Carbon black and hydrogen production process analysis

The adoption of new environmentally responsible technologies, as well as, energy efficiency improvements in equipment and processes help to reduce CO2 rate emission into the atmosphere, contributing in delaying the consequences of intensive use of fossil fuels. For more effective actions, it is necessary to make the transition from the fossil-based to the renewable source economy. In this context, hydrogen fuel has a special role as clean vector of energy. Hydrogen has the potential to be decisive in mitigating greenhouse gas emissions, but fossil fuels high profitability due to global energy dependency actually drives the global economy.While renewable energy sources are not worldwide fully established, new technologies should be developed and used for the recovery of energetic streams nowadays wasted, to decarbonize hydrocarbons and to improve systems efficiency creating a path that can help nations and industries in the needed energy economy transition. Hydrogen gas can be generated by various methods from different sources such as coal and water. Currently, almost all of the hydrogen production is for industrial purpose and comes from the Steam Reforming, while the use of hydrogen in fuel cells is only incipient.The article analysis the plasma pyrolysis of hydrocarbons as a decarbonization option to contribute as a step towards hydrogen economy. It presents the Carbon Black and Hydrogen Process (CB&H Process) as an alternative option for hydrogen generation at large scale facility, suitable for supplying large amounts of high-purity carbon in elemental form. CB&H Process refers to a plant with hydrogen thermal plasma reactor able to decompose Hydrocarbons (HC's) into Hydrogen (H2) and Carbon Black (CB), a cleaner technology than its competing processes, capable of generating two products with high added value. Considering the Brazilian context in which more than 80% of the generated electricity comes from renewable sources, the use of electricity as one of the inputs in the process does not compromise the objective of reducing greenhouse gas emissions. It is important to consider that the use of renewable energy to produce two products derived from fossil fuels in a clean way represents integration of technologies into a more efficient system and an arrangement that contributes to the transition from fossil fuels to renewables.The economic viability of the CB&H process as a hydrogen generation unit (centralized) for refining applications also depends on the cost of hydrogen production by competing processes. Steam Methane Reforming (SMR) is a widespread method that produces twice the amount of hydrogen generated by natural gas plasma pyrolysis, but it emits CO2 gas and consumes water, while CB&H process produces solid carbon. For this reason, the paper seeks the carbon production cost by plasma pyrolysis as a breakeven point for large-scale hydrogen generation without water consumption and carbon dioxide emissions.     

Design of a future hydrogen supply chain: A multi period model for Turkey

There is no doubt that energy will have one of highest priorities in agendas of strategic plans of countries. Since fossil fuels are running out and carbon emissions are more important than ever, researchers seek alternative clean and efficient energy sources. One of the best alternatives is hydrogen. The systems in which hydrogen flows from its production to end users are called hydrogen supply chains (HSC). Since hydrogen is not in active use, its HSC infrastructure is not complete and should be planned very carefully. We study the design of HSC of Turkey to meet the hydrogen demand of the period between 2021 and 2050. Our aim is to minimize total cost of the HSC while meeting the demand of the transportation sector. We address the problem by using a mixed integer programming (MIP) model and derive several insights for the future HSC. The results show that while decentralization (being able to fulfill the demand from local production facilities) is 12% in the first period, this rate raises up to 48% by the end of the planning horizon. Analysis also reveal that almost all grids do not produce and import hydrogen simultaneously, i.e., they either produce or import hydrogen. The results are robust in the sense that solutions of different optimality gaps have minor differences in terms of established facilities.     

Political,economic and environmental impacts of biomass-based hydrogen

The purpose of this study is to assess the political, economic and environmental impacts of producing hydrogen from biomass. Hydrogen is a promising renewable fuel for transportation and domestic applications. Hydrogen is a secondary form of energy that has to be manufactured like electricity. The promise of hydrogen as an energy carrier that can provide pollution-free, carbon-free power and fuels for buildings, industry, and transport makes it a potentially critical player in our energy future. Currently, most hydrogen is derived from non-renewable resources by steam reforming in which fossil fuels, primarily natural gas, but could in principle be generated from renewable resources such as biomass by gasification. Hydrogen production from fossil fuels is not renewable and produces at least the same amount of CO₂ as the direct combustion of the fossil fuel. The production of hydrogen from biomass has several advantages compared to that of fossil fuels. The major problem in utilization of hydrogen gas as a fuel is its unavailability in nature and the need for inexpensive production methods. Hydrogen production using steam reforming methane is the most economical method among the current commercial processes. These processes use non-renewable energy sources to produce hydrogen and are not sustainable. It is believed that in the future biomass can become an important sustainable source of hydrogen. Several studies have shown that the cost of producing hydrogen from biomass is strongly dependent on the cost of the feedstock. Biomass, in particular, could be a low-cost option for some countries. Therefore, a cost-effective energy-production process could be achieved in which agricultural wastes and various other biomasses are recycled to produce hydrogen economically. Policy interest in moving towards a hydrogen-based economy is rising, largely because converting hydrogen into useable energy can be more efficient than fossil fuels and has the virtue of only producing water as the by-product of the process. Achieving large-scale changes to develop a sustained hydrogen economy requires a large amount of planning and cooperation at national and international alike levels.     

