Effect of concrete mixing parameters on propagation of ultrasonic waves

An experimental study was conducted to evaluate the effect of concrete aggregate gradation, water–cement ratio, and curing time on measured ultrasonic wave velocity (UPV). 30 × 30 × 10 cm Portland cement concrete slabs were cast for ultrasonic evaluation, while 10 cm diameter by 20 cm height cylinders were cast for compressive strength evaluation The slabs and cylinders were prepared using Portland cement and limestone aggregate. Two slabs were cast from each combination of coarse aggregate gradations and water cement ratio (0.40, 0.45, 0.50, and 0.55). Four ASTM gradations were considered, ASTM No: 8, 67, 56, and 4. These gradations have nominal maximum aggregate size 25, 4.75, 19.3, and 12.5 mm, respectively.The ultrasonic equipment used in this study was the portable ultrasonic non-destructive digital indicating tester (PUNDIT) with a generator having an amplitude of 500 V producing 54 kHz waves. The time needed to transfer the signal between the transducers was recorded and used to calculate the signal velocity, which was used as a parameter in the evaluation. Ultrasonic measurements were performed at 3, 7, 28, and 90 days after concrete casting.The results of the analysis indicated that water–cement ratio was found to have a significant effect on UPV. The UPV was found to decrease with the increase of water cement ratio. Aggregate gradation was also found to have significant effect on UPV. In general, the larger the aggregate size used in preparing Portland cement concrete, the higher the measured velocity of ultrasonic waves. Also, UPV was found to be increased as concrete curing time increased. Concrete compressive strength was found to be significantly affected by water–cement ratio and coarse aggregate gradation. Lower water–cement ratio produced higher concrete strength. Also, the concrete compressive strength increased as maximum aggregate size decreased.     

Durability design and performance of self-consolidating lightweight concrete

In terms of the durability, the reduction in cement paste is crucial to both volume stability and long-term performance of concrete. The objective of this paper is to compare the performance of lightweight concrete under different w/cm ratio and different cement paste content. The slump and slump flow spread of fresh self-consolidating lightweight concrete (SCLWC) are designed to be within 230–270 and 550–650 mm, respectively. The test results indicate that the 91-day compressive strength of SCLWC is up to 56 MPa when cement content is 386 kg/m³ and water content is 150 kg/m³. If enough cement paste is used, then the less the paste amount and the denser the packing of aggregate, the higher the strength efficiency of cement and the electric resistance, and the lower the chloride ion penetrability capacity of SCLWC.     

Influence of fly ash on strength and sorption characteristics of cold-bonded fly ash aggregate concrete

Cold-bonded fly ash aggregate concrete with fly ash as part of binder or fine aggregate facilitates high volume utilization of fly ash in concrete with minimum energy consumption. This paper investigates the influence of fly ash on strength and sorption behaviour of cold-bonded fly ash aggregate concrete due to partial replacement of cement and also as replacement material for sand. While cement replacement must be restricted based on the compressive strength requirement at desired age, replacement of sand with fly ash appears to be advantageous from early days onwards with higher enhancement in strength and higher utilization of fly ash in mixes of lower cement content. Microstructure of concrete was examined under BSEI mode. Replacement of sand with fly ash is effective in reducing water absorption and sorptivity attributable to the densification of both matrix and matrix–aggregate interfacial bond. Cold-bonded fly ash aggregate concrete with a cement content of 250 kg/m³, results in compressive strength of about 45 MPa, with a total inclusion of around 0.6 m³ of fly ash in unit volume of concrete.     

Damage to cement concrete pavements due to exposure to organic compounds in a cold region

Pop-out and disaggregation of aggregate in a 1-year old cement concrete pavement originally mixed with air-entraining (AE) water-reducing agent was observed after the pavement had been exposed to ethylene glycol based snow-melting agent on the surface in the winter. The study used: gas chromatography–mass spectrometry (GC–MS) tests, ¹H Nuclear Magnetic Resonance (NMR) tests, X-ray fluorescence analysis, emission spectral analysis (ICP), elution tests in anion type surfactant solution conducted for mortar and aggregate taken from the cement concrete where pop-out had occurred, as well as samples made by cement paste in the laboratory. Tests of the tensile strength, thermal-stress, and three-dimensional crack analysis by micro-focus computerized tomography (CT) scanner were conducted for specimens (2.5 × 2.5 × 10 cm) taken from the cement concrete where pop-out had occurred and with cement concrete samples made in the laboratory. Microscope observations and Electron Probe Micro Analyzer (EPMA) analysis were conducted for thin samples (2.5 × 2.5 cm and 20 μm thick) taken from the cement concrete where pop-out had occurred. The tests results showed that organic compounds contained in the cement reacted with the cement during the hardening process, generating cracks and gel in the cement paste. It was established that these caused the pop-out of the aggregate, together with the effects of the ethylene glycol based snow-melting agent that the cement concrete had been exposed to. No pop-out or disaggregation of aggregate were found in cement concrete at a repaired section, at the same location, with aggregate of low absorbing water ratio in this cold region and in place for 2 years.     

