粤北瑶梅地区钨矿成矿地质条件分析

粤北瑶梅地区位于华南湘赣粤钨矿成矿区的南部成矿带西南段(徐克勤,1984),沿着瑶岭复背斜的核部由西向东分布有瑶岭、石人嶂、梅子窝等三个中大型的石英脉(脉带)型钨矿床及河口山、师坑山和文政坑等小型钨矿床(点),构成一个钨矿化集中区(图1).     

粤北梅子窝钨锡矿床地质特征及其成矿年龄研究

对梅子窝钨锡矿床含矿石英脉进行了Rb-Sr同位素年代学研究,获得石英Rb-Sr等时线年龄为150±5Ma,与前人在同一地区获得的师姑山钨铋矿和石人嶂钨矿含矿石英脉中共生辉钼矿物Re-Os等时线年龄(154~159Ma)在实验误差范围内一致。研究表明,南岭中段始兴地区的钨矿、钨锡矿和钨铋矿的形成时代分布在150~160Ma之间,同属南岭地区中生代大规模成岩成矿作用高峰期的产物。     

广东石人嶂钨矿床晶质铀矿研究进展简述

<正>铀矿是国家大力发展清洁能源的矿物原料与重要战备资源,晶质铀矿是铀矿资源的重要来源。许多产铀花岗岩体中发现有晶质铀矿,但在其他岩类中发现晶质铀矿的报道还非常的少(张少琴等,2009),在石人嶂钨矿床中发现晶质铀矿更显意义重大。广东石人嶂钨矿是粤北的重要矿山,在开展石人嶂钨矿伴生银工作中,朱文凤通过显微镜鉴定及扫描电镜能谱分析,在石英钨矿脉、云英岩     

广东石人嶂钨矿床钨品位的分形特征初步研究

<正>本文根据矿山生产数据资料,统计分析钨矿床在垂向上的品位及矿化强度变化规律,并结合分形理论探对石人嶂钨矿深部进行成矿预测。1钨品位垂向统计分布特征不少实践得以证实,某些成矿元素统计参数能有效反映矿床矿化强度变化趋势(庞保成等,2005;陈宏毅和钱建平,2011)。本文收集石人嶂     

大吉山钨矿中钨铌锰矿与富钨铌锰矿的交生现象及其成因探讨

文章对大吉山钨锰矿矿石进行了电子探针分析 ,发现了一种主要元素为Nb、Ta、Fe、Mn、W的复杂氧化物矿物———钨铌锰矿。这种矿物与富钨铌锰矿交生 ,在成分上与后者呈渐变过渡。证实在自然界中黑钨矿与铌钽铁矿之间可能存在着广泛的W_Nb(Ta)类质同像置换现象。通过对其成分、形态和共生关系的研究 ,结合大吉山钨矿的形成期次 ,联系矿体与区域内两期花岗岩的内在关系 ,对大吉山钨矿的成因机制进行了探讨     

广东石人嶂钨矿14~#脉流体特征初探

<正>石人嶂钨矿地处粤北始兴县东南部,面积约为2.6 km2,现为资源危机型矿山。本文在对矿床地质特征研究的基础上,着重对14#脉石英样品中的流体包裹体进行分析,初步探讨成矿流体的地球化学性质及其来源。1矿区地质概况石人嶂钨矿位于华南湘赣粤钨矿成矿区南部成矿带西南段,瑶岭复背斜的东部。矿区出露地层主要为寒武系()、奥陶系(O)浅变质砂     

大吉山钨矿中钨银锰矿与富钨铌锰矿的交生现象及其成因探讨

文章对大吉山钨锰矿矿石进行了电子探针分析，发现了一种主要元素为Nb、Ta、Fe、Mn、W的复杂氧化物矿物——钨铌锰矿。这种矿物与富钨铌锰矿交生，在成分上与后者呈渐变过渡。证实在自然界中黑钨矿与铌钽铁矿之间可能存在着广泛的W—Nb(Ta)类质同像置换现象。通过对其成分、形态和共生关系的研究，结合大吉山钨矿的形成期次，联系矿体与区域内两期花岗岩的内在关系，对大吉山钨矿的成因机制进行了探讨。     

