Brazilian biodiesel: The case of the palm's social projects

The Brazilian biodiesel program has created great demand for biodiesel. The production of oleaginous derived biodiesel produced by small-scale farmers is a key objective of PNPB. The Social Fuel Seal is one of the instruments for achieving this goal. Five years after the mandatory implementation of program, Brazil is among the world's leading producers of biodiesel. However, the goal of the productive insertion of small-scale farmers in Brazil's less favored regions has not been fully achieved. The Brazilian government has faced difficulties to promote regional development based on PNPB, consequently not reaching the audacious goals that were set at the beginning of the program. In this context of difficulties, the productive arrangements with palm oil should be emphasized. This paper submits in detail the model developed by Agropalma – in partnership with public agencies – together with family farming in the North of the country. These social projects are taken as reference and can promote social inclusion in the country's national biodiesel productive chain. Moreover, this case can serve as an assessment tool for other countries that seek to invest in the production of biodiesel with the concern for the social production inclusion of disadvantaged small-scale family farmers.     

Brazilian Biodiesel Policy: Social and environmental considerations of sustainability

The objective of this article is to analyze the Brazilian Biodiesel Policy (PNPB) and to identify the social and environmental aspects of sustainability that are present or absent within it. Biofuels, namely alcohol and biodiesel, have been increasing in popularity on a global scale due to their potential as alternative and renewable energy sources. Brazil, a vast country blessed with abundant natural resources and agricultural land, has emerged as a global leader in the production of biofuels. This article includes a brief analysis of the concept of sustainable development, which served as a basis to evaluate the Policy documents. Although PNPB's implementation, which began in 2004, is still within its initial stage, it was possible to identify and elaborate on the environmental and social aspects of the Policy, namely: the social inclusion of family farmers; regional development; food security; influencing the carbon and energy balance of biodiesel; promoting sustainable agricultural practices and a diversity of feedstock.     

Potentialities of energy generation from waste and feedstock produced by the agricultural sector in Brazil: The case of the State of Paraná

The State of Paraná contributes significantly for the Brazilian production of sugar cane, ethanol, soybeans and pigs. In addition to the current production of ethanol, the State has a huge potential for electricity, biodiesel and biogas production. This paper presents an overview of the current situation regarding energy generation from the agricultural sector in the State, an assessment of the potentialities of energy generation from sugar cane residues and pig agricultural chains, as well as an analysis of the socioeconomic factors underlying the availability of feedstock for biodiesel production. This study has shown that it is possible to expand the energy supply in the State using residual biomass from the sugar cane and pig production. On the other side, the biodiesel production increase in the State will depend on the expansion in the consumption of products that use the cake as raw material; the increase in the feedstock availability other than canola, castor beans and sunflower; the increase of the number of family farmers as feedstock providers, so as to ensure access for biodiesel producers to the Social Fuel Stamp.     

Ethanol and food production by family smallholdings in rural Brazil: Economic and socio-environmental analysis of micro distilleries in the State of Rio Grande do Sul

In light of the perspectives of ethanol from sugar cane industry in Brazil and the biofuelscurrent international debate, certain questions ought to be examined. The framework for future expansion of ethanol production, to meet with supply needs at national and international levels using the current production model, does not take into consideration the prospect of Brazil's regional and rural development. Although currently there are no impediments to the culture of sugar cane in Rio Grande do Sul (RS) State, Brazil's largest producer of biodiesel, it imports 98% of its demand for ethanol from São Paulo and other regions. The promotion of ethanol market in that State might pass for a productive model different from the practice in industrial monocultures, given their cultural and agricultural characteristics. The IFES (Integrated Food and Energy System) from COOPERBIO -n Cooperativa Mista de Produção, Industrialização e Comercialização de Biocombustíveis do Brasil Ltda., established on an experimental basis in the State, presents multiple economic, social and environmental benefits, potentializing the present food procuction by smallholders and favoring a sugar cane ethanol greater consumption in the inland of RS State. With a few tweaks and adequate governmental policies and instruments, the expansion of this model may even cover the current demand in the State. In addition to the production of energy and foods less dependent on fossil fuels, this model contributes for preservation of ecosystem services and for climate smart rural sustainable development.     

