珠江口悬浮物和沉积物中Ba的界面地球化学

本文首次研究了珠江口石油开发区水域悬浮物和沉积物中Ba的可交换态、碳酸盐结合态、铁锰氧化物结合态、有机结合态和结晶态等五种化学形态的含量分布,并讨论了它们的界面地球化学过程。     

盐酸、温度、时间及粒径对海洋沉积物碳酸盐去除的影响

通过南海北部表层沉积物相同体积不同盐酸浓度(0.1和1.0 mol.L-1)、不同温度(23和60℃)、不同时间(6、12和24h)和不同颗粒粒径样品(<160μm和<32μm)的交叉条件实验,利用各条件实验后样品的总碳含量及稳定碳同位素组成分析结果,研究了盐酸、温度、时间及颗粒粒径对碳酸盐去除的影响。结果表明,从提高沉积物碳酸盐盐酸酸解反应速率和效率及获取稳定可靠的TOC、δ13C有机质等参数的角度出发:(1)盐酸用量及浓度是最重要的影响因素;(2)升高反应温度是不必要的,升高反应温度既会抑制反应的进行,又会导致盐酸浓度下降并加速有机质分解,从而对沉积物总有机碳含量及其δ13C等的准确分析产生不利影响;(3)在1.0 mol.L-1盐酸过量的条件下,碳酸盐的大量分解在6h之前已基本完成;(4)颗粒粒径愈小,愈有利于样品的均匀混合及反应的进行,相应的分析结果离散度亦愈小。     

沉积速率的随时间尺度变化和礁与碳酸盐台地的沉没

浅水碳酸盐系统提供的沉积物和垂向加积的最大速率很重要,因为这一速率决定了礁或碳酸盐台地的生与死。海洋中大部分碳酸盐沉淀发生在水体的光照部分,因此大量的生产限于透光带,约在海洋１００ｍ水深以上。当台地顶部没于不透光深度时,碳酸盐的生产停止,台地将被淹没。礁或台地的生或死取决于一种平衡,就是相对海平面变化速率和碳酸盐系统加积并保持台地顶部位于透光区的最大速率间的平衡。在这个报告中,作者首次提出和评价了这个假说：礁和台地的生长潜力与碳酸盐平均生长速率遵循相同的尺度变化趋势。１　比率相关和沉积速率的比例…     

南海东北部之海水碳酸盐现况

为探讨南海的海水碳酸盐现况，本文利用“海研一号”三个航次（第266、287及316航次）的机会，搜集南海东北角的碳酸盐因子，如温度盐度、pH值、总碱度及总二氧化碳等。南海深层水具有西菲律宾海水深约2200m的水团特性，实测结果显示此两水团的碳酸盐因子并没有明显的差异。由滞留时间、无机碳及有机碳分解速率计算结果显示，南海深层水的滞留时间以40a较为合理。     

近平衡状态海水中方解石和文石沉淀速率及动力学研究

利用"freedrift"开放反应系统,研究人工海水中近沉淀平衡状态时二氧化碳分压(p(CO2))的变化对方解石、文石沉淀速率及其动力学方程的影响.反应在恒定的温度(25.0℃±0.2℃)、p(CO2)环境下进行,通过实验得到了不同p(CO2)环境下,方解石和丈石的沉淀速率及动力学方程.研究发现:(1)晶体类型和碳酸盐...     

渤海湾海冰及黄河口河冰的剪切性质

本文叙述了冰的剪切实验方法,此实验是一种小规模的野外实验,主要测试渤海湾海冰及黄河口河冰在不同温度和不同形变速率情况下的剪切强度.冰的剪切强度是冰的温度和形变速率的函数.在一定的温度和形变速率范围内,冰的剪切强度随着冰的温度降低和形变速率的加快而变,超过了一定的范围,冰的剪切强度随着冰的温度降低和形变速率的加大而变小.     

沉积物中碳酸盐~(14)C年龄的可靠性

本文根据放射性碳杂志上发表的300余个~(14)C年龄数据及在中国和澳大利亚进行的野外调查,对土壤碳酸盐的形成途径,稳定同位素成份,钙结核的生长速率及古气候效应等问题进行了讨论.可区别出的三个δ~(13)C丰值,看来与环境和碳的来源无关.而土壤碳酸盐~(14)C年龄分布频率揭示它们形成于相对温暖-潮湿的古气候期.“老碳”的混入及土壤碳酸盐缓慢的生长速率是主要的误差来源.δ~(13)C值不能用于校正土壤碳酸盐的~(14)C年龄.     