广东石人嶂钨矿床深部找矿及其启示

<正>石人嶂钨矿位于广东北部韶关市始兴县城南20 km,是著名的华南钨矿成矿域的重要组成部分(韦龙明等,2008),石人嶂矿化带长850 m,宽300 m,已勘查的矿脉56个,矿体(脉)长70¹130 m,钨矿脉产状210°1130 m,钨矿脉产状210°²40°∠75°240°∠75°⁸2°,目前开采的矿石类型均为黑钨矿石英脉型矿石,钨矿脉分布严格受花岗岩体控制,主要金属矿物均为黑钨矿,局部富集锡石、含砷黄铁矿、黄铜     

粤北梅子窝钨矿区隐伏花岗闪长岩锆石SHRIMP U-Pb年龄与~(40)Ar/~(39)Ar成矿年龄及其地质意义

梅子窝钨矿位于粤北瑶岭—梅子窝钨矿带的东部,成矿作用同期形成白云母的40Ar/39Ar年龄为(155.9±0.6)Ma,与华南中生代燕山期大规模W,Sn成矿作用的年龄一致,代表梅子窝钨矿的成矿年龄。矿床下部600m中段附近出现的隐伏黑云母花岗闪长岩体的锆石SHRIMPU-Pb年龄为(430.4±3.6)Ma,为加里东期,与成矿作用无关。因此,矿区不存在前人提出的两套叠加的"五层楼"成矿模式。成矿年龄与隐伏花岗闪长岩的年龄显示梅子窝钨矿的形成可能与更深部的隐伏燕山期花岗岩有关,矿床向深部可能延伸更大。     

粤北地区锡矿成矿规律及找矿前景

粤北地区锡矿主要有石英脉带型锡矿、矽卡岩型锡矿、矽卡岩-破碎带复合型锡矿、脉状锡铅锌多金属矿、花岗岩风化壳型锡矿、云英岩型锡矿和砂锡矿等类型。根据区域成矿地质和物化探异常等特征,认为粤北地区石英脉型锡矿与矽卡岩-破碎带复合型锡矿具有良好的找矿前景,前者可作为今后该区域锡矿的主要找矿类型。根据区域成矿地质特征划分为5个找矿远景区,即锯板坑—瑶岭找矿远景区、杉木洞—禾尚田找矿远景区、大东山找矿远景区、岭脚找矿远景区、谢家山找矿远景区。     

Molybdenite Re–Os and muscovite 40Ar/39Ar dating of quartz vein-type W–Sn polymetallic deposits in Northern Guangdong, South China

Northern Guangdong is an important part of Nanling tungsten–tin metallogenic belt, South China. The tungsten mineralization in this area consists of mainly quartz–wolframite vein-type mineralization, with W–Sn polymetallic deposits mostly distributed at the outer contact zone between concealed Late Jurassic granitic stocks and Cambrian–Ordovician low-metamorphosed sandstones and shales. Molybdenite Re–Os and muscovite ⁴⁰Ar/³⁹Ar isotopic dating of three typical tungsten vein-type deposits (Yaoling, Meiziwo, and Jubankeng) in northern Guangdong, show that two episodes of Late Jurassic W–Sn polymetallic mineralization occurred in this area: an early episode during the Late Jurassic (158–159?Ma) represented by the Yaoling, Hongling, and Meiziwo tungsten deposits, and a younger event during the Early Cretaceous (138?Ma) represented by the Jubankeng deposit. Analysis of available radiometric ages of several W–Sn deposits in the Nanling region indicate that these deposits formed at several intervals during the Mesozoic at 90–100, 134–140, 144–162, and 210–235?Ma, and that large-scale W–Sn mineralization in this region occurred mainly between 150 and 160?Ma.     