Optimisation of using lightweight aggregates in mitigating autogenous deformation of concrete

Experiments were conducted to determine the effects of using dispersed saturated lightweight aggregates (LWAs) as water reservoirs in mitigating the autogenous deformation of high performance concrete and to establish the optimum solutions as a combination of a number of factors affecting the fracture and mechanical characteristics of concrete. For this purpose, in concretes prepared with a constant low water to cement ratio, normal aggregates were replaced by natural LWAs with size fractions of 2–4 mm or 4–8 mm at three different volume fractions such as 10%, 20% and 30% of the total aggregate volume of concrete. The results indicate that the inclusion of fine fraction of LWAs in concrete reduces the autogenous deformation significantly compared to that of the coarse fraction. It is also shown that concretes with fine fraction of LWAs have enhanced fracture and mechanical properties compared to those with coarse fraction of LWAs. Increasing the replacement ratio of LWAs mitigates autogenous deformation, while having an unfavourable effect on fracture and mechanical properties of concrete for both size replacements. A multi-objective simultaneous optimisation technique, in which the response surface method (RSM) is incorporated, is used to optimise the mitigation ratio of autogenous deformation and fracture parameters of high strength concretes in an effort to obtain a more ductile concrete with less autogenous deformation.     

Characterization of concrete blocks containing petroleum-contaminated soils

This paper presents the results of a study on the potential use of petroleum-contaminated soil (PCS) in the manufacturing of concrete blocks. PCS was obtained from Fahud asset area in northern Oman, where contaminated soils are typically transported for treatment. Hollow blocks of size 400 × 200 ×200 mm, widely used in Oman, were manufactured with a mix proportion of 1:2:4:0.8 for cement, coarse aggregate, sand, and water, respectively. The coarse aggregate had a 10 mm maximum aggregate size. PCS was subjected to the toxicity characteristic leaching procedure (TCLP). The chemical analysis of the extract indicated that the concentrations of metals and organic compounds did not exceed the maximum contaminant levels set by USEPA for TCLP extracts. Different mixes were prepared by replacing the sand with PCS with percentages up to 80% by sand weight in the mix. Five different tests were conducted on the concrete blocks: density, compressive strength, absorption, compressive strength of a masonry column, and thermal conductivity. The compressive strength test was conducted after 14 and 28 days of curing. The other tests were performed after 28 days of curing. Results indicated that PCS can be used with a replacement percentage up to 60% to produce concrete blocks meeting the Omani Standard specifications. The results also indicate potential deterioration when more than 60% PCS are used.     

The role of industrial by-products in self-compacting concrete

The development of self-compacting concrete is considered as a milestone achievement in concrete technology due to several advantages. In order to be self-compactable the fresh concrete must show high fluidity besides good cohesiveness. For the purpose of evaluating these properties, several concrete mixtures were prepared with a water to cement ratio of 0.45 in the presence of an acrylic-based superplasticizer at a dosage ranging from 1% to 2% by weight of very fine material fraction (maximum 150 μm). Either limestone powder or fly ash or recycled aggregate powder (that is a powder obtained from the rubble recycling process) were used as mineral addition, in order to assure adequate rheological properties, in terms of cohesiveness, in the self-compacting concretes. Preliminary rheological tests were carried out on cement pastes containing these mineral additions. In some cases, recycled instead of natural aggregate was used by substituting either the coarse or the fine aggregate fraction. The fresh concrete properties were evaluated through slump flow, L-box test and segregation resistance. Compressive strength of concrete was determined at 1, 3, 7 and 28 days of wet curing. Results obtained showed that an optimization of self-compacting concrete mixture seems to be achievable by the simultaneous use of rubble powder and coarse recycled aggregate with improved fresh concrete performance and unchanged concrete mechanical strength.     

