Determination of water balance equation components in irrigated agricultural watersheds using SWAT and MODFLOW models : A case study of Samalqan plain in Iran

Increasing water demands,especially in arid and semi-arid regions,continuously exacerbate groundwater as the only reliable water resources in these regions.Samalqan watershed,Iran,is a groundwater-based irrigation watershed,so that increased aquifer extraction,has caused serious groundwater depletion.So that the catchment consists of surface water,the management of these resources is essential in order to increase the groundwater recharge.Due to the existence of rivers,the low thickness of the alluvial sediments,groundwater level fluctuations and high uncertainty in the calculation of hydrodynamic coefficients in the watershed,the SWAT and MODFLOW models were used to assess the impact of irrigation return flow on groundwater recharge and the hydrological components of the basin.For this purpose,the irrigation operation tool in the SWAT model was utilized to determine the fixed amounts and time of irrigation for each HRU(Hydrological Response Unit)on the specified day.Since the study area has pressing challenges related to water deficit and sparsely gauged,therefore,this investigation looks actual for regional scale analysis.Model evaluation criteria,RMSE and NRMSE for the simulated groundwater level were 1.8 m and 1.1%respectively.Also,the simulation of surface water flow at the basin outlet,provided satisfactory prediction(R²=0.92,NSE=0.85).Results showed that,the irrigation has affected the surface and groundwater interactions in the watershed,where agriculture heavily depends on irrigation.Annually 11.64 Mm3 water entered to the aquifer by surface recharge(precipitation,irrigation),transmission loss from river and recharge wells 5.8 Mm3 and ground water boundary flow(annually 20.5 Mm³).Water output in the watershed included ground water extraction and groundwater return flow(annually 46.4 Mm³)and ground water boundary flow(annually 0.68 Mm³).Overally,the groundwater storage has decreased by 9.14 Mm3 annually in Samalqan aquifer.This method can be applied to simulate the effects of surface water fluxes to groundwater recharge and river-aquifer interaction for areas with stressed aquifers where interaction between surface and groundwater cannot be easily assessed.     

An assessment of the potential and impacts of winter water banking in the Sokh aquifer, Central Asia

The dynamics of artificial recharge of winter surface flows coupled with increased summer groundwater use for irrigation in the Sokh aquifer (Central Asia) have been investigated. Water release patterns from the giant Toktogul reservoir have changed, as priority is now given to hydropower generation in winter in Kyrgyzstan. Winter flows have increased and summer releases have declined, but the Syr Darya River cannot pass these larger winter flows and the excess is diverted to a natural depression, creating a 40?×?10⁹m³ lake. A water balance study of all 18 aquifers feeding the Fergana Valley indicated the feasibility of winter groundwater recharge in storage created by summer abstraction. This modeling study examines the dynamics of the process in one aquifer over a 5-year period, with four scenarios: the current situation; increased groundwater abstraction of around 625 million (M) m³/year; groundwater abstraction with an artificial recharge of 144 Mm³/year, equivalent to the volume available in low flow years in the Sokh River; and with a larger artificial recharge of 268 Mm³/year, corresponding to high flow availability. Summer surface irrigation diversions can be reduced by up to 350 Mm³ and water table levels can be lowered.     

Groundwater recharge dams in arid areas as tools for aquifer replenishment and mitigating seawater intrusion: example of AlKhod, Oman

Groundwater depletion and seawater intrusion constitute major challenges along coastal aquifers in arid areas. This paper assesses the role of groundwater recharge dams constructed to replenish aquifers and fight seawater intrusion with reference to AlKhod dam, Oman, sited 7 km from the coast on a gravely unconfined aquifer. Water table rise in piezometers located downstream from the dam shows regular patterns correlating with magnitude of wadi flow, whereas upstream piezometers show irregular patterns. Controlled release of water captured by the dam optimizes water percolation and enhances artificial recharge which was estimated in the wet years 1997, 2003 and 2005 as 15, 22 and 27 Mm³, respectively, using water table fluctuation method. Recharge contributed 40–60 % of the total annual abstraction. Groundwater salinity increased in the 1980s and 1990s and the saline/freshwater interface advanced inland, but has receded partially after 1997 (highest rainfall) and completely after 2005 indicated by reduction in electrical conductivity and thickening of freshwater lens. The recession is attributed to the dam’s induced recharge and reduction of pumping in 2004 following the commissioning of Barka desalination plant. Integrating artificial recharge with groundwater resources management is therefore an effective measure to replenish aquifers in arid areas and mitigate seawater intrusion along the coasts.     

