A novel combined biomass and solar energy conversion-based multigeneration system with hydrogen and ammonia generation

In the present study, an innovative multigeneration plant for hydrogen and ammonia generation based on solar and biomass power sources is suggested. The proposed integrated system is designed with the integration of different subsystems that enable different useful products such as power and hydrogen to be obtained. Performance evaluation of designed plant is carried out using different techniques. The energetic and exergetic analyses are applied to investigate and model the integrated plant. The plant consists of the parabolic dish collector, biomass gasifier, PEM electrolyzer and hydrogen compressor unit, ammonia reactor and ammonia storage tank unit, Rankine cycle, ORC cycle, ejector cooling unit, dryer unit and hot water production unit. The biomass gasifier unit is operated to convert biomass to synthesis gaseous, and the concentrating solar power plant is utilized to harness the free solar power. In the proposed plant, the electricity is obtained by using the gas, Rankine and ORC turbines. Additionally, the plant generates compressed hydrogen, ammonia, cooling effect and hot water with a PEM electrolyzer and compressed plant, ammonia reactor, ejector process and clean-water heater, respectively. The plant total electrical energy output is calculated as 20,125 kW, while the plant energetic and exergetic effectiveness are 58.76% and 55.64%. Furthermore, the hydrogen and ammonia generation are found to be 0.0855 kg/s and 0.3336 kg/s.     

Design and analysis of a new solar hydrogen plant for power,methane, ammonia and urea generation

In this paper, a solar power-based combined plant for power, hydrogen, methane, ammonia and urea production is proposed. A parabolic trough collector is utilized for the system prime mover. Moreover, steam Rankine cycle, organic Rankine cycle, hydrogen production and compression subsystem, ammonia, methane and urea production units, single-effect absorption cooling unit, and freshwater production plant are integrated together to develop the present system for better system performance and cost-effectiveness and reduced environmental impact. In order to analyze and evaluate the proposed multigeneration plant, thermodynamic, parametric and economic studies are performed. According to the assessment results, it is found that energetic and exergetic efficiencies of the present multigeneration plant are 66.12% and 61.56%, respectively. The comparisons of the subsystem and overall plant efficiencies show that the highest energetic and energetic efficiencies belong to freshwater production plant by 79.24% and 75.62%, respectively. In addition, the present parametric analysis indicates that an increase in the reference temperature, solar radiation intensity and working pressure of the solar process has a positive effect on the plant's performance. The cost analysis reveals that as the solar radiation intensity and the working pressure of the solar process increase, the hydrogen generation cost decreases. Furthermore, the hydrogen generation cost is achieved to be 1.94 $/kgH₂ at 650 W/m² of the solar radiation intensity, with other parameters remaining constant.     

Energy and exergy analyses and optimization study of an integrated solar heliostat field system for hydrogen production

In this paper, we propose an integrated system, consisting of a heliostat field, a steam cycle, an organic Rankine cycle (ORC) and an electrolyzer for hydrogen production. Some parameters, such as the heliostat field area and the solar flux are varied to investigate their effect on the power output, the rate of hydrogen produced, and energy and exergy efficiencies of the individual systems and the overall system. An optimization study using direct search method is also carried out to obtain the highest energy and exergy efficiencies and rate of hydrogen produced by choosing several independent variables. The results show that the power and rate of hydrogen produced increase with increase in the heliostat field area and the solar flux. The rate of hydrogen produced increases from 0.006 kg/s to 0.063 kg/s with increase in the heliostat field area from 8000 m² to 50,000 m². Moreover, when the solar flux is increased from 400 W/m² to 1200 W/m², the rate of hydrogen produced increases from 0.005 kg/s to 0.018 kg/s. The optimization study yields maximum energy and exergy efficiencies and the rate of hydrogen produced of 18.74%, 39.55% and 1571 L/s, respectively.     

