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1.
杭州城区土壤的磁性与磁性矿物学及其环境意义   总被引:18,自引:0,他引:18       下载免费PDF全文
对杭州城区四个不同功能区块土壤进行了系统的环境磁学测定,结果表明城市土壤的磁化率平均值为128×10-8m3·kg-1,频率磁化率平均值3.6%(样品数=182),城市土壤呈现明显的磁性增强. 城市土壤的磁化率与频率磁化率呈极显著指数负相关,表明城市土壤磁性增强明显区别于自然成土过程引起的以超顺磁性(SP)颗粒为主的表土磁性增强机理. 统计分析表明,城市土壤磁化率与软剩磁和饱和等温剩磁(SIRM)呈显著直线正相关,说明亚铁磁性矿物是城市土壤剩余磁性的主要载体. 综合等温剩磁获得曲线、热磁曲线、磁滞回线等岩石磁学测定和SEM/EDX分析,城市土壤的磁性矿物以磁铁矿和赤铁矿为主,磁性矿物以假单畴-多畴(PSD-MD)颗粒存在,粒度明显大于成土过程形成的磁性颗粒,这些磁性颗粒主要来自燃料燃烧、汽车尾气等环境污染物. 因此,城市土壤磁测可作为城市土壤污染监测、污染空间分布和污染物来源判断的新手段.  相似文献   

2.
西安市道路灰尘磁学特征及其对环境的响应   总被引:5,自引:0,他引:5       下载免费PDF全文
西安市道路表面灰尘样品的环境磁学研究显示磁化率(χ)、非磁滞磁化率(χARM)以及饱和等温剩磁(SIRM)均比较高,表明样品中磁性矿物含量较高.其中磁化率(χ)主要受人类活动强度影响,而非磁滞磁化率(χARM)及饱和等温剩磁(SIRM)则由人为活动强度和磁性矿物种类共同决定.κ-T曲线以及等温剩磁(IRM)获得曲线显示样品中磁铁矿和磁赤铁矿等亚铁磁性矿物占主导,并可能含有少量的单质铁,其相对含量与人类活动种类有关:与单纯的交通排放及冶金活动相比,密集的人群流动可带来更多的单质铁矿物.磁畴图谱显示磁性矿物粒径变化不大,以准单畴及多畴颗粒等粗颗粒为主,明显大于成土作用形成的磁性颗粒.综合磁性矿物含量种类以及粒径可辨别污染及污染来源,提供污染监测的磁学手段,并初步进行污染来源划分.  相似文献   

3.
钢铁厂周围不同污染介质的磁学性质及环境意义   总被引:8,自引:2,他引:6       下载免费PDF全文
为了通过钢铁厂周围不同污染介质的磁学性质研究,实现对环境污染的有效监测,本文系统地采集了河北兴隆和湖南娄底两个钢铁厂周围的树皮和草表面的飞灰、土壤及不同树种的年轮样品.其中前三者用来反映现今污染源,而树木年轮用来追踪长时间尺度的污染历史.通过综合岩石磁学实验分析(包括热磁曲线、磁滞性质和低温实验等)、电子扫描电镜(SEM)和能谱(EDX)以及X射线衍射(XRD)分析,发现钢铁厂周围现今污染源中的主要粗颗粒磁性矿物为磁铁矿、赤铁矿和纯铁.其中8~50 μm的球形磁铁矿颗粒和呈棱角状的铁颗粒是钢铁厂污染物的特征磁性矿物.对不同树种来说,其中香樟树和枫树树木年轮中的磁性矿物以顺磁性物质为主, 不适合用于环境磁学的污染监测.而柳树中的磁性矿物(主要为磁铁矿)与现今污染源的磁性矿物相符.以上研究表明多参数岩石磁学测量并辅以微观分析等手段,可以精确地提取磁性矿物的种类及粒度特征, 判别重工业区污染源,为应用磁学方法来监测环境污染提供依据.  相似文献   

4.
应用环境磁学方法研究了2008年奥运会前后北京市朝阳区大气降尘及对照点表土样品的磁学特征.结果表明,所有样品中载磁矿物主要为低矫顽力的亚铁磁性矿物(主要为磁铁矿).但大气降尘样品的磁性颗粒粒度较表土偏粗;磁性矿物含量高于表土样品,大气降尘除来自于自然源外,更多为来自于人为因素的结果.大气降尘磁化率与空气污染物浓度随时间...  相似文献   

