南海北部MD12-3432站MIS 11期以来底栖有孔虫反映的古环境变化

南海具有典型边缘海特征,其北部陆坡由于具有高沉积速率的地层剖面,可以用于研究亚轨道尺度气候变化。本研究以南海北部陆坡下部MD12 3432柱状样(19°16.88′N,116°14.52′E,水深2 125 m)为主要研究材料,分析其粗组分百分含量、底栖有孔虫丰度和特定环境指示属种的百分含量与丰度,并结合相关研究结果,运用多指标综合分析,重建了南海北部陆坡MIS 11期(距今约40万年)以来的表层初级生产力和底层水溶解氧含量的演化情况。与之前研究不同,本研究发现MIS11期以来南海北部的古生产力在温暖的间冰期高、在寒冷的冰期低,且主要受控于东亚夏季风影响下低纬地区降水强度的变化。在MIS 7期和MIS 9期可能有较高溶解氧含量的底层水进入南海北部,导致在高生产力的暖期中,喜氧的低生产力指示种Cibicidoides wuellerstorfi丰度增加。     

南海南部120ka以来元素地球化学记录的东亚夏季风变迁

利用XRF岩芯元素扫描仪对南海南部MD05-2896孔岩芯样品进行1 cm间隔的元素测试。该孔底部年龄约为120ka。研究表明,南海南部间冰期夏季风活动增强,上升流发育;夏季风和降雨带来的陆源有机物输入增加,提高了表层的生产力;冰期夏季风减弱,陆源有机物输入减少,表层生产力降低。海洋表层生产力在MIS3早期(60~40 ka)较高,指示该时有特强的夏季风,上升流作用增强。Ba/Ti值表明东亚夏季风的强弱变化,并与北半球夏季日射量基本呈线性关系,体现了东亚夏季风演化的天文驱动机制。     

南海的氧同位素3期

以南海北、西、南部3个沉积速率相对较高而且连续的沉积柱状样MD2904,MD2901和MD2897为基础,通过粒度、碳酸盐、有机地球化学和元素分析,并综合前人研究成果,对南海MIS3期进行探讨。结果显示,南海MIS3是末次冰期中的弱暖期,海水表层古温度比相邻的MIS2和MIS4期略高,但是明显比MIS1和MIS5期低。MIS3的最大特点就在于其气候的不稳定性,发生了多次气候快速变化事件。在格陵兰冰芯中记录的千年尺度快速气候变化事件（D/O事件和Heinrich事件）基本上在南海北、西、南部都有响应,具有与全球同步的特征。南海MIS3古生产力都显示出较高的特点,这与东亚季风有着密切的关系,北部主要受冬季风影响,西部和南部主要受夏季风影响。南海南部MIS3表现出比MIS5更高的古生产力和更强的夏季风强度,这一特点有待更进一步深入研究。     

MIS2期南海北部粘土矿物记录的东亚夏季风快速变化

运用伊利石结晶度线性剥离法,定量计算了华南、台湾和吕宋这 3 个主要物源区对南海北部陆坡MD12-3432和MD12-3434两个岩芯(分别为50. 80 m和8. 33 m)MIS 2期粘土相对贡献量的时间序列变化.结果显示,台湾对两个岩芯的贡献最大(36%~62%),吕宋的贡献次之(28%~50%),二者之和一般大于90%,而来自华南的贡献最小(3%~17%).台湾和吕宋的贡献量呈现显著反向的千年时间尺度快速波动,二者贡献量随东亚夏季风增强或减弱而显著变化,因此,吕宋/台湾贡献量比值可以用于指示东亚夏季风的快速演化.吕宋/台湾粘土贡献量比值在B?lling-Aller?d和Dansgaard-Oeschger 2事件期间的增加,反映了同时期东亚夏季风的快速增强;而在Heinrich 1和Heinrich 2事件期间的减小,则指示了东亚夏季风的减弱.吕宋/台湾贡献量比值对东亚夏季风快速变化的指示,在一定程度上要明显优于蒙脱石/(伊利石+绿泥石)比值.南海北部MIS 2期粘土矿物对东亚夏季风快速变化的响应具有明显的空间差异性,受洋流搬运扰动和物源控制作用影响,陆坡相对浅水区粘土矿物记录的东亚夏季风快速变化信息相对有限,而深水稳定的沉积环境则更有利于保存东亚夏季风快速变化信息.     

