Co–gasification of coal/biomass blends in 50 kWe circulating fluidized bed gasifier

This paper reports gasification of coal/biomass blends in a pilot scale (50 kWe) air-blown circulating fluidized bed gasifier. Yardsticks for gasification performance are net yield, LHV and composition and tar content of producer gas, cold gas efficiency (CGE) and carbon conversion efficiency (CCE). Net LHV decreased with increasing equivalence ratio (ER) whereas CCE and CGE increased. Max gas yield (1.91 Nm³/kg) and least tar yield (5.61 g/kg of dry fuel) was obtained for coal biomass composition of 60:40 wt% at 800 °C. Catalytic effect of alkali and alkaline earth metals in biomass enhanced char and tar conversion for coal/biomass blend of 60:40 wt% at ER = 0.29, with CGE and CCE of 44% and 84%, respectively. Gasification of 60:40 wt% coal/biomass blend with dolomite (10 wt%, in-bed) gave higher gas yield (2.11 Nm³/kg) and H₂ content (12.63 vol%) of producer gas with reduced tar content (4.3 g/kg dry fuel).     

Characteristics of cyclone gasification of rice husk

The gasification characteristics of the rice husk were studied in a cyclone gasifier using air as the gasifying medium to generate the fuel gas with available heating value and less tar content. The influence of equivalence ratio on temperature profiles, composition and low heating value of the produced gas, tar content, carbon conversion and cold gas efficiency was investigated. The equivalence ratios considered in this study were 0.20–0.32. The results show that the optimal equivalence ratio is 0.29 and the maximum temperature of gasification should be lower than 1000 °C. In order to optimize the performance of the cyclone gasifier, the main body of the gasifier was lengthened and air staged gasification was carried out. The low heating value of the produced gas, carbon conversion, cold gas efficiency and tar content are 4.72 MJ/Nm³, 57.5%, 37.3% and 1.85 g/Nm³, respectively.     

Experimental study on biomass gasification in a double air stage downdraft reactor

This work presents an experimental study of the gasification of a wood biomass in a moving bed downdraft reactor with two-air supply stages. This configuration is considered as primary method to improve the quality of the producer gas, regarding its tar reduction. By varying the air flow fed to the gasifier and the distribution of gasification air between stages (AR), being the controllable and measurable variables for this type of gasifiers, measuring the CO, CH₄ and H₂ gas concentrations and through a mass and energy balance, the gas yield and its power, the cold efficiency of the process and the equivalence ratio (ER), as well as other performance variables were calculated. The gasifier produces a combustible gas with a CO, CH₄ and H₂ concentrations of 19.04, 0.89 and 16.78% v respectively, at a total flow of air of 20 Nm³ h⁻¹ and an AR of 80%. For these conditions, the low heating value of the gas was 4539 kJ Nm⁻³. Results from the calculation model show a useful gas power and cold efficiency around 40 kW and 68%, respectively. The resulting ER under the referred operation condition is around 0.40. The results suggested a considerable effect of the secondary stage over the reduction of the CH₄ concentration which is associated with the decreases of the tar content in the produced gas. Under these conditions the biomass devolatilization in the pyrolysis zone gives much lighter compounds which are more easily cracked when the gas stream passes through the combustion zone.     

First and second law thermodynamic analysis of a single and dual-stage ignition biomass downdraft gasifier

The dual-stage ignition biomass downdraft gasifier is an enormous tar reduction technology as against a single-stage ignition biomass gasification. Exergetic analysis of the system guides toward a possible performance enhancement. In dual-stage gasification, around 67.76% of input exergy is destructed in the several components, while 9.16% is obtained as a useful exergy output and 24.34% is found to be as a useful energy output there. The entire unit was assessed with a progressively rising electric load from 15.24 kW to 38.86 kW. The enhanced producer gas quality comes from 57% combustible gas with a higher heating value of 6.524 MJ/Nm³ and tar content of 7 mg/Nm³ after the paper filter, whereas the biomass consumption rate is 58 kg/h at the greatest load with the grate temperature of 1310–1370 °C. The samples of exhaust gas emissions are obtained environmentally favorable. The results even described that the dual-stage ignition biomass downdraft gasifier has significantly greater energetic and exergetic efficiency as compared to the single-stage gasifier.     

