用于掺铒光纤放大器泵浦源的高性能980nm InGaAs应变量子阱激光器

利用分子束外延方法研制出了高质量的ＩｎＧａＡｓ／ＡｌＧａＡｓ庆变量子阱激光器外延材料，其最低的阈值电流密度可达到１２０Ａ／ｃｍ＾２，激光波长在９８０ｎｍ左右。获得了高性能的适合于掺铒光纤放大器用的９８０ｎｍ量子阱激光器泵浦源，其典型的阈值电流为１５ｍＡ，外微分量子效率的典型值和最好值分别为０．８ｍＷ／ｍＡ和１．０ｍＷ／ｍＡ，线性输出功率大于１２０ｍＷ，在２０℃－５０℃的特征温度Ｔ０为１２５Ｋ。器件     

GaAs／GaAlAs低阈值垂直腔面发射激光器

通过对增益波导型ＧａＡｓ／ＧａＡｌＡｓ垂直腔面发射激光器的材料生长和工艺制作的研究，实现了在室温下的脉冲激射。其激射阈值电流低达１０ｍＡ，输出光功率不低于０．３ｍｗ，有的可达０．７ｍｗ以上，器件单横模、单纵模工作，线宽小于４人。     

量子点激光器及其应用研究

报道了分子束外延生长出自组装垂直耦合ＩｎＡｓ／ＧａＡｓ大功率量子点激光器材料和器件。对腔长为８００μｍ,室温下和７７Ｋ下边续激射阈值电流密度分别为２１８Ａ／Ｃｃｍ＾２和４９Ａ／ｃｍ＾２,波长为９６０ｎｍ,最大输出功率大于１Ｗ。首次报道在０．５４Ｗ工作下,寿命超过３０００小时,功率仅下降０．４９display status０     

实用化GaInP—AlGaInP半导体量子阱可见光激光器

用低压ＭＯＶＰＥ方法研制出了波长为６５５ｎｍ与６７０ｎｍ的ＧａＩｎＰ－ＡｌＧａＩｎＰ半导体量子阱可见激光器，并已形成一定的批量生产能力。器件的阈值电流典型值为４５ｍＡ，输出光功率不小于５ｍＷ，最高工作温度不低于５０℃，预计２０℃时寿命接近１００，０００小时，主要技术指标与目前进口的同类产品水平相当，完全可以满足实用要求。     

实用化GaInP－AlGaInP半导体量子阱可见光激光器

用低压ＭＯＶＰＥ方法研制出了波长为６５５ｎｍ与６７０ｎｍ的ＧａＩｎＰ－ＡｌＧａＩｎＰ半导体量子阱可见光激光器，并已形成一定的批量生产能力。器件的阈值电流典型值为４５ｍＡ，输出光功率不小于５ｍＷ，最高工作温度不低于５０℃，预计２０℃时寿命接近１００，０００小时，主要技术指标与目前进口的同类产品水平相当，完全可以满足实用要求。     

1.48μm大功率GaInAsP／InP激光器

用两步液相外延法研制出１．４８μｍ大功率ＧａＩｎＡｓＰ／ＩｎＰ激光器，尾纤输出功率大于３０ｍＷ。用作掺铒光纤放大器的泵浦光源，双向泵浦小信号增益２８ｄＢ，经较长时间的实际运行，表明器件性能稳定可靠，温度特性好。     

准连续在功率二维层叠量子阱激光器列阵

研究了大功率列阵器件的量子阱结构，材料生长，列阵结构，了技术与封装技术，研制了６条层叠ＧａＡｓ／ＡｌＣａＡｓ量子阱激光器列阵，其峰值功率为４０４Ｗ，电－光转换效率高达４３．３％。     

1．52μmInGaAsP／InP分别限制量子阱激光器

报导了在６００℃生长温度下以三甲基镓（ＴＭＧａ）和三甲基铟（ＴＭＩｎ）为Ⅲ族源，用低压金属有机气相沉积（ＬＰ－ＭＯＣＶＤ）技术生长出的高质量１．６０μｍ和１．３μｍＩｎＧａＡｓＰ材料，以及在其分别限制量子讲结构生长的情况下，用质子轰击方法制得的条形结构量子阱激光器。该激光器在室温下直流阈值电流为１００ｍＡ。     