Micro-analysis of the role of interfacial transition zone in “salt weathering” on concrete

When concrete elements are partially immersed in the sulfate environment, researchers always attribute “salt weathering”, “salt crystallization” or “physical attack” to the failure of concrete. However, there were few micro-analysis evidences to support this view. In this paper, an attempt was carried out to study whether salt weathering is really responsible for the concrete damage.As we know, the interfacial transition zone (ITZ) between paste and aggregate plays a determining role in the performance of concrete. In this paper, we focused on the role of ITZ in “salt weathering” on concrete. Concrete specimens, made with coarse aggregate and cement paste, were partially exposed to a 5% sodium sulfate solution and a 5% magnesium sulfate solution respectively, in a controlled environment (20 ± 2 °C, and 60 ± 5% RH). After 8 months of exposure, a micro-analysis is performed by means of XRD, ESEM and EDS. The experimental results showed that, in the upper part of concrete above the Na₂SO₄ solution, damage initiated in the ITZ between paste and aggregate due to the formation of ettringite and gypsum. Salt crystallization cannot occur on the paste surface in the ITZ, but it was found on the aggregate surface after damage initiation due to chemical sulfate attack. On the other hand, salt crystallization could occur in the carbonated concrete. There was no trace of salt crystallization in the concrete partially exposed to MgSO₄ solution.     

Water absorption,permeability, and resistance to chloride-ion penetration of lightweight aggregate concrete

This paper presents an experimental study to evaluate effect of cumulative lightweight aggregate (LWA) content (including lightweight sand) in concrete [water/cement ratio (w/c) = 0.38] on its water absorption, water permeability, and resistance to chloride-ion penetration. Rapid chloride penetrability test (ASTM C 1202), rapid migration test (NT Build 492), and salt ponding test (AASHTO T 259) were conducted to evaluate the concrete resistance to chloride-ion penetration. The results were compared with those of a cement paste and a control normal weight aggregate concrete (NWAC) with the same w/c and a NWAC (w/c = 0.54) with 28-day compressive strength similar to some of the lightweight aggregate concrete (LWAC). Results indicate that although the total charge passed, migration coefficient, and diffusion coefficient of the LWAC were not significantly different from those of NWAC with the same w/c of 0.38, resistance of the LWAC to chloride penetration decreased with increase in the cumulative LWA content in the concretes. The water penetration depth under pressure and water sorptivity showed, in general, similar trends. The LWAC with only coarse LWA had similar water sorptivity, water permeability coefficient, and resistance to chloride-ion penetration compared to NWAC with similar w/c. The LWAC had lower water sorptivity, water permeability and higher resistance to chloride-ion penetration than the NWAC with similar 28-day strength but higher w/c. Both the NWAC and LWAC had lower sorptivity and higher resistance to chloride-ion penetration than the cement paste with similar w/c.     

Effect of palm oil fuel ash fineness on the microstructure of blended cement paste

This paper presents the effect of palm oil fuel ash fineness on the microstructure of blended cement paste. Palm oil fuel ash (POFA) was ground to two different finenesses. Coarse and high fineness palm oil fuel ash, with median particle sizes of 15.6 and 2.1 μm, respectively, were used to replace ordinary Portland cement (OPC) at 0%, 20% and 40% by binder weight. A water to binder (W/B) ratio of 0.35 was used for all blended cement pastes. The amorphous ground palm oil fuel ash was characterized by the Rietveld method. The compressive strength, thermogravimetric analysis and pore size distribution of the blended cement pastes were investigated. The test results indicate that the ground palm oil fuel ash was an amorphous silica material. The compressive strengths of the blended cement pastes containing coarse POFA were as high as that of OPC cement paste. Blended cement paste with high fineness POFA had a higher compressive strength than that with coarse POFA. The blended cement pastes containing 20% of POFA with high fineness had the lowest total porosity. The Ca(OH)₂ contents of blended cement paste containing POFA decreased with increasing replacement of POFA and were lower than those of the OPC cement paste. In addition, the POFA fineness had an effect on the reduction rate of Ca(OH)₂. Furthermore, the critical pore size and average pore size of blended cement paste containing POFA were lower than those of the OPC cement paste. The incorporation of high fineness POFA decreased the critical pore size and the average pore size of blended cement paste as compared to that with coarse POFA.     

Recycled concrete made with different natural coarse aggregates exposed to high temperature

The recycled aggregates obtained from crushed waste concretes have different characteristics from those of natural aggregates. For that reason, the mixture proportions and the fresh and hardened properties of recycled concretes are different. The performance of recycled concrete exposed to high temperatures is not a very well-known subject since most studies have been conducted on conventional concretes. Recycled concretes with water/cement (w/c) ratios of 0.40 and 0.70, and made with three different types of natural coarse aggregate were exposed to 500 °C for 1 h. These concretes were evaluated by the ultrasonic method, resonance frequency, static modulus of elasticity and compressive strength, before and after heating, and compared with those obtained on similar conventional concretes containing the same type of natural coarse aggregate. The conventional and recycled concretes made with quartzitic coarse aggregate performed better after the heat treatment.     