Hydrogen-rich gas production from biomass steam gasification in an updraft fixed-bed gasifier combined with a porous ceramic reformer

This paper investigates the hydrogen-rich gas produced from biomass employing an updraft gasifier with a continuous biomass feeder. A porous ceramic reformer was combined with the gasifier for producer gas reforming. The effects of gasifier temperature, equivalence ratio (ER), steam to biomass ratio (S/B), and porous ceramic reforming on the gas characteristic parameters (composition, density, yield, low heating value, and residence time, etc.) were investigated. The results show that hydrogen-rich syngas with a high calorific value was produced, in the range of 8.10–13.40 MJ/Nm³, and the hydrogen yield was in the range of 45.05–135.40 g H₂/kg biomass. A higher temperature favors the hydrogen production. With the increasing gasifier temperature varying from 800 to 950 °C, the hydrogen yield increased from 74.84 to 135.4 g H₂/kg biomass. The low heating values first increased and then decreased with the increased ER from 0 to 0.3. A steam/biomass ratio of 2.05 was found as the optimum in the all steam gasification runs. The effect of porous ceramic reforming showed the water-soluble tar produced in the porous ceramic reforming, the conversion ratio of total organic carbon (TOC) contents is between 22.61% and 50.23%, and the hydrogen concentration obviously higher than that without porous ceramic reforming.     

Experimental analysis of air-steam gasification of biomass with coal-bottom ash

Biomass gasification is an attractive option for producing high-quality syngas (H₂+CO) due to its environmental advantages and economic benefits. However, due to some technical problems such as tar formation, biomass gasification has not yet been able to achieve its purpose. The purpose of this work was to study the catalytic activity of coal-bottom ash for fuel gas production and tar elimination. Effect of gasification parameters including reaction temperature (700–900 °C), equivalence ratio, EQR (0.15–0.3) and steam-to-biomass ratio, SBR (0.34–1.02) and catalyst loading (5.0–13 wt %) on gas distribution, lower heating value (LHV) of gas steam, tar content, gas yield and H₂/CO ratio was studied. The tar content remarkably decreased from 3.81 g/Nm³ to 0.97 g/Nm³ by increasing char-bottom ash from 5.0 wt% to 13.0 wt%. H₂/CO significantly increased from 1.12 to 1.54 as the char-bottom ash content in the fuel increased from 5.0 wt% to 13.0 wt%.     

Non-catalytic autothermal gasification of woody biomass

The non-catalytic autothermal gasification of woody biomass with air and steam mixtures is thermodynamically and experimentally investigated. A laboratory-scale fixed-bed downdraft reactor was used to gasify fine-grained woody biomass particles (German conifer, mean particle size = 133.7 μm) at atmospheric pressure and at 900-1020 K, with an equivalence ratio (ER) in the range 0.3-0.4 and a steam-to-biomass ratio (SB) in the range 0-0.6. The gasification efficiency and carbon conversion peaked at 35% and 83%, respectively, for ER = 0.4 and SB = 0.6. Hydrogen yield increased with both ER and SB within the ranges considered. The corresponding volumetric lower heating value of the dry gaseous product varied from 2.0 to 3.4 MJ/Nm³.     

An experimental study on air gasification of biomass micron fuel (BMF) in a cyclone gasifier

Biomass micron fuel (BMF) produced from feedstock (energy crops, agricultural wastes, forestry residues and so on) through an efficient crushing process is a kind of powdery biomass fuel with particle size of less than 250 μm. Based on the properties of BMF, a cyclone gasifier concept has been considered in our laboratory for biomass gasification. The concept combines and integrates partial oxidation, fast pyrolysis, gasification, and tar cracking, as well as a shift reaction, with the purpose of producing a high quality of gas. In this paper, characteristics of BMF air gasification were studied in the gasifier. Without outer heat energy input, the whole process is supplied with energy produced by partial combustion of BMF in the gasifier using a hypostoichiometric amount of air. The effects of equivalence ratio (ER) and biomass particle size on gasification temperature, gas composition, gas yield, low-heating value (LHV), carbon conversion and gasification efficiency were studied. The results showed that higher ER led to higher gasification temperature and contributed to high H₂-content, but too high ER lowered fuel gas content and degraded fuel gas quality. A smaller particle was more favorable for higher gas yield, LHV, carbon conversion and gasification efficiency. And the BMF air gasification in the cyclone gasifier with the energy self-sufficiency is reliable.     