Hydrogeological investigation of groundwater artificial recharge by treated wastewater in semi-arid regions: Korba aquifer (Cap-Bon Tunisia)

Korba aquifer is one of the most typical examples of overexploited coastal aquifer in the Mediterranean countries. In fact, from 1985, a considerable piezometric level drop, water salinization, and seawater intrusion were registered in the aquifer. In December 2008, Tunisian authorities initiated a general plan to groundwater management in order to augment groundwater resources, restore the piezometric levels, and improve water quality. The plan consists of artificial recharge of groundwater used treated wastewater through three infiltration basins. During the first 4 years (from December 2008 to December 2012), 1.41 Mm³ of treated wastewater was injected to the Korba aquifer. This study presents a hydrogeological assessment of groundwater evolution during the recharge processes. In this study, 32 piezometric and chemical surveys of 70 piezometers and observed wells are used to present hydrogeological investigation and water quality evolution of wastewater reuse through artificial recharge in Korba coastal aquifer. The piezometric evolution maps are used to specify the positive effect in groundwater level that exceeding 1.5 m in some regions. The interpretation of salinity evolution maps are used to indicate the improving of groundwater quality.     

Delineation of potential recharge area using a hybrid model,case of Djelfa Hadjia watershed

Groundwater potential map is important for environmental assessment and water resources management. In this work, a groundwater recharge potential map was established for the watershed of Oued Djelfa Hadjia in Algeria, based on new multiparameters hybrid model. The model has hydroclimatic parameters, geological settings, slope factor, and stream network density factor as inputs. The groundwater recharge estimated by the model range from 0.71 to 14 mm. The model allows delineation of potential area of recharge. The total water abstraction in Djelfa city is about of 14 hm³; however, the calculated groundwater recharge is about 3 mm/year (min 0.71 mm and max 14 mm), which correspond to an average recharge volume of 3.9 hm³ which mean that the aquifer is under over exploitation.     

Groundwater flow dynamics of weathered hard-rock aquifers under climate-change conditions: an illustrative example of numerical modeling through the equivalent porous media approach in the north-western Pyrenees (France)

A numerical groundwater model of the weathered crystalline aquifer of Ursuya (a major water source for the north-western Pyrenees region, south-western France) has been computed based on monitoring of hydrological, hydrodynamic and meteorological parameters over 3 years. The equivalent porous media model was used to simulate groundwater flow in the different layers of the weathered profile: from surface to depth, the weathered layer (5?·?10^?8?≤?K?≤?5?·? 10^?7 m s^?1), the transition layer (7?·?10^?8?≤?K?≤?1?·? 10^?5 m s^?1, the highest values being along major discontinuities), two fissured layers (3.5?·?10^?8?≤?K?≤?5?·?? 10^?4 m s^?1, depending on weathering profile conditions and on the existence of active fractures), and the hard-rock basement simulated with a negligible hydraulic conductivity (K = 1 10 ^?9 ). Hydrodynamic properties of these five calculation layers demonstrate both the impact of the weathering degree and of the discontinuities on the groundwater flow. The great agreement between simulated and observed hydraulic conditions allowed for validation of the methodology and its proposed use for application on analogous aquifers. With the aim of long-term management of this strategic aquifer, the model was then used to evaluate the impact of climate change on the groundwater resource. The simulations performed according to the most pessimistic climatic scenario until 2050 show a low sensitivity of the aquifer. The decreasing trend of the natural discharge is estimated at about ?360 m³ y^?1 for recharge decreasing at about ?5.6 mm y^?1 (0.8 % of annual recharge).     