Thermodynamic performance analysis and environmental impact assessment of an integrated system for hydrogen and ammonia generation

A novel multigeneration plant that's using natural gas for power, hydrogen, ammonia, and hot water generation, is planned and analyzed, in the current paper. The suggested combined plant integrated with four sub-systems, which are the Brayton cycle, reheat Rankine cycle, the high-temperature steam electrolyzer for hydrogen production, and ammonia synthesis processes. Also, thermodynamic analysis and environmental impact assessment are conducted for the designed plant and sub-systems. Moreover, the sustainability index analysis of this proposed study is conducted. The effects of some important indicators on the performance and on the environmental impact of the modeled system and sub-processes are also studied. According to analyses results, it is noted that the energetic and exergetic efficiencies of the suggested system are 51.83% and 70.27%, respectively, and also the total CO₂ emission rate is 11.4 kg/kWh for the integrated plant. Furthermore, the total irreversibility rate is computed as 40007.68 kW, and furthermore, the combustion chamber has a maximum irreversibility rate with 20,033 kW, among the proposed plant components.     

Parametric analysis of a solar energy based multigeneration plant with SOFC for hydrogen generation

Renewable energy-based hydrogen production plants can offer potential solutions to both ensuring sustainability in energy generation systems and designing environmentally friendly systems. In this combined work, a novel solar energy supported plant is proposed that can generate hydrogen, electricity, heating, cooling and hot water. With the suggested integrated plant, the potential of solar energy usage is increased for energy generation systems. The modeled integrated system generally consists of the solar power cycle, solid oxide fuel cell plant, gas turbine process, supercritical power plant, organic Rankine cycle, cooling cycle, hydrogen production and liquefaction plant, and hot water production sub-system. To conduct a comprehensive thermodynamic performance analysis of the suggested plant, the combined plant is modeled according to thermodynamic equilibrium equations. A performance assessment is also conducted to evaluate the impact of several plant indicators on performance characteristics of integrated system and its sub-parts. Hydrogen production rate in the suggested plant according to the performance analysis performed is realized as 0.0642 kg/s. While maximum exergy destruction rate is seen in the solar power plant with 8279 kW, the cooling plant has the lowest exergy destruction rate as 1098 kW. Also, the highest power generation is obtained from gas turbine cycle with 7053 kW. In addition, energetic and exergetic efficiencies of solar power based combined cycle are found as 56.48% and 54.06%, respectively.     

A new integrated renewable energy system for clean electricity and hydrogen fuel production

In this paper, a new renewable energy-based cogeneration system for hydrogen and electricity production is developed. Three different methods for hydrogen production are integrated with Rankine cycle for electricity production using solar energy as an energy source. In addition, a simple Rankine cycle is utilized for producing electricity. This integrated system consists of solar steam reforming cycle using molten salt as a heat carrier, solar steam reforming cycle using a volumetric receiver reactor, and electrolysis of water combined with the Rankine cycle. These cycles are simulated numerically using the Engineering Equation Solver (EES) based on the thermodynamic analyses. The overall energetic and exergetic efficiencies of the proposed system are determined, and the exergy destruction and entropy generation rates of all subcomponents are evaluated. A comprehensive parametric study for evaluating various critical parameters on the overall performance of the system is performed. The study results show that both energetic and exergetic efficiencies of the system reach 28.9% and 31.1%, respectively. The highest exergy destruction rates are found for the steam reforming furnace and the volumetric receiver reforming reactor (each with about 20%). Furthermore, the highest entropy generation rates are obtained for the steam reforming furnace and the volumetric receiver reforming reactor, with values of 174.1 kW/K and 169.3 kW/K, respectively. Additional parametric studies are undertaken to investigate how operating conditions affect the overall system performance. The results report that 60.25% and 56.14% appear to be the highest exergy and energy efficiencies at the best operating conditions.     

Design and thermodynamic modeling of a renewable energy based plant for hydrogen production and compression

In the examined paper, a solar and wind energy supported integrated cycle is designed to produce clean power and hydrogen with the basis of a sustainable and environmentally benign. The modeled study mainly comprises of four subsystems; a solar collector cycle which operates with Therminol VP1 working fluid, an organic Rankine cycle which runs with R744 fluid, a wind turbine as well as hydrogen generation and compression unit. The main target of this work is to investigate a thermodynamic evaluation of the integrated system based on the 1st and 2 nd laws of thermodynamics. Energetic and exergetic efficiencies, hydrogen and electricity generation rates, and irreversibility for the planned cycle and subsystems are investigated according to different parameters, for example, solar radiation flux, reference temperature, and wind speed. The obtained results demonstration that the whole energy and exergy performances of the modeled plant are 0.21 and 0.16. Additionally, the hydrogen generation rate is found as 0.001457 kg/s, and the highest irreversibility rate is shown in the heat exchanger subcomponents. Also, the net power production rate found to be 195.9 kW and 326.5 kW, respectively, with organic Rankine cycle and wind turbine. The final consequences obtained from this work show that the examined plant is an environmentally friendly option, which in terms of the system's performance and viable, for electrical power and hydrogen production using renewable energy sources.     

