黑云杉林大气CO2稳定同位素组成δ13C,δ18O的分析

研究CO₂稳定同位素特征可以揭示光合、呼吸作用等众多信息,从而有助于了解生态系统与环境之间的碳循环过程。利用大气CO₂浓度及其稳定同位素的测定资料,分析稳定同位素比δ¹³C、δ¹⁸O,发现两者具有相似的时空分布特征。主要表现在δ¹³C和δ¹⁸O在冠层内具有明显的垂直变化趋势,冠层上部重同位素含量较高,而底部含量较低。从时间变化看,δ¹³C和δ¹⁸O在午后到日落具有较高的水平,而凌晨,δ¹³C和δ¹⁸O较低。运用Keeling图法分析δ¹³C、δ¹⁸O和CO2浓度的关系,发现δ¹³C值主要受光合和呼吸作用影响,与CO₂浓度的高低密切相关;而δ¹⁸O的变化比较复杂,因为δ¹⁸O除受光合、呼吸强度影响外,还取决于环境空气湿度。     

天目山柳杉树轮δ^13C对华东地区降水序列的重建

对采自天目山的柳杉树轮进行交叉定年后，得到树轮的δ^13C年序列。将δ^13C年序列去除大气CO2的影响，保留其高频振荡部分。利用华东地区部分气象站的降水资料，通过主成份分析，分析了降水与树轮δ^13C之间的关系。考虑滞后效应，利用回归方法重建了过去一百多年来的华东地区不同时段的降水序列，并分析了其变化特征。     

福建三明市春季PM2.5中有机碳、元素碳和水溶性离子特征分析

2014年3月13日至4月20日在福建三明市利用PM_2.5中流量采样器采集大气中PM_2.5膜样品,测定了PM_2.5的质量浓度,并用热/光碳分析仪和离子色谱分析了其组分变化特征.结果表明,三明市观测期间PM_2.5的平均质量浓度为73.61±0.73 μg/m³,有机碳(OC)和元素碳(EC)的平均质量浓度分别为7.26±1.00和5.63±0.27 μg/m³,水溶性离子中SO₄^2-、NH₄⁺、NO₃^-和Na⁺的质量浓度分别为18.08±12.19、4.18±3.56、2.77±1.16和2.73±0.23 μg/m³,总和占总水溶性离子的87.76%.结合后向轨迹分析了福建三明市的污染物来源特征.该地区OC/EC的平均比值小于2,SOC(二次有机碳)生成量很少,主要以一次有机污染物为主,OC、EC与K⁺的相关性分析表明OC、EC与K⁺的来源相近,可以判断OC、EC绝大部分来源是生物质燃烧产生的污染物.在水溶性离子分析中,观测期间NO₃^-/SO₄^2-为0.159±0.02,表明三明市主要以固定源为主,机动车辆等移动源贡献较少.     

山西省城市大气CO2本底筛分对比及特征分析

基于典型城市站太原站2018年3月—2019年2月的大气CO₂在线观测资料，利用筛分法（Meteorological filtering method，MET）和黑碳示踪法（Black Carbon tracer，BC）进行本底/非本底的筛分，得到了本底浓度的变化特征。结果表明，太原大气CO₂浓度季均值冬季最高，夏季最低；不同季节呈"单峰型"日变化特征，日振幅均在26.0×10^-6以上；4个季节CO₂浓度与地面风速存在显著负相关关系；CO₂浓度抬升区域主要受当地工业布局的影响，最大抬升幅度在秋季达17.4×10^-6；使用气象筛分法（MET）得到年均本底浓度为（431.4±19.9）×10^-6，人为排放等对其影响为23.5×10^-6，年振幅比同纬度其它本底站大，为34.5×10^-6；黑碳示踪法（BC）得到冬季季均本底浓度为（445.0±22.9）×10^-6，比MET筛分法得到的季均值高0.8×10^-6，两种筛分法得到的CO₂浓度变化趋势一致。     