Greenhouse gas emissions and energy balance of palm oil biofuel

The search for alternatives to fossil fuels is boosting interest in biodiesel production. Among the crops used to produce biodiesel, palm trees stand out due to their high productivity and positive energy balance. This work assesses life cycle emissions and the energy balance of biodiesel production from palm oil in Brazil. The results are compared through a meta-analysis to previous published studies: Wood and Corley (1991) [Wood BJ, Corley RH. The energy balance of oil palm cultivation. In: PORIM intl. palm oil conference – agriculture; 1991.], Malaysia; Yusoff and Hansen (2005) [Yusoff S, Hansen SB. Feasibility study of performing an life cycle assessment on crude palm oil production in Malaysia. International Journal of Life Cycle Assessment 2007;12:50–8], Malaysia; Angarita et al. (2009) [Angarita EE, Lora EE, Costa RE, Torres EA. The energy balance in the palm oil-derived methyl ester (PME) life cycle for the cases in Brazil and Colombia. Renewable Energy 2009;34:2905–13], Colombia; Pleanjai and Gheewala (2009) [Pleanjai S, Gheewala SH. Full chain energy analysis of biodiesel production from palm oil in Thailand. Applied Energy 2009;86:S209–14], Thailand; and Yee et al. (2009) [Yee KF, Tan KT, Abdullah AZ, Lee KT. Life cycle assessment of palm biodiesel: revealing facts and benefits for sustainability. Applied Energy 2009;86:S189–96], Malaysia. In our study, data for the agricultural phase, transport, and energy content of the products and co-products were obtained from previous assessments done in Brazil. The energy intensities and greenhouse gas emission factors were obtained from the Simapro 7.1.8. software and other authors. These factors were applied to the inputs and outputs listed in the selected studies to render them comparable. The energy balance for our study was 1:5.37. In comparison the range for the other studies is between 1:3.40 and 1:7.78. Life cycle emissions determined in our assessment resulted in 1437 kg CO₂e/ha, while our analysis based on the information provided by other authors resulted in 2406 kg CO₂e/ha, on average. The Angarita et al. (2009) [Angarita EE, Lora EE, Costa RE, Torres EA. The energy balance in the palm oil-derived methyl ester (PME) life cycle for the cases in Brazil and Colombia. Renewable Energy 2009;34:2905–13] study does not report emissions. When compared to diesel on a energy basis, avoided emissions due to the use of biodiesel account for 80 g CO₂e/MJ. Thus, avoided life cycle emissions associated with the use of biodiesel yield a net reduction of greenhouse gas emissions. We also assessed the carbon balance between a palm tree plantation, including displaced emissions from diesel, and a natural ecosystem. Considering the carbon balance outcome plus life cycle emissions the payback time for a tropical forest is 39 years. The result published by Gibbs et al. (2008) [Gibbs HK, Johnston M, Foley JA, Holloway T, Monfreda C, Ramankutty N, et al., Carbon payback times for crop-based biofuel expansion in the tropics: the effects of changing yield and technology. Environmental Research Letters 2008;3:10], which ignores life cycle emissions, determined a payback range for biodiesel production between 30 and 120 years.     

Biodiesel production by ultrasound-assisted transesterification: State of the art and the perspectives

In the present paper state-of-the art and perspectives of ultrasound-assisted (UA) biodiesel production from different oil-bearing materials using acid, base and enzyme catalysts are critically discussed. The ultrasound action in biodiesel production is primarily based on the emulsification of the immiscible liquid reactants by microturbulence generated by radial motion of cavitation bubbles and the physical changes on the surface texture of the solid catalysts generating new active surface area. The importance of ultrasound characteristics and other process variables for the biodiesel yield and the reaction rate is focused on. UA transesterification is compared with other techniques for biodiesel production. Several different developing methods reducing the biodiesel production costs such as the optimization of process factors, the development of the process kinetic models, the use of phase transfer catalysts, the application of the continuous process, the design of novel types of ultrasonic reactors and the in situ ultrasound application in transesterification of oily feedstocks are also discussed.     

A model for biodiesel supply chain: A case study in Iran

Biodiesel is here considered as an alternative fuel in Iran in order to benefit from environmental aspects and contribution to final energy demand. An analytical tool is developed to consider different scenarios in biodiesel production. This study provides a regional framework in terms of techno-economic parameters to deeply understand the agricultural, technical, and economic aspects of biodiesel supply chain of Iran including resources, production, distribution, and consumer. The study further assesses the potential of biodiesel production in different geographical regions of Iran. It reveals the contribution of current potential resources to make the future biodiesel demand.     

Does biodiesel make sense?