白令海北部陆坡100ka来的古海洋学记录及海冰的扩张历史

白令海北部陆坡B2-9柱状样中生源组分的研究显示, 自MIS5.3期以来表层生产力指标的粗组分和蛋白石含量呈阶梯状增加, 反映表层生产力阶段式的增长.全新世表层生产力达到最高, 并且MIS3.2~2期高, 比MIS5.3~3.3期最低.高有机碳含量对应于高C/N比值, 显示有机碳混合来源, 不能作为表层生产力的指标.MIS5.1, 3.3~3.2期和全新世高的有机碳含量和C/N比值反映间冰期陆源有机物质输入量的增加.MIS5.3期至中全新世, 不断增加的陆源砂级和粉砂级颗粒组分说明随着气候的逐渐变冷, 陆架海冰在不断扩张.伐冰碎屑和碳屑颗粒冰期、间冰段和末次冰消期升高, 而间冰期降低, 反映冰期白令海陆架海冰扩张和间冰期海冰消融的过程.冰期海冰扩张与北美大陆气候的相互关联, 揭示了晚第四纪冰期旋回中白令海海冰扩张及其对全球气候变化的响应.      

南海北部一百万年以来的表层古生产力变化：来自ODP1144站的蛋白石记录

通过南海北部ODP 1144站蛋白石含量测定及其堆积速率的计算,并结合氧同位素记录等相关资料,获得南海北部1050ka以来高分辨率的表层古生产力变化与冰期旋回和东亚季风的关系。约900ka以来,蛋白石含量及其堆积速率较900ka以前明显增加,反映了“中更新世革命”事件之后,全球气候变冷,并导致表层生产力的提高。由于第四纪冰期旋回中的冬、夏季风的加强,加上1144站特殊的地理位置,使该站在冰期时表层生产力增加,间冰期时表层生产力降低。浮游有孔虫氧同位素记录与蛋白石含量及其堆积速率的时间序列频谱分析结果显示,三者均出现了相对应的偏心率周期、斜率周期和岁差周期,说明该站表层生产力的变化主要受地球轨道周期的驱动。     

越南岸外晚第四纪上升流与东亚夏季风变迁

通过对南海西部越南岸外１７９５４—３柱状样中浮游和底栖有孔虫的定量分析,结合碳酸钙、有机碳和稳定同位素数据,获得南海西部上升流区近２０万年来的古海洋学记录,进而讨论了晚第四纪东亚夏季风的变迁。结果表明,在间冰期,尤其是末次间冰期,越南岸外出现表层海水古温度低、温跃层浅、生产力高,同时底层海水富营养的现象,说明上升流的存在,且该上升流有从氧同位素５期(ＭＩＳ５期)向１期逐渐减弱的趋势。结合南海现代海流及生产力分布的研究,推断该上升流由东亚夏季风驱动,其强弱的变化说明,东亚夏季风在近２０万年来有间冰期增强、冰期减弱,且从ＭＩＳ５期向ＭＩＳ１期递减的特征。     

南黄海北部晚更新世以来常量元素记录的化学风化作用

以南黄海北部高沉积速率柱状样DLC70-3孔作为研究对象,对沉积物的黏土矿物和常量元素地球化学组成进行了综合分析。结果显示,DLC70-3孔沉积物中黏土矿物组合以伊利石为主,其次为蒙皂石,绿泥石和高岭石含量较低;绝大部分样品中伊利石与蒙皂石含量的比值<6,表明沉积物主要来源于黄河物质的输送。研究认为DLC70-3孔沉积物的化学风化指标CIA值受到海平面变化和源区气候变化共同控制,其中源区的气候变化为主要控制因素,而海平面变化造成的机械沉积分异作用主要影响27.80~38.00 m（MIS 4）层位沉积物的CIA值。CIA值显示在MIS 5和MIS 3期大陆化学风化作用较强,与内陆黄土高原地区夏季风和化学风化指标的变化趋势一致,尤其是在MIS 3早期（40~60 ka）记录的化学风化作用非常强,反映了黄河流域地区出现强夏季风降雨过程。     