江淮之间夏季雨滴谱特征分析

分析了2011—2013年夏季(6—8月)滁州地基雨滴谱观测资料,根据雨强及其随时间的变化将降水分成对流降水和层云降水,分析不同降水类型的雨滴谱特征。结果表明:滁州地区对流降水的质量加权直径D_m和标准化参数lgN_w的平均值分别为1.67 mm和3.91 mm^-1·m^-3,层云降水D_m和lgN_w的平均值分别为1.18 mm和3.57 mm^-1·m^-3,对流降水雨滴平均尺度更大。N_w相比Γ分布参数N₀能更好地反映总数浓度N_t的大小。Γ分布3参数均随雨强的增大而减小,当雨强增长到一定程度时,μ(谱型)和Λ(斜率)趋于常数。研究了μ-Λ关系和Z(反射率因子)-R(雨强)关系。对流降水和层云降水的Z-R关系分别为Z=408R^1.20和Z=301R^1.21。新的Z-R关系和经典Z-R关系(Z=300R^1.40)反演的雨强相比实际观测值均偏小,但新的Z-R关系反演的雨强与实际观测值更接近。     

锡林浩特草原CO2通量特征及其影响因素分析

利用锡林浩特国家气候观象台开路涡度相关系统、辐射土壤观测系统,测得的长期连续通量观测数据,对锡林浩特草原2009—2011年期间的CO₂通量观测特征进行了分析。结果表明:CO₂通量存在明显的年际、季节和日变化特征。3 a中NEE年际变率达到200 g·m^-2,季节变率最大达到460 g·m^-2,日变化幅度生长季最大达到0.25 mg·m^-2·s^-1。通过不同时间尺度碳通量与温度、水分、辐射等环境因子的分析,认为CO₂通量日变化主要受温度和光合有效辐射影响,而季节变化和年变化主要受降水和土壤含水量的影响。降水强度及时间分布是制约牧草CO₂吸收的关键因素,大于15%的土壤含水量有利于促进牧草生长。     

天目山柳杉树轮δ~(13)C对华东地区降水序列的重建

对采自天目山的柳杉树轮进行交叉定年后 ,得到树轮的δ1 3C年序列。将δ1 3C年序列去除大气 CO2 的影响 ,保留其高频振荡部分。利用华东地区部分气象站的降水资料 ,通过主成份分析 ,分析了降水与树轮δ1 3C之间的关系。考虑滞后效应 ,利用回归方法重建了过去一百多年来的华东地区不同时段的降水序列 ,并分析其变化特征。     

三亚地区冬春季大气污染特征观测研究

为了研究海南省三亚地区冬春季大气污染状况,于2011年12月—2013年4月的冬春季节在三亚鹿回头村(监测点位于三亚市郊,三面临海,周围没有工业污染源)开展了大气主要污染物(NO_x、O₃、PM_2.5)的连续监测,利用观测数据对三亚地区冬春季大气污染变化特征进行分析.结果表明:三亚地区大气污染物浓度均低于国家一级标准的浓度值,NO、NO₂、NO_x、O₃、PM_2.5质量浓度的日平均值(平均值±标准差)分别为(2.1±2.2)、(5.2±3.4)、(7.3±3.8)、(59.8±28.4)和(17.5±14.3)μg·m^-3.在污染物的日变化方面,NO_x、PM_2.5呈现典型的双峰型,其峰值分别出现在08:00和17:00,峰谷在13:00;O₃的日变化为单峰型,峰值出现在13:00.通过后向轨迹分析发现,三亚地区大气污染物受局地源排放和外源输送的共同影响,来自陆地的气流易造成污染物的积累,而来自海上的气流则有利于污染物的清除.     

树轮δ13C的角分布及其在气候重建中的应用

利用天目山的两棵柳杉和庐山的一棵冷杉共3个树盘,分析了树轮δ¹³C沿方位的变化。结果表明,树轮在不同方位上的δ¹³C值不同,存在方位角分布,平均最大差异为0.8‰～1.5‰。各方位的δ¹³C年序列间存在较好的相关性,变化趋势基本一致,表明各方位δ¹³C都记录了基本相同的气候信息。δ¹³C的方位差异与其年际差异在量级上大致相当,具有独立的研究意义。通过柳杉一号树轮与气候要素的研究表明,从树轮δ¹³C的角分布中能够提取出更多有气候意义的信息,而且相对于多个方位的平均和全轮均匀采样而言,重建的精度和可靠性有所提高。     