An ocean thermal energy conversion based system for district cooling,ammonia and power production

In this study, a novel Ocean Thermal Energy Conversion (OTEC) based tri-generation system that produces ammonia, cooling and power is developed and analysed. This OTEC plant operates on the naturally existing temperature difference that exists in various depths of the ocean. The OTEC plant used in this study is operated using a single-stage ammonia Rankine cycle. The discharge seawater from the condenser in the organic Rankine cycle is used to provide district cooling. Two different operation cases of the analysed system are considered, where for the first case 50% of the power produced is stored in the form of ammonia during the off-peak hours. The second case is for complete power production proposed for peak hours. For the case where 50% of the power produced (case 1) is used to produce ammonia the highest energy and exergy efficiency is found to be 1.37% and 56.17% respectively. As for the case where, only power is produced (case 2) the maximum energy and exergy efficiency of the OTEC plant is found to be 1.83% and 78.02% respectively. The corresponding maximum power production was 6612 kW and 13,224 kW for cases 1 and 2. The maximum hydrogen and ammonia production rate is found to be 94.35 kg/h and 534.7 kg/h at peak efficiency values. The cooling duty at the peak energy and exergy efficiency is found to be 64.4 MW where the condenser temperature is 11.38 °C.     

Thermodynamic analysis of a multigeneration system using solid oxide cells for renewable power-to-X conversion

A hybrid renewable-based integrated energy system for power-to-X conversion is designed and analyzed. The system produces several valuable commodities: Hydrogen, electricity, heat, ammonia, urea, and synthetic natural gas (SNG). Hydrogen is produced and stored for power generation from solar energy by utilizing solid oxide electrolyzers and fuel cells. Ammonia, urea, and synthetic natural gas are produced to mitigate hydrogen transportation and storage complexities and act as energy carriers or valuable chemical products. The system is analyzed from a thermodynamic perspective, the exergy destruction rates are compared, and the effects of different parameters are evaluated. The overall system's energy efficiency is 56%, while the exergy efficiency is 14%. The highest exergy destruction occurs in the Rankine cycle with 48 MW. The mass flow rates of the produced chemicals are 0.064, 0.088, and 0.048 kg/s for ammonia, urea, and SNG, respectively.     

Techno-economic analysis and optimization of a proposed solar-wind-driven multigeneration system; case study of Iran

This paper performs a thermo-economic assessment of a multi-generation system based on solar and wind renewable energy sources. This system works to generate power, freshwater, and hydrogen, which consists of the following parts: the solar collectors, Steam Rankine subsystem, Organic Rankine subsystem, desalination part, and hydrogen production and compression unit. Initially, the effects of variables including reference temperature, solar radiation intensity, wind speed, and solar cycle mass flow rate, which depend on weather conditions and affect the performance of the integrated system, were investigated. The thermodynamic analysis results showed that the overall study's exergy efficiency, the rate of hydrogen and freshwater production, and total cost rate are 33.3%, 7.92 kg/h, 1.6398 kg/s, and 61.28 $/h, respectively. Also, the net power generation rate in the Steam and Organic Rankine subsystems and wind turbines are 315 kW, 326.52 kW, and 226 kW, respectively. The main goal of this study is to minimize the total cost rate of the system and maximize the exergy efficiency and hydrogen and freshwater production rate of the total system. The results of optimization showed that the exergy efficiency value improved by 20.7%, the hydrogen production rate increased by 1%, and the total cost rate value declined by 2%. Moreover, the optimum point is similar to a region in Hormozgan province, Iran. So, this region is proposed for building the power plant.     

