Coupled solute transport through a polymer-enhanced bentonite

Polymer-enhanced bentonites for geoenvironmental containment barriers, such as bentonite-polyacrylic-acid composite (BPC), generally have low hydraulic conductivity (e.g., k < 10^?10 m/s) even when exposed to aggressive waste solutions. However, understanding of diffusion and membrane behavior properties of enhanced bentonites and associated impacts on coupled contaminant transport through the barrier remains limited. In this study, hydraulic conductivity (k), effective diffusion coefficients (D*), and membrane efficiencies (ω) were measured for BPC with 3.2 % polymer content (by mass; referred to as BPC-3.2). Tests were performed with potassium chloride (KCl) solutions ranging from dilute (2.5 mM) to aggressive (400 mM) concentrations. As concentration increased, D* increased by a factor of three, ω decreased by two orders of magnitude, and k remained relatively low (1.2 × 10^?11 to 2.9 × 10^?11 m/s). The experimental results were paired with an existing coupled solute transport model to evaluate the significance of membrane behavior and diffusion on predicted total solute flux through a geosynthetic clay liner (GCL) and a GCL overlying an attenuation layer. The predicted mass flux was diffusion dominated, with the diffusive flux greater than the advective flux by one to two orders of magnitude. Membrane behavior reduced predicted total solute flux through the GCL by 5.8 to 61 %. The results demonstrate the role of coupled solute transport in the long-term performance of bentonite barriers, and advance understanding of contaminant transport in BPC.     

Performance of multicomponent GCLs in high salinity impoundment applications

The interface transmissivity (θ) of two multicomponent geosynthetic clay liners (GCLs) is investigated upon hydration and permeation with a highly saline solution (TDS ≈ 260,000 mg/l; Na⁺ ~ 95,000 mg/l; K⁺~12,000 mg/l) at two stress levels (10 kPa and 150 kPa). One GCL had a smooth 0.2 mm-thick coating whereas the second GCL had a textured 1 mm-thick coating. For both GCLs, the interface transmissivity after 2-weeks is shown to be higher than at steady-state. The lower the geomembrane's (GMB) stiffness, the lower interface transmissivity. However, the effect is generally diminished at steady state and higher stress. The effect of GMB stiffness at 10 kPa is shown to be 1.6-times that at 150 kPa. Similarly, the 2-week and steady state interface transmissivity for the textured GMB was higher at 10 kPa than at 150 kPa. Coating texture and coating orientation are shown to have a significant effect on GMB/multicomponent GCL interface transmissivity. A hole in the coating aligned with GMB hole creates an additional flow path at the coating/GCL interface (θ_Geofilm/GCL), however most of the flow occurs at the coating/GMB interface (θ_Geofilm/GMB).     

Failure mechanisms of geosynthetic clay liner and textured geomembrane composite systems

The objective of this study was to evaluate shear behavior and failure mechanisms of composite systems comprised of a geosynthetic clay liner (GCL) and textured geomembrane (GMX). Internal and interface direct shear tests were performed at normal stresses ranging from 100 kPa to 2000 kPa on eight different GCL/GMX composite systems. These composite systems were selected to assess the effects of (i) GCL peel strength, (ii) geotextile type, (iii) geotextile mass per area, and (iv) GMX spike density. Three failure modes were observed for the composite systems: complete interface failure, partial interface/internal failure, and complete internal failure. Increasing normal stress transitioned the failure mode from complete interface to partial interface/internal to complete internal failure. The peak critical shear strength of GCL/GMX composite systems increased with an increase in GMX spike density. However, the effect of geotextile type and mass per area more profoundly influenced peak critical shear strength at normal stress > 500 kPa, whereby an increase in geotextile mass per area enhanced interlocking between a non-woven geotextile and GMX. Peel strength of a GCL only influenced the GCL/GMX critical shear strength when the failure mode was complete internal failure.     

