The Infrared Hall Effect in YBCO: Temperature and Frequency Dependence of Hall Scattering

We measure the Hall angle, _H , in YBCO films in the far- and mid-infrared to determine the temperature and frequency dependence of the Hall scattering. Using novel modulation techniques we measure both the Faraday rotation and ellipticity induced by these films in high magnetic fields to deduce the complex conductivity tensor. We observe a strong temperature dependence of the mid-infrared Hall conductivity in sharp contrast to the weak dependence of the longitudinal conductivity. By fitting the frequency dependent normal state Hall angle to a Lorentzian _H () = _H /( _H – i) we find the Hall frequency, _H , is nearly independent of temperature. The Hall scattering rate, _H , is consistent with _H T ² up to 200 K and is remarkably independent of IR frequency suggesting non-Fermi liquid behavior.     

Breakup of an anomolously viscous liquid film in a centrifugal force field

An equation is obtained for the breakup radius with consideration of tipping moments and Laplacian pressure forces acting on the liquid ridge at the critical point.Notation K, n rhenological constants - density - surface tension - r current cup radius - R maximum cup radius - r_c critical radius for film breakup - ¯r=¯r=r/R dimensionless current radius - ¯r_c=r_c/R dimensionless critical radius - ₀, _c actual and critical film thicknesses - current thickness - R_r ridge radius - h₀ ridge height - h current ridge height - ₀ limiting wetting angle - current angle of tangent to ridge surface - angle between axis of rotation and tangent to cup surface - angular velocity of rotation - q volume liquid flow rate - v₁ and v meridional and tangential velocities - =4vv _lm/r,=4v_m/r dimensionless velocities - M moments of surface and centrifugal forces - M_v moment from velocity head - p_r pressure within ridge - P_vm pressure from velocity head - p_m, p_pm pressures from centrifugal force components tangent and normal to cup surface - deviation range of breakup radius from calculated value - ¯r_max, ¯r_min limiting deviations of breakup radius - _c angle of tangent to curve _c/°₀=f(¯r) at critical point - t random oscillation of ratio _c/_c Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 1, pp. 51–56, July, 1980.     

Thermal Expansion and Isothermal Compressibility of TlIn1 – xNdxSe2 (0 ≤ x≤ 0.08) Crystals

The thermal expansion coefficient () and isothermal compressibility ( _T ) of TlIn_{1 – x} Nd _x Se₂(0 x 0.08) crystals were measured between 77 and 400 K. In the range 77–160 K, both and _T increase with temperature, the increase in being much steeper. At higher temperatures, and _T change very little. The observed composition dependences of and _T are interpreted in terms of energy-band structure.     

Impulse approximation in solid helium

The incoherent dynamic form factorS _i(Q, ) is evaluated in solid helium for comparison with the impulse approximation (IA). The purpose is to determine theQ values for which the IA is valid for systems such as helium where the atoms interact via a potential having a steeply repulsive but not infinite hard core. For³He,S _i(Q, ) is evaluated from first principles, beginning with the pair potential. The density of statesg() is evaluated using the self-consistent phonon theory andS _i(Q, ) is expressed in terms ofg(). For solid⁴He reasonable models ofg() using observed input parameters are used to evaluateS _i(Q, ). In both casesS _i(Q, ) is found to approach the impulse approximationS _IA(Q, ) closely for wave vector transfersQ20 Å^–1. The difference betweenS _i andS _IA, which is due to final state interactions of the scattering atom with the remainder of the atoms in the solid, is also predominantly antisymmetric in (–_R), where _R is the recoil frequency. This suggests that the symmetrization procedure proposed by Sears to eliminate final state contributions should work well in solid helium.     

Zero Sound Attenuation Near the Quantum Limit in Normal Liquid 3He Close to the Superfluid Transition

The zero sound attenuation of normal liquid ³He has been studied over a range of temperatures from slightly above the superfluid transition temperature, T _c, to approximately 10mK at the constant pressures of 1 and 5bar. Using longitudinal LiNbO₃ transducers, operating both on and off resonance, the experiment was performed at 15 discrete frequencies located in several broadband frequency windows, including 16–25, 60–70, and 105–111MHz. The results are compared to Landau's prediction for the attenuation of zero sound in the quantum limit, (k _B Tk _B T _F), where ₀(P,T, )= (P) T ²{1+(/2k _B T)²}. Calibration of the received zero sound signals was performed by measuring the temperature dependence of the first sound attenuation from 30 to 800mK at those same frequencies and pressures. The data are compared to previous results.     

