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1.
多壁碳纳米管改性环氧树脂胶黏剂实验研究   总被引:3,自引:2,他引:1  
将一种环氧树脂和表面羟基化的多壁碳纳米管(MWCNTs)按照质量比100:0.1进行配比,以超声波分散法制备MWCNTs/环氧树脂胶黏剂,考察了两种硅烷偶联剂KH550和KH560对MWCNTs改性效果的影响.采用FTIR、DSC、DMA、流变仪研究了MWCNTs对胶黏剂固化行为和流变特性的影响,并结合断口形貌观察,测...  相似文献   

2.
为提高玻纤增强环氧树脂复合材料的力学性能,采用静电植绒法将多壁碳纳米管(MWCNTs)附着在玻纤织物表面,得到改性的玻纤织物。利用一种低黏度的环氧树脂和所制得的改性织物,采用真空辅助成型工艺(VARI)制备了MWCNTs改性格玻纤织物/环氧树脂复合材料层合板,表征了层合板的力学性能。对进行力学实验后的MWCNTs改性玻纤织物/环氧树脂复合材料试样断口进行了SEM和OPM观察。结果显示:与未添加MWCNTs的玻纤织物/环氧树脂复合材料层合板相比,添加了MWCNTs的层合板的拉伸强度降低了10.24%,弯曲强度降低了13.90%,压缩强度降低了17.33%,拉伸模量和弯曲模量分别提高了19.38%和16.04%,压缩模量提高了13%;MWCNTs与玻纤织物之间的结合较弱,在拉伸作用下,存在明显的脱粘和分层;将改性玻纤织物在200℃下热压处理2h后,制备的MWCNTs改性玻纤织物/环氧树脂复合材料层合板的力学性能均有所提高,热压处理后树脂与玻纤织物之间的界面结合得到改善。  相似文献   

3.
用强酸氧化法与等离子体镀膜法分别对原始多壁碳纳米管(MWCNTs)进行表面修饰,制备了MWCNTs改性氰酸酯/环氧树脂基纳米复合材料。对复合材料的断裂面进行SEM分析,研究了表面处理方法对复合材料室温及低温力学性能的影响。结果表明,经等离子体镀膜表面修饰后的MWCNT在基体中分散更为均匀,与基体的界面结合力更强。经等离子体镀膜表面改性后的MWCNTs复合材料,当MWCNTs质量分数为0.3%时,其室温及低温拉伸强度、弹性模量和冲击强度较纯氰酸酯/环氧树脂基体均有不同程度的提高。  相似文献   

4.
俞科静  张洁  郏余晨  曹海建  钱坤 《功能材料》2012,43(22):3131-3134,3138
首先采用浓硫酸/浓硝酸对多壁碳纳米管(MWCNTs)进行混酸氧化处理,再将氧化后的CNTs与DOPO改性后的硅烷偶联剂(DOPO-KH560)进行改性,制备了DOPO-KH560表面化学修饰的MWC-NTs。在此基础上,将改性前后的CNTs分散在环氧树脂体系中,制成样条,研究了处理前后样条力学性能的变化。材料表面结构的红外光谱(FT-IR)分析表明,CNTs混酸氧化成功,表面成功引入了羟基和羧基,而且DOPO-KH560成功接枝到酸化CNTs上。材料微结构的透射电子显微镜(TEM)观察表明,酸化后MWCNTs被截短,分散性变好,接枝DOPO-KH560后CNTs表面包覆了一层低聚物。对处理后的样条进行力学性能测试并用扫描电镜(SEM)分析观察断面形态的变化。结果表明,环氧树脂中加入CNTs,能有效地增加环氧树脂的韧性和强度,且加入原CNTs、氧化CNTs、改性后的CNTs时增强增韧效果逐渐增加,加入最终CNTs后环氧树脂的增强增韧效果最明显。  相似文献   