青岛市秋冬季霾期PM1及其含碳组分理化特征及来源研究

对2017年11月1日—2018年1月31日与2018年11月1日—2019年1月31日连续两年青岛市大气PM₁进行监测,获取了PM₁中含碳组分的变化趋势,结合国控站点监测数据和气象条件,分析了秋冬季PM₁来源.结果表明：2017、2018年秋冬季观测期间PM₁日均质量浓度分别为40.58±25.98、42.55±25.05 μg/m³;霾日质量浓度分别为84.71±16.70、81.52±18.39 μg/m³.与2017年相比,2018年同期PM₁质量浓度增长4.85%,霾日下降3.76%.2017年霾日PM₁中OC、EC质量浓度分别为13.67±3.95、3.95±1.02 μg/m³,2018年分别为16.48±6.34、3.34±1.16 μg/m³.与2017年相比,2018年霾日OC质量浓度增长20.56%,EC下降15.44%.2017、2018年霾日SOC质量浓度分别是非霾日的1.28和2.15倍,表明霾污染发生时易发生有机碳二次转化.含碳组分主成分分析均解析出3个因子.因子1解释变量均最大,分别为58.98%、67.14%,其表征含碳组分主要源于生物质燃烧、燃煤、道路扬尘及汽油车尾气等排放源.由后向气流轨迹分析得出,2017、2018年秋冬季气团轨迹多起源于内蒙古,经河北、天津、山东等省市抵达青岛.     

Variations of δ^18 O in Precipitation along Vapor Transport Paths

Three sampling cross sections along the south path starting from the Tropics through the vapor passage in the Yunnan-Guizhou Plateau to the middle-low reaches of the Yangtze River, the north path from West China, via North China, to Japan under the westerlies, and the plateau path from South Asia over the Himalayas to the northern Tibetan Plateau, are set up, based on the IAEA (International Atomic Energy Agency)/WMO global survey network and sampling sites on the Tibetan Plateau. The variations, and the relationship with precipitation and temperature, of the δ^18 O in precipitation along the three cross sections are analyzed and compared. Along the south path, the seasonal differences of mean δ^18 O in precipitation are small at the stations located in the Tropics, but increase markedly from Bangkok towards the north, with the 51so in the rainy season smaller than inthe dry season. The δ^18 O sovalues in precipitation fluctuate on the whole, which shows that there are different vapor sources. Along the north path, the seasonal differences of the mean δ^18 O in precipitation for the stations in the west of Zhengzhou are all greater than in the east of Zhengzhou. During the cold half of the year, the mean δ^18 O in precipitation reaches its minimum at Uriimqi with the lowest temperature due to the wide, cold high pressure over Mongolia, then increases gradually with longitude, and remains at roughly the same level at the stations eastward from Zhengzhou. During the warm half of the year, the δ^18 O values in precipitation are lower in the east than in the west, markedly influenced by the summer monsoon over East Asia. Along the plateau path, the mean δ^18 O values in precipitation in the rainy season are correspondingly high in the southern parts of the Indian subcontinent, and then decrease gradually with latitude. A sharp depletion of the stable isotopic compositions in precipitation takes place due to the very strong rainout of the stable isotopic compositions in vapor in the process of lifting over the southern slope of the Himalayas. The low level of the δ^18 O in precipitation is from Nyalam to the Tanggula Mountains during the rainy season,but δ^18 O increases persistently with increasing latitude from the Tanggula Mountains to the northern Tibetan Plateau because of the replenishment of vapor with relatively heavy stable isotopic compositions originating from the inner plateau. During the dry season, the mean δ^18 O values in precipitation basically decrease along the path from the south to the north. Generally, the mean δ^18 O in precipitation during the rainy season is lower than in the dry season for the regions controlled by the monsoons over South Asia or the plateau, and opposite for the regions without a monsoon or with a weak monsoon.     

