共查询到18条相似文献,搜索用时 140 毫秒
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硫酸盐侵蚀是影响混凝土耐久性的重要因素之一。对于混凝土硫酸盐侵蚀问题的研究具有重要的意义。主要研究了外界环境中硫酸盐对混凝土的侵蚀破坏,从物理硫酸盐侵蚀和化学硫酸盐侵蚀两方面论述了混凝土外部硫酸盐侵蚀的类型及破坏特征,并对外部硫酸盐侵蚀过程中石膏的形成作为膨胀源进行了讨论。 相似文献
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主要研究了外界环境中硫酸盐对混凝土的侵蚀破坏,从物理硫酸盐侵蚀和化学硫酸盐侵蚀两方面论述了混凝土外部硫酸盐侵蚀的类型及破坏特征,并对外部硫酸盐侵蚀过程中石膏的形成作为膨胀源进行了讨论,为混凝土性能的进一步研究提供了技术支持。 相似文献
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普通C40混凝土抗硫酸盐侵蚀性能研究 总被引:2,自引:0,他引:2
硫酸盐侵蚀破坏是一个复杂的物理化学过程,同时也是混凝土化学侵蚀中最广泛和最普通的形式。硫酸根离子与水泥石中一些固相组分发生化学反应,对混凝土结构的破坏通常始于棱角处,进而表面剥落,伴随着着裂缝发育层层推进,极端情况下有可能导致结构崩溃。本文通过普通C40混凝土在5%浓度的硫酸盐溶液中相对较长时间的浸泡,采用抗折强度的剩余来表征其抗蚀性能,并对侵蚀机理进行了初步的探讨,为类似环境下混凝土结构的抗硫酸盐侵蚀性能的研究提供了基础性参考资料。 相似文献
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对水泥、掺CM型抗硫酸盐类侵蚀防腐剂的水泥砂浆、混凝土和钢筋混凝土的防腐蚀进行了试验研究,讨论了CM型抗硫酸盐类侵蚀防腐剂对防止钢筋锈蚀、混凝土防腐蚀的作用;掺CM型抗硫酸盐类侵蚀防腐剂能控制混凝土的腐蚀应力,抵抗化学侵蚀以及物理的作用,提高钢筋混凝土的耐久性. 相似文献
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通过对受硫酸盐侵蚀不同时期的混凝土试件进行剪切试验和微观扫描,分析半浸泡条件下硫酸盐侵蚀对混凝土抗剪强度和破坏模式的影响机制,并与全浸泡条件进行对比。试验结果表明:硫酸盐侵蚀会导致混凝土抗剪强度出现经时退化现象;随着暴露时间的增长,混凝土抗剪强度组件中的黏结组件(黏聚力表征)和剪胀组件(剪胀率表征)均呈现逐渐降低的趋势,与全浸泡条件相比,半浸泡条件下的降幅较小,三种水灰比试件的残余剪胀率分别为0.237(0.38)、0.206(0.45)和0.182(0.52);摩擦组件(内摩擦角表征)在半浸泡条件下呈现非线性降低的变化规律,并没有出现全浸泡条件下的前期摩擦增强现象(2%~6%的内摩擦角增长),9个月时的内摩擦角降幅达24.9%(0.38)、32.8%(0.45)和52.3%(0.52);微观分析表明该现象与其微观侵蚀机理密切相关,与全浸泡条件不同,半浸泡条件下试件以物理结晶型损伤为主;不同的微观侵蚀机理导致试件在受剪力作用时的剪切面破坏模式存在显著差异,全浸泡条件下,侵蚀后试件剪切面的破坏模式以骨料翻滚、剥离和剪切面附近基质挤压滑移等形式为主,而半浸泡条件下,基质开裂和剪胀滑移等形式占据主导。 相似文献
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Sulfate attack is one of several chemical mechanisms of concrete deterioration. Exposure of concrete structures in the sulfate environments may lead to detrimental chemical, microstructural, and physical changes in the concrete matrix, resulting in serious deteriorations and service life reduction. Partial replacement of cement with slag is one of the efficient methods for improving concrete resistance against sulfate attack. In this paper the performance of copper slag contained concrete in sulfate solution is investigated. In this regard, an experimental study including expansion measurements, compressive strength degradation and microstructural analysis were conducted in sulfate solution on concretes made by replacing 0%, 5%, 10% and 15% of cement with copper slag waste. The results of this study emphasized the effectiveness of copper slag replacement in improving the concrete resistance against sulfate attack. 相似文献
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Concrete structures in service may be suffer from sulfate attack, which may lead to the deterioration of both static and dynamic properties of concrete, and therefore jeopardize their performance in earthquake events. To predict the seismic performance of sulfate-damaged concrete structures, the rate-dependent strength, deformation behavior and energy absorption capacity of concrete specimens under sulfate attack were investigated. First, half of the specimens were initially cured under sulfate attack for 4 