Biomass-based hydrogen production: A review and analysis

In this study, various processes for conversion of biomass into hydrogen gas are comprehensively reviewed in terms of two main groups, namely (i) thermo-chemical processes (pyrolysis, conventional gasification, supercritical water gasification (SCWG)), and (ii) biological conversions (fermentative hydrogen production, photosynthesis, biological water gas shift reactions (BWGS)). Biomass-based hydrogen production systems are discussed in terms of their energetic and exergetic aspects. Literature studies and potential methods are then summarized for comparison purposes. In addition, a biomass gasification process via oxygen and steam in a downdraft gasifier is exergetically studied for performance assessment as a case study. The operating conditions and strategies are really important for better performance of the system for hydrogen production. A distinct range of temperatures and pressures is used, such as that the temperatures may vary from 480 to 1400 °C, while the pressures are in the range of 0.1–50 MPa in various thermo-chemical processes reviewed. For the operating conditions considered the data for steam biomass ratio (SBR) and equivalence ratio (ER) range from 0.6 to 10 and 0.1 to 0.4, respectively. In the study considered, steam is used as the gasifying agent with a product gas heating value of about 10–15 MJ/Nm³, compared to an air gasification of biomass process with 3–6 MJ/Nm³. The exergy efficiency value for the case study system is calculated to be 56.8%, while irreversibility and improvement potential rates are found to be 670.43 and 288.28 kW, respectively. Also, exergetic fuel and product rates of the downdraft gasifier are calculated as 1572.08 and 901.64 kW, while fuel depletion and productivity lack ratios are 43% and 74.3%, respectively.     

Effect of the type of gasifying agent on gas composition in a bubbling fluidized bed reactor

It is commonly accepted that gasification of coal has a high potential for a more sustainable and clean way of coal utilization. In recent years, research and development in coal gasification areas are mainly focused on the synthetic raw gas production, raw gas cleaning and, utilization of synthesis gas for different areas such as electricity, liquid fuels and chemicals productions within the concept of poly-generation applications. The most important parameter in the design phase of the gasification process is the quality of the synthetic raw gas that depends on various parameters such as gasifier reactor itself, type of gasification agent and operational conditions. In this work, coal gasification has been investigated in a laboratory scale atmospheric pressure bubbling fluidized bed reactor, with a focus on the influence of the gasification agents on the gas composition in the synthesis raw gas. Several tests were performed at continuous coal feeding of several kg/h. Gas quality (contents in H₂, CO, CO₂, CH₄, O₂) was analyzed by using online gas analyzer through experiments. Coal was crushed to a size below 1 mm. It was found that the gas produced through experiments had a maximum energy content of 5.28 MJ/Nm³ at a bed temperature of approximately 800 °C, with the equivalence ratio at 0.23 based on air as a gasification agent for the coal feedstock. Furthermore, with the addition of steam, the yield of hydrogen increases in the synthesis gas with respect to the water–gas shift reaction. It was also found that the gas produced through experiments had a maximum energy content of 9.21 MJ/Nm³ at a bed temperature range of approximately 800–950 °C, with the equivalence ratio at 0.21 based on steam and oxygen mixtures as gasification agents for the coal feedstock. The influence of gasification agents, operational conditions of gasifier, etc. on the quality of synthetic raw gas, gas production efficiency of gasifier and coal conversion ratio are discussed in details.     