A thermal performance evaluation of a new integrated gas turbine-based multigeneration plant with hydrogen and ammonia production

In this study, a new combined system driving a gas turbine cycle has been proposed for seven useful outputs of power, hydrogen, ammonia, heating-cooling, drying and hot water. The proposed integrated plant mainly consists of the gas turbine cycle, Rankine cycle, two organic Rankine cycles, ejector-based cooling, hydrogen production and liquefaction, ammonia production and storage, drying and hot water generation sub-systems. In order to demonstrate that the designed system is an efficient and environmentally plant, the performance analysis was performed by using a software package. Before performing the performance assessment of the plant, the mathematical model of the integrated plant is prepared in accordance with thermodynamic equations. Basic equilibrium equations are used for the thermodynamic equations used. Obtaining multiple useful outputs from the system also have the positive effect on the system effectiveness. The energetic effectiveness of integrated plant for multigeneration with hydrogen and ammonia production is computed to be 62.18% and exergetic efficiency is 58.37%. In addition, the energetic and exergetic effectiveness of hydrogen production and liquefaction process are 57.92% and 54.23%, respectively.     

Assessment of hydrogen production from waste heat using hybrid systems of Rankine cycle with proton exchange membrane/solid oxide electrolyzer

A techno-economic assessment of hydrogen production from waste heat using a proton exchange membrane (PEM) electrolyzer and solid oxide electrolyzer cell (SOEC) integrated separately with the Rankine cycle via two different hybrid systems is investigated. The two systems run via three available cement waste heats of temperatures 360 °C, 432 °C, and 780 °C with the same energy input. The waste heat is used to run the Rankine cycle for the power production required for the PEM electrolyzer system, while in the case of SOEC, a portion of waste heat energy is used to supply the electrolyzer with the necessary steam. Firstly, the best parameters; Rankine working fluid for the two systems and inlet water flow rate and bleeding ratio for the SOEC system are selected. Then, the performance of the two systems (Rankine efficiency, total system efficiency, hydrogen production rate, and economic and CO₂ reduction) is investigated and compared. The results reveal that the two systems' performance is higher in the case of steam Rankine than organic, while a bleeding ratio of 1% is the best condition for the SOEC system. Rankine output power, total system efficiency, and hydrogen production rate rose with increasing waste heat temperature having the same energy. SOEC system produces higher hydrogen production and efficiency than the PEM system for all input waste heat conditions. SOEC can produce 36.9 kg/h of hydrogen with a total system efficiency of 23.8% at 780 °C compared with 27.4 kg/h and 14.45%, respectively, for the PEM system. The minimum hydrogen production cost of SOEC and PEM systems is 0.88 $/kg and 1.55 $/kg, respectively. The introduced systems reduce CO₂ emissions annually by about 3077 tons.     

Hydrogen as a battery for a rooftop household solar power generation unit

Decentralization of electrical power generation using rooftop solar units is projected to develop to not only mitigate power losses along transmission and distribution lines, but to control greenhouse gases emissions. Due to intermittency of solar energy, traditional batteries are used to store energy. However, batteries have several drawbacks such as limited lifespan, low storage capacity, uncontrolled discharge when not connected to a load and limited number of charge/discharge cycles. In this paper, the feasibility of using hydrogen as a battery is analyzed where hydrogen is produced by the extra diurnal generated electricity by a rooftop household solar power generation unit and utilized in a fuel cell system to generate the required electrical power at night. In the proposed design, two rooftop concentrated photovoltaic thermal (CPVT) systems coupled with an organic Rankine cycle (ORC) are used to generate electricity during 9.5 h per day and the extra power is utilized in an electrolyzer to produce hydrogen. Various working fluids (Isobutane, R134a, R245fa and R123) are used in the ORC system to analyze the maximum feasible power generation by this section. Under the operating conditions, the generated power by ORC as well as its efficiency are evaluated for various working fluids and the most efficient working fluid is selected. The required power for the compressor in the hydrogen storage process is calculated and the number of electrolyzer cells required for the hydrogen production system is determined. The results indicate that the hybrid CPVT-ORC system produces 2.378 kW of electricity at 160 suns. Supplying 65% of the produced electricity to an electrolyzer, 0.2606 kg of hydrogen is produced and stored for nightly use in a fuel cell system. This amount of hydrogen can generate the required electrical power at night while the efficiency of electrolyzer is more than 70%.     