国产金属有机化合物TMGa,TMAl,TMIn和TMSb的MOVPE鉴定

利用我们研制的常压ＭＯＶＰＥ设备对国产ＴＭＧａ、ＴＭＡｌ、ＴＭＩｎ和ＴＭＳｂ进行了鉴定，为此分别生长了ＧａＡｓ、ＡｌＧａＡｓ、ＩｎＰ、ＧａＳｂ外延层和ＧａＡｓ／ＡｌＡｓ、ＧａＳｂ／ＩｎＧａＳｂ超晶格和ＧａＡｓ／ＡｌＧａＡｓ量子阱结构。表征材料纯度的７７Ｋ载流予迁移率分别达到ＧａＡｓ：μ＿ｎ＝５６６００ｃｍ￣２／Ｖ·ｓ，Ａｌ＿（０．２５）Ｇａ＿（０．７５）Ａｓ：μ＿ｎ＝５１６０ｃｍ￣２／Ｖ·ｓ，ＩｎＰ：μ＿ｎ＝６５３００ｃｍ￣２／Ｖ·ｓ，ＧａＳｂ：μ＿ｐ＝５０７６ｃｍ￣２／Ｖ·ｓ。由１０个周期的ＧａＡｓ／ＡｌＡｓ超晶格结构组成的可见光区布拉格反射器已观测到很好的反射光谱和双晶Ｘ射线回摆曲线上高达±２０级的卫星峰。ＧａＡｓ／Ａｌ＿（０．３５）Ｇａ＿（０．６５）Ａｓ量子阱最小阱宽为１０，在ｌｉＫ下由量子尺寸效应导致的光致发光峰能量移动为３９０ｍｅＶ，其线宽为１２ｍｅＶ。这些结果表明上述金属有机化合物已达到较高质量。     

室温连续工作的GaAs／AlGaAs垂直腔面发射激光器列阵

报导了由选择氧化法研制的ＧａＡｓ／ＡｌＧａＡｓ垂直腔面发射激光器，ＤＢＲ中的ＡｌＡｓ经选择氧化形成的氧化层作为有源区的横向电流限制层，器件的最低阈值电流为３．８ｍＡ，输出功率大于ｌｍＷ，发散角小于７．８°，高频测量脉冲上升沿达１００ｐｓ，并由此器件制成了２×３二维列阵。     

Structural and optical properties of AlxOy/Pt/AlxOy multilayer absorber

We report on the microstructure and optical properties of Al_xO_y–Pt–Al_xO_y interference-type multilayer films, deposited by electron beam (e-beam) deposition onto corning 1737 glass, silicon (1 1 1) and copper substrates. The structural properties were investigated by Rutherford backscattering spectrometry, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy and atomic force microscopy. The optical properties were extracted from specular reflection/transmission, diffuse reflectance and emissometer measurements. The stratification of the coatings consists of a semi-transparent middle Pt layer sandwiched between two layers of Al_xO_y. The top and bottom Al_xO_y layers were non-stoichiometric with no crystalline phases present. The Pt layer is in the fcc crystalline phase with a broad size distribution and spheroidal shape in and between the rims of Al_xO_y. The surface roughness of the stack was found to be comparable to the inter-particle distance. The optical calculations confirm a high solar absorptance of ∼0.94 and a low thermal emittance of ∼0.06 for the multilayer stack, which is attributed not only to the optimized nature of the multilayer interference stacks, but also to the specific surface morphology and texture of the coatings. These optical characteristics validate the spectral selectivity of the Al_xO_y–Pt–Al_xO_y interference-type multilayer stack for use in high temperature solar-thermal applications.     

Optimization of AlxOy/Pt/AlxOy multilayer spectrally selective coatings for solar-thermal applications

Spectrally selective Al_xO_y/Pt/Al_xO_y multilayer absorber coatings were deposited onto corning 1737 glass, Si (111) and copper substrates using electron beam (e-beam) vacuum evaporator at room temperature. The employment of ellipsometric measurements and optical simulation was proposed as an effective method to optimize and deposit multilayer solar absorber coatings. The optical constants (n and k) measured using spectroscopic ellipsometry, showed that both Al_xO_y layers, which used in the coatings, were dielectric in nature and the Pt layer was semi-transparent. The optimized multilayer coatings exhibited high solar absorptance α ∼ 0.94 ± 0.01 and low thermal emittance ? ∼ 0.06 ± 0.01 at 82 °C. The Rutherford backscattering spectroscopy (RBS) data of Al_xO_y/Pt/Al_xO_y multilayer absorber indicated the Al_xO_y layers present in the coating were nearly stoichiometry. The scanning electron microscope analysis (SEM) result indicated that the average diameter and inter-particles distance of Pt grains were statistically about 146 ± 0.17 nm and 6-10 ± 0.2 nm respectively.     

Anomalous Hall Effect in Sn1?x?yMnxEuyTe and Sn1?x?yMnxEryTe Mixed Crystals

The Anomalous Hall Effect (AHE) was investigated in IV–VI ferromagnetic semimagnetic semiconductors of Sn_1–x Mn _x Te codoped with either Eu or Er. The analysis of experimental data is as follows. Hall resistivity and magnetization showed that AHE coefficient R _s depends on temperature and its value decreases with thetemperature increase. We observe that above ferromagnet–paramagnet transition temperature R _s changes sign. We discuss the possible physical mechanisms responsible for observed temperature dependence of R _s , particularly change of the sign.     