Increased use of district heating in industrial processes – Impacts on heat load duration

Current knowledge of the potential for an increased use of industrial district heating (DH) due to conversions of industrial processes to DH is limited. In this paper, a Method for Heat Load Analysis (MeHLA) for exploring industrial DH conversions has been developed. This method can be a helpful tool for analyzing the impact different industrial processes have on the local DH system, when processes that utilize electricity and other fuels, convert to utilizing DH. Heat loads for different types of industries and processes are analyzed according to characteristics such as temperature levels and time-dependency. MeHLA has been used to analyze 34 Swedish industries and the method demonstrates how conversion of industrial processes to DH can result in heat load duration curves that are less outdoor temperature-dependent and more evenly distributed over the year. An evenly distributed heat load curve can result in increased annual operating time for base load DH plants such as cogeneration plants, leading to increased electricity generation. In addition to the positive effects for the DH load duration curve, the conversions to DH can also lead to an 11% reduction in the use of electricity, a 40% reduction in the use of fossil fuels and a total energy end-use saving of 6% in the studied industries. Converting the industrial processes to DH will also lead to a potential reduction of the global carbon dioxide emissions by 112,000 tonnes per year.     

Sustainable energy: A review of gasification technologies

Biomass has been widely recognized as a clean and renewable energy source, with increasing potential to replace conventional fossil fuels in the energy market. The abundance of biomass ranks it as the third energy resource after oil and coal. The reduction of imported forms of energy, and the conservation of the limited supply of fossil fuels, depends upon the utilization of all other available fuel energy sources. Energy conversion systems based on the use of biomass are of particular interest to scientists because of their potential to reduce global CO₂ emissions. With these considerations, gasification methods come to the forefront of biomass-to-energy conversions for a number of reasons. Primarily, gasification is more advantageous because of the conversion of biomass into a combustible gas, making it a more efficient process than other thermochemical processes. Biomass gasification has been studied widely as an efficient and sustainable technology for the generation of heat, production of hydrogen and ethanol, and power generation. Renewable energy can have a significant positive impact for developing countries. In rural areas, particularly in remote locations, transmission and distribution of energy generated from fossil fuels can be difficult and expensive, a challenge that renewable energy can attempt to correct by facilitating economic and social development in communities. This paper aims to take stock of the latest technologies for gasification.     

Spatial optimization of Jatropha based electricity value chains including the effect of emissions from land use change

Jatropha was identified as a potential feedstock to satisfy off-grid and on-grid energy solutions. However, the potential has been questioned due to agronomic frustrations, the lack of an organized value chain and heavy criticism on biofuels due to emissions triggered by land use change (LUC). To contribute to the realistic integration of Jatropha in rural development, this article proposes a modeling approach to probe the feasibility of Jatropha-based electrification in rural Africa and the layout of such a value chain.A multi-component modeling setup is presented, featuring a life cycle inventory, spatial modeling and the optimization model, OPTIMASS. In this modeling setup, OPTIMASS is parameterized with data regarding the global warming potential and the potential location of each operation in the value chain including cultivation sites and related LUC emissions. This enables OPTIMASS to spatially design the Jatropha-based on-grid and off-grid electrification value chain (i.e. cultivation, transport and storage, biofuel production and electricity generation) in Southern Mali with minimal GWP to reach 10% substitution of fossil fuels for Jatropha in electricity production for a current and two future electricity demand scenarios.Analysis of the optimization results demonstrates that emissions from transporting the oil are lower than LUC emissions per harvestable seed of other sites. Finally, it can be said that harnessing the entirety of the Jatropha value chain is crucial to make it GWP competitive relative to fossil fuels in which the location of plantations is crucial to attain low LUC-related emissions and viable yields.     