The Interplay of Electronic and Nuclear Magnetism in PtFe x at Milli-, Micro-, and Nanokelvin Temperatures

We have measured ac susceptibility, nuclear magnetic resonance, and nuclear heat capacity of two PtFe _x samples with concentrations of magnetic impurities x = 11 ppm and 41 ppm at magnetic fields (0 ± 0.05) mTB248 mT. The susceptibility data have been measured at temperatures of 0.3 KT100 mK, no hint for nuclear magnetic ordering could be detected to a temperature of 0.3 K. The nuclear heat capacity data taken at 1.4 KT10 mK show enhanced values which scale with x at low polarization. This effect is described by a model assuming an internal magnetic field caused by the impurities. No indication for nuclear magnetic ordering could be detected to 1.4 K. The nuclear magnetic resonance experiments have been performed on these samples at 0.8 KT0.5 mK and 2.5 mTB22.8 mT as well as on three other samples with x = 5, 10, 31 ppm in a different setup at 40 KT0.5 mK and at 5.4 mTB200 mT. Spin-lattice and effective spin-spin relaxation times ₁and ₂ ^* of ¹⁹⁵ Pt strongly depend on x and on the external magnetic field. No temperature dependence of ₁and ₂ ^* could be detected and the NMR data, too, give no hint for nuclear magnetic ordering to 0.8 K.     

Spectral shape dependence in the very strong coupling regime of Eliashberg theory

The effect of ² F() shape dependence on several physical properties of superconductors is studied at various values of the strong coupling indexT _c/ _ln . Our results indicate that the degree of shape dependence of each property is sensitive to the value ofT _c/ _ln . Generally, for the region we examine, 0.25T _c/ _ln 1.3, the dependence on shape is found to be higher than in the conventional strong coupling regimeT _c/ _ln 0.2. However, with the exception of the mass enhancement parameter , the amount of shape dependence does not increase steadily withT _c/ _ln and there appears to be regions of maximum shape sensitivity.     

Transport results from untwinned YBCO: Washboard frequency of the vortex lattice,and the quasiparticle mean free path

The washboard frequency of the moving vortex lattice in untwinned YBa₂ Cu₃ O_6.93 may be observed through mode-locking to an externally applied ac current of frequency _ext. The interference between and _ext results in jumps in the dc current-voltage characteristics when and _ext are harmonically related¹. The interference effect disappears in the vortex liquid state. The Hall conductivity _xy below T_c in YBCO contains contributions² from a positive quasiparticle (qp) term (H) and a negative vortex term (1/H). The qp term is surprisingly large well below T_c and implies a large gap anisotropy and a long qp mean free path (mfp). The thermal Hall effect³ _xy is closely related to the qp _xy; _xy is produced by asymmetric scattering of qp by pinned vortices. The qp mfp at H = 0, extracted from _xy and extended to low T by _xy, increases remarkably from 90 Å at T_c to more than 0.5m at 22 K.     

The age hardening effect in Ti-6 Al-4 V due to ω and α precipitation in the β grains

The structure at room temperature of a quenched TA6V titanium alloy has been investigated. This structure is + or + according to the treatment temperature; it is always metastable. During ageing the grains decomposed by the reaction + + +; this decomposition was accompanied by a large increase of the 0.2% yield stress. No structural modification was observed in. The and phase of TA6V were separately investigated in the form of single-phase alloys. The hardness of was insensitive to ageing, while was considerably hardened by and; we deduced that the strengthening of the minor phase during ageing is mainly responsible for the hardening of TA6V.     

Nonlinear Response of a Continuous Wave NMR Spectrometer for Samples with a Large Magnetization

We present a new insight in the response of a CW NMR spectrometer for highly magnetized samples above 100 MHz. The spectrometer is a bridge made of a magic T. The output of the bridge is proportional to the reflection coefficient, , of a resonant circuit, which is built with a coil containing the sample. The sensitivity of the reflection coefficient to the complex susceptibility of the sample, () = () – j(), depends on the quality factor, Q, of the circuit and filling factor, . When the condition Q 1 is not fulfilled, we show indeed that the use of a simple crystal detector, which is only sensitive to || gives rise to a strong nonlinear response of the spectrometer. Measurements of the complex value of by means of phase sensitive detection allow to recover a linear behavior. We discuss and illustrate those issues with a few circuits we designed for our measurements on liquid ³ He with spin polarizations up to 15 %. A method is described to build in a reproducible and predictable way resonant circuits matched to 50 in the frequency range 100 – 400 MHz with a quality factor as high as 1000 at 4 K.     

Shear viscosity of the B phase of superfluid3He

The shear viscosity (T) in the Balian-Werthamer (BW) state of superfluid ³ He is calculated variationally throughout the region 0t 1(t=T/T _c) from the transport equation for Bogoliubov quasiparticles. Coherence factors are treated exactly in the calculation of the collision integral. The numerical result for =_s= _s(T)/_n(T_c) agree very well with experiment in the range 0.8t1.0. Analytic expressions = 0.577 (1–1.0008t) and =1–(23/64) [=(T)/k _B T] are obtained in the low-temperature region and in the vicinity ofT _c, respectively. From the numerical analysis it is shown that the latter equation is valid only in the temperature range 0.9997t1.0.Supported by the Research Institute for Fundamental Physics, Kyoto University.     

