Vibration damping characteristics of carbon fiber-reinforced composites containing multi-walled carbon nanotubes

Vibration damping characteristic of nanocomposites and carbon fiber reinforced polymer composites (CFRPs) containing multiwall carbon nanotubes (CNTs) have been studied using the free and forced vibration tests. Several vibration parameters are varied to characterize the damping behavior in different amplitudes, natural frequencies and vibration modes. The damping ratio of the hybrid composites is enhanced with the addition of CNTs, which is attributed to sliding at the CNT-matrix interfaces. The damping ratio is dependent on the amplitude as a result of the random orientation of CNTs in the epoxy matrix. The natural frequency shows negligible influence on the damping properties. The forced vibration test indicates that the damping ratios of the CFRP composites increase with increasing CNT content in both the 1st and 2nd vibration modes. The CNT-epoxy nanocomposites also show similar increasing trends of damping ratio with CNT content, indicating the enhanced damping property of CFRPs arising mainly from the improved damping property of the modified matrix. The dynamic mechanical analysis further confirms that the CNTs have a strong influence on the composites damping properties. Both the dynamic loss modulus and loss factor of the nanocomposites and the corresponding CFRPs show consistent increases with the addition of CNTs, an indication of enhanced damping performance.     

The effects of carbon nanotubes on mechanical and thermal properties of woven glass fibre reinforced polyamide-6 nanocomposites

This paper presents a preliminary investigation on the effects of incorporating carbon nanotubes (CNT) into polyamide-6 (PA6) on mechanical, thermal properties and fire performance of woven glass reinforced CNT/PA6 nanocomposite laminates. The samples were characterized by tensile and flexural tests, thermal gravimetric analysis (TGA), heat distortion temperature (HDT) measurements, thermal conductivity and cone calorimeter tests. Incorporation of up to 2 wt% CNT in CNT/PA6/GF laminates improved the flexural stress of the laminates up to 36%, the thermal conductivity by approximately 42% and the ignition time and peak HRR time was delayed by approximately 31% and 118%, respectively.     

Effect of carbon nanotube modified epoxy adhesive on CFRP-to-steel interface

The effects of carbon nanotube (CNT) modified epoxy adhesive on CFRP-to-steel interfaces were investigated using double strap joints. The bond behaviours studied were failure modes, bond interface at microlevel, bond strength, effective bond length, CFRP strain distribution and bond-slip relationships.For the first time, a novel type of failure in the CFRP-steel joint was discovered, attributable to weak bonding between woven mesh and CFRP fibres. This failure mode prevented exploitation of the full potential of the carbon fibres and the CNT modified epoxy adhesive. Joints bonded with CNT-epoxy adhesive had an effective bond length of about 60 mm, whereas that of joints bonded with pure epoxy was about 70 mm. The CNT-epoxy adhesive can transfer more load from the host structure to the bonded CFRP laminates, consequently modifying bond behaviour. It is therefore expected that CNT-epoxy nanocomposites will assist in the strengthening and rehabilitation of steel infrastructures using CFRP laminates.     

Effect of CNTs addition on the erosive wear response of epoxy resin and carbon fibre composites

In the current study we investigated the effect of carbon nanotubes (CNTs) addition on the erosive wear response of epoxy resin and carbon fibre reinforced laminates (CFRPs) and demonstrated the positive synergy of CNTs and carbon fibres, which resulted in almost 50% decrease of the erosion rate (ER) of the CFRPs at high impact angles (90°). Incorporation of CNTs led in slight increase of the ER of the epoxy systems, especially at low impact angles. The relative fibre orientation in the CFRPs had a negligible effect on the erosive wear response mainly due to the quasi isotropic nature of the tested CFRPs. Based on the erosion efficiency parameter the response of the epoxy systems was characterised as semi-brittle, while CFRPs behaved in a brittle manner. Scanning electron micrograph provided evidence that the presence of CNTs reduced the amount of broken and/or detached fibres in the case of CFRPs.     

Mechanical properties of carbon fiber/fullerene-dispersed epoxy composites

This study examined the effect of fullerene dispersion on the mechanical properties of carbon-fiber reinforced epoxy matrix composites (CFRPs). Mechanical properties such as tension, compression, open-hole compression, comparession after impact (CAI), binding, short beam shear, and interlaminar fracture toughness were evaluated for [0]₈, [90]₁₆, [45/0/?45/90]_2S laminates. Tension and compression strengths increased 2–12% by dispersing 0.5% of fullerene into the matrix resin. Furthermore, interlaminar fracture toughness of the composite was improved by about 60%. It was revealed that a small amount of fullerene (0.1–1 wt.%) increased the failure strain of epoxy resin itself, thereby improving the CFRP strength.     

Investigation of galvanic corrosion between AISI 1018 carbon steel and CFRPs modified with multi-walled carbon nanotubes

In this article, we investigate the effect of modified carbon fiber-reinforced polymer (CFRP) composites when galvanically coupled with AISI 1018 carbon steel. Two different resins were used to manufacture the CFRPs: neat epoxy resin, and epoxy resin modified with multi-walled carbon nanotubes (MWCNTs). The specimens of composite (the cathode of the galvanic cell) and metal (the anode of the galvanic cell) were paired and immersed in electrolyte (NaCl solution, 2 % by weight) at 40 °C, to simulate a corrosive environment and accelerate the electrochemical reaction. Results of corrosion rate (CR) and mass loss rate (MR) were obtained, and the electrical resistances of the CFRPs were also measured. This new study shows that the MWCNTs do not have a statistically significant impact on the corrosion and mass loss rate results, and that both types of CFRP composites have statistically the same electrical resistance. Therefore, common methods used in the engineering practice in conventional hybrid CFRP/steel joints and repairs may be sufficient to delay galvanic corrosion, as there is no increased liability.     

Effect of moisture on elastic and viscoelastic properties of epoxy and epoxy-based carbon fibre reinforced plastic filled with multiwall carbon nanotubes

In this study, we investigated the peculiarities of moisture absorption and moisture-induced effects on the elastic and viscoelastic flexural properties of epoxy resin and carbon fibre reinforced plastic (CFRP) filled with multiwall carbon nanotubes (MWCNTs). Short-term cyclic creep-recovery tests of moistened epoxy and CFRP filled with MWCNTs revealed improvements in creep resistance for both materials. The addition of MWCNTs to the epoxy resin suppressed the moisture absorption by the material, causing a reduction in the diffusion coefficient by 31% and equilibrium moisture content by 15%. The addition of MWCNTs reduced the flexural strength of moistened epoxy and CFRP samples by approximately half, and also lowered the flexural modulus by ∼1.4 and ∼3 times, elastic strain by 1.25 and 1.04 times, viscoelastic strain by 1.39 and 1.03 times, and plastic strain by 2.68 and 1.60 times, respectively.     

Damage evolution behavior of CFRP laminates under post-impact fatigue with water absorption environment

In this study, the damage evolution behavior was evaluated considering the effect of the textile structure and water absorption. Damage observation was conducted by the integration of non-destructive and direct observation methods. Candidate textile reinforcements were T300-3k plain woven fabric (PW) and T700S-12k multi-axial knitted fabric (MA). The effect of water absorption on the performances of compression