Self-healing of circular and slit defects in GCLs upon hydration from silty sand under applied stress

The self-healing of a GCL with artificial defects (circular holes and rectangular slits, both with and without the carrier geotextile preserved below the holes) upon hydration on a Godfrey silty sand (GSS) subgrade with w_fdn = 5, 10 and 16% under 2–100 kPa is examined. Circular holes with the carrier geotextile missing below holes with diameters up to 25.4 mm self-healed on the w_fdn = 5% and 10% GSS but not on 16% GSS, while none self-healed when carrier geotextile was preserved below the holes. When DI water was introduced to the surface under 100 kPa, circular holes with diameter up to 38.1 mm self-healed. Neither the single 15 mm-wide slit nor double 15 mm-wide parallel slits with 20 mm-wide strip of undamaged GCL between them resting on w_fdn = 10% GSS under 20 kPa fully self-healed. The introduction of simulated synthetic landfill leachate (SSL) to the GCL surface under 70 kPa did not result in self-healing. Post-hydration k tests found that GCL without a carrier geotextile below a hole up to 25.4 mm in diameter would not have a significant adverse effect on the hydraulic conductivity compared with an intact GCL provided the permeant was tap water rather than SSL.     

Influence of pore water chemistry on GCL self-healing with hydration from silica sand

The self-healing of a GCL with a circular hole is examined in experiments where the GCL, overlain by geomembrane, is hydrated from a silica sand subgrade (SSS) having three different pore water chemistries. Factors considered included: hole size, subgrade initial moisture content w_fdn, GCL mass per unit area, and overburden stress (20–100 kPa). GCL self-healing is better for w_fdn = 16% than for w_fdn = 10%, which is better than for 5%, when the SSS pore water has negligible cations (ionic strength, I < 0.1 mM). However, only the 14.3 mm-diameter hole fully self-healed and only when w_fdn = 16%. In contrast, when the GCL is hydrated from SSS with pore water having an ionic strength, I, of 20 and 30 mM, the self-healing for w_fdn = 5% is better than for w_fdn = 10%, which is better than for w_fdn = 16%, although none of the holes self-healed. When a ~0.5 m hydraulic head was applied above the GCL under σ_v = 20–100 kPa, a 38.1 mm-diameter hole self-healed with water having I < 0.1 mM, a 25.4 mm-diameter hole self-healed with pore water with I = 20 mM and 30 mM, but none self-healed with simulated synthetic landfill leachate (SSL). Post-hydration hydraulic conductivity (k) tests with SSL suggest that a hole up to 14.3 mm-diameter would not pose a significant adverse impact on the k compared to an intact GCL; however, this is not the case for the larger holes tested.     

Effect of prehydration,permeant, and desiccation on GCL/Geomembrane interface transmissivity

A laboratory investigation was conducted on two different conventional GCLs (one with fine granular and another one with powdered bentonite) to explore the effect of prehydration and permeant fluid; GCL desiccation on the interface transmissivity, θ, between the interfaces of a 1.5 mm-thick high-density polyethylene (HDPE) geomembrane (GMB) and a GCL. The study also aimed to assess the self-healing capacity of desiccated GCLs for three different permeant solutions under a range of applied stresses (10–150 kPa). It was found that at stresses less than 70 kPa, θ was dominated by variability in the initial contact condition between the GMB-GCL interfaces. The effect of other factors was largely masked by the contact variability. At 100–150 kPa, the effects of initial variability were largely eliminated, but there was no notable effect of other factors on θ in the absence of desiccation. GCL desiccation increased θ by up to three orders of magnitude than an intact specimen at 10–100 kPa. Even at 150 kPa, desiccated specimens had a θ ≤ 8.0 × 10⁻⁹ m²/s for all specimens tested. The chemical composition of the permeant solutions, crack width, and nature of bentonite could play an important role in healing the cracks of desiccated GCLs.     