In situ infiltration test using a reclaimed abandoned river bed: managed aquifer recharge in Shijiazhuang City,China

Managed aquifer recharge (MAR) is necessary for water resources management in arid and semiarid regions. Infiltration rate is often a decisive limiting factor in site selection for MAR. In order to avoid scale effects in the application of infiltration rate parameters, the largest in situ infiltration test in China was undertaken between August 19 and August 30, 2009 to measure the infiltration rate of the field selected for MAR in Shijiazhuang City, China. The in situ test lasted for 10 days, and about 1.82 × 10⁷ m³ of water was introduced into the infiltration field. Groundwater level variations were monitored during the test. Monitoring showed that the infiltration rate of surface water was 1.5 m/day, which means that about 10–15 × 10⁸ m³/a of water could be injected into the target aquifer. Also, groundwater level variations showed that the northern part of the infiltration field had a higher infiltration rate, as predicted, and the test result supplied a sound foundation for validation of the groundwater numerical simulation, which will be of benefit for future predictions of the response of the groundwater level to artificial recharge engineering. Finally, an artificial recharge plan was proposed based on the infiltration test results and the water source conditions, which would be useful for the development of MAR programs and management of local water resources.     

Constraining flow paths of saline groundwater at basin margins using hydrochemistry and environmental isotopes: Lake Cooper,Murray Basin,Australia

Solutes in saline groundwater (total dissolved solids up to 37 000 mg/L) in the Lake Cooper region in the southern margin of the Riverine Province of the Murray Basin are derived by evapotranspiration of rainfall with minor silicate, carbonate and halite dissolution. The distribution of hydraulic heads, salinity, percentage modern carbon (pmc) contents, and Cl/Br ratios imply that the groundwater system is complex with vertical flow superimposed on lateral flow away from the basin margins. Similarities in major ion composition, stable (O, H, and C) isotope, and ⁸⁷Sr/⁸⁶Sr ratios between groundwater from the shallower Shepparton Formation and the deeper Calivil – Renmark aquifer also imply that these aquifers are hydraulically interconnected. Groundwater in the deeper Calivil – Renmark aquifer in the Lake Cooper region has residence times of up to 25 000 years, implying that pre-land-clearing recharge rates were <1 mm/y. As in other regions of the Murray Basin, the low recharge rates account for the occurrence of high-salinity groundwater. Shallow (<20 m) groundwater yields exclusively modern ¹⁴C ages and shows a greater influence of evaporation over transpiration. Both these observations reflect the rise of the regional water-table following land clearing over the last 200 years and a subsequent increase in recharge to 10 – 20 mm/y. The rise of the regional water-table also has increased vertical and horizontal hydraulic gradients that may ultimately lead to the export of salt from the Lake Cooper embayment into the adjacent fresher groundwater resources.     

Modeling of groundwater flow for Mujib aquifer, Jordan

Jordan is an arid country with very limited water resources. Groundwater is the main source for its water supply. Mujib aquifer is located in the central part of Jordan and is a major source of drinking water for Amman, Madaba and Karak cities. High abstraction rates from Mujib aquifer during the previous years lead to a major decline in water levels and deterioration in groundwater quality. Therefore, proper groundwater management of Mujib aquifer is necessary; and groundwater flow modeling is essential for proper management. For this purpose, Modflow was used to build a groundwater flow model to simulate the behavior of the flow system under different stresses. The model was calibrated for steady state condition by matching observed and simulated initial head counter lines. Drawdown data for the period 1985–1995 were used to calibrate the transient model by matching simulated drawdown with the observed one. Then, the transient model was validated by using drawdown data for the period 1996–2002. The results of the calibrated model showed that the horizontal hydraulic conductivity of the B2/A7 aquifer ranges between 0.001 and 40m/d. Calibrated specific yield ranges from 0.0001 to 0.15. The water balance for the steady state condition of Mujib aquifer indicated that the total annual direct recharge is 20.4 × 10⁶m³, the total annual inflow is 13.0 × 10⁶ m³, springs discharge is 15.3 × 10⁶ m³, and total annual outflow is 18.7 × 10⁶ m³. Different scenarios were considered to predict aquifer system response under different conditions. The results of the sensitivity analysis show that the model is highly sensitive to horizontal hydraulic conductivity and anisotropy and with lower level to the recharge rates. Also the model is sensitive to specific yield     