南海西部54万年以来元素地球化学记录及其反映的古环境演变

通过对南海西部上升流区MD05-2899孔开展高分辨率碳酸盐地层学和XRF岩芯扫描元素地球化学分析,重建了晚第四纪54万来以来东亚夏季风的演化历史,探讨海平面升降对南海西部陆源碎屑供应量的影响。研究选用了ln(Ba/Al)作为该海区古生产力的指标,ln(Br/Al)作为有机物的指标,ln(Ti/Al)作为陆源碎屑供应量的指标。研究结果显示,东亚夏季风在过去54万年以来强度不断增强,具有明显的冰期—间冰期旋回特征,在间冰期强盛和冰期减弱,是控制该海区有机物含量变化的主要因素。东亚夏季风不断强盛可能直接导致了南海周边陆地降雨增强,河流径流量加大,使得南海西部上升流区域的陆源碎屑供应量在间冰期明显高于冰期。研究发现,当相对海平面低于-60 m的时候,大面积暴露的巽他陆架可能向南海西部深水区输入大量陆源碎屑物质,造成研究站位的陆源碎屑供应量在冰盛期出现高值。因此,晚第四纪的东亚夏季风演化和海平面升降共同控制了南海西部上升流区陆源碎屑物质供应量的变化。     

末次冰期以来南海北部下陆坡区沉积有机质地球化学特征及其意义

选取南海北部下陆坡-深海平原过渡带典型沉积柱状样,通过对其沉积有机质的整体有机地球化学特征进行表征,探讨了南海下陆坡-深海平原区沉积有机质在冰期/间冰期旋回中的赋存状态、来源变化以及与古气候环境之间的相应关系。结果表明,总有机碳（TOC）、总氮（TN）和有机质稳定碳同位素（δ13Corg）与冰期/间冰期旋回有明显的对应关系,冰期时对应高值,间冰期时对应低值;而有机质稳定氮同位素（δ15N）表现为全新世时其值偏低,末次冰消期其值偏高,与气候旋回没有相关性; C/N值和δ13Corg值都表明南海北部下陆坡沉积有机质来源是陆相和海相的混源,且在末次冰期/间冰期尺度上主要以海相来源为主。     

Late Quaternary Upwelling Intensity and East Asian Monsoon Forcing in the South China Sea

Foraminifera from two cores off eastern Vietnam and the northwestern Philippines, where modern summer and winter monsoon-driven upwelling occurs in the South China Sea, respectively, were analyzed to evaluate the changes in paleoproductivity and upper water structure over the last 220,000 yr. We observed enhanced organic carbon flux and a shoaled thermocline when upwelling intensified off eastern Vietnam during interglacial ages and off the northwestern Philippines during glacial ages. This indicates that the East Asian summer monsoon increased while the winter monsoon decreased during interglacial ages. Particularly, the upwelling reached a maximum off eastern Vietnam during late marine isotopic stage (MIS) 5 and off the northwestern Philippines during MIS 2, implying that the summer monsoon decreased gradually since MIS 5 while the winter monsoon displayed an opposite trend. The variations in upwelling proxies exhibit a distinct cyclicity with frequencies near 41,000 yr and 23,000 yr off eastern Vietnam, in contrast to a strong frequency peak near 100,000 yr off the northwestern Philippines. We suggest that the East Asian summer monsoon has been forced by changes in solar insolation associated with precession and obliquity, while ice-volume forcing is probably a primary factor in determining the strength and timing of the East Asian winter monsoon but with less important insolation forcing.     

Late Quaternary glacial–interglacial variations in sediment supply in the southern Drake Passage

Geochemical characteristics of marine sediment from the southern Drake Passage were analyzed to reconstruct variations in sediment provenance and transport paths during the late Quaternary. The 5.95 m gravity core used in this study records paleoenvironmental changes during the last approximately 600 ka. Down-core variations in trace element, rare earth element, and Nd and Sr isotopic compositions reveal that sediment provenance varied according to glacial cycles. During glacial periods, detrital sediments in the southern Drake Passage were mostly derived from the nearby South Shetland Islands and shelf sediments. In contrast, interglacial sediments are composed of mixed sediments, derived from both West Antarctica and East Antarctica. The East Antarctic provenance of the interglacial sediments was inferred to be the Weddell Sea region. Sediment input from the Weddell Sea was reduced during glacial periods by extensive ice sheets and weakened current from the Weddell Sea. Sediment supply from the Weddell Sea increased during interglacial periods, especially those with higher warmth such as MIS 5, 9, and 11. This suggests that the influence of deep water from the Weddell Sea increases during interglacial periods and decreases during glacial periods, with the degree of influence increasing as interglacial intensity increases.     