海水中-氧化氮的化学发光法测定

基于鲁米诺-H2O2混合溶液作为发光液与海水中NO发生反应产生发光信号的原理,提出了一种测定海水中痕量NO的化学发光法.确定了化学发光法测定NO的最佳条件:pH9.2、浓度1×10-2 mol/dm3的碳酸盐为缓冲体系,鲁米诺浓度为8.4×10-5 mol/dm3,H2O2浓度为1×10-2 mol/dm3,测定温度为...     

稀土元素在成岩型海洋铁锰结核中的富集特征及机制

借助相分析中的偏提取方法对取自东太平洋深海平原上的成岩型铁锰结核进行了选择性提取实验以研究稀土元素在其中各矿物或氧化物相中的分布模式以及铁氧化物和锰氧化物对稀土元素的吸附机制.结果显示,尽管1 nm-水锰矿相对无定形铁的氧化物/氢氧化物而言是成岩型结核中的优势矿物,但是稀土元素主要富集在无定形铁的氧化物/氢氧化物中.虽然稀土元素在海水中主要是以碳酸盐络合物的形式存在,但是无定形铁的氧化物/氢氧化物则是从海水中获得自由稀土元素离子来络合,而1 nm-水锰矿则直接吸附稀土元素的碳酸盐络合物.因此,无定形铁的氧化物/氢氧化物对稀土元素来说具有比1 nm-水锰矿更强的络合能力.成岩型结核的Ce负异常是由于成岩型结核形成于缺氧微环境中,该环境不能把可溶性的Ce~(3+)氧化成不溶性的Ce~(4+)发生沉淀.     

末次冰期以来南海南部千年尺度的古海洋学

对南海南部MD05-2896柱状样22.8 kaBP以来的深海沉积物进行了浮游有孔虫和颗石藻化石定量分析.通过转换函数、特定有孔虫属种含量及比值和颗石藻Florisphaera profunda百分含量等探讨了南海南部海水表层温度、上部水体结构、初级生产力以及碳酸盐溶解作用等变化趋势和周期性.结果表明:18 kaBP以前及10 kaBP以来,海水表层温度较高,碳酸盐溶解作用较强,温跃层营养跃层较深,初级生产力较低.18～10 kaBP冰期时,海水表层温度最低,碳酸盐溶解作用变弱,营养跃层和温跃层变浅,初级生产力较高.频谱分析结果显示,22.8 kaBP以来的气候变化具有明显的周期性,以类D/O事件的千年尺度周期为主,其中最主要的周期为1 500年.     

Sequence stratigraphic analysis of Eocene Rock Strata,Offshore Indus,southwest Pakistan

In this study, seismic data from two wells (Pak G2-1 and Indus Marine-1C) and age diagnostic larger benthic foraminifera (LBF) within drill cuttings has been used for the first time to identify depositional sequences within the carbonates in the Offshore Indus Basin, Pakistan. The Offshore Indus is tectonically categorized as a passive continental margin where carbonates occur as shelf carbonates in the near offshore and on volcanic seamounts in deeper waters. Seismic data analysis has indicated the presence of minor faults and carbonate buildups above the igneous basement in the south. Patterns of the seismic reflections enabled definition of three seismic facies units identified as: Unit 1 basement, represented by chaotic, moderate amplitude reflection configuration; while parallel bedding and the drape of overlying strata is typical character of Unit 2, carbonate mound facies. The younger Miocene channels represent Unit 3. The diagnosis of Alveolina vredenburgi/cucumiformis biozone confirmed the Ilerdian (55–52 Ma) stage constituting a second order cycle of deposition for the Eocene carbonates (identified as Unit 2). The carbonate succession has been mainly attributed to an early highstand system tract (HST). The environmental conditions remained favorable leading to the development of keep-up carbonates similar to pinnacle buildups as a result of aggradation during late transgressive system tract and an early HST. The carbonate sequence in the south (Pak G2-1) is thicker and fossiliferous representing inner to middle shelf depths based on fauna compared to the Indus Marine-1C in the north, which is devoid of fossils. Three biozones (SBZ 5, SBZ 6 and SBZ 8) were identified based on the occurrence of LBF. The base of the SBZ 5 zone marks the larger foraminifera turnover and the Paleocene–Eocene (P–E) boundary. The LBF encountered in this study coincides with earlier findings for the P–E boundary. Our findings indicate that the entire Ilerdian stage ranges from 55.5 to 52 Ma that was the episode of warmer water conditions on the carbonate shelves leading to the diversification of K-strategist larger foraminifera. The larger foraminiferal assemblage encountered in this study confirms the findings. The possible indication of stratigraphic-combination traps, revealed as reflection terminations, make carbonate mounds in the south a potential exploration target.     