Cape Grim isotope measurements — A preliminary assessment

Measurements of the stable carbon isotope ratio in atmospheric CO₂ permit a distinction between variations resulting from biospheric and oceanic exchange. In situ extraction of CO₂ from Cape Grim air (41°S) for isotopic analysis commenced in 1977; however difficulties with technique reliability were experienced until 1982. Since 1982, 2.6 years of relatively consistent values have accumulated.For a preliminary assessment of the latter data, estimates of the isotopic behaviour from the global transport and inter-reservoir exchange model of Pearman and Hyson (1985) have been employed. The assessment demonstrates the precision requirements of a carbon isotope monitoring program and the relevance of the isotope measurements as a constraint on parameterization of the model.Clear evidence of the changes due to fossil fuel combustion is seen in the year-to-year differences in ¹³C, with the mean and standard error of the overall trend being –0.025±0.005 yr^-1. A significant seasonal variation in ¹³C is apparent, despite considerable inter-annual variability possibly associated with the 1982/83 ENSO phenomena. The average peak-to-peak amplitude is 0.055±0.014 with a maximum on day 85±15 (approx. 26 March).There is some evidence for a complex seasonal inter-relationship between concentration and isotope ratio, both in the Cape Grim data and in Mook et al. (1983) South Pole data, but with marked differences between the stations, and with both different from the model estimates.In particular, the Cape Grim results suggest that exchange with Southern Hemisphere biosphere is the main contributor to the seasonal variation in isotope ratio at this latitude.     

Humidity Effect and Its Influence on the Seasonal Distribution of Precipitation δ18O in Monsoon Regions

The humidity effect, namely the markedly positive correlation between the stable isotopic ratio in precipitation and the dew-point deficit △Td in the atmosphere, is put forward firstly and the relationships between the δ18O in precipitation and △Td are analyzed for the Urumqi and Kunming stations, which have completely different climatic characteristics. Although the seasonal variations in δ18O and △Td exhibit differences between the two stations, their humidity effect is notable. The correlation coefficient and its confidence level of the humidity effect are higher than those of the amount effect at Kunming, showing the marked influence of the humidity conditions in the atmosphere on stable isotopes in precipitation.Using a kinetic model for stable isotopic fractionation, and according to the seasonal distribution of meanmonthly temperature at 500 hPa at Kunming, the variations of the δ18O in condensate in cloud aresimulated. A very good agreement between the seasonal variations of the simulated mean δ18O and themean monthly temperature at 500 hPa is obtained, showing that the oxygen stable isotope in condensateof cloud experiences a temperature effect. Such a result is markedly different from the amount effect atthe ground. Based on the simulations of seasonal variations of δ18O in falling raindrops, it can be foundthat, in the dry season from November to April, the increasing trend with falling distance of δ18O in fallingraindrops corresponds remarkably to the great ATd, showing a strong evaporation enrichment function infalling raindrops; however, in the wet season from May to October, the δ18O in falling raindrops displaysan unapparent increase corresponding to the small ATd, except in May. By comparing the simulated meanδ18O at the ground with the actual monthly δ18O in precipitation, we see distinctly that the two monthlyδ18O variations agree very well. On average, the δ18O values are relatively lower because of the highlymoist air, heavy rainfall, small △Td and weak evaporation enrichment function of stable isotopes in thefalling raindrops, under the influence of vapor from the oceans; but they are relatively higher because of the dry air, light rainfall, great △Td and strong evaporation enrichment function in falling raindrops, under the control of the continental air mass. Therefore, the δ18O in precipitation at Kunming can be used to indicate the humidity situation in the atmosphere to a certain degree, and thus indicate the intensity of the precipitation and the strength of the monsoon indirectly. The humidity effect changes not only the magnitude of the stable isotopic ratio in precipitation but also its seasonal distribution due to its influence on the strength of the evaporation enrichment of stable isotopes in falling raindrops and the direction of the net mass transfer of stable isotopes between the atmosphere and the raindrops. Consequently, it is inferred that the humidity effect is probably one of the foremost causes generating the amount effect.     