Enhanced trace pollutants removal efficiency and hydrogen production in rice straw gasification using hot gas cleaning system

This study investigates the enhancement of tar and trace gaseous pollutants (e.g. hydrogen sulfide (H₂S) and hydrogen chloride (HCl) removal efficiency derived from rice straw gasification using an integrated hot-gas cleaning system. A bubbling fluidized bed gasifier was used by controlling the temperature at 800 °C and equivalence ratio (ER) ranging 0.2 to 0.4. The hot gas cleaning system was operated at 250 °C and designed to combine three types of absorbents including zeolite, calcined dolomite, and activated carbon. Tar, H₂S, and HCl removal efficiency and enhanced hydrogen production were also discussed. The experimental results indicated that light fraction tar removal efficiency was higher than 90% and the overall tar removal efficiency was approximately 70%. In the case of ER 0.4, the syngas tar content was decreased from 71.88 g/Nm³ (without hot gas cleaning system) to 16.53 g/Nm³ (with hot gas cleaning system). The tar removal efficiency is nearly 77% using the hot gas cleaning system. The HCl and H₂S removal efficiency ranged from 94% to 98% and from 80.7% to 83.92%, respectively. In the case of ER 0.3 and with the hot gas cleaning system, the HCl and H₂S concentrations in cleaned syngas gas were less than 40 ppm and 100 ppm, respectively. Meanwhile, the hydrogen concentration of produced gas was also increased from 6.82% to 9.83% with hot gas cleaning system used. It means that the hot gas cleaning system can effectively remove HCl and H₂S from produced gas in gasification, but also it has good potential for improving syngas quality and enhancing gas turbine application in the future.     

Downdraft gasifier structure and process improvement for high quality and quantity producer gas production

The current study reveals several efficient amenities that can affect the gasification process to improve syngas quality and yield. A comprehensive study was carried out using a 24 kW downdraft gasifier to evaluate the effect of uniform air distribution in the oxidation zone, additional throat on the reactor temperature distribution and the overall gasification process. The effect of fuel moisture, equivalence ratio, gasifying agent type and pre-treatment of the gasifying agent on producer gas yield and composition were also evaluated. The biomass feeding rate was 30–40 kg/h, and the maximum gas flow rate was 90 m³/h. When corn cobs and waste wood (carpenter waste) with moisture content from 5 to 30% were used as feed stock, with 70 °C air as the gasifying/oxidizing agent, the energy value of the producer/syngas obtained was 6.31 and 6.66 MJ/m³, respectively. The heating value was improved to 6.72 and 8.43 MJ/m³ when using 150 °C air-steam mixture as the gasifying agent, with the optimum equivalence ratio of 0.30. The methane, hydrogen and carbon monoxide concentration (on volume basis) were 6.20, 19.32 and 21.00. The average amount of syngas produced from 1 kg of corn cobs and waste wood were 2.94 and 2.62 m³, while the average amount of tar produced was 2.2 and 1.8 g/Nm³ respectively. The investigation revealed that uniform air distribution in the oxidation zone, fuel moisture content, gasifying agent type and the pre-treatment of gasifying agent played a significant role in enhancing the quantity and quality of the producer gas.     

Gasification and power generation characteristics of woody biomass utilizing a downdraft gasifier

Energy utilization from biomass resources has started to attract public attention as a method to reduce CO₂ emissions. In this study, the characteristics of syngas production from biomass gasification were investigated in a downdraft gasifier that was combined with a small gas engine system for power generation. Syngas temperatures from the gasifier were maintained at a level of 700-1000 °C. When the air ratio for gasification was 0.3-0.35, the low heating value of syngas was 1100-1200 kcal Nm⁻³ and the cold gas efficiency 69-72%. Tar concentration in raw syngas was around 3.9-4.4 g Nm⁻³. Syngas combustion in the gas engine after purification showed that HC concentration was below 200 ppm, and NOx concentration was below 40 ppm in the exhaust gas.     