Surface and subsurface conceptual model of an arid environment with respect to mid- and late Holocene climate changes

The water demand in arid regions is commonly covered by groundwater resources that date back to more humid periods of the Pleistocene and Holocene. Within the investigated arid part of SE Saudi-Arabia information about climate, groundwater levels, and pumping rates are only available for regions where groundwater extractions occur at present-day. For the prediction of the impact of long-term climate changes on groundwater resources an understanding of the hydrogeological and hydrological past and the development of the aquifers is necessary. Therefore, all available information about hydrology and hydrogeology for the past 10,000 years BP were collected and compiled to a conceptual model of the aquifer development on the Arabian Peninsula since the last Ice-Age. The climatic history was displayed by changes in precipitation, temperature and recharge during the mid-S and late Holocene. The hydrogeological development is described by groundwater ages, sea level fluctuations, movement of the coastline, and the development of sabkhas. The most sensitive parameter to describe the development of aquifer system is recharge. Present-day recharge was calculated with the hydrological model system HEC-HMS accounting for current precipitation, temperature, wind, soil types, and geomorphology. With respect to changes in precipitation and temperature over the past 10,000 years the temporal and spatial variability of groundwater recharge was calculated using empirical equations valid for semi-arid and arid settings. Further inflow into the groundwater system results from surface water infiltration in wadi beds, while natural outflow from the groundwater system occurs by discharge to the Gulf, evaporation from sabkhas, and spring discharge. Backward predictions can be verified by sedimentological observations of palaeo-river systems and lakes indicating that groundwater levels reached temporarily the surface under wetter climate conditions and ¹⁴C groundwater ages displaying groundwater residence times.     

Assessing seasonal variations and aquifer vulnerability in coastal aquifers of semi-arid regions using a multi-tracer isotopic approach: the case of Grombalia (Tunisia)

The Grombalia aquifer (NE Tunisia) is an example of an important source of water supply for regional and national development, where the weak controls over abstraction, fertilizer application and waste disposal, coupled with limited knowledge of aquifer dynamics, is causing aquifer over-exploitation and water quality degradation. Assessing the key role of groundwater in water-resources security is therefore of paramount importance to support new actions to preserve water quality and quantity in the long-run. This study presents one of the first investigations targeted at a complete assessment of aquifer dynamics in the Grombalia aquifer. A multi-tracer hydrogeochemical and isotopic (δ²H, δ¹⁸O and ³H) approach was used to study the influence of seasonal variation on piezometric levels, chemical and isotopic compositions, and groundwater recharge. A total of 116 samples were collected from private wells and boreholes during three periods in a 1 year monitoring campaign (February–March 2014, September 2014 and February 2015). Results revealed the overall unsuitability of groundwater for drinking and irrigation purposes (NO₃?>?50 mg/L in 51% of the wells; EC >1,000 μS/cm in 99% of the wells). Isotopic balance coupled to piezometric investigation indicated the contribution of the shallow aquifer to deep groundwater recharge. The study also revealed the weakness of ‘business as usual’ management practices, highlighting possible solutions to tackle water-related challenges in the Grombalia region, where climate change, population growth and intensive agricultural activities have generated a large gap between demand and available water reserves, hence becoming a possible driver for social insecurity.     

Stochastic groundwater modeling of a sedimentary aquifer: evaluation of the impacts of abstraction scenarios under conditions of reduced recharge