5.
采用混酸氧化及表面接枝改性的方法制备了表面含不同官能团的多壁碳纳米管(MWCNTs), 并研究了不同MWCNTs对环氧树脂的低温(77 K)抗冲击性能及热膨胀系数(CTE)的影响。结果表明: 通过接枝反应将—NCO基团封端的PEO齐聚物引入MWCNTs表面, 可提高MWCNTs在环氧树脂基体中的分散性, 加强MWCNTs与环氧树脂的界面作用; 相对于纯环氧树脂, 添加质量分数为0.5%的纯MWCNTs、 氧化MWCNTs和表面接枝MWCNTs改性后的环氧树脂的低温冲击强度分别升高了10.27%、 26.13%和32.95%, 而CTE则分别降低了14.79%、 29.59%和40.29%。这表明表面接枝改性MWCNTs可明显提高环氧树脂基体的低温抗冲击性能并降低环氧树脂在玻璃化转变温度下的CTE。  相似文献   

6.
采用超声波振荡与超声波破碎两种分散方法制备了低含量碳纳米管(CNTs)增强的环氧树脂, 研究了CNTs对树脂流变特性、 固化特性和力学性能的影响。进一步采用该树脂体系通过真空灌注工艺(VARIM)制备了CNTs含量为0.01%的CNTs-玻璃纤维/环氧树脂复合材料层板, 研究了两种分散方式下CNTs对复合材料层板力学性能的影响和CNTs的增强机制。结果表明: 超声波破碎分散使CNTs长度变短, 分散性更好, 与超声波振荡分散方式相比, CNTs对树脂增黏效果和树脂固化反应的影响更明显。采用双真空灌注工艺, 两种超声波分散方式下CNTs均提高了复合材料的弯曲性能、 层间剪切性能和树脂与纤维的粘结强度, 而单真空灌注工艺下CNTs的增强效果不明显, 说明受纤维过滤作用的影响, 选择合适的灌注工艺和CNTs分散方式, 低含量CNTs可实现对灌注工艺复合材料层板的增强。  相似文献   

7.
对多壁碳纳米管(MWCNTs)进行改性处理,得到表面接枝1,3,5-苯三甲酸的碳纳米管(B-MWCNTs)。分别将MWCNTs和B-MWCNTs分散在环氧树脂基体及上浆剂中,通过缠绕成型法制备含有MWCNTs的碳纤维增强环氧树脂预浸料,并采用热压成型工艺制备MWCNTs/碳纤维环氧树脂复合材料层合板。结果表明,B-MWCNTs在环氧树脂基体和上浆剂中的分散状态明显优于MWCNTs。添加B-MWCNTs后复合材料的玻璃化转变温度(Tg)和失重5%时对应的温度均有所提高。而且,添加B-MWCNTs可以明显提高碳纤维环氧树脂复合材料的力学性能。当MWCNTs含量为0.5%(质量分数)时,B-MWCNTs/碳纤维环氧树脂复合材料层合板的压缩强度、层间剪切强度和冲击后压缩强度(CAI)分别提高了14.3%,37.1%和23.4%。  相似文献   

8.
利用氨基化多壁碳纳米管(MWCNTs-NH2)与环氧化合物苄基缩水甘油醚(EP 692)和十二-十四烷基缩水甘油醚(EP AGE)反应,通过球磨工艺制备了两种不同分子结构环氧化合物上浆处理的多壁碳纳米管(MWCNTs)MWCNTs-692和MWCNTs-AGE。将均为1wt%的MWCNTs-NH2,MWCNTs-692和MWCNTs-AGE分别添加到二氨基二苯甲烷(DDM)固化双酚A二缩水甘油醚(DGEBA)环氧树脂体系中,分析了三种MWCNTs对树脂体系黏温关系、固化动力学、热力学性能和弯曲性能的影响。FT-IR,TGA和XPS测试表明,EP 692和EP AGE通过共价键接枝到碳纳米管的表面。与MWCNTs-NH2相比,MWCNTs-692和MWCNTs-AGE可以有效提高碳纳米管在环氧树脂基体中的分散性和相容性,减少纳米粒子对树脂体系黏度和固化动力学的影响。此外,添加上述三种碳纳米管都可以改善纯环氧树脂体系的储能模量和弯曲性能,其中经过含有刚性分子结构上浆剂处理的MWCNTs-692增强效果最为显著。添加1wt%MWCNTs-692后,MWCNTs-692/环氧树脂复合材料的常温储能模量提高了30.6%,弯曲强度和模量分别提高了18.8%和22.5%。  相似文献   