In several countries biodiesel blending programs have been implemented looking for reduction in fossil fuel dependence and environmental benefits, including climate change mitigation. The current global biodiesel production, from different fatty raw materials, reaches about 6 billion liters per year and represents 10% of whole biofuel production. Nevertheless, in many cases the actual advantages of biodiesel production and usage are not clearly evaluated. Essentially, the feasibility of biodiesel production can be determined by its efficiency in solar energy conversion, as indicated by agro-industrial productivity and energy balance parameters, which expresses a relative demand of natural resources (land and energy) to produce biofuel. Taking into account the Brazilian conditions, in this paper an assessment of biodiesel production is presented, comparing four different productive systems. According to this evaluation, soybean and castor are limitedly feasible, whereas tallow and palm oil represent more suitable alternatives. The selection of an efficient productive system is crucial for the rationality of biodiesel production.     

Comparison of palm oil, Jatropha curcas and Calophyllum inophyllum for biodiesel: A review

The world today is faced with serious global warming and environmental pollution. Besides, fossil fuel will become rare and faces serious shortage in the near future. This has triggered the awareness to find alternative energy as their sustainable energy sources. Biodiesel as a cleaner renewable fuel has been considered as the best substitution for diesel fuel due to it being used in any compression ignition engine without any modification. The main advantages of using biodiesel are its renewability and better quality of exhaust gas emissions. This paper reviews the production, performance and emission of palm oil, Jatropha curcas and Calophyllum inophyllum biodiesel. Palm oil is one of the most efficient oil bearing crops in terms of oil yield, land utilization, efficiency and productivity. However, competition between edible oil sources as food with fuel makes edible oil not an ideal feedstock for biodiesel production. Therefore, attention is shifted to non-edible oil like Jatropha curcas and Calophyllum inophyllum. Calophyllum inophyllum oil can be transesterified and being considered as a potential biodiesel fuel. Compared to Palm oil and Jatropha biodiesel industry, biodiesel from Calophyllum inophyllum is still in a nascent state. Therefore, long term endurance research and tribological studies need to be carried out before Calophyllum inophyllum oil base biodiesel can become an alternative fuel in future.     

Production of biodiesel using high free fatty acid feedstocks

The enormous challenges faced in the search for suitable and profitable feedstocks to produce biodiesel cannot be over-emphasis. This paper has provided an overview of different catalysts used in processing different kinds of feedstocks for the production of biodiesel. Although the process of biodiesel production from refined feedstocks is less cumbersome and could provide biodiesel yield of more than 98%, but its product cost is high. Thus, the recent biodiesel production from low-quality feedstocks, though presents challenges but has equally provided biodiesel yield comparable to that obtained from refined feedstocks. Furthermore the physicochemical properties of biodiesel derived from low-quality feedstocks are discussed. Additionally economic evaluation of biodiesel from low-quality feedstocks is examined. The result showed that if less expensive feedstocks are used to produce biodiesel, a 25% reduction in cost production is possible. Thus making biodiesel price reasonably closed to the price of petro-diesel.     

Economic feasibility of biodiesel production from Macauba in Brazil

In this work the economic feasibility of biodiesel production in Brazil by using the Macauba oil as raw matter is studied. The software SIMB-E, in which a cash flow model applied to biodiesel production is implemented, was used during simulations. Economic indexes related to biodiesel production features, as well as the competitiveness between selling prices of biodiesel and petrodiesel were considered. It was found that all of the 8 simulated scenarios were potentially profitable, but only 2 of them presented competitive biodiesel selling prices, being considered as worthwhile projects. These were seed-oil plants with alkaline transesterification. Results also indicated that the success of biodiesel production still requires additional revenues beyond that derived from biodiesel itself, including income from the feedstock coproducts and glycerol. Macauba showed to be a potential crop to be used in biodiesel production. However, the domestication and improvement on processing of this species are indispensable to ensure its availability of long-term use.     

Comparison of performance characteristics of agricultural tractor diesel engine operating on home and industrially produced biodiesel

Owing to unstable diesel fuel prices in the world market, many farmers have been looking for alternative fuels. Vegetable oils are one of the alternatives, which can be used as fuel in diesel engines either in the form of straight vegetable oil or in the form of biodiesel. This study aims to present experimental data by utilization of home and industrial biodiesel as fuel in an agricultural tractor diesel engine. The home biodiesel production was made from different vegetable oils (crude rapeseed, edible sunflower and waste oil) with the process of one‐stage‐based catalyzed transesterification. A commercially available agricultural tractor ZETOR 7745 was employed. Measurements were taken on the power take‐off shaft by electrical dynamometer FROMENT XT200. According to the results, agricultural tractor diesel engine operating on home biodiesel fuels had better performance characteristics related to industrially produced biodiesel and similar to conventional diesel fuel. Copyright © 2009 John Wiley & Sons, Ltd.     