A transient finite difference groundwater flow model has been calibrated for the Nasia sub-catchment of the White Volta Basin. This model has been validated through a stochastic parameter randomization process and used to evaluate the impacts of groundwater abstraction scenarios on resource sustainability in the basin. A total of 1500 equally likely model realizations of the same terrain based on 1500 equally likely combinations of the data of the key aquifer input parameters were calibrated and used for the scenario analysis. This was done to evaluate model non-uniqueness arising from uncertainties in the key aquifer parameters especially hydraulic conductivity and recharge by comparing the realizations and statistically determining the degree to which they differ from each other. Parameter standard deviations, computed from the calibrated data of the key parameters of hydraulic conductivity and recharge, were used as a yardstick for evaluating model non-uniqueness. All model realizations suggest horizontal hydraulic conductivity estimates in the range of 0.03–78.4 m/day, although over 70 % of the area has values in the range of 0.03–14 m/day. Low standard deviations of the horizontal hydraulic conductivity estimates from the 1500 solutions suggest that this range adequately reflects the properties of the material in the terrain. Lateral groundwater inflows and outflows appear to constitute significant components of the groundwater budgets in the terrain, although estimated direct vertical recharge from precipitation amounts to about 7 % of annual precipitation. High potential for groundwater development has been suggested in the simulations, corroborating earlier estimates of groundwater recharge. Simulation of groundwater abstraction scenarios suggests that the domain can sustain abstraction rates of up to 200 % of the current estimated abstraction rates of 12,960 m³/day under the current recharge rates. Decreasing groundwater recharge by 10 % over a 20-year period will not significantly alter the results of this abstraction scenario. However, increasing abstraction rates by 300 % over the period with decreasing recharge by 10 % will lead to drastic drawdowns in the hydraulic head over the entire terrain by up to 6 m and could cause reversals of flow in most parts of the terrain.     

Watershed-scale response of groundwater recharge to inter-annual and inter-decadal variability in precipitation (Alberta,Canada)

Groundwater recharge sets a constraint on aquifer water balance in the context of water management. Historical data on groundwater and other relevant hydrological processes can be used to understand the effects of climatic variability on recharge, but such data sets are rare. The climate of the Canadian prairies is characterized by large inter-annual and inter-decadal variability in precipitation, which provides opportunities to examine the response of groundwater recharge to changes in meteorological conditions. A decadal study was conducted in a small (250 km²) prairie watershed in Alberta, Canada. Relative magnitude of annual recharge, indicated by water-level rise, was significantly correlated with a combination of growing-season precipitation and snowmelt runoff, which drives depression-focussed infiltration of meltwater. Annual precipitation was greater than vapour flux at an experimental site in some years and smaller in other years. On average precipitation minus vapour flux was 10 mm y^?1, which was comparable to the magnitude of watershed-scale groundwater recharge estimated from creek baseflow. Average baseflow showed a distinct shift from a low value (4 mm y^?1) in 1982–1995 to a high value (15 mm y^?1) in 2003–2013, indicating the sensitivity of groundwater recharge to a decadal-scale variability of meteorological conditions.     

Pumping dry: an increasing groundwater budget deficit induced by urbanization,industrialization, and climate change in an over-exploited volcanic aquifer

A methodology is proposed to improve the groundwater budget model by determining the past, present, and future recharge and discharge rates. The model is applied to an increasingly urbanized and industrialized region with drying tendencies: the Toluca Valley, Mexico. This study includes spatially variable recharge determined from the historical climate data, the climate change predictions, and the multiple parameters used in the Hydrologic Evaluation of Landfill Performance (HELP3) model. Using HELP3 a spatial discretization for the average recharge is obtained and estimated at 376 million cubic meters per year (Mm³/year). When considering climate change predictions, by 2050 the average scenario projects recharge to decrease by 15 Mm³/year (from 376 to 361 Mm³/year), and in a worst case scenario up to a maximum decrease of 88 Mm³/year (from 376 to 288 Mm³/year). Groundwater pumping has increased steadily since 1970 and is estimated at 495 Mm³/year for 2010. The current average deficit estimated for 2010 is 172 Mm³/year with average projections increasing to over 292 Mm³/year by 2050. This study of two of the most important components of the water cycle (recharge and discharge) clearly shows that the decreasing water availability in the Toluca basin is due mainly to groundwater pumping and that the current pumping rates are not sustainable. The current deficit can be considered problematic and projections based on expected water consumption and climate change reinforce the need for management of the water resources to be addressed.     

