历程.研究表明南海南部和东部边缘经历了多个微板块从俯冲到碰撞的演变历程,形成了陆-陆碰撞、弧-陆碰撞、洋-弧俯冲等多个特征迥异的板块边界.南海南部陆缘属于古南海俯冲拖曳构造区,婆罗洲西北沙捞越-曾母地块率先碰撞,随后经历了婆罗洲东北沙巴-南沙地块碰撞、西南巴拉望-卡加延岛弧碰撞.南部多个微板块碰撞导致古南海呈剪刀式从西向东逐渐关闭和消亡,总体形成了以微地块碰撞、深海槽发育和造山带前缘巨厚沉积充填为特色的碰撞陆缘.东部陆缘属于菲律宾海俯冲-碰撞构造区,南海东部洋壳自中新世开始向菲律宾海板块俯冲,弧-陆碰撞仅局限于东部陆缘南北两端.澳洲-印度板块、菲律宾海板块与欧亚板块相互作用控制了南海边缘海闭合过程,南海正在进行的关闭过程主要集中在东缘和南缘,东缘呈现了以南海洋壳消亡为特征的闭合过程,而南缘则呈现以微陆块碰撞为特征的古南海闭合过程.显然,南部后扩张期陆缘演变可为边缘海闭合过程研究提供极佳的范例,同时对我国海洋权益保护和南海大陆边缘动力学研究具有重要意义.      

Uronic and other organic acids in Baltic Sea and Black Sea sediments

Organic acids were released from marine sediments by acid hydrolysis. Ion-exchange chromatography and GC-MS were used to separate and identify the acids. The major compounds detected were galacturonic, glucuronic, mannuronic, 4-O-methylglucuronic, cellobiouronic, guluronic, glyceric, glycolic, lactic and erythronic acids. Numerous biouronic (sugar-uronic acid compounds) and aldonic acids were also found. The low abundance of uronic acids characteristic of terrigenous plants and the similarity of the biouronic composition to that of marine algae indicate a marine algal source for the acids in the sediment. Results from the Black Sea are compared with those from the Baltic Sea and several diagenetic transformations are discussed.     

Organic Geochemistry of Black Sea cores

Six Black Sea bottom sediments samples were analyzed for their organic content (chloroform extract and humic compounds) by elemental analysis, liquid and gas chromatography, various chemical methods and especially infra-red spectroscopy. Four of these samples came from an euxinic facies (“unit 2”) and two from a normally oxygenated facies below (“unit 3”).Even though important differences exist between the two sets of samples, the origin of the organic matter was found to be the same for both facies; this origin is mixed, with the marine contribution slightly predominant over the terrestrial one.Consequently, the compositional differences originate in the different environmental conditions in the sedimentary basin. More precisely, the euxinic facies appears to “preserve” the organic matter, on both quantitative and qualitative grounds. This effect is due more to the anoxic and toxic nature of the environment than to the reducing conditions.The sulfur incorporation in relatively small molecules does not proceed by a rapid biochemical pathway, but by slow and abiotic reactions.     

Scaling the Baltic Sea environment

The Baltic Sea environment has since the early 1970s passed through several phases of spatial objectification in which the ostensibly well-defined semi-enclosed sea has been framed and reframed as a geographical object for intergovernmental environmental politics. Based on a historical analysis of this development, this article suggests that environmental politics critically depend on the delineation of relatively bounded spaces that identify and situate particular environmental concerns as spatial objects for politics. These spaces are not simply determined by ‘nature’ or some environmental-scientific logic, but should rather be seen as temporal outcomes of scale framing processes, processes that are accentuated by contemporary conceptions of the environment (or nature) in terms of multi-scalar ecosystems. This has implications for how an environmental concern is perceived and politically addressed.     

海冰反照率参数化方案的研究回顾

在全球变暖的背景下,北极海冰在发生快速变化,海冰覆盖范围明显减小,厚度显著变薄,积雪/海冰—反照率正反馈机制在此背景下变得愈发重要。气候系统和单一海冰模式采用了从简单到复杂的海冰反照率参数化方案。首先对模式中的海冰反照率参数化进行了回顾,并结合对现有卫星反照率产品问题的分析,概述了前人对参数化的评估研究工作。在此基础上进一步讨论了气候模式中海冰反照率参数化方案存在的问题,一方面目前的反照率参数化对海冰融池和冰间水道等物理过程的考虑还不够完善,另一方面反照率参数化方案的发展受到观测数据可用性的制约。最后对参数化的发展方向进行了初步探讨。     

南海海泥中甲烷水合物生成特性的实验研究

在定容条件下,实验研究了甲烷水合物在含水量不同的多孔海泥中的生成特性。所使用的海泥平均孔径为12178 nm,总孔容为4997×10-2 ml/g,比表面积为16412 m2/g。所用海泥样品含水量为40%,实验的温度范围为27415~28115 K,初始生成压力范围为102~144 MPa。实验结果表明,甲烷水合物在海泥中的生成速率以及气体消耗量随着初始压力的增加而增大,随着温度的降低而增大。海泥的复杂孔隙结构能够促进水合物的成核,但会降低水的最终转化率,其作用随着温度的升高与压力的降低而增大。     

Miocene-pleistocene volcanism of deep-water basins of the Sea of Japan and Sea of Okhotsk

This paper reports the results of petrographic and geochemical studies of the Miocene-Pleistocene volcanic rocks that accompanied the formation of the deep-water basins of the Sea of Japan and Sea of Okhotsk. The geochemical types of these rocks, their geodynamic settings, and their derivation from different magmatic sources were determined. The marginal-sea basaltoids of the Sea of Japan are derivatives of fluid-enriched mantle (EMI), while the volcanics of the Kurile basin were generated from mantle enriched in continental crust (EMII). In spite of the different conditions of their genesis, they share some common geochemical features, in particular, their calc-alkaline signatures. These traces of the influence of sialic crust on magma generation confirm the development of the basins of both these seas on continental basement.     

Tertiary Sea Level Changes and Sequence Stratigraphic Framework in East China Sea Shelf Basin

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