Artificial neural networks used for the prediction of the cetane number of biodiesel

Cetane number (CN) is one of the most significant properties to specify the ignition quality of any fuel for internal combustion engines. The CN of biodiesel varies widely in the range of 48–67 depending upon various parameters including the oil processing technology and climatic conditions where the feedstock (vegetable oil) is collected. Determination of the CN of a fuel by an experimental procedure is a tedious job for the upcoming biodiesel production industry. The fatty acid composition of base oil predominantly affects the CN of the biodiesel produced from it. This paper discusses the currently available CN estimation techniques and the necessity of accurate prediction of CN of biodiesel. Artificial Neural Network (ANN) models are developed to predict the CN of any biodiesel. The present paper deals with the application of multi-layer feed forward, radial base, generalized regression and recurrent network models for the prediction of CN. The fatty acid compositions of biodiesel and the experimental CNs are used to train the networks. The parameters that affect the development of the model are also discussed. ANN predicted CNs are found to be in agreement with the experimental CNs. Hence, the ANN models developed can be used reliably for the prediction of CN of biodiesel.     

Life cycle assessment and life cycle costing of bioethanol from sugarcane in Brazil

Brazil has always been the pioneer in the application of bioethanol as a main fuel for automobiles, hence environmental and economic analyses of the Brazilian ethanol industries are of crucial importance. This study presents a comparative life cycle assessment (LCA) on gasoline and ethanol as fuels, and with two types of blends of gasoline with bioethanol, all used in a midsize car. The focus is on a main application in Brazil, sugarcane based ethanol. The results of two cases are presented: base case—bioethanol production from sugarcane and electricity generation from bagasse; future case—bioethanol production from both sugarcane and bagasse and electricity generation from wastes. In both cases sugar is co-produced. The life cycles of fuels include gasoline production, agricultural production of sugarcane, ethanol production, sugar and electricity co-production, blending ethanol with gasoline to produce E10 (10% of ethanol) and E85 (85%), and finally the use of gasoline, E10, E85 and pure ethanol. Furthermore, a life cycle costing (LCC) was conducted to give an indication on fuel economy in both cases. The results show that in the base case less GHG is emitted; while the overall evaluation of these fuel options depends on the importance attached to different impacts. The future case is certainly more economically attractive, which has been the driving force for development in the ethanol industry in Brazil. Nevertheless, the outcomes depend very much on the assumed price for crude oil. In LCC a steady-state cost model was used and only the production cost was taken into account. In the real market the prices of fuels are very much dependent on the taxes and subsidies. Technological development can help in lowering both the environmental impact and the prices of the ethanol fuels.     

The role of technology transfer for the development of a local wind component industry in Chile

This paper contributes to the debate about climate change technology transfer by analysing barriers and enablers for a Chilean company starting up the production of wind blades. Literature on the role of technology transfer for the development and deployment of local renewable energy technologies in developing countries often refers to success stories in Brazil, India and China. Instead, this case study highlights the different challenges faced by smaller emerging economies. The paper argues that successful technology transfer in a smaller economy like Chile requires: a minimum internal demand and access to regional markets to attract foreign knowledge providers; a focus in the types of technologies where the recipient country or company have a competitive advantage; and active learning processes by the recipient company. Lessons are drawn for improving the design and implementation of technology-push and market-pull policies in small or medium emerging economies.     

Biodiesel production from Jatropha curcas oil

In view of the fast depletion of fossil fuel, the search for alternative fuels has become inevitable, looking at huge demand of diesel for transportation sector, captive power generation and agricultural sector, the biodiesel is being viewed a substitute of diesel. The vegetable oils, fats, grease are the source of feedstocks for the production of biodiesel. Significant work has been reported on the kinetics of transesterification of edible vegetable oils but little work is reported on non-edible oils. Out of various non-edible oil resources, Jatropha curcas oil (JCO) is considered as future feedstocks for biodiesel production in India and limited work is reported on the kinetics of transesterification of high FFA containing oil. The present study reports a review of kinetics of biodiesel production. The paper also reveals the results of kinetics study of two-step acid–base catalyzed transesterification process carried out at pre-determined optimum temperature of 65 and 50 °C for esterification and transesterification process, respectively, under the optimum condition of methanol to oil ratio of 3:7 (v/v), catalyst concentration 1% (w/w) for H₂SO₄ and NaOH and 400 rpm of stirring. The yield of methyl ester (ME) has been used to study the effect of different parameters. The maximum yield of 21.2% of ME during esterification and 90.1% from transesterification of pretreated JCO has been obtained. This is the first study of its kind dealing with simplified kinetics of two-step acid–base catalyzed transesterification process carried at optimum temperature of both the steps which took about 6 h for complete conversion of TG to ME.     