Strength and stiffness of compacted crushed concrete aggregate

A comprehensive series of drained triaxial compression tests were performed on crushed concrete aggregate (CCA) moist as compacted. When compared to ordinary natural well-graded gravelly soils, the peak strength and stiffness increase more significantly with dry density, while the effect of the degree of saturation during compaction is much less significant. In a range of confining pressure of 30–600 kPa, the strength and stiffness of well-compacted CCA is similar to, or, in some cases even higher than, typical selected high-class backfill materials (e.g., well-graded gravelly soil of crushed quarry hard rock). The strength and stiffness of CCA with a maximum particle size D_max=37.5 mm obtained from a typical concrete crushing plant are noticeably lower than CCA sieved to D_max=19 mm compacted using the same energy. However, when compacted to the same dry density, the original CCA exhibits the strength and stiffness higher than the sieved CCA. Effects of the strength of original concrete on the strength and stiffness of compacted CCA are insignificant, while the strength and stiffness of compacted CCA are, respectively, noticeably higher than, or similar to, the original concrete aggregate (i.e., natural gravelly soil) compacted using the same energy. All these results indicate that well-compacted CCA can be used as the backfill material for important civil engineering soil structures requiring a high stability while allowing a limited amount of deformation.     

Influence of soaking and polymerization conditions on the properties of polymer concrete

An experimental investigation was conducted to study the effect of soaking time and polymerization temperature on the mechanical and physical properties of polymer-impregnated concrete. Soaking time was controlled in 4, 8, 12, 16, 20 and 24 h, polymerization temperature was set at 70, 80 and 90 °C for 0.5, 1, 2, 4, 6, 12 and 24 h in impregnation process, respectively. Cylindrical concrete specimens with water/cement ratios of 0.45 and 0.65 were impregnated with methyl methacrylate (MMA) and benzoyl peroxide (BPO) mixtures. The polymer loading increases as immersion time increases until 12 h. Based on compressive strength and surface absorption, optimum polymerization temperature is 70 °C for Mix A (high cement content) and 80 °C for Mix B (low cement content). Polymer impregnation not only increases concrete strength and resistivity but also greatly decreases surface absorption comparing with normal concrete. SEM and MIP observations indicate that the micro-pores and meso-pores of PIC specimens are filled with PMMA and the total pore volume and maximum pore size are reduced significantly.     

Concrete building blocks made with recycled demolition aggregate

A study undertaken at the University of Liverpool has investigated the potential for using recycled demolition aggregate in the manufacture of precast concrete building blocks. Recycled aggregates derived from construction and demolition waste (C&DW) can be used to replace quarried limestone aggregate, usually used in coarse (6 mm) and fine (4 mm-to-dust) gradings. The manufacturing process used in factories, for large-scale production, involves a “vibro-compaction” casting procedure, using a relatively dry concrete mix with low cement content (≈100 kg/m³). Trials in the laboratory successfully replicated the manufacturing process using a specially modified electric hammer drill to compact the concrete mix into oversize steel moulds to produce blocks of the same physical and mechanical properties as the commercial blocks. This enabled investigations of the effect of partially replacing newly quarried with recycled demolition aggregate on the compressive strength of building blocks to be carried out in the laboratory. Levels of replacement of newly quarried with recycled demolition aggregate have been determined that will not have significant detrimental effect on the mechanical properties. Factory trials showed that there were no practical problems with the use of recycled demolition aggregate in the manufacture of building blocks. The factory strengths obtained confirmed that the replacement levels selected, based on the laboratory work, did not cause any significant strength reduction, i.e. there was no requirement to increase the cement content to maintain the required strength, and therefore there would be no additional cost to the manufacturers if they were to use recycled demolition aggregate for their routine concrete building block production.     

再生混凝土三向受压试验及强度准则

为了研究再生混凝土的三向受压力学性能,以强度等级、围压值和再生骨料取代率为变化参数,设计24个试件进行常规三向受压试验.试验观察了试件的破坏形态,获取了其峰值应力、峰值应变、应力-应变全过程曲线等重要数据,并提出了三向受压状态下再生混凝土的强度、弹性模量和峰值应变计算式.结果表明:三向受压状态下,再生混凝土表现为剪切型破坏;随着围压值的增大,再生混凝土的弹性模量、峰值应力及峰值应变均显著增大,并且峰点后的应力-应变曲线下降段较平缓,再生混凝土的延性提高.最后利用莫尔-库仑理论探讨了再生混凝土的破坏准则.     