9.
聚硅氧烷改性环氧树脂体系的制备,形态与性能   总被引:23,自引:0,他引:23  
聚胡氧烷-环氧树脂体系微相分离形态形成过程不同于一般反应性液体橡胶改性环氧树脂。此体系微相分离结构是在预反应过程中形成的,是聚硅氧烷在环氧树脂中的分散和聚结两种趋势共同作用的结果。预反应中形成的嵌段共聚物使该体系微相分散微细而且均匀,一未改性环氧树脂相比,经预反应制得的固化物弯曲杨氏模量和玻璃态线性热膨胀系数均有明显下降,因此内应力大幅度降低,抗开理解指数大为提高;而直接共混法改性环氧树脂低应力化  相似文献   

10.
采用浓硫酸/浓硝酸氧化处理多壁碳纳米管(MWCNTs),再将氧化后的碳纳米管与硅烷偶联剂(KH560)进行接枝,制备了硅烷偶联剂表面化学修饰的MWCNTs。在此基础上,将改性前后的碳纳米管分散在环氧树脂体系中,涂覆处理碳纤维。研究处理前后碳纤维力学性能和界面性能的变化。通过红外光谱(FTIR)和透射电镜(TEM)分析,表明KH560已成功接枝到多壁碳纳米管上;通过分散性实验证明了改性后的碳纳米管分散性提高;对处理后的碳纤维进行力学性能测试,并用扫描电镜(SEM)观察分析断面形态变化,结果表明,当碳纳米管的含量为0.5%时,改性碳纳米管处理的碳纤维拉伸强度和拉伸模量分别提高23.83%和7.11%,界面性能增强。  相似文献   

11.
Uniform treatment of multiwalled carbon nanotubes by plasma treatment has been investigated using a custom-built stirring plasma system. A thin plasma polymer with high levels of amine groups has been deposited on MWCNTs using a combination of continuous wave and pulsed plasma polymerization of heptylamine in the stirring plasma system. Scanning electron microscopy showed that the plasma polymerization improved the dispersion and interfacial bonding of the MWCNTs with an epoxy resin at loadings of 0.1, 0.3 and 0.5 wt%. The flexural and thermal mechanical properties of plasma polymerized MWCNT/epoxy nanocomposites were also significantly improved while untreated MWCNT/epoxy nanocomposites showed an opposite trend. The epoxy with 0.5 wt% plasma polymerized MWCNTs had the greatest increase in flexural properties, with the flexural modulus, flexural strength and toughness increasing by about 22%, 17% and 70%, respectively.  相似文献   

12.
Nanocomposites based on epoxy resin and different weight percentages of unmodified, oxidized, and silanized multi-walled carbon nanotubes (MWCNTs) were prepared by cast molding method. Effects of MWCNTs content on the flexural properties were examined. The results showed that as the loading of the MWCNTs increased, improved flexural strength and flexural modulus were observed. The mechanical properties decreased when the MWCNTs content exceeded 0.2 wt.% due to agglomeration of MWCNTs. These results prove the effect of functionalization on the interfacial adhesion between epoxy and MWCNTs. This was further confirmed by morphology study of fractured surfaces of nanocomposites by SEM and TEM.  相似文献   

13.
In this study, we investigated the peculiarities of moisture absorption and moisture-induced effects on the elastic and viscoelastic flexural properties of epoxy resin and carbon fibre reinforced plastic (CFRP) filled with multiwall carbon nanotubes (MWCNTs). Short-term cyclic creep-recovery tests of moistened epoxy and CFRP filled with MWCNTs revealed improvements in creep resistance for both materials. The addition of MWCNTs to the epoxy resin suppressed the moisture absorption by the material, causing a reduction in the diffusion coefficient by 31% and equilibrium moisture content by 15%. The addition of MWCNTs reduced the flexural strength of moistened epoxy and CFRP samples by approximately half, and also lowered the flexural modulus by ∼1.4 and ∼3 times, elastic strain by 1.25 and 1.04 times, viscoelastic strain by 1.39 and 1.03 times, and plastic strain by 2.68 and 1.60 times, respectively.  相似文献   