Membrane behavior of bentonite-amended compacted clay

The performance of landfill liners can be enhanced if they exhibit a semipermeable membrane behavior, which restricts the migration of contaminants. Consequently, enhancing the membrane property of clays used for liners is becoming increasingly important. As bentonite has already proven to be an excellent additive for improving the membrane behavior of clay, the hydraulic conductivities and membrane behaviors of a locally available clay, known as Fukakusa clay, amended with different amounts of dry bentonite (5%, 10%, 15%, and 20%) were herein evaluated. The chemico-osmotic efficiency coefficient, ω, was obtained under different concentration differences of KCl solution (0.5, 1, 5, 10, and 50 mM) for specimens in rigid-wall cells. The test results show that the ω of unamended clay is very low and can be ignored unless amended with bentonite, and that hydraulic conductivity k is suitably low (1.58×10⁻⁹ m/s). Additionally, ω decreased as the KCl concentration increased, which is consistent with the theory that increasing concentration causes progressively greater shrinkage of the diffuse-double layers of the clay particles. Furthermore, the mechanisms that influence the membrane behavior are discussed from the viewpoints of the diffuse-double layer and the interparticle pore size with the assistance of SEM.     

Unloading behavior of clays measured by CRS test

The unloading behavior of clays was studied by the Constant Rate of Strain (CRS) test, for three clays: two of them are reconstituted and the other was intact. In the conventional CRS test where the stress monotonically increases, the distribution of the pore water pressure in a specimen is assumed to be parabolic, the effective stress is calculated and then the compression behavior is evaluated. However, this assumption cannot be directly applied the unloading condition. In this study, the pore pressure distribution under unloading was simulated by a cubic polynomial under the assumption that hydraulic conductivity does not change in the unloading process. A unique relation in the e–log σ′_v relation was found, irrespective of both the magnitude of stress or strain and the compression index, C_c, at the unloading test, when the consolidation pressure is normalized by σ′_vmax, which is the consolidation pressure before the unloading test. In addition, the creep strain, which is gained by constant loading before the unloading test, was shown to have a great effect on the unloading behavior: that is, the soil behaves stiffly when subjected to a constant load for a prolonged period of time. A strain rate dependency in the unloading process was also observed particularly for heavily unloaded specimens. The unloading behavior was also investigated by the conventional constant load test. The test results show reasonable agreement with those obtained from the CRS test.     

Performance monitoring and numerical assessment of a test embankment with preloading and vertical drains on Texcoco lacustrine soft clays

This paper presents the performance monitoring results and long-term numerical analyses of a 2.8-m-high test embankment with vertical drains on soft highly compressible clays during a four years and two months observation period (1525 days). The peculiar study site is characterized by thick layers of lacustrine soft clay with water contents up to 300%, void ratios between 7 and 9 and ratios C_α/C_c range from 0.06 to 0.03. The loading applied by the test embankment was 43.4 kPa. The vertical drains installed were of two types: sand and prefabricated. The settlements that only take into account the effect of the preloading embankment at the end of the observation period were 2.62 m and 2.71 m, in the zones with sand and prefabricated vertical drains, respectively. The settlement measured by regional subsidence was 0.47 m. The ultimate primary settlement was approximately 2.0 m and was estimated by two observational methods based on field settlement records. The settlement developed by secondary consolidation in the embankment ranged from 0.62 m to 0.71 m at the end of the observation period. The test embankment behavior was simulated by 2D and 3D numerical analyses. The 2D analyses used a theory to convert the axisymmetric drainage into plane drainage. The long-term numerical results and the field measurements were compared and discussed.     

砾石含量对成都粘土力学特性的影响

通过三轴剪切试验,研究分析含砾成都粘土的力学特性。主要进行成都粘土与砾石不同配比的混合土三轴剪切试验,按照砾石含量的质量百分数进行分组。进行了四种围压(50kPa、100kPa、200kPa和400kPa)作用时的固结排水与固结不排水试验,并得出如下结论:①低围压时(σ1-σ3)随砾石含量的增加而提高;高围压时,20%试样(σ1-σ3)最低,依次是0%试样、40%试样;②随砾石含量的增加,割线刚度有所提高;③CD试验中,试样未出现体胀现象,40%试样体缩量较小;CU试验中,未出现孔隙水压力减小趋势,40%试样孔隙水压力值较高。     

Properties of very soft clays: A study of thixotropic hardening and behavior under low consolidation pressure