二次搅拌工艺对混凝土性能影响的试验研究

针对传统混凝土搅拌工艺中存在的问题,讨论了先拌水泥砂浆法、先拌水泥净浆法、水泥裹砂法、水泥裹石法、粗细骨料全造壳法等二次搅拌工艺,研究了不同工艺流程对混凝土搅拌质量的影响,测试了不同条件下混凝土的匀质性、抗压强度指标及功率消耗,并与传统搅拌工艺进行了对比试验.在对不同工艺流程试验研究的基础上,结合目前普遍使用的双卧轴搅拌机的点,提出了提高搅拌速度的等速二次投料搅拌方案.结果表明：这种二次搅拌工艺较传统搅拌工艺能明显提高混凝土的搅拌质量和效率,改善了混凝土界面过渡区的粘结强度.     

Mechanical and elastic behaviour of concretes made of recycled-concrete coarse aggregates

In this paper an investigation of mechanical behaviour and elastic properties of recycled-aggregate concretes is presented. These concretes were prepared by alternatively using two different (coarse and finer coarse) recycled-aggregate fractions both made of recycled concrete coming from a recycling plant in which rubble from demolition is collected and suitably treated. Several concrete mixtures were prepared by using only virgin aggregates (as reference), 30% finer coarse recycled aggregate replacing fine gravel and 30% coarse recycled aggregate replacing gravel. Five different water to cement ratios were adopted as: 0.40, 0.45, 0.50, 0.55 and 0.60. Concrete workability was in the slump range of 190–200 mm. Compression tests were carried out after 28 days of wet curing. In addition, concrete elastic modulus and drying shrinkage were evaluated. Results obtained showed that structural concrete up to C32/40 strength class can be manufactured by replacing 30% virgin aggregate with recycled-concrete aggregate. Moreover, a correlation between elastic modulus and compressive strength of recycled-aggregate concrete was found and compared to those reported in the literature. Finally, on the basis of drying shrinkage results, particularly if finer coarse recycled-concrete aggregate is added to the mixture, lower strains could be detected especially for earlier curing time.     

Mechanical properties of normal and high strength concretes subjected to high temperatures and using image analysis to detect bond deteriorations

The effect of high temperatures, up to 250 °C, on mechanical properties of normal and high strength concretes with and without silica fume was investigated, and image analysis was performed on split concrete surfaces to see the change in bond strength between aggregate and mortar. Specimens were heated up to elevated temperatures (50, 100, 150, 200, 250 °C) without loading and then the residual compressive and splitting tensile strength, as well as the static modulus of elasticity of the specimens were determined. For normal strength concrete residual mechanical properties started to decrease at 100 °C, while using silica fume reduced the losses at high temperatures. In terms of percent residual properties, high strength concrete specimens performed better than normal strength concrete specimens for all heating cycles. Image analysis studies on the split surfaces have been utilized to investigate the effect of high temperatures on the bond strength between aggregate and mortar. Image analysis results showed that reduced water–cement ratio and the use of silica fume improved the bond strength at room temperature, and created more stable bonding at elevated temperatures up to 250 °C.     

尺寸效应对水泥净浆与粗骨料界面黏结性能的影响

分析了粗骨料的尺寸对混凝土过渡区界面黏结性能的影响,并通过劈裂抗拉试验、压剪试验获得了粗骨料和硬化水泥浆之间的劈裂抗拉强度及抗剪强度.结果表明:粗骨料的尺寸对界面过渡区的黏结性能有较大的影响,界面黏结强度随粗骨料尺寸的增大而减小;水灰比越低,界面黏结性能越好;粗骨料的类型对界面过渡区黏结性能也有较大性能的影响.     

Experimental investigations on the influence of paste composition and content on the properties of Self-Compacting Concrete

The aim of this paper is to investigate the influence of paste composition and paste volume on the fresh and hardened properties of Self-Compacting Concrete. Nineteen SCC mixtures were investigated for different paste composition and paste volume. Fresh concrete tests such as slump flow, J ring, and V funnel test were performed; hardened concrete tests were limited to compressive strength. The results revealed that slump flow and J ring flow increased with increase in paste volume. A simple empirical equation was proposed for the determination of the paste volume for the required slump flow of SCC. Compressive strength of the different SCC mixtures ranged between 20 MPa and 70 MPa.