Syngas production from biomass gasification in China: A clean strategy for sustainable development

Biomass gasification, which can be categorized as a set of relatively clean processes, is a good option for hydrogen production. The main purpose of the present work was to focus on the use of natural olivine as a bed material to minimize the tar content and enhance the hydrogen yield. The catalytic gasification tests were carried out in a fluidized bed gasifier using steam as the fluidizing medium. Hydrogen yield slightly increased from 51.9 to 53.1 g/kg biomass, as biomass particle size (BP) decreased from 5.0 to 2.0 mm. The yield of tar also decreased from 0.15 to 0.07 g/Nm³ with BP decreasing from 5.0 to 2.0 mm. With an increase in the catalyst-to-biomass ratio (C/B) from 0.2 to 0.8, HY increased from 47.8 to 51.9 g/kg biomass and tar content (TC) decreased from 0.8 to 0.15 g/Nm³. Temperature and steam/biomass ratio (S/B) were also affected the syngas composition and HY, significantly.     

Biomass gasification in a 100 kWth steam-oxygen blown circulating fluidized bed gasifier: Effects of operational conditions on product gas distribution and tar formation

Biomass gasification is one of the most promising technologies for converting biomass, a renewable source, into an easily transportable and usable fuel. Two woody biomass fuels Agrol and willow, and one agriculture residue Dry Distiller’s Grains with Solubles (DDGS), have been tested using an atmospheric pressure 100 kWth steam-oxygen blown circulating fluidized bed gasifier (CFB). The effects of operational conditions (e.g. steam to biomass ratio (SBR), oxygen to biomass stoichiometric ratio (ER) and gasification temperature) and bed materials on the composition distribution of the product gas and tar formation from these fuels were investigated. Experimental results show that there is a significant variation in the composition of the product gas produced. Among all the experiments, the averaged concentration of H₂ obtained from Agrol, willow and DDGS over the temperature range from 800 to 820 °C was around 24 vol.%, 28 vol.% and 20 vol.% on a N₂ free basis, respectively. A fairly high amount of H₂S (∼2300 ppmv), COS (∼200 ppmv) and trace amounts of methyl mercaptan (<3 ppmv) on a N₂ free basis were obtained from DDGS. Due to a relatively high content of K and Cl in DDGS fuel, an alkali-getter (e.g. kaolin) was added to avoid agglomeration during gasification. Higher temperatures and SBR values were favorable for increasing the mole ratio of H₂ to CO and the tar decomposition but less advantageous for the formation of CH₄. Meanwhile, higher temperatures and SBR values also led to higher gas yields, whereas a higher SBR caused a lower carbon conversion efficiency (CCE%), cold gas efficiency (CGE%) and heating values of the product gas due to a high steam content in the product gas. From solid phase adsorption (SPA) results, the total tar content obtained from Agrol was the highest at around 12.4 g/Nm³, followed by that from DDGS and willow gasification. The lowest tar content produced from Agrol, willow and DDGS using Austrian olivine (Bed 1) as bed materials was 5.7, 4.4 and 7.3 g/Nm³, values which were obtained at a temperature of 730, 820 and 730 °C, SBR of 1.52, 1.14 and 1.10, and ER of 0.36, 0.39 and 0.37, respectively.     

Simulation and economic evaluation of biomass gasification with sets for heating,cooling and power production

In this work, syngas was used directly as fuel source for the renewable CCHP system, which can be producted through biomass gasification process. The advantages and limitation of entrained flow gasifier are compared, followed by discussion on the key parameters that are critical for the optimum production of syngas. Gasification agent of 450 °C temperature and 30 atm pressure has been proposed as a optical solution to a entrained flow gasifier using air as gasification agent at 0.27 ER (oxygen equivalence ratio), in that it provides a syngas of 5.665 MJ/m³ LHV and up to 77% gasification efficiency. Depending on the key parameters of gasification process, the properties of syngas produced can be varied. It is thus essential to thoroughly understand the cogeneration system to identify the suitable methods for a renewable CCHP system. These process was simulated using Aspen Plus to perform the rigorous material and energy balances. The results obtained from simulation and experiment agreed well. This paper later focused on economic evaluation of the entire process, as well as the environmental benefits. The renewable CCHP system could able to attain lower CO₂ and SO₂ emission with total energy efficiency and gas yield of 75.43% and 2.476 m³/kg respectively.     