5.
对甘肃西山坪遗址剖面样品进行磁化率、频率磁化率、热磁分析、非磁滞剩磁和等温剩磁等一系列岩石磁学实验测试,分析环境磁学参数特征变化,试图探讨西山坪遗址研究意义,为今后深入研究该沉积序列蕴含的古环境记录提供了岩石磁学基础.结果表明:西山坪遗址剖面沉积物中磁性矿物主要以低矫顽力的磁铁矿和磁赤铁矿为主,高矫顽力磁性矿物赤铁矿含量极其有限,越向剖面表层,强磁性矿物含量逐渐增加.磁性矿物颗粒表现出黄土的典型特征,以单畴、准单畴为主,含有一定量的超顺磁颗粒,颗粒度越向剖面表层越细.从物源上看,遗址沉积物主要来自近源的黄土风尘堆积,主要是风成堆积,并混合大量人类活动信息,给今后综合研究岩石磁学与人类活动特征的关系有一定借鉴意义.  相似文献   

6.
本文对黄土高原和天山黄土区表土进行系统的岩石磁学和粒度测试分析,探讨了表土磁性特征及其环境意义,结果表明表土中的强磁性矿物均为磁铁矿和磁赤铁矿,弱磁性矿物为赤铁矿和纤铁矿或针铁矿,黄土高原黄土地层中的磁赤铁矿至少有部分属于风积成因.黄土高原表土中磁化率与频率磁化率呈良好的正相关,气候作用是主导黄土高原表上磁化率增强的主...  相似文献   

7.
长江口潮滩沉积物的磁学性质及其与粒度的关系   总被引:43,自引:0,他引:43  
对长江口潮滩沉积物的环境磁学研究表明, 沉积物磁性特征由多畴/假单畴磁铁矿所主导. 磁铁矿除陆源碎屑成因外, 在磁性最强的石洞口排污口附近沉积物中出现了球形磁性颗粒, 系工业污染的产物. 粒度是影响长江口潮滩沉积物磁性特征的重要因素, 磁化率、饱和等温剩磁与8~16 mm粒级含量呈正相关, 而非磁滞剩磁磁化率等指示细颗粒亚铁磁性矿物的参数与<4 mm乃至<32 mm粒级组分高度正相关. 这一特征表明, 在将磁化率作为污染物含量代用指标时, 需考虑粒度造成的磁化率波动的可能影响, 非磁滞剩磁磁化率则可以作为沉积物细粒级组分的代用指标, 并应用于污染物含量的粒度校正.  相似文献   

8.
对苏北盆地兴化1#钻孔岩心沉积物进行了质量磁化率、频率磁化率、变化曲线、等温剩磁和磁滞回线等参数的测试分析,结果表明,粘土质沉积物中的主要载磁矿物为磁铁矿和赤铁矿;砂质沉积物中的磁性矿物除了磁铁矿和赤铁矿外,还含有少量的磁赤铁矿和针铁矿.针铁矿普遍存在于钻孔下部的样品中.整个钻孔沉积物中的磁性矿物颗粒都是介于单畴和多畴之间的准单畴颗粒,但粘土质沉积物中的磁性矿物颗粒更趋近于单畴颗粒,而砂质沉积物中的磁性矿物颗粒更趋近于多畴.根据不同的磁性矿物组合特征,选择合理的温度和磁场强度区间对古地磁退磁结果进行分析,得到沉积物可靠的特征剩磁方向,为古地磁年代学提供依据.  相似文献   

9.
典型沙漠绿洲城市表土磁性特征及环境指示意义   总被引:8,自引:0,他引:8  
选取典型沙漠绿洲城市(乌海、石嘴山、银川)表土为研究对象,对其环境磁学性质、土壤质地与重金属含量分布进行系统研究.结果表明,乌海市和石嘴山市表土为典型砂土,银川市为砂壤土.三个城市表土样品均以较粗的MD-PSD颗粒的亚铁磁性矿物(磁铁矿)为主导,磁化率均值分别为152×10-8、104×10-8和117×10-8 m3·kg-1.乌海市表土磁性矿物含量和磁性颗粒大小都显著高于石嘴山和银川市.重金属(Cr、Cu、Pb、Zn、Fe)的污染负荷指数(PLI)均显示,三个城市表土均存在轻度污染特征.同时磁化率和污染负荷指数在非工业区表现出点状高值分布,在工业区表现为面状高值分布特征.乌海市表土磁参数与重金属的相关系数显著高于石嘴山和银川,表明磁参数对于污染来源单一地区的污染程度评估更具优势.尽管三个城市表土磁学性质存在较大差异,但其磁化率均随污染负荷指数的增加呈现相同程度的递增.磁化率可以作为宁夏平原地区表土重金属污染程度评估的统一有效的代用指标.  相似文献   