Interactions between the surface water and groundwater in the western shoreline of Lake Nasser, Upper Egypt

The present study indicates that the factors controlling the hydraulic relation between surface water and groundwater at the western lake shoreline change from one locality to another. This depends upon the lithological characteristics and the major structures. In the southern sectors, sedimentation at the bottom and sides of the lake prevents the water movement to the Nubian sandstone aquifer. The potentiometric map reveals that the water level altitudes range between 170 m in the vicinity of the lakeshore line and 110 m west of the lake. The groundwater flow lines show that the main recharge to the aquifer comes from the southwest direction, as well as from the lake inland to variable distances (about 30 Km). During the present study, Darcy’s law was applied to calculate the recharge from the western shoreline of Lake Nasser to the adjacent Nubian aquifer. The maximum value of seepage was at Garf Hussein (27.71?×?10⁶ m³/year), which may be related to high permeability and hydraulic gradient. Also, it may be related to the N–S strike faults that cut the area on both sides of the Lake, and the groundwater is expected to have free circulation through the faults of this trend. The minimum value was recorded in Adindan section (0.61?×?10⁶ m³/year). This may be related to the limited recharge from the lake to the aquifer, due to the sedimentation that dislocates this recharge.     

Hydrochemical and isotopic behaviour of a Saharan phreatic aquifer suffering severe natural and anthropic constraints (case of Oued-Souf region, Algeria)

An approach combining the use of water dissolved chemical species and isotopic fingerprints has been used to understand the behavior of a phreatic aquifer and to determine the origin of its different water components. This aquifer is located in the large sedimentary basin of the Great Oriental Erg (Algeria) and overlies two deeper aquifers: the Complexe Terminal (CT) and the Continental Intercalaire (CI). Besides the deterioration of its groundwater quality, its water table has risen during the last 20 years. A water budget surplus between 950 and 2500 l s^?1 was estimated. Down-gradient groundwater evolution (south-north) has shown that the mineralisation increases from 1.23 to 5.20 g l^?1 due to evaporite minerals dissolution. Chemical and isotopic data demonstrated that in addition to rainfall there is a contribution from the CT and CI aquifers. The latter are tritium-free and less mineralized than the phreatic aquifer. Their radiocarbon contents are very low (<10 pmC, percent modern Carbon) (Pleistocene recharge) whereas quite the contrary is observed for the superficial aquifer which exhibits fairly high and variable C-14 activities (50–100 pmC), evidence of recent recharge. On the basis of tritium contents, two groundwater groups were identified for the phreatic aquifer.     

Hydrogeochemical and isotopic evidence of groundwater evolution and recharge in aquifers in Beijing Plain, China

An investigation was conducted in Beijing to identify the groundwater evolution and recharge in the quaternary aquifers. Water samples were collected from precipitation, rivers, wells, and springs for hydrochemical and isotopic measurements. The recharge and the origin of groundwater and its residence time were further studied. The groundwater in the upper aquifer is characterized by Ca-Mg-HCO₃ type in the upstream area and Na-HCO₃ type in the downstream area of the groundwater flow field. The groundwater in the lower aquifer is mainly characterized by Ca-Mg-HCO₃ type in the upstream area and Ca-Na-Mg-HCO₃ and Na-Ca-Mg-HCO₃ type in the downstream area. The δD and δ¹⁸O in precipitation are linearly correlated, which is similar to WMWL. The δD and δ¹⁸O values of river, well and spring water are within the same ranges as those found in the alluvial fan zone, and lay slightly above or below LMWL. The δD and δ¹⁸O values have a decreasing trend generally following the precipitation → surface water → shallow groundwater → spring water → deep groundwater direction. There is evidence of enrichment of heavy isotopes in groundwater due to evaporation. Tritium values of unconfined groundwater give evidence for ongoing recharge in modern times with mean residence times <50 a. It shows a clear renewal evolution along the groundwater flow paths and represents modern recharge locally from precipitation and surface water to the shallow aquifers (<150 m). In contrast, according to ¹⁴C ages in the confined aquifers and residence time of groundwater flow lines, the deep groundwater is approximately or older than 10 ka, and was recharged during a period when the climate was wetter and colder mainly from the piedmont surrounding the plain. The groundwater exploitation is considered to be “mined unsustainably” because more water is withdrawn than it is replenished.     