Optimization and analysis of a hydrogen supply chain in terms of cost,CO2 emissions,and risk: the case of Turkey

The transportation sector, which is largely dependent on oil, is faced with many problems such as the danger of depletion of fossil fuels that are harmful to the environment. Moreover, the situations such as epidemics and war cause excessive fluctuations in oil prices. Therefore, there is a need for new solutions based on alternative energy sources for a sustainable transportation sector. Hydrogen fuel cell electric vehicles (HFCEV) are one of the significant alternatives for an efficient, zero emissions and sustainable transportation system. Considering the potential investment in HFCEV technology, the need for a cost effective, green, and low risk Hydrogen Supply Chain (HSC) network infrastructure is inevitable. In this study, the HSC design of the Turkish transportation sector over a 25-year period (2026–2050) is investigated. The problem is modeled using a multi-period mixed integer linear programming (MIP) model. Three objectives are addresses: cost, carbon dioxide (CO₂) emissions and safety risk. In order to consider the uncertainty in the hydrogen demand, five different scenarios are analyzed using fuzzy concept. There are four main results. First, unit hydrogen cost is found to be very high due to low demand and high capital cost in the initial period (2026–2031). Second, HSC network is established in a decentralized setting in all scenario solutions. The level of decentralization gets stronger over time and with increasing demand. Third, short-distance road transport is generally preferred for hydrogen transport. Fourth, since the aim is to minimize cost, CO₂ emissions, and risk level, a mixed production strategy based on cost-oriented SMR and zero-emissions-oriented Electrolysis (ELE) is observed in all scenarios.     

Mathematical and computational approaches for design of biomass gasification for hydrogen production: A review

The ever growing environmental concern caused by excessive use of fossil fuels in energy and transportation systems triggered considerable investigations on alternative energy sources such as biomass. Furthermore, the availability and security of fossil fuels to meet future global energy need are also subjected to uncertainty. For these reasons, the world's current focus is shifted towards hydrogen-based future economy. Gasification is a proven technology to produce satisfactory yield of hydrogen. Many studies have been performed to increase the production yield. Due to the extensive range of investigations, mathematical and computational approaches have been applied to conduct these studies. Thus, this paper aims to update and broaden the review coverage by incorporating works done to materialize the investigations on the potential of producing hydrogen from biomass via gasification encompassing mathematical modeling, simulation, optimization, process heat integration and cogeneration. Each of these subjects is reviewed and analyzed which helped to identify their respective strength and areas which require further research effort.     

A review of hydrogen production and supply chain modeling and optimization

This paper reviews recent optimization models for hydrogen supply chains and production. Optimization is a central component of systematic methodologies to support hydrogen expansion. Hydrogen production is expected to evolve in the coming years to help replace fossil fuels; these high expectations arise from the potential to produce low-carbon hydrogen via electrolysis using electricity generated by renewable sources. However, hydrogen is currently mainly used in refinery and industrial operations; therefore, physical infrastructures for transmission, distribution, integration with other energy systems, and efficient hydrogen production processes are lacking. Given the potential of hydrogen, the greenfield state of infrastructures, and the variability of renewable sources, systematic methodologies are needed to reach competitive hydrogen prices, and design hydrogen supply chains. Future research topics are identified: 1) improved hydrogen demand projections, 2) integrated sector modeling, 3) improving temporal and spatial resolutions, 4) accounting for climate change, 5) new methods to address sophisticated models.     

A preliminary infrastructure design to use fossil fuels with carbon capture and storage and renewable energy systems

This paper proposes a design methodology for energy infrastructure to address the recent economic and environmental challenges. The proposed energy infrastructure was based on the recognition that fossil fuels will be used for some time with renewable energy sources because renewables are currently unable to replace fossil fuels entirely. A two-fold strategy for the energy infrastructure design is proposed. One is to minimize the negative impact of fossil fuel systems by installing carbon capture and storage (CCS) facilities to reduce greenhouse gas emissions. The other is to accelerate the introduction of renewable energy systems in their place. The design of integrated energy infrastructure is transformed as a Mixed Integer Linear Programming (MILP) problem. Cases of installing CCS and H₂ as a renewable energy source in Korea are illustrated with a discussion of the systematic design of energy infrastructure.