months and the other half of the specimens were cured in a room environment for comparison. Then axial compressive experiments for concrete specimens with different strain rates were carried out. Experimental results show that sulfate attack had a significant impact on the dynamic properties of concrete. Sulfate attack makes concrete strength more sensitive to strain rate. With increasing strain rates, the peak strain and energy absorption capacity of control and sulfate attacked concrete tend to increase, but they are greatly decreased by disruptive expansion and chemical deterioration induced by sulfate attack. Finally, the failure phenomenon was shown and the damage mechanism of specimens was discussed. 相似文献
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The function of tunnels is degraded due to sulfate ambient, which has spread widely in Western China. The characteristics of tunnel concrete damage, development of cracks, structure deformation, and the safety factor of tunnel liner suffering from sulfate attack are studied in this work using field investigation and laboratory tests. The main damage styles of tunnel lining structure included structure cracking, spalling, leakage filtration, degradation, and corrosion. These indicate that either physical damage by crystal erosion or chemical dissolution damage – or both – may have occurred. They appeared in the liners with weak waterproof ability, poor compaction, and high hydraulic gradient. The crack of the tunnel liner first developed at the vault, and there were more cracks at the vault than in other places when the load was high. Crack width and structure deformation increased with load and erosion time as exponential functions, whereas the safety factor was reduced as a negative exponential function. 相似文献
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对透水型生态混凝土在不同浓度硫酸盐干湿循环条件下进行了侵蚀试验,测定了透水型生态混凝土的抗压强度耐蚀系数、相对动弹性模量和质量变化率。并辅以SEM电镜和EDS成分分析,探究了不同浓度硫酸盐侵蚀下试件微观损伤过程和侵蚀破坏规律。试验结果表明:在硫酸盐干湿环境下,透水型生态混凝土的抗压强度耐蚀系数、质量变化率均呈现出先上升再下降的变化趋势。浓度越高,侵蚀破坏的周期越短。通过微观分析发现,试件侵蚀产物多为硫酸钠结晶、钙矾石和石膏以及少量碳化碳硫硅钙石结晶。此外,实验室烘干会加速试件本身和侵蚀结晶碳化,生成碳硫硅钙石结晶。 相似文献
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盐湖、盐渍土地区水位变幅区的混凝土材料劣化问题突出。该文开展不同质量浓度硫酸盐溶液干湿循环侵蚀作用下玄武岩纤维混凝土侵蚀试验、材料力学试验和微观测试,测试分析混凝土试件抗压强度、劈裂抗拉强度、质量变化、相对动弹性模量等参数的演变规律,揭示不同浸泡浓度及龄期下玄武岩纤维混凝土的劣化机制;结合混凝土试件侵蚀后的表观形态和细观结构特征,研究不同侵蚀周期下掺玄武岩纤维混凝土的细观结构演变机理。结果表明:掺入长度6mm玄武岩纤维的混凝土抗压及劈裂抗拉强度增强效果优于长度12mm纤维;硫酸盐和干湿循环侵蚀作用下玄武岩纤维混凝土劣化规律受硫酸盐溶液浓度、干湿循环次数和纤维掺量3个因素协同作用影响,干湿循环作用下硫酸盐侵蚀产物主要为石膏型侵蚀和钙矾石型侵蚀。掺玄武岩纤维混凝土抗硫酸盐侵蚀能力明显优于于素混凝土。 相似文献
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混凝土硫酸盐侵蚀试验方法研究 总被引:12,自引:1,他引:12
主要分析了混凝土硫酸盐侵蚀的机理,对美国现行的两个硫酸盐侵蚀试验方法存在的问题进行了分析、讨论.提出设计一个合适的混凝土快速试验方法应该考虑的因素. 相似文献
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以掺有不同粉煤灰量的混凝土试件为研究对象,将3种配合比的混凝土试件暴露在具有典型盐渍土特征的宁夏地区,选取相对质量和相对动弹性模量作为评价参数,通过比较分析得出一种更加适合盐渍土地区现场暴露混凝土耐久性损伤的综合评价参数。同时结合现场暴露混凝土微观分析对盐渍土地区混凝土受硫酸盐侵蚀的劣化机理进行了研究,从微观角度分析了盐渍土地区混凝土耐久性能变化的原因。结果表明:混凝土在盐渍土地区受到复杂的化学侵蚀,与土壤中的硫酸盐反应生成了硫铝酸钙晶体填充在孔隙中,综合损伤评价参数能很好地描述盐渍土地区混凝土的耐久性。 相似文献