10.
北京密云水库表层沉积物磁性矿物的鉴别   总被引:1,自引:0,他引:1       下载免费PDF全文
本文对密云水库表层沉积物中的磁性矿物进行了岩石磁学和透射电子显微学的综合研究.本实验建立的磁选方法实现将70%~85%左右的磁性矿物从沉积物中分离出来.岩石磁学研究表明,密云水库沉积物中的磁性矿物以多畴和单畴磁铁矿为主,还含有少量高矫顽力弱磁性载磁矿物(可能为赤铁矿).对磁选矿物的透射电镜观测表明,样品中部分单畴磁铁矿具有纳米尺寸和化学纯度高等特点,为拉长的立方-八面体磁铁矿,是趋磁细菌产生的化石磁小体;多畴磁铁矿多数具有微米尺寸,形状不规则,为碎屑成因;超顺磁磁铁矿粒径约为5~20nm,且含硅、铝等元素,可能为自生成因.研究结果表明,岩石磁学和透射电子显微学的综合应用可以更全面、准确地分析沉积物中磁性矿物的成分、含量、粒径和化学成分等信息,为环境磁学、生物地磁学和古地磁学研究提供依据.  相似文献   

11.
The concentrations of four selected heavy metals (Pb, Zn, Ni and Cr) were measured on 167 topsoil samples collected from the city of Xuzhou, China via inductively coupled plasma mass spectroscopy (ICP-MS). It was found that Pb and Zn were principally derived from anthropogenic inputs whereas Cr and Ni distributions were mainly controlled by parent materials. The spatial distribution patterns of Pb, and Zn were similar to that from low field magnetic susceptibility (χlf), suggesting interaction among them. Two threshold values for magnetic susceptibility and frequency-dependent susceptibility percentage (χfd) were applied to discriminate between polluted and unpolluted samples according to their magnetic susceptibility, resulting in 109 samples populating the “polluted” subset. The Pb and Zn concentrations of the “polluted” subset were statistically significantly higher than those measured in the “unpolluted” one. The heavy metal concentrations were also investigated varying the magnetic susceptibility thresholds to change the “polluted” subset.  相似文献   

12.
Soil magnetometry was used for detailed mapping of immission load over the territory of the Giant Mountains National Park. This project is a continuation of our previous study, which suggested that low-field magnetic susceptibility of topsoils in this region is controlled by atmospherically deposited anthropogenic ferromagnetic particles. In the present study, we have compiled a map of topsoil magnetic susceptibility on the basis of measurements on more than 460 sites. Elevated values of magnetic susceptibility can be attributed to local sources of pollution, located within and at the margins of the Park. We have identified a group of heavy metals of anthropogenic origin, present in the topsoils, and found a positive correlation between the concentration of Pb and magnetic susceptibility. Our results prove that magnetic mapping is a sensitive, fast and robust method, which can be advantageously applied to regions with relatively low degree of pollution, such as the Giant Mountains National Park.  相似文献   

13.
Expansion of a Plane Wave into Gaussian Beams   总被引:6,自引:0,他引:6  
Magnetic susceptibility measurements on topsoils have often been used during the last few years to detect anthropogenic pollution. In most cases, a Bartington susceptibility meter for field measurements was used. However, up to now, no standard procedure has been developed for carrying out such investigations. The purpose of our study was to test the compatibility of different set-ups of instruments used for this purpose and the possible influences of subjective (human) factors. Field magnetic susceptibility measurements, carried out with four different Bartington MS2D instruments in strictly defined positions, are very consistent both for low and high values. The correlation coefficient between the magnetic susceptibility values recorded with different Bartington MS2D probes reached 97–98%. A test area was mapped independently by two groups, without any restrictions concerning the choice and distribution of the measured points, but respecting a few standard conditions (e.g., measuring at a distance from tree trunks; on the flattest place possible; recording between 10–30 values per point). The resulting susceptibility maps show the same general features in both cases, suggesting that the measuring strategy applied is suitable for topsoil magnetic screening. The methodology proposed can be used to map magnetic susceptibility on a larger scale—for example Europe—providing large sets of representative data and eliminating border-transition biases and human errors.  相似文献   

14.
This study characterized the magnetic property and levels of heavy metals of the topsoils near a cement plant. The concentrations of five selected heavy metals (Pb, Cu, Zn and Cd) were measured on 32 topsoil samples (0–20 cm) collected near a cement plant via inductively coupled plasma/mass spectroscopy (ICP-MS). The orders of enrichment factors (EF), on average, were Cd (7.3) > Cu (3) > Zn (2.9) > Pb (2.1), respectively. A self-organizing map (SOM) was applied to the concentrations of heavy metals for “correlation hunting”. Mineral magnetic concentration parameters, such as the specific magnetic susceptibility (χ), susceptibility of anhysteretic remanent magnetization (χARM), saturation isothermal remanent magnetization (SIRM), together with interparametric ratios (such as IRM 100mT/SIRM, SIRM/χ, χARM/SIRM) show that ferrimagnetic, superparamagnetic (SP) and multi-domain (MD) minerals dominated the soils. The results of correlation analysis indicate that copper showed a significant correlation with χ, χARM and SIRM but such a relationship with χ, χARM and SIRM was only weakly identified for Zn, Cd and Pb.  相似文献   