Rare earth elements in cold seep carbonates from the southwestern Dongsha area,northern South China Sea

The circulation of methane-rich fluids at cold seeps often leads to the precipitation of seep carbonates close to the seafloor along continental margins, which can be used as records of past fluid seepage. Rare earth element (REE) concentrations in seep carbonates have been used to trace fluid sources and provide information on associated biogeochemical processes at cold seeps. The REE concentrations of a series of carbonates collected from cold seeps in the southwestern Dongsha area of the northern South China Sea are analyzed in this study. The total REE contents (ΣREE) of the seep carbonates analyzed show a wide variation from 17 ppm to 523 ppm with an average ΣREE value of 54 ppm, which are higher than the typical marine carbonate values of ∼28 ppm commonly reported and also higher than those of the carbonates from other cold seep areas. A positive correlation between Fe–Mn content and ΣREE was observed. These results suggest that the seep carbonates of this study were primarily controlled by the methane-derived fluid from which they precipitated. The Fe-rich dolomite and siderite, which are the main components of the carbonates, are responsible for the enrichment of the REE. A slight positive Ce anomaly observed in the shale-normalized REE patterns of the studied seep carbonates suggests that they formed in anoxic conditions, and the correlations between Ce/Ce* and La_N/Sm_N, Ce/Ce* and Dy_N/Sm_N, Ce/Ce* and ΣREE further reveal that the REE characteristics of most seep carbonate samples preserve the original redox conditions in which they precipitated and late diagenesis has had little effect on the REE. However, the REE characteristics of sub-samples DS2-2B, DS1-6A and DS1-7A are very different from those of the other sub-samples, indicating a greater impact of late diagenesis and post-oxidation favored REE enrichment.     

湖泊自生碳酸盐含量环境记录

湖泊沉积物碳酸盐含量TCC的变化可反映环境或气候信息.TCC值的变化主要反映干旱和湿润的变化,而与气温变化对应关系不明显,TCC高值可能分别对应暖干、冷干和暖湿环境;这取决于气温和水分对TCC的综合影响程度.碳酸盐一般与细粒沉积物对应的关系可能只反映与搬运条件有关,而与水位高低无关;不同类型的碳酸盐矿物及其饱和指数可能影响TCC与干湿的对应关系;构造也可以影响TCC变化.对于一个钻孔岩芯不同层位而言,TCC的指示意义可能发生变化.     

礼乐盆地碳酸盐岩时空分布特征及构造意义

对碳酸盐岩(台地与生物礁)的研究具有重要的油气地质意义和科学价值。渐新世以来, 礼乐盆地及周缘开始了大规模的碳酸盐建造, 至今还有一定规模生物礁持续发育。文章通过拖网约束、井震对比和地震相类比方法对礼乐盆地周缘碳酸盐岩的发育特征、构造背景和时空分布规律进行系统研究。结果表明, 礼乐盆地主要发育孤立、前隆、掀斜断块型台地及生物礁。碳酸盐岩时空发育特征为: 1) 渐新世—早中新世以构造前隆和掀斜断块控制的开阔台地为主, 生物礁零星发育; 2) 早中新世—中中新世表现为大量孤立台地和生物礁; 3) 中中新世之后, 发生台地和礁的淹没, 盆地内主要发育点礁。结合构造背景和重磁特征分析表明, 古隆起、掀斜断块、前隆迁移和岩浆活动为控制礼乐盆地不同时期碳酸盐岩发育的主要构造要素。现今礼乐盆地及周缘大量生长的珊瑚礁, 主要发育在上新世—更新世岩浆活动形成的海山之上。     

日本海西部大陆坡自生碳酸盐的特征与成因

对日本海西部大陆坡沉积物柱状样中的自生碳酸盐样品进行了X射线衍射、扫描电镜、地球化学和碳氧同位素组成的系统研究。X射线衍射和扫描电镜分析结果表明,碳酸盐主要组成矿物为颗粒状自生高镁方解石微晶,放射状自生文石微晶仅在一个层位出现。结合碳酸盐的地球化学组成,认为研究区碳酸盐来自于富Ca2+、Mg2+和HCO3-流体的沉淀。中度亏损的13C(-33.85‰～-39.53‰)表明碳来自于甲烷的厌氧氧化,同时,这也是研究区海底存在甲烷冷泉的重要证据。重氧同位素比值(5.28‰～5.31‰)则指示着富18O流体来源,而该流体应源于天然气水合物的分解。综上可知,研究区碳酸盐来自于研究区甲烷冷泉上升流的沉淀,指示着海底更深处天然气水合物的存在与分解。     