Late Quaternary climatic control on erosion and weathering in the eastern Tibetan Plateau and the Mekong Basin

High-resolution siliciclastic grain size and bulk mineralogy combined with clay mineralogy, rubidium, strontium, and neodymium isotopes of Core MD01-2393 collected off the Mekong River estuary in the southwestern South China Sea reveals a monsoon-controlled chemical weathering and physical erosion history during the last 190,000 yr in the eastern Tibetan Plateau and the Mekong Basin. The ranges of isotopic composition are limited throughout sedimentary records: ⁸⁷Sr/⁸⁶Sr = 0.7206–0.7240 and ε_Nd(0) = −11.1 to −12.1. These values match well to those of Mekong River sediments and they are considered to reflect this source region. Smectites/(illite + chlorite) and smectites/kaolinite ratios are used as indices of chemical weathering rates, whereas the bulk kaolinite/quartz ratio is used as an index of physical erosion rates in the eastern Tibetan Plateau and the Mekong Basin. Furthermore, the 2.5–6.5 μm/15–55 μm siliciclastic grain size population ratio represents the intensity of sediment discharge of the Mekong River and, in turn, the East Asian summer monsoon intensity. Strengthened chemical weathering corresponds to increased sediment discharge and weakened physical erosion during interglacial periods. In contrast, weakened chemical weathering associated with reduced sediment discharge and intensified physical erosion during glacial periods. Such strong glacial–interglacial correlations between chemical weathering/erosion and sediment discharge imply the monsoon-controlled weathering and erosion.     

南海沉积物中的黏土矿物:指示东亚季风演化历史?

黏土矿物以其示踪洋流变化和揭示物源区同时期气候变化的能力,近年来在南海沉积古环境研究中的地位日益显现。但是,南海黏土矿物能否用于直接指示东亚季风演化历史的研究仍然颇为争议。本研究认为,南海黏土矿物主要受控于物源区供给和洋流搬运作用,黏土矿物本身不具同时期气候条件特征。以南海北部为例,珠江、台湾和吕宋岛这三个主要物源区无论是冰期还是间冰期都提供相同的黏土矿物组合,这些黏土矿物在输入到南海后分别受到不同洋流的搬运。因此,南海晚第四纪黏土矿物组合用于指示东亚季风演化历史的应用是通过洋流的搬运作用来实现的,在不同海区的应用效果不同。     

The Combined Effect of Tibetan Plateau Uplift and Glacial-Interglacial Cycles on the Quaternary Evolution of the East Asian Monsoon: Evidence from South China Sea Sediments

The siliciclastic sediments of the uppermost section of 185 mcd(meters composite depth) from ODP Site 1146 on the northern continental slope of the South China Sea(SCS) were partitioned according to their sources using end-member modeling on grain-size data. The goal was to evaluate the evolution of the East Asian monsoon over the past 2 million years. The siliciclastic sediments were described as hybrids of four end-members, EM1, EM2, EM3, and EM4, with modal grain sizes of 8–22 μm, 2–8 μm, 31–125 μm, and 4–11 μm, respectively. EM1 and EM3 are interpreted as eolian dust and EM2 and EM4 as fluvial mud. The ratio of eolian dust to fluvial mud((EM1+EM3)/(EM2+EM4)) is regarded as an indicator of the East Asian monsoon. The variation in this ratio not only shows periodical oscillations consistent with oxygen isotope stages, but also exhibits a phased increasing trend corresponding with the phased uplifts of the Tibetan Plateau, indicating that the evolution of the East Asian Monsoon was controlled not only by glacial-interglacial cycles, but also by the phased uplifts of the Tibetan Plateau during the Quaternary.