The athermal α → ω transformation in Zr-2 at% Nb alloy

The athermal transformation in Zr-2 at.% Nb alloy has been investigated by transmission electron microscopy. Analysis of the selected-area diffraction pattern has shown that the orientation relationships between the omega and the parent-phase in quenched Zr-2 at.% Nb alloy are the same as have been previously observed for the reaction in pure zirconium. Thus it was deduced that the direct transition has taken place in the alloy during cooling. The-originated -particles were visualized using the dark-field technique. The formation of the athermal omega in the-region of-stabilized Zr-Nb alloy is discussed in terms of the relative positions of the free energy equilibrium curvesT ₀ ,T ₀ ,T ₀ and the correspondingM _s ,M _s andT _s start curves. It is concluded that the omega phase can occur over a much wider range of alloy compositions than is usually recognized on the basis of transformation data.     

Intensity of critical opalescence of helium-4

We present measurements of the critical opalescence of helium-4. The results are analyzed by the Einstein and Ornstein-Zernike theory and the power laws. We obtain ==1.17±0.02, ==0.62±0.1,/=4.5±0.3,P _c =1706.008 mm Hg, andT _c =5,189.863 mK (T ₅₈ ). The critical behavior of helium-4 is almost the same as that of classical fluids and the influence of the quantum nature of helium-4 is not as evident as has been claimed.     

Dependence of 2Δ0/k B T c on the shape of electron-phonon spectral density

The effect on the ratio of the gap to the critical temperature 2₀/k _B T _c of various possible shapes for the electron-phonon spectral density is studied. The calculations are carried out keepingT _c andT _c /_ln fixed, where _ln is a characteristic phonon energy. When only realistic shapes known to occur in nature are considered, the ratio 2₀/k _B T _c shows little variation with shape. On the other hand, when the analysis is extended to a two--function model, much larger variations are possible, particularly when fairly extreme nonphysical values are used for the positions in frequency of the functions.     

Delayed retardation phenomena of fatigue crack growth in various steels and alloys

The delayed retardation phenomena of fatigue crack growth resulting from a single application of overload were investigated for five steels, two aluminium alloys and a titanium alloy. As long as the small scale yielding condition was satisfied at the overloaded crack tips, the retardation behaviour of these materials was expressed consistently by four parameters; the peak/baseline stress ratio, r, the exponent in the Paris equation, m, the overload-affected zone size, _D, and the crack distance at the minimum rate of crack growth, _B. Then the parameters, _B and _D, characterizing the retardation phenomena for these materials were determined. The retardation of aluminium alloys was stronger than that of the other materials. This is attributed to the lower value of _B/ _D in aluminium alloys than in the other materials. In the case of r=2, the overload-affected zone sizes, _D, were nearly equal to 1.5 ₀ in HT80 steel and aluminium alloys, slightly lower than 1.5 ₀ in SNCM8 steel and much larger than 1.5 ₀ in A553 steel and the titanium alloy, where ₀ is the monotonic plastic zone size calculated according to the Dugdale model. The dependence of retardation on baseline stress intensity, K ₁, appeared somewhat complicated. In the cases of A553 steel and A2017 aluminium alloy the amount of retardation increased with increasing K ₁ value, while in the cases of HT80 steel and Ti-6A1-4V titanium alloy the tendency appeared in the reverse direction. The former behaviour was related to the change in the stress state from plane strain to plane stress at the overloaded crack tips and the latter was related to the threshold of stress intensity.     

Standard Gibbs' energies of formation of BaCuO2, Y2Cu2O5 and Y2BaCuO5

The Gibbs' energies of formation of BaCuO₂, Y₂Cu₂O₅ and Y₂BaCuO₅ from component oxides have been measured using solid state galvanic cells incorporating CaF₂ as the solid electrolyte under pure oxygen at a pressure of 1.01×10⁵ Pa BaO + CuO BaCuO₂ G _f,ox ^o (± 0.3) (kJ mol^–1)=–63.4–0.0525T(K) Y₂O₃ + 2CuO Y₂Cu₂O₂ G _f,ox ^o (± 0.3) (kJ mol^–1)=18.47–0.0219T(K) Y₂O₃ + BaO + CuO Y₂BaCuO₅ G _f,ox ^o (± 0.7) (kJ mol^–1)=–72.5–0.0793T(K) Because the superconducting compound YBa₂Cu₃O_7– coexists with any two of the phases CuO, BaCuO₂ and Y₂BaCuO₅, the data on BaCuO₂ and Y₂BaCuO₅ obtained in this study provide the basis for the evaluation of the Gibbs' energy of formation of the 1-2-3 compound at high temperatures.     