南海北部冷泉碳酸盐岩层状结构及其地质意义

通过对南海北部冷泉碳酸盐岩的结构进行研究,发现了3种不同的层状结构:结核状碳酸盐岩的微纹层和烟囱状碳酸盐岩平行及垂直烟囱壁的层。不同层的微结构、化学成分、矿物等方面的研究结果表明:结核状碳酸盐岩层的各个微纹层在结晶程度、矿物形态、孔隙度等方面不同,但化学成分变化不大;对于烟囱状碳酸盐岩,与烟囱壁平行的内外层之间矿物、成岩程度等不同,垂直烟囱壁的不同层之间碳酸盐矿物含量不同。碳酸盐岩不同的层状结构是其形成时地质、物理、化学和生物等信息的反映,对于恢复其形成时的古环境具有重要意义。     

Les carbonates associés à la macrofaune des sables fins littoraux en Méditerranée nord-occidentale

The carbonates associated with the macrofauna of shallow fine sands have been evaluated at six stations located at five different sites on the French Mediterranean coast. The carbonate content of forty species or zoological groups has been estimated. At each station the mean calcimass has been calculated during a year-long cycle, showing the participation of the different zoological groups, mainly molluscs and echinoderms. The comparison of calcimass and associated biomass shows that CaCO₃/AFDW ratio fluctuates between 1.6 to 19.3. These values are similar to those obtained in some rocky bottom communities. Calcimass values usually largely exceed biomass ones; therefore the carbon linked to carbonates cannot be excluded from the carbon balance including macrofauna, which are usually represented only by biomass organic matter. According to mean longevity of species providing CaCO₃, the annual carbonate production by macrobenthos in Mediterranean fine sands can be roughly estimated as being one third of its calcimass value.     

琼东南盆地南部早中新世碳酸盐岩台地的地震解释

The southern uplift of the Qiongdongnan Basin is a deepwater area in which no wells have beens drilled. The Miocene-Quaternary strata in the Xisha Islands, which are located 40–100 km to the south, are composed of carbonate reef formations. Paleotectonic and paleogeographic analyses of the basin suggest that the southern uplift experienced favorable geological conditions for the development of carbonate reefs during the Miocene.The high-impedance carbonates have high amplitudes and low frequencies on seismic profiles. The reefs are distributed on paleotectonic highs and are thicker than the contemporaneous formations. A forward model of the variation in carbonate thickness based on lithological and velocity information from wells in nearby regions can simulate the seismic response of carbonates with different thicknesses. We identified several important controlling points for determining the thickness of carbonates from seismic profiles, including the pinchout point,the λ/4 thickness point, and the λ/2 thickness point. We depict a carbonate thickness map in the deepwater area of the southern Qiongdongnan Basin based on this model. The carbonate thickness map, the paleotectonic and paleogeographic background, and the seismic response characteristics of reefs suggest that the carbonates that developed on the southern uplift of the Qiongdongnan Basin during the Miocene were mainly an isolated carbonate platform peninsula and ramp deposits. It consisted of gentle ramp platform, steep slope platform,platform depression, gravity flow, and reef bank facies.     

黄河三角州沿岸及相邻渤海海域碳酸盐研究(英文)

对黄河三角州陆地上河道,河口、潮间带及毗邻渤海海域沉积物中的碳酸盐含量作了分析,在此基础上划分出含量不同的沉积区和亚区。沉积区的划分和其物源有十分良好的对应关系,同一沉积区内的亚区则主要和粒度有关,从而间接反映了水动力环境与生物作用的控制性影响。黄河口沉积物中碳酸盐含量与粒度成反比,其他物源的沉积物则各不相同。黄河口及邻近渤海海域中粘土粒级和碳酸盐含量等值线反映出黄河细粒级沉积物扩散的方向、强度和范围。海洋生源沉积是影响渤海东部和中部沉积物中碳酸盐含量分布的主要因素。     

Geochemical study on the formation of carbonate sediment

It is indeed my great honor to receive the Oceanographical Society of Japan Prize (1986) for my geochemical study on the formation of carbonate sediment. The present article reviews my work on crystal form and minor element distribution in marine biogenic carbonates, which is an important part of my study on the above title. The contents of this article are: (1) outline of my research work, (2) aim of geochemical study on carbonate sediment, (3) basic knowledge for crystal form and minor element distribution in carbonates, (4) influence of chemical constituents dissolved in a parent solution on the polymorphic crystallization of calcium carbonate, (5) crystal form and type of marine biogenic carbonates, (6) synthesis of magnegian calcite in aqueous solution, (7) distribution of minor elements between solution and calcium carbonate precipitate, (8) amount of biogenic carbonate deposition annually in the ocean and (9) role of biogenic carbonate accumulating on the sea floor in the geochemical balance of chemical elements.