In a study on the properties of very soft clays, bender element testing was used to evaluate thixotropic hardening behavior; that is, to measure the stiffness with resting time under constant volume and water content. A laboratory vane test, which measures the undrained shear strength of the materials, was also carried out for comparison purposes. To investigate the mechanism of the thixotropic phenomenon, a consolidation test with very low pressure was also performed in a cell equipped with bender elements. The most important findings from this study are as follows: (1) regardless of soil types, the effect of thixotropy was significant around the liquid limit state and less remarkable at the lower and higher ranges; (2) the shear modulus at the liquid limit after 24 h resting is around 200 kPa; (3) the correlation between the shear modulus and the undrained shear strength of very soft clays is similar to that of cement-treated soil proposed by Seng and Tanaka (2011); (4) the increment of the shear modulus developed in the thixotropy process appears to be noticeably higher than that in the secondary consolidation process. It is believed that these findings are very useful to establish a new theory for the consolidation of ground filled by very soft clays or dredged soils with extremely high water content as well as to understand the effects of ageing on the consolidation properties of natural soils.     

Interface transmissivity of conventional and multicomponent GCLs for three permeants

A laboratory investigation of the interface transmissivity is reported for five different geosynthetic clay liners (GCLs) and a range of different geomembranes (GMBs) for a range of stresses from 10 to 150?kPa. The GCLs were prehydrated under normal stress before permeation. The GCLs examined comprised three multicomponent (a smooth coated, a smooth laminated, and textured coated) and two conventional (one with granular and one with powdered sodium bentonite) GCLs. The effect of a 4?mm circular defect in the coating of a multicomponent GCL directly below the 10?mm diameter hole in the GMB is investigated. The effect of GMB stiffness and texture is examined. Additionally, the effect of hydration and permeation of smooth coated GCL with highly saline solution and synthetic landfill leachate (SL3) is presented. It is shown that the 2-week interface transmissivity (θ_2-week) can be one to two orders of magnitude higher than steady-state interface transmissivity (θ _steady-state) at low stresses (10?kPa–50?kPa), whereas at high stresses (150?kPa) the variation is substantially less. For a smooth coated GCL hydrated and permeated with reverse osmosis (RO) water, GMB stiffness and texture has a limited effect on interface transmissivity when the coating is placed in contact with GMB at normal stresses of 10?kPa–150?kPa, whereas coating indentations result in much high interface transmissivity when placed in contact with GMB. GCL prehydration and permeation with highly saline solutions leads to higher interface transmissivity compared to RO water. With a 4.0?mm defect in the coating, the interface transmissivity between the coating and woven geotextile is higher than that between the coating and GMB for the stress levels and GCL examined.     

Long-term consolidation behavior interpreted with isotache concept for worldwide clays

The consolidation characteristics interpreted with the isotache concept have been studied by many researchers, including the authors. The aim of most of these studies has been to calculate secondary consolidation with high accuracy in order to evaluate the long-term settlement of large-scale structures. In a previous study, the long-term consolidation characteristics of Osaka Bay clay, collected from the construction site of the Kansai International Airport, were examined, and a simplified method based on the isotache concept, using a compression curve and the relationship between the consolidation yield stress (preconsolidation pressure) and the strain rate, was proposed. The former and the latter were obtained from constant rate of strain consolidation (CRS) tests and long-term consolidation (LT) tests, respectively. The latter is expressed by an equation with three isotache parameters. In addition, it is noteworthy that the isotache parameters can be commonly determined for the Osaka Bay clays retrieved from various depths up to 300 m below the seabed. In the present study, the proposed method was applied to worldwide clays with various characteristics using the common values for the isotache parameters determined for the Osaka Bay clays. It was found that the long-term consolidation behavior of those worldwide clays can be well characterized by the proposed method, along with the common values for the isotache parameters.     