Water resources assessment in the Minqin Basin: an arid inland river basin under intensive irrigation in northwest China

The Minqin Basin is at the lower reach of the Shiyang River of Gansu province in northwest China. Dramatic decline in groundwater level has resulted from over-abstraction of groundwater since the late 1950s to satisfy increasing irrigation and other demands. Severe water shortage led to environmental degradation. To better understand the spatial–temporal variation of groundwater levels and to evaluate the groundwater resources in the region, a three-dimensional regional groundwater flow model was built and calibrated under transient condition. The MODFLOW program was used and the research area was discretized as a square network with cell size of 400 × 400 m. The model showed that the aquifer was under destructive stress, with a groundwater resource deficit of 260 million cubic meters per year (Mm³/year) on average. Since the inflow of surface water from the upstream basin has declined to about 100–150 Mm³/year in recent decades, the irrigation return flow had become the main recharge and accounted for 60.6% of total recharge; meanwhile, abstraction by pumping wells took 99.2% from the total groundwater discharge.     

Determining groundwater degradation from irrigation in desert-marginal northern China

Groundwater degradation from irrigated agriculture is of concern in semi-arid northern China. Data-scarcity often means the causes and extent of problems are not fully understood. An irrigated area in Inner Mongolia was studied, where abstraction from an unconfined Quaternary aquifer has increased threefold over 20 years to 20 million m³/year; groundwater levels are falling at up to 0.5 m/year; and groundwater is increasingly mineralised (TDS increase from 400 to 700–1,900 mg/L), with nitrate concentrations up to 137 mg/L N. Residence-time (chlorofluorocarbons), stable-isotope and hydrogeochemical indicators helped develop a conceptual model of groundwater system evolution, demonstrating a direct relationship between modern water proportion and the degree of groundwater mineralisation, indicating that irrigation-water recycling is reducing groundwater quality. The investigations suggest that before irrigation development, active recharge to the aquifer from wadis significantly exceeded groundwater inflow from nearby mountains, previously held to be the main groundwater input. Away from active wadis, groundwater is older with a probable pre-Holocene component. Proof-of-concept groundwater modelling supports geochemical evidence, indicating the importance of wadi recharge and irrigation return flows. Engineering works protecting the irrigated area from flooding have reduced good quality recharge; active recharge is now dominated by irrigation returns, which are degrading the aquifer.     

Effect of diffuse recharge and wastewater on groundwater contamination in Douala,Cameroon

High water demand for domestic use in Douala with over 3 million inhabitants is met mainly by shallow groundwater. Field measurements and water sampling in January 2015 were carried out to examine the major controls on the groundwater composition and spatial view of ions in the water, timing of recharge and link between the recharge process and quality of the water. Fifty-two water samples were analysed for major ions and stable hydrogen and oxygen isotopes. Low pH values (3.61–6.92) in the groundwater indicated an acidic aquifer; thus, prone to acidification. The dominant water type was Na–Cl. Nitrate, which exceeded the WHO guide value of 50 mg/l in 22% of the groundwater, poses a health problem. Mass ratios of Cl^?/Br^? in the water ranged from 54 to 3249 and scattered mostly along the mixing lines between dilute waters, septic-tank effluent and domestic sewage. A majority of the samples, especially the high NO₃ ^? shallow wells, clustered around the septic-tank effluent-end-member indicating high contamination by seepage from pit latrines; hence, vulnerable to pollution. Stable isotopes in the groundwater indicated its meteoric origin and rapid infiltration after rainfall. The δ¹⁸O values showed narrow ranges and overlaps in rivers, springs, open wells and boreholes. These observations depict hydraulic connectivity, good water mixing and a homogeneous aquifer system mainly receiving local direct uniform areal recharge from rainfall. The rapid and diffused recharge favours the leaching of effluent from the pit toilets into the aquifer; hence, the high NO₃ ^? and Cl^? in shallow wells. Silicate weathering, ion exchange and leaching of waste from pit toilets are the dominant controls on the groundwater chemistry. Drilling of deep boreholes is highly recommended for good-quality water supply. However, due the hydraulic connection to the shallow aquifer, geochemical modelling of future effects of such an exploitation of the deeper aquifer should support groundwater management and be ahead of the field actions.