Bulk crystalline BaPb34Bi14O3: A ceramic superconductor

The preparation conditions of the high T_C ceramic superconductor Ba(Pb,Bi)O₃ is correlated with the superconducting transition. Transition onsets of all materials are similar, but transition widths and transition completeness is strongly dependent on firing temperature. Only materials prepared over a narrow temperature range, resulting in a nearly ideal weight loss, have a complete and narrow transition.     

Interfacial microstructure of NiSix/HfO2/SiOx/Si gate stacks

Integration of NiSi_x based fully silicided metal gates with HfO₂ high-k gate dielectrics offers promise for further scaling of complementary metal-oxide- semiconductor devices. A combination of high resolution transmission electron microscopy and small probe electron energy loss spectroscopy (EELS) and energy dispersive X-ray analysis has been applied to study interfacial reactions in the undoped gate stack. NiSi was found to be polycrystalline with the grain size decreasing from top to bottom of NiSi_x film. Ni content varies near the NiSi/HfO_x interface whereby both Ni-rich and monosilicide phases were observed. Spatially non-uniform distribution of oxygen along NiSi_x/HfO₂ interface was observed by dark field Scanning Transmission Electron Microscopy and EELS. Interfacial roughness of NiSi_x/HfO_x was found higher than that of poly-Si/HfO₂, likely due to compositional non-uniformity of NiSi_x. No intermixing between Hf, Ni and Si beyond interfacial roughness was observed.     

Tc trend in high-Tc superconductors

In our previous works, we have shown that most existing ceramic superconductors can be considered to be built of superconductor-semiconductor composite and we have estimated the change in phonon spectrum of the intrinsic superconductor unit if a semiconductor unit is attached to it. Moreover, the proximity effect under the size quantization condition has been examined in the superconductor-semiconductor composite. Each of the stated effects by itself could causeT _c enhancement in general as more semiconductor blocks are added to the system. We extend our study in this paper to analyze the combined actions of phonon spectral change and proximity effect without size quantization condition onT _c variation in members of the Tl₁ series of high-T _c superconductors. Our results indicate that an optimumT _c is obtained if the stated effects are included in the idealized unit cells of the superconductors made up of a superconductor-semiconductor array.     

Electrostriction in Pb (Zn13Nb23)O3

The electrostriction in $\text{Pb (Zn}{}_{\mathrm{<mtext>1</mtext><mtext>3</mtext>}}\text{Nb}{}_{\mathrm{<mtext>2</mtext><mtext>3</mtext>}}\text{)}\text{O}{}_3$ crystals has been investigated using a strain gauge method. In the ferroelectric phase below 140 C, the strain vs the electric field shows a hysteresis, which is ascribed to the effect of ferroelectric domains. A quadratic relation holds between the strain x and the electric polarization P as x = QP² above about 170 C in the paraelectric phase. Values of the electrostrictive Q coefficients are determined from the measurements near 190 C, as Q₁₁ = 1.6·10^?2m⁴/C², Q₁₂ = ?0.86·10^?2m⁴/C², and Q₄₄ = 0.85·10^?2m⁴/C².     

Synthesis of a new perovskite Pb(Li14Nb34)O3

A high-pressure technique was adopted to obtain perovskite-type $\text{Pb(Li}{}_{\mathrm{<mtext>1</mtext><mtext>4</mtext>}}\text{Nb}{}_{\mathrm{<mtext>3</mtext><mtext>4</mtext>}}\text{)}\text{O}{}_3$. A new perovskite $\text{Pb(Li}{}_{\mathrm{<mtext>1</mtext><mtext>4</mtext>}}\text{Nb}{}_{\mathrm{<mtext>3</mtext><mtext>4</mtext>}}\text{)}\text{O}{}_3$ was characterized to have a cubic symmetry with $\text{a}{}_{\mathrm{<mtext>o</mtext>}}\text{= 4.069}\text{A}\text{?}$; Li and Nb ions in the B-site of perovskite lattice may be in a random arrangement.     

Magnetic,electrical and thermal studies on the V1−xMox02

The monoclinic-to-tetragonal structure transition of oxides V_1?xMo_x0₂ with $\text{0≤}\text{x}\text{≤0.20}$ has been studied by means of DTA, X-ray diffraction, magnetic susceptibility (powder samples) and electrical conductivity (single crystals) measurements within the temperature region 80 K to 400 K. A linear decrease of the transition temperature of 11 K per atom % Mo was observed. The magnetic susceptibility of the low temperature phase was found to be temperature independent paramagnetic for all preparations. Electrical conductivity measurements on the same phase showed crystals with $\text{x}\text{? 0.04}$ to be semiconducting, while a metallic behavior was observed in the region $\text{0.10 ?}\text{x}\text{? 0.14}$.