14.
声学黑洞(Acoustic Black Holes,ABH)效应是利用结构厚度以一定幂函数形式减小,致使弯曲波的相速度逐渐减小而实现能量逐渐聚集,理想情况下弯曲波波速减小为0从而无法传递到结构边缘,也就不会发生反射。声学黑洞效应使得结构产生高能量密度区域,因此能高效应用于能量回收和振动噪声控制。为了研究二维声学黑洞结构具有弯曲波能量聚集效应,运用有限元分析软件ABAQUS建立了二维声学黑洞模型,从时域上研究弯曲波在声学黑洞区域的传播过程,结合有限元数值结果与振动功率流的结果分析弯曲波能量聚集过程。最后通过激光超声实验系统对二维声学黑洞中弯曲波传播过程进行成像与分析,实验结果验证了二维声学黑洞结构对弯曲波能量的聚集效应。  相似文献   

15.
In this study, two types of thermoplastic matrices (low melting point polyethylene terephthalate (LPET) fiber and polypropylene (PP) fiber) and glass fiber/epoxy resin/multi-walled carbon nanotubes (MWCNTs) were used to fabricate the thermoplastic and thermoset composite materials with 3D biaxial warp-knitted fabrics. Thermoplastic and thermoset composites were fabricated using hot-press and resin transfer molding (RTM) methods. The fabricated samples were tested with tensile and three-point flexural tests. In thermoplastic composites, samples in the 90° direction and LPET matrix showed the best tensile and flexural properties with an improvement of 39 and 21% tensile modulus and strength, 16 and 8% flexural modulus and strength compared to the PP samples in the same direction. In thermoset composites, samples in the 90° direction and MWCNTs showed the best improvement of the flexural modulus and strength with 97 and 58% compared to the samples without MWCNTs. This improvement can most likely be attributed to an increase in interfacial adhesion due to the presence of the carbon nanotubes.  相似文献   

16.
在空气中用高频高压电子加速器辐照多壁碳纳米管(MWCNTs),采用红外光谱、能谱分析、拉曼光谱和透射电镜表征分析辐照处理对碳纳米管结构的影响;通过原位复合法制备MWCNT/环氧树脂(EP)复合材料.采用场发射扫描电镜、热失重分析和动态力学分析研究辐照处理MWCNTs对环氧树脂热稳定性的影响.结果表明:电子束辐照处理使MWCNTs表面接入了少量的含氧基团,同时破坏了MWCNTs的完整结构,当辐照剂量为170 kGy时,接枝含氧基团的量最多(约为4%),且结构破坏程度较小.与原始MWCNT/EP体系相比,经电子束辐照处理后的MWCNTs在EP中分散得更均匀,并能使材料的最大热分解温度和玻璃化转变温度较纯EP有所提高,在EP中加入质量分数0.5%的经170kGy辐照处理后的MWCNTs,能够使材料的最大热分解温度和玻璃化转变温度分别提高约14℃和8℃.  相似文献   

17.
Two types of multi-walled carbon nanotubes (MWCNTs) functionalized with different amino-organics, dicyanodiamide and phenylbiguanide, respectively, were achieved in this paper. The physico-chemical properties of MWCNTs before and after amino group modification were characterized by thermogravimetric analysis (TGA), Raman spectroscopy and inverse gas chromatography (IGC). The results showed that amino-functionalization changed evidently the surface properties of MWCNTs, such as the dispersive surface energy (decreased from 122.95 mJ/m2 to 18.65 mJ/m2 and 25.69 mJ/m2, respectively) and specific surface energy (decreased from 8.84 mJ/m2 to 0.56 mJ/m2 and 4.60 mJ/m2, respectively) for two functionalized MWCNTs. And then, the interfacial adhesion states of the functionalized MWCNTs/epoxy nanocomposites were investigated using scanning electron microscope (SEM) and dynamic mechanical analysis (DMA). The results also indicated that the dispersion of MWCNTs in epoxy resin and the interfacial adhesion of MWCNTs/epoxy nanocomposites were both strongly dependent on the surface physico-chemical properties of functionalized MWCNTs, and the effect of MWCNTs functionalized by phenylbiguanide with slightly higher polarity was better.  相似文献   

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