The transverse acoustic impedance of He II

The complex shear acoustic impedance of liquid He II has been measured at frequenciesf(=/2) of 20.5, 34.1, and 47.8 MHz from 30 mK to the -point T (2.176 K). The impedanceZ was found from the temperature dependence of the quality factor and the resonant frequency of a thickness shear mode quartz crystal resonator immersed in the liquid. The relationship for a hydrodynamic viscous liquidZ(T)=(1–i)(f _n )^1/2 was used to measure the temperature dependence of the viscosity (T) using tabulated values of the normal fluid density _n (T). Deviations from hydrodynamic behavior occurred when the viscous penetration depth was less than the superfluid healing length, the phonon mean free path, and the roton mean free path. Near the -point,Z(T)/Z(T) was frequency dependent and a value for the superfluid healing lengtha=(0.10±0.01)^–2/3 nm was found, where =(T–T)/T. The effects of van der Waals forces near the crystal surface were also observed and a layer model was used to interpret the measurements. Below 1.8 K only rotons contribute significantly toZ and we determined the roton relaxation time as _r =8.5×10^–14 T ^–1/3 exp (8.65/T) sec. Below 1.2 K, _r >1 and we investigated the breakdown of hydrodynamics in this region. ForT<0.6 K the resonant frequency of the crystals decreased by f/f=2×10^–7, but the origin of this effect is not yet known.Financial support provided by the SERC, Bedford College, and the Central Research Fund, University of London.     

The extraction of ionic conductivities and hopping rates from a.c. conductivity data

Over a wide range of frequencies, the a.c. conductivity of ionic materials shows two regions of frequency-dependent conductivity. These are each characterized by a term K _p ^{1–n n} where K, n are constants, _p is a fundamental frequency identified with the hopping rate and is the measuring frequency. This behaviour is an example of Jonscher's Law of Dielectric Response for ionic conductors. In many cases, the region of low-frequency dispersion approximates to a frequency-independent plateau which may be taken as the d.c. conductivity. In others, a significant low-frequency dispersion is present and cannot be ignored in determining the effective d.c. conductivity. A method for the extraction of d.c. conductivities, hopping rates and for estimating carrier concentration effects is described. Data for three different types of material, single-crystal LiGaO₂, -alumina and Na/Ag -alumina are used to illustrate the method.     

Viscoelastic and rheological behavior of concentrated colloidal suspensions

Molecular approaches are discussed to the density (), viscoeleastic (), and rheological () behavior of the viscosity(,,) of concentrated colloidal suspensions with 0.3 < < 0.6, where, is the volume fraction, the applied frequency, and ; the shear rate. These theories are based on the calculation of the pair distribution functionP ₂(r,,), wherer is the relative position of a pair of colloidal particles. The linear viscoelastic behavior(,,=0) follows from an equation forP ₂(r,,) derived from the Smoluchowski equation for small, generalized to large by introducing the spatial ordering and (cage) diffusion typical for concentrated suspensions. The rheological behavior(,,=0) follows from an equation forP ₂(r,) of a dense hard-sphere fluid derived from the Liouville equation. This leads to a hard-sphere viscosity^hs(,) which yields the colloidal one(,) by the scaling relation(,) ₀=^hs(,) _B, where ₀ is the solvent viscosity. _B is the dilute hard-sphere (Boltzmann ) viscosity and the's are appropriately scaled,(,) and(,) agree well with experiment. A unified theore for(,,) is clearly needed and pursued.Paper presented at the Twelfth Symposium on Thermophysical Properties, June 19–24, 1994. Boulder, Colorado, U.S.A.     

Relationship between the energy supply parameters and the physicochemical l characteristics of polymer compositions during drying and thermal processing

The effect of the type of energy supply on the formation of temperature and concentration fields in the thermal processing of polymer compositions is considered.Notation T₀, T initial and current temperature of the coating - T_m temperature of the air - =(T-T_o)/(T_m-T₀) dimensionless temperature of the coating - a thermal diffusivity - A absorption power of the coating - D diffusion coefficient - thermal conductivity - c thermal capacity - density - _k convective heat transfer coefficient - i number of moles of reacting groups per unit volume of polymer - K₀ factor in front of the exponential - R gas constant - u concentration - Q thermal effect of the reaction - q_n density of the incident radiant flux - =x/ dimensionless coordinate over the thickness of the coating - Ki=Aq_n /(T_m-T₀) Kirpichev criterion characterizing the thermal effect of the reaction - Ki_p=Qi/c (T_m-T₀) analog of the Predvoditelev criterion, characterizing the rate of occurrence of a chemical excess in the system - Bu= Bouguer criterion - Lu=D/a Lykov number - Fo=a/² Fourier number - Bi= _k Biot number Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 1, pp. 26–33, July, 1980.