Spatial and temporal variation of rainwater stable isotopes in Egypt and the east Mediterranean

Summary ?By analyzing normalized variables, it was found that the latitudinal secular variations of the rainwater deuterium fractionation ratio δ²H, oxygen fractionation ratio δ¹⁸O, vapor pressure, and surface temperature were almost non-linear, occurred in parallel, and decreased with latitude. The rate of depletion around the equator is asymmetric and smaller to the south of 45° S than to the north of 45° N. In the east Mediterranean, the rate of change of δ¹⁸O with height was found to be −.2‰ per 100 m and that of δ²H is comparable with the dry lapse rate in the atmosphere. Analysis of the annual time series of δ²H at Alexandria has indicated that variations show sinusoidal waveform with a major cycle of two years that accounts for 68% of the total variance. Although the quasi-biannual cycle in the atmosphere has small amplitude in the lower layers of the atmosphere at East Mediterranean latitudes, the major cycle in annual series of δ²H or δ¹⁸O may be linked to the quasi-biannual oscillation in the atmosphere. It was also found that the first three Empirical Orthogonal Functions (EOF) account for 72% of the seasonal variation of δ²H and share 68% of the seasonal variation of δ¹⁸O. Share of variances of monthly EOF in the months of the year indicate that the main underlying factors that cause fractionation processes for δ²H and δ¹⁸O are similar across the east Mediterranean especially in late winter and early spring. Received May 13, 2002; revised July 8, 2002; accepted August 6, 2002     

近60年中国日降水量分区及气候特征

根据中国国家级地面气象站均一化降水数据集,使用1956~2015年512个台站的日降水量资料,通过旋转经验正交函数（REOF）得到七个分区。比较了各分区平均日降水量的年内变化和多年倾向率差异:我国偏南分区的小雨日数减少,大雨、暴雨日数、日降水量的区域年均值增加;偏北分区的小雨、大雨、暴雨日数、降水量年均值为递减;长江中下游区（东北区）日降水量、小雨日数、暴雨日数的年均值的近60年倾向率分别是0.0071 mm a-1（-0.0010 mm a-1）、-0.0729 d a-1（-0.0615 d a-1）、0.0132 d a-1（-0.0007 d a-1）。100°E以西地区:小雨、中雨日数在增加,无雨日数显著减少,日降水量的年均值呈递增特点。通过自相关函数和小波功率谱估计,揭示了七个分区的日降水量年均值普遍存在2~4 a周期震荡。使用NCEP/NCAR月均再分析资料,以区域日降水量年均值为指数得到500 hPa、700 hPa、850 hPa回归风系数场、旱涝年整场水汽通量和水汽通量散度差异场相结合分析,结果表明:"东高西低,南高北低"环流型和区域降水有密切关系,水汽差异场是上述环流特点的反映。     

Atmospheric CO along the Trans-Siberian Railroad and River Ob: source identification using isotope analysis

The concentration, radiocarbon (¹⁴C) and stable isotope (¹³C and ¹⁸O) content of CO have been determined in air samples collected across Russia (about 8,500 km) and along the Ob river during the summer of 1999 to study the CO sources and sinks. An instrumented carriage on the Trans-Siberian railway and a boat on the river Ob were used as atmospheric measurement platforms. In general, CO mixing ratios, CO stable isotope ratios, as well as the abundances of ¹⁴CO over West Siberia were similar to those found at remote northern hemispheric baseline monitoring stations. Identified sources of CO along the Ob appear to be connected to methane oxidation based on an inferred δ¹³C_source = −36.8 ± 0.6‰, while the value for δ¹⁸O_source = 9.0 ± 1.6‰ identifies it as burning. Thus flaring in the oil and gas production can be supposed to be a source. The extreme ¹³C depletion and concomitant ¹⁸O enrichment for two of the boat samples unambiguously indicates contamination by CO from combustion of natural gas (inferred values δ¹³C_source = −40.3‰ and δ¹⁸O_source = 17.5‰). For these two samples, that have strongly elevated ¹⁴CO concentrations, the industrial area near Tomsk is identified as a source area using meteorological calculations. Along the Trans-Siberian Railroad background CO was to various degrees contaminated with CO from methane combustion (δ¹³C_source = −35.7 ± 6.2‰ and δ¹⁸O_source = 10.3 ± 1.8‰). The impact of industrial burning was discernable in the vicinity of Perm-Kungur.     