Transesterification of marine macroalgae using microwave technology

Biodiesel is renewable and environmental friendly, with calori?c value equivalent to regular fossil fuel. This fuel can be produced from a variety of feedstocks, such as ?rst-generation biodiesel feedstock (corn, peanut, soybean), second generation (jatropha, animal fats, waste cooking oils, macroalgae), and third generation (microalgae). Among these feedstocks, biodiesel production from microalgae has drawn special attention for different reasons: they have high lipid content and high growth rates; they are tolerant to severe environmental conditions; they offer the possibility of sequester carbon dioxide from the ?ue gases; their harvesting and transportation are economical compared to other crops; and they have very high photosynthetic yields compared to other terrestrial plants. The advantage of using macroalgae recollected on the beaches as raw material is that allows to obtained energy from a residue.

Microwave-assisted extraction and transesteri?cation of microalgae is being researched as a solution for biodiesel production by its benefits, such as shorter reaction times and less amount of heat energy to obtain biodiesel. It is due to the fact that microwaves can easily penetrate through the cell wall structure to extract and transesterify the oils into biodiesel.

The aim of this research was to explore the possibility of carrying out the microwave-assisted transesterification of three marine macroalgae (brown and green). Different experimental runs were carried out with different process parameters such as macroalgae-to-methanol ratio, reaction time and catalyst concentrations. Based on the obtained results, the best conditions for microwave-assisted transesteri?cation reaction were macroalgae-to-methanol ratio of 1:15 (wt/vol), sodium hydroxide concentration of 2 wt% and reaction time of 3 min.     

Modeling the land requirements and potential productivity of sugarcane and jatropha in Brazil and India using the LPJmL dynamic global vegetation model

The governments of Brazil and India are planning a large expansion of bioethanol and biodiesel production in the next decade. Considering that limitation of suitable land and/or competition with other land uses might occur in both countries, assessments of potential crop productivity can contribute to an improved planning of land requirements for biofuels under high productivity or marginal conditions. In this paper we model the potential productivity of sugarcane and jatropha in both countries. Land requirements for such expansions are calculated according to policy scenarios based on government targets for biofuel production in 2015. Spatial variations in the potential productivity lead to rather different land requirements, depending on where plantations are located. If jatropha is not irrigated, land requirements to fulfill the Indian government plans in 2015 would be of 410 000 to 95 000 km² if grown in low or high productivity areas respectively (mean of 212 000 km²). In Brazil land requirements, are of 18 000–89 000 km² (mean of 29 000 km²), suggesting a promising substitute to soybean biodiesel. Although future demand for sugarcane ethanol in Brazil is approximately ten times larger than in India, land requirements are comparable in both countries due to large differences in ethanol production systems. In Brazil this requirement ranges from 25 000 to 211 000 km² (mean of 33 000 km²) and in India from 7000 to 161 000 km² (mean 17 000 km²). Irrigation could reduce the land requirements by 63% and 41% (24% and 15%) in India (Brazil) for jatropha and sugarcane respectively.     

Capturing latecomer advantages in the adoption of biofuels: The case of Argentina

Although Argentina came late to the biofuels revolution, a series of measures taken recently at federal and provincial government level have created new opportunities. New federal laws on biofuels promotion have sparked an investment boom. The main activity has been in the biodiesel sector—partly because diesel is the dominant fuel sector in Argentina, and partly because the country had already engineered a soy revolution over the past 15 years, becoming the world's largest exporter of soy oil and soy meal. Biodiesel allows this revolution to be extended—from soy as foodstuff to soy as fuelstock. The biodiesel revolution now underway promises to extend Argentina's latecomer advantages by combining greater scale and lower costs with introduced technical innovations such as genetically modified crops and no-till farming. In this way, Argentina can be seen to be demonstrating the superiority of biofuel production in countries of the South over the conditions obtaining in countries of the North—including superior resources availability, superior energetics and lower costs. Whereas Brazil has demonstrated its superiority in sugarcane-based ethanol, Argentina is about to demonstrate its superiority in soy-based biodiesel.