Geomembrane strains from coarse gravel and wrinkles in a GM/GCL composite liner

The physical response of a 1.5-mm-thick, high-density polyethylene geomembrane (GM) is reported when placed on top of a needle-punched geosynthetic clay liner (GCL), buried beneath 50-mm coarse gravel and subjected to vertical pressure in laboratory experiments. Local strains in the geomembrane caused by indentations from the overlying gravel and deflections of a wrinkle in the geomembrane are quantified. A peak strain of 20% was calculated when a flat geomembrane was tested without a protection layer at an applied vertical pressure of 250 kPa. Strains were smaller with a nonwoven needle-punched geotextile protection layer between the gravel and geomembrane. Increasing the mass per unit area of the geotextile up to 2200 g/m² reduced the geomembrane strain. However, none of the geotextiles tested were sufficient to reduce the geomembrane strain below an allowable limit of 3%, for the particular 50-mm gravel tested and when subjected to a vertical pressure of 250 kPa. Increasing the initial GCL water content and reducing the stiffness of the foundation layer beneath the GCL were found to increase the geomembrane strains. These local strains were greater when a wrinkle was present in the geomembrane. The wrinkle in the geomembrane experienced a decrease in height and width. The wrinkle deformations lead to larger pressures beside the wrinkle and hence producing larger local strains. A 150-mm-thick sand protection layer was effective in limiting the peak strain to less than 0.3% even with a wrinkle in the geomembrane, at a vertical pressure of 250 kPa.     

Influence of polymer enhancement on water uptake,retention and barrier performance of geosynthetic clay liners

This paper explores the influence of polymer enhancement on water uptake and retention by geosynthetic clay liners (GCLs) across a wide suction range (up to 10⁶ kPa), including the low suction regime (0.1–10 kPa) typically omitted in past studies. The suction measurement methods used enabled elucidation of water uptake and retention behaviour through the framework of GCL pore structures and their corresponding suction regimes. Polymer enhanced GCLs (PE-GCLs) have high maximum water uptake, and both the water entry and air expulsion values tend to be high. Due to high swelling, the onset of geotextile confinement for PE-GCLs was observed at high suctions. The impact of polymer becomes more apparent when the bentonite achieves a pseudo-two-layer interlayer hydration state at a suction of about 40 MPa (RH = 75%). The hydration mechanism for the polymer fraction in bentonite is unique to the specific polymer type, polymer dosage, and manufacturing process. The water retention behaviour at the low suction range is caused by the in-filling of geotextile pores, bentonite swelling and extrusion, and polymer water adsorption. Insights from this study can form the basis for developing a more suitable bimodal generalised model for fitting the water retention curves of GCLs.     

Water retention curves of a geosynthetic clay liner under non-uniform temperature-stress paths

This paper presents a novel suction-controlled chamber that permits the determination of the full water retention curves of geosynthetic clay liners (GCLs) under non-uniform temperature-stress paths. It investigates field conditions encountered in brine ponds (low confining stress settings) and heap leach pads (high confining stress settings) during construction and operation stages. Consequently, the analysis of the moisture dynamics in a GCL was defined under the wetting path (construction) and drying path (operation). High vertical stresses were found to facilitate a more rapid water uptake as capillarity is established faster than at low, confined stresses. In general, the drying curves increase the water desorption over the suction range investigated due to the low water viscosity caused by high temperatures. The wetting of the GCL at 20 °C and drying at 70 °C under either low, confined stress (2 kPa) or high confining stress (130 kPa) shows a reduction in the volumetric water contents. Furthermore, on the drying path, the coupled effect of elevated temperature and high confining stress accelerates water desorption leading possibly to potential desiccation.     

Shear strength and failure mechanism of needle-punched geosynthetic clay liner

The internal shear strength of a geosynthetic clay liner (GCL) within composite liner systems is crucial for the stability of landfills and should be carefully considered in the design. To explore the shear strength and failure mechanism of the extensively used needle-punched GCL, a series of displacement-controlled direct shear tests with five normal stress levels (250–1000 kPa) and eight displacement rates (1–200 mm/min) were conducted. The shear stress to horizontal displacement relationships exhibit well-defined peak shear strengths and significant post-peak strength reductions. The monitoring results of the thickness change indicate that the degree of volumetric contraction is related to the reorientation of fibers and dissipation of pore water pressure. Furthermore, the peak and residual shear strengths both depend on the displacement rate because of the rate-dependent tensile stiffness of needle-punched fibers and shear strength of the soil/geosynthetic interface. Through additional tests and lateral comparison, it was discovered that the shear behavior of sodium bentonite, degree of hydration, and pore water pressures all affect the shear mechanisms of the NP GCL. In particular, the failure mode transfers from fiber pullout to fiber rupture with the increase in water content as the hydrated bentonite particles facilitate the stretching of needle-punched fibers.     