Development and thermodynamic assessment of a novel solar and biomass energy based integrated plant for liquid hydrogen production

In this paper, a combined power plant based on the dish collector and biomass gasifier has been designed to produce liquefied hydrogen and beneficial outputs. The proposed solar and biomass energy based combined power system consists of seven different subplants, such as solar power process, biomass gasification plant, gas turbine cycle, hydrogen generation and liquefaction system, Kalina cycle, organic Rankine cycle, and single-effect absorption plant with ejector. The main useful outputs from the combined plant include power, liquid hydrogen, heating-cooling, and hot water. To evaluate the efficiency of integrated solar energy plant, energetic and exergetic effectiveness of both the whole plant and the sub-plants are performed. For this solar and biomass gasification based combined plant, the generation rates for useful outputs covering the total electricity, cooling, heating and hydrogen, and hot water are obtained as nearly 3.9 MW, 6584 kW, 4206 kW, and 0.087 kg/s in the base design situations. The energy and exergy performances of the whole system are calculated as 51.93% and 47.14%. Also, the functional exergy of the whole system is calculated as 9.18% for the base working parameters. In addition to calculating thermodynamic efficiencies, a parametric plant is conducted to examine the impacts of reference temperature, solar radiation intensity, gasifier temperature, combustion temperature, compression ratio of Brayton cycle, inlet temperature of separator 2, organic Rankine cycle turbine and pump input temperature, and gas turbine input temperature on the combined plant performance.     

Investigation of hydrogen production performance of chlor-alkali cell integrated into a power generation system based on geothermal resources

In present study, hydrogen production performance of chlor-alkali cell integrated into a power generation system based on geothermal resource is studied. The basic elements of the novel system are a separator, a steam power turbine, an organic Rankine cycle (ORC), an air cooled condenser, a saturated NaCl solution reservoir tank and a chlor-alkali cell. To enhance the performance of the cell, the saturated NaCl solution is heated by the waste heat from the ORC. So, this integrated system generates significant amount of electricity for the city grid and also yields three main products those are hydrogen, chlorine and sodium hydroxide. According to the parametric study, when the temperature of a geothermal resource varies from 140 to 155 °C, the electrical power generation increases from nearly 2.5 MW to 3.9 MW and hydrogen production increases from 10.5 to 21.1 kg-h. Thus, when the geothermal resource temperature of 155 °C, the energy efficiency of the system is 6.2% and the exergetic efficiency is 22.4%. As a result, the geothermal energy potential plays a key role on the integrated system performance and the hydrogen production rate.     

Investigation of an integrated system with industrial thermal management options for carbon emission reduction and hydrogen and ammonia production

A new integrated energy system employing the cement slag waste heat is uniquely proposed in this study. The core focus of the proposed system is to generate clean hydrogen thermochemically and convert it into ammonia. The designed system consists of the copper–chlorine (Cu–Cl) cycle, a cryogenic air separation unit and a steam Rankine cycle while the useful commodities produced by the proposed system are hydrogen, ammonia, oxygen, hot water and electricity. A CO₂ emission analysis is also conducted to calculate the emissions which can be avoided by recovering this waste heat. The Aspen Plus simulation software is utilized to model and simulate the proposed integrated system. A thermochemical water splitting process is incorporated into the system for hydrogen production. The cryogenic air separation unit is integrated in order to separate nitrogen from the air. This proposed system also reduces the environmental effects of the flue gas emitted by the cement industry. Multiple parametric studies are performed to investigate the system performance by varying operating conditions and state properties. The energy analysis is implemented on each component of the designed system. The overall energy efficiency of the system is concluded as 30.1%. The amount of CO₂ emissions which can be avoided by utilizing this waste heat is 29.64 ktonne/5 years.     