粤北连平地区钨锡多金属矿床成矿时代研究

粤北连平地区钨锡多金属矿床类型主要为石英脉型.采用云母Ar-Ar法和石英包裹体Rb-Sr法.分别获得:锯板坑含钨锡石英脉中的云母Ar-Ar坪年龄为(139.2±1.5)Ma(等时线年龄为143.6±3.9 Ma,MSWD:0.30):鸡啼石含钨石英脉中石英包裹体Rb-Sr等时线年龄为(155.4±5.1)Ma(MSWD=2.1).结果表明该区存在燕山早期和燕山早晚过渡期两期钨锡多金属成矿作用,并且认为:(1)鸡啼石钨矿为南岭地区中生代大规模成岩成矿作用高峰期(150～160 Ma)的产物;(2)南岭地区140 Ma左右也有大型钨锡多金属矿的形成.这一成果为研究区域成矿规律,指导区域找矿提供了重要同位素年代学依据.     

粤北始兴地区石英脉型钨矿成矿时代的确定及其地质意义

粤北始兴地区钨矿的主体为石英脉型。通过对含矿石英脉中辉钼矿Re-Os同位素测定,获得等时线年龄及模式年龄的加权平均值分别为:师姑山钨铋矿(154.2±2.7)Ma(MSWD=0.29)和(154.0±2.0)Ma(MSWD=0.047);石人嶂钨矿(159.1±2.2)Ma(MSWD=3.9)和(157.6±1.6)Ma(MSWD=0.62)。结果表明它们为南岭地区中生代大规模成岩成矿作用高峰期的产物。这为进一步研究区域成矿规律,指导区域找矿提供了重要同位素年代学依据。     

广东梅子窝钨矿“五层楼”叠加现象探讨

广东梅子窝钨矿是我国石英脉型钨矿"五层楼"矿化模型理论形成的发源地。近年来,钻探和矿山生产揭露显示钨矿脉已向下延伸到花岗岩体内部二、三百米仍然没有尖灭,与传统的"五层楼"矿化模型存在出入。在前人工作基础上,通过系统的野外观察,深入细致地对比研究发现,矿区深部存在有两期隐伏花岗岩侵入活动,分别形成了两期石英脉型钨矿化,它们在空间上互相叠置,纵向上"五层楼"相互错位,构成"五层楼"叠加,这对矿区深部找矿具有重大指导意义。     

华南南岭地区石英脉型钨矿床蚀变晕形成机制

中国地质工作者在20世纪80年代已发现南岭地区许多石英脉型钨矿床的蚀变晕宽度随深度递减,然而这一蚀变特征的形成机制至今仍未得到较好的解释。通过模拟热液运移和硅从裂隙带向邻近围岩的扩散过程,发现流体温度和围岩孔隙度是影响石英脉型钨矿床蚀变特征的重要变量。高温和高孔隙度会加速硅从裂隙向邻近围岩扩散,从而形成较宽的蚀变。在围岩孔隙度均一分布的情况下,由于深部温度高于浅部,深部围岩蚀变宽于浅部蚀变。围岩孔隙度随深度递减会抵消温度对硅扩散速率的影响,使深部围岩形成较窄的蚀变。围岩孔隙度随深度递减可能是形成石英脉型钨矿床蚀变宽度随深度减小的有效机制。前人将钨矿蚀变特征归因于岩浆热液过渡性流体不均一的物理性质,该研究为这一科学问题提供新的解释。     