Experimental study on sawdust gasification in a spout–fluid bed reactor

This paper summarizes the experimental results of sawdust gasification in a spout–fluid bed reactor. Three scenarios were investigated in this study. In the base case scenario, a total of 15 experiments consisting of three different flow rates (55, 65 and 75 m³ h^{? 1}) of primary air of each of having five equivalence ratios (ER) (0.35, 0.3, 0.25, 0.2 and 0.15) were conducted. The influence of secondary air in the freeboard and the effect of the recirculation of carryover captured by the cyclone to the reactor's freeboard at an ER of 0.25 were investigated in two other scenarios. Higher heating values of 3.02 and 5.15 MJ Nm^{? 3} were obtained with the ER values of 0.35 and 0.15, respectively, in the base case. However, opposite trend was observed for the tar content in the producer gas. At ER of 0.35, a value of 2.35 g Nm^{? 3} was found compared with 8.4 g Nm^{? 3} at ER of 0.15. The tar content in the producer gas was reduced from 5.63 to 1.53 g Nm^{? 3} when secondary air was supplied in the freeboard due to an increase in temperature. The gasification efficiency was increased from 24.96% at the base case to 36.22% with the recirculation of carryover. Higher heating value of producer gas was found to be 4.2–4.4 MJ Nm^{? 3} in this case. The second law analysis of this process estimated the average exergy efficiency as 35.92% at ER of 0.35 and it increased with increasing ER. The recirculation of carryover not only increased the carbon conversion efficiency but also the exergy efficiency. Copyright © 2010 John Wiley & Sons, Ltd.     

Performance evaluation of an innovative 100 kWth dual bubbling fluidized bed gasifier through two years of experimental tests: Results of the BLAZE project

In this work, the results of two years of experimental tests on an innovative dual bubbling fluidized bed gasifier are reported. These are related to the activities of the BLAZE project (Horizon 2020) for the integration of steam biomass gasification and solid oxide fuel cell. Several tests were carried out on the pilot-scale reactor at various operating conditions, and in this work the results are reported in terms of dry gas composition and yield, organic and inorganic contaminants (tar, particulate matter, H₂S). The compact design of the gasifier (a single reactor with two concentric chambers and in-situ hot gas cleaning and conditioning) reduces the heat losses and produces close to nitrogen-free syngas. Preliminary tests using a filter candle filled with conventional catalyst, installed in the freeboard of the gasifier, show that the tar content dropped to about 2 g/Nm³, and the H₂ concentration increased up to 41%_vol,dry.     

Hydrogen-rich gas production from biomass air and oxygen/steam gasification in a downdraft gasifier

Biomass gasification is an important method to obtain renewable hydrogen. However, this technology still stagnates in a laboratory scale because of its high-energy consumption. In order to get maximum hydrogen yield and decrease energy consumption, this study applies a self-heated downdraft gasifier as the reactor and uses char as the catalyst to study the characteristics of hydrogen production from biomass gasification. Air and oxygen/steam are utilized as the gasifying agents. The experimental results indicate that compared to biomass air gasification, biomass oxygen/steam gasification improves hydrogen yield depending on the volume of downdraft gasifier, and also nearly doubles the heating value of fuel gas. The maximum lower heating value of fuel gas reaches 11.11 MJ/N m³ for biomass oxygen/steam gasification. Over the ranges of operating conditions examined, the maximum hydrogen yield reaches 45.16 g H₂/kg biomass. For biomass oxygen/steam gasification, the content of H₂ and CO reaches 63.27–72.56%, while the content of H₂ and CO gets to 52.19–63.31% for biomass air gasification. The ratio of H₂/CO for biomass oxygen/steam gasification reaches 0.70–0.90, which is lower than that of biomass air gasification, 1.06–1.27. The experimental and comparison results prove that biomass oxygen/steam gasification in a downdraft gasifier is an effective, relatively low energy consumption technology for hydrogen-rich gas production.