15.
A new rapid method for identifying relative grain size variations in magnetic involves the parameter anhysteretic susceptibility (χARM, i.e. specific ARM obtained in a 1 Oe steady field), which is particularly sensitive to the single domain (SD) and small pseudo-single domain (PSD) grains of the finer magnetite fraction. A second parameter, low-field susceptibility (χ), is relatively more sensitive to the coarser magnetite fraction (larger PSD and smaller multidomain (MD) grains). We can then obtain a measure of the ratio of coarse- to fine-grain magnetite for large numbers of samples by plotting χARversusχ. A simple idealized model based on sized magnetite samples is proposed to explain the use of the χARMversusχ plot for detecting relative grain-size changes in the magnetic content of natural materials. The sediments of three lakes that contain magnetite or a similar magnetic carrier and have a wide range of values of χARM and χ are used to test the model.The model is used to interpret the magnetic variations observed, and the interpretations are supported by high-field hysteresis measurements of the same sediments. The combination of the high-field hysteresis method of Day et al. [1] and the χARM vs. χ method is a powerful technique allowing the rapid identification of both the relative grain size and domain state for large numbers of samples containing magnetite. The χARMvs.χ method should be used as an intial means of identifying distinct groups of samples.The high-field hysteresis method should then be applied to a few representative samples from each group to confirm the initial interpretation.  相似文献   

16.
李春梅  王红亚 《湖泊科学》2012,24(4):615-622
对贵州省麦岗水库沉积物环境磁性特征的研究表明,亚铁磁性矿物主导了沉积物矿物磁性特征,但同时也存在反铁磁性矿物等其他矿物,超顺磁颗粒在沉积物中广泛存在.在所选矿物磁性参数中,χlf、χfd、SOFT与粒度不相关;χARM、SIRM、F300与粒度相关,但相关系数不高;χARM/χlf、χARM/SIRM和粒度显著相关,可以作为粒度的代用指标.研究结果显示,磁性参数确实可以作为粒度的代用指标.但对比研究表明,在不同沉积环境,甚至相似沉积环境的沉积物中,矿物磁性参数和粒度的关系可能不同,在特定沉积环境中,利用磁性参数作为粒度的代用指标应该在充分研究的基础上进行,使研究结果更为可靠.  相似文献   

17.
Pitambar  Gautam  Ulrich  Blaha  Erwin  Appel 《Island Arc》2005,14(4):424-435
Abstract Soil profiles of the Kathmandu urban area exhibit significant variations in magnetic susceptibility (χ) and saturation isothermal remanence (SIRM), which can be used to discriminate environmental pollution. Magnetic susceptibility can be used to delineate soil intervals by depth into normal (< 10?7 m3/kg), moderately enhanced (10?7–< 10?6 m3/kg) and highly enhanced (≥ 10?6 m3/kg). Soils far from roads and industrial sites commonly fall into the ‘normal’ category. Close to a road corridor, soils at depths of several centimeters have the highest χ, which remains high within the upper 20 cm interval, and decreases with depth through ‘moderately magnetic’ to ‘normal’ at approximately 30–40 cm. Soils in the upper parts of profiles in urban recreational parks have moderate χ. Soil SIRM has three components of distinct median acquisition fields (B1/2): soft (30–50 mT, magnetite‐like phase), intermediate (120–180 mT, probably maghemite or soft coercivity hematite) and hard (550–600 mT, hematite). Close to the daylight surface, SIRM is dominated by a soft component, implying that urban pollution results in enrichment by a magnetite‐like phase. Atomic absorption spectrometry of soils from several profiles for heavy metals reveals remarkable variability (ratio of maximum to minimum contents) of Cu (16.3), Zn (14.8) and Pb (9.3). At Rani Pokhari, several metals are well correlated with χ, as shown by a linear relationship between the logarithmic values. At Ratna Park, however, both χ and SIRM show significant positive correlation with Zn, Pb and Cu, but poor and even negative correlation with Fe (Mn), Cr, Ni and Co. Such differences result from a variety of geogenic, pedogenic, biogenic and man‐made factors, which vary in time and space. Nevertheless, for soil profiles affected by pollution (basically traffic‐related), χ exhibits a significant linear relationship with a pollution index based on the contents of some urban elements (Cu, Pb, Zn), and therefore it serves as an effective parameter for quantifying the urban pollution.  相似文献   

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