An investigation of the controls on Irish precipitation δ18O values on monthly and event timescales

This two-year study investigates the relative influence of meteorological variables (precipitation amount and temperature), atmospheric circulation, air mass history, and moisture source region on Irish precipitation oxygen isotopes (δ¹⁸O_p) on event and monthly timescales. Single predictor correlations reveal that on the event scale, 20% of δ¹⁸O_p variability is attributable to the amount effect and 7% to the temperature effect while on the monthly timescale the North Atlantic Oscillation accounts for up to 20% of δ¹⁸O_p variability and the amount and temperature effects are not significant. In comparison, multivariate linear regression reveals that the interaction of temperature and precipitation amount explains up to 40% of δ¹⁸O_p variance at event and monthly timescales. Five-day kinematic back trajectories suggest that the amount-weighted mean δ¹⁸O_p value of southerly- and northerly-derived events are lower by 2‰ relative to events derived from the west. Because air mass history and atmospheric circulation appear to influence δ¹⁸O_p in Ireland, Irish paleo-δ¹⁸O_p proxy records are best interpreted as reflecting a combination of parameters, not just paleotemperature or paleorainfall.     

冰芯中所记录的气候异常与ENSO事件

通过对３００ＢＰ以来记录于中国古里雅冰芯中的降水和δ１８Ｏ等环境气候信息记录及ＥＮ－ＳＯ事件的分析,发现ＥＮＳＯ的发生与古里雅降水异常显著相关。在厄尔尼诺年,古里雅冰芯中的降水与δ１８Ｏ均负异常,即ＥＮＳＯ与古里雅的降水偏少,温度偏低相联系。     

NUMERICAL SIMULATION OF THE SEASONAL VARIATION OF TROPOSPHERIC OZONE OVER CHINA

An updated version of the Regional Acid Deposition Model(RADM)driven by meteorologicalfields derived from Chinese Regional Climate Model(CRegCM)is used to simulate seasonal variationof tropospheric ozone over the eastern China.The results show that:(1)Peak O_3 concentration moves from south China to north China responding to the changing ofsolar perpendicular incidence point from south to north.When solar perpendicular incidence pointmoves from north to south,so does the peak O_3 concentration.(2)In the eastern China.the highest O_3 month-average concentration appears in July.thelowest in January and the medium in April and October.The pattern mainly depends on the solarradiation,the concentration of O_3 precursors NO_x and NMHC and the ratio of NMHC/NO_x.(3)Daily variations of O_3 over the eastern China are clear.Namely,O_3 concentrations rise withthe sun rising and the maximums appear at noon.then O_3 concentrations decrease.The highest dailyvariation range of O_3 appears in summer(40×10~(-9) in volume fraction)and the lowest in winter(20×10~(-9) in volume fraction).(4)Daily variations of O_3 over the western China are not clear.The daily variation range of O_3 isless than 10×10~(-9) in volume fraction.     

A stable oxygen, but not carbon, isotope chronology of Callitris columellaris reflects recent climate change in north-western Australia

We investigated the dendroclimatic potential of stable carbon (δ¹³C) and oxygen (δ¹⁸O) abundances in tree rings of Callitris columellaris F. Muell. Tree-ring chronologies were constructed from the central Pilbara, north-western Australia and span 1919–1999. Variation in δ¹⁸O was more strongly related to climate than δ¹³C; ecological and physiological factors may have dampened the climate signal in the δ¹³C chronology. Tree-ring δ¹⁸O was most strongly correlated with relative humidity (RH) and rainfall (r = −0.36 and −0.39) of the wettest months of the summer period, January and February. The correlation with RH reflects its effect on evaporative enrichment of leaf water. However, tree-ring δ¹⁸O may also partly reflect the variability in ¹⁸O signatures of rainfall, which are influenced by the amount of rainfall and atmospheric humidity. From the δ¹⁸O chronology, we inferred that from 1919 to 1955 summers were relatively dry and warm, but since 1955, summers in the Pilbara region have become increasingly cooler and more humid. Since 1980, conditions have been the wettest and coolest of the last 80 years. These inferred changes in climate correspond to a measured increase in rainfall since 1980 in north-western Australia associated with a greater intensity of tropical cyclones. We conclude that δ¹⁸O abundances in tree rings of C. columellaris have significant potential for reconstructing the climate of semi-arid Australia, a region for which observational climate records are sparse.