Comparison of Mechanical Behavior of Two Overconsolidated Clays: Yamashita and Louiseville Clays

A site investigation program was carried out at the Yamashita site, Yokohama, Japan, by means of laboratory as well as field tests. It was found from the investigation that the clayey layer is overconsolidated with an OCR of about 2.0. It is evident from geological consideration that this overconsolidation may not have been caused by stress change, but was probably due to structure effects such as cementation or delayed consolidation. The physical and mechanical properties of the Yamashita clay is compared with those of Louiseville clay, a Champlain Sea Clay widely distributed in Quebec, eastern Canada, and a well known cemented clay. Louiseville clay was retrieved by Japanese sampler and transported to the Port and Harbour Research Institute (PHRI) for laboratory investigation. Comparison of the two clays shows that strength properties such as the stress-strain curve or stress path for both clays are very similar to each other. However, the pattern of the e-log p curve measured by Constant Rate of Strain oedometer, particularly beyond the yield consolidation pressure, is remarkably different between the two clays.     

Ageing Effects on Consolidation Properties—Based on the Site Investigation of Osaka Pleistocene Clays—

Soil samples were recovered from the Osaka basin, where Holocene as well as Pleistocene marine clays are thickly deposited. It is found from X-ray diffraction analysis that the component of clay minerals for these day layers is almost identical through all depths. 'This fact suggests that the origin of these sediments has not been drastically changed through at least more than 1,000,000 years. Using data obtained by oedometer tests, this paper examines ageing effects on consolidation properties. It is found that void ratio for the Pleistocene clays keeps large even under high in situ effective overburden pressure (p_vo′). Salinity of pore fluid decreases with depth and becomes nearly zero at depths deeper than 70 m. However, the change in salinity does not give any influences on the index properties, suggesting that the relatively large void ratio for the Pleistocene clays is caused by other reasons than leaching. It is also found that the Pleistocene clays reveal no particular differences in consolidation properties, but fundamentally similar to those of Holocene clays'. There is no distinguished difference in the overconsolidation ratio (OCR), non-linearity of the e-log p' relation after yield consolidation pressure including the maximum compression index (C_cmax) and the hydraulic conductivity (k). The only prominent difference in the Osaka Pleistocene clays, compared to the Holocene clay, is relatively small void ratio due to the large p_vo′.     

Stress-controlled direct shear testing of geosynthetic clay liners I: Apparatus development

The use of geosynthetic clay liners (GCLs) in waste containment applications can induce long-term normal and shear stresses as well as expose GCLs to elevated temperatures and non-standard hydration solutions. Considering the importance of GCL internal shear strength to the design and integrity of waste containment barrier systems, innovative laboratory testing methods are needed to assess shear behavior of GCLs. There were two main objectives of this study: (i) develop a stress-controlled direct shear apparatus capable of testing GCLs exposed to elevated temperatures and hydrated in non-standard solutions; and (ii) assess internal shear behavior of GCLs under varying experimental conditions (e.g., stress, temperature, solution). These two objectives were partitioned into a two-paper set, whereby Part I (this paper) focuses on the shear box design and Part II focuses on an assessment of shear behavior. The direct shear apparatus includes a reaction frame to mitigate specimen rotation that develops from an internal moment within needle-punched reinforced GCLs. Rapid-loading shear tests were conducted to assess functionality of the apparatus and document baseline shear behavior for a heat-treated and a non-heat treated needle-punched GCL with comparable peel strength. These two GCLs failed at comparable applied shear stress; however, the heat-treated GCL yielded lower shear deformation and failure occurred via rupture of reinforcement fiber anchors, whereas the non-heat treated GCL yielded larger shear deformation and failure via pullout of reinforcement fibers.