The geochemistry of tungsten in Bulgarian coals

This paper discusses the tungsten geochemistry in coal, based on the behavior of this element in 14 Bulgarian deposits. The W contents range from 0.5–4335 ppm in the ash and from 0.01–784 ppm in the coals. In four of the deposits the tungsten content proved to be 16 to 100 times higher than the Clarke value for sedimentary rocks. No correlation has been found between the W concentration and either the age of the coal-bearing strata or the coal rank. The deposits were divided in three groups on the basis of the relationship between tungsten and ash content. The role of sorption ash and terrigenous ash in tungsten binding was evaluated for each group. The correlation between tungsten and organic matter is demonstrated by the increased contents of tungsten in the ash of the low-ash coals, its concentration in the lighter coal fractions, its extraction from the coals by HF and NaOH only, and by model experiments. Sorption ash concentrates tungsten; terrigenous ash is a carrier of tungsten.Of the petrographic constituents of coal, vitrain was found to concentrate the largest amounts of tungsten.In two of the deposits richest in tungsten, there is a very distinct zonality in its vertical distribution — tungsten concentration decreases from the bottom to the top of the coal bed. This zonality might be explained by the diffusion (syngenetic or diagenetic with respect to the coal-forming process) through the coal bed of aqueous solutions enriched in tungsten.The wide range of variation of the tungsten concentrations, the considerable differences in the mean contents and the dispersions between the individual deposits show that tungsten is very sensitive to the differences of the source area.Coal deposits enriched in tungsten may be expected in the following favourable environments: (1) in areas with nitrogen-bearing thermal waters containing increased amounts of tungsten; (2) source areas with tungsten mineralizations; and (3) country rocks consisting of acid granitoids whose Clarke values of tungsten are the highest as compared to the other types of rocks.     

Silver and Sulfosalt Minerals in Tungsten Deposits,South China

Silver occurs in South China wolframited-quartz veins in three forms:(1)as micro inclusions of Ag2S and AgBiS2,(2) as argentite and matildite as a result of exsolution and(3)as Ag-bearing sulfosalts and independent silver minerals.According to mineral assemblaged the Ag-bearing tungsten deposits are classified as two types:(1)Ag-bearing W-Bi deposits in eastern Nanling,where gustavite has been found and（2）Ag-bearing W-Sn(Sb)deposits which are mainly distributed in western Nanling.The authors consider that the enrichment of silver and sulfosalt minerals in the lower parts of pneumato-hypothermal tungsten deposits is the result of reversed vertical zoning caused by high concentrations of F and S in the ore-forming fluids.     

南岭锡钨多金属矿区碱长花岗岩的厘定及其意义

南岭地区锡钨多金属矿成矿作用主要与燕山早期花岗岩岩浆活动有关,这些花岗岩一直被认为是黑云母花岗岩、二长花岗岩、细粒二长花岗岩等,少量矿区岩体顶部出现钠长石花岗岩。通过对湖南瑶岗仙钨矿岩体的深入解剖,以及对杮竹园、黄沙坪、锡田、邓阜仙、栗木、梅子窝等矿区花岗岩全面的岩矿鉴定和电子探针分析,确定钨矿区致矿花岗岩的长石主要为碱性长石,其中绝大部分样品中钠长石An<5,因此确定这些花岗岩均属于碱长花岗岩。与成矿有关的由浆液过渡态流体形成的云英岩包体中的钠长石更加富Na,An<3。碱长花岗岩的成分以及钠长石成分在岩体顶部约1 000 m深度范围内无明显垂向变化。致矿花岗岩体中部分早期花岗岩包体、晚期花岗斑岩,部分花岗岩基以及印支期花岗岩、加里东期花岗闪长岩等,钠(斜)长石An值明显高,很多属更长石、中长石甚至基性长石。这种包含有两种碱性长石的碱长花岗岩由富挥发分的岩浆形成,在岩体顶部附近广泛发生液态不混溶作用,是导致锡钨多金属矿富集成矿的主要分异方式。钨锡矿区碱长花岗岩钠长石An值明显低于区域大花岗岩基或不致矿花岗岩,可作为花岗岩的钨锡成矿评价标志之一。