Design and modeling of a multigeneration system driven by waste heat of a marine diesel engine

In this study, a novel marine diesel engine waste heat recovery layout is designed and thermodynamically analyzed for hydrogen production, electricity generation, water desalination, space heating, and cooling purposes. The integrated system proposed in this study utilizes waste heat from a marine diesel engine to charge an organic Rankine and an absorption refrigeration cycle. The condenser of the Organic Rankine Cycle (ORC) provides the heat for the single stage flash distillation unit (FDU) process, which uses seawater as the feedwater. A portion of the produced freshwater is used to supply the Polymer Electrolyte Membrane (PEM) electrolyzer array. This study aims to store the excess desalinated water in ballast tanks after an Ultraviolet (UV) treatment. Therefore it is expected to preclude the damage of ballast water discharge on marine fauna. The integrated system's thermodynamic analysis is performed using the Engineering Equation Solver software package. All system components are subjected to performance assessments based on their energy and exergy efficiencies. Additionally, the capacities for power generation, freshwater production, hydrogen production, and cooling are determined. A parametric study is conducted to evaluate the impacts of operating conditions on the overall system. The system's overall energy and exergy efficiencies are calculated as 25% and 13%, respectively, where the hydrogen production, power generation, and freshwater production capacities are 306.8 kg/day, 659 kW, and 0.536 kg/s, respectively. Coefficient of Performance (COP) of the absorption refrigeration cycle is calculated as 0.41.     

Thermodynamic analysis and optimization of an integrated solar thermochemical hydrogen production system

In this study, thermodynamic analysis of solar-based hydrogen production via copper-chlorine (Cu–Cl) thermochemical water splitting cycle is presented. The integrated system utilizes air as the heat transfer fluid of a cavity-pressurized solar power tower to supply heat to the Cu–Cl cycle reactors and heat exchangers. To achieve continuous operation of the system, phase change material based on eutectic fluoride salt is used as the thermal energy storage medium. A heat recovery system is also proposed to use the potential waste heat of the Cu–Cl cycle to produce electricity and steam. The system components are investigated thoroughly and system hotspots, exergy destructions and overall system performance are evaluated. The effects of varying major input parameters on the overall system performance are also investigated. For the baseline, the integrated system produces 343.01 kg/h of hydrogen, 41.68 MW of electricity and 11.39 kg/s of steam. Overall system energy and exergy efficiencies are 45.07% and 49.04%, respectively. Using Genetic Algorithm (GA), an optimization is performed to evaluate the maximum amount of produced hydrogen. The optimization results show that by selecting appropriate input parameters, hydrogen production rate of 491.26 kg/h is achieved.     

Assessment of an integrated solar hydrogen system for electrochemical synthesis of ammonia

In this paper, a solar based electrochemical system is designed, built and tested to synthesize ammonia and hydrogen from nitrogen and saturated steam. Ammonia can serve as a sustainable fuel and is in heavy demand by the fertilizer industry. However, the conventional methods rely on hydrogen produced from fossil fuels. Hydrogen can be supplied back by implementing fuel cells and feeding electricity back to the system, directed to the conventional ammonia production methods as a reactant, or sold as a fuel. A simple and direct system is studied to pose a sustainable option for ammonia and hydrogen production. Very high concentrations of Nano iron catalyst are used to promote the concentration of ammonia at the output. The reactor is designed for continuous flow and can be disassembled for varying tests and scenarios. The maximum concentration of ammonia is found to be 950 ppm measured with excess reactant supply. Increasing nitrogen flow rates along with decreasing steam flow rates render increasing concentration results. The system at optimum conditions consumes 650 mA at 1.7 V. The low power requirements and valuable products of the system encourage further studies. Additionally, a solar energy based system is proposed as a renewable approach to ammonia synthesis with a fuel cell component to increase the efficiency by reducing the power consumption to 60% of its original value.     

Thermodynamic investigation of a concentrating solar collector based combined plant for poly-generation

The detailed thermodynamic evaluation for combined system assisted on solar energy for poly-generation are studied in this paper. This poly-generation cycle is operated by the concentrating solar radiation by using the parabolic dish solar collector series. The beneficial exits of this integrated plant are the electricity, fresh-water, hot-water, heating-cooling, and hydrogen while there are different heat energy recovery processes within the plant for development performance. A Rankine cycle with three turbines is employed for electricity production. In addition to that, the desalination aim is performed by utilizing the waste heat of electricity production cycle in a membrane distillation unit for fresh-water generation. Also, a PEM electrolyzer sub-component is utilized for hydrogen generation aim in the case of excess power generation. Finally, the hot-water production cycle is performed via the exiting working fluid from the very high-temperature generator of the cooling cycle. Moreover, based on the thermodynamic assessment outputs, the whole energy and exergy efficiencies of 58.43% and 54.18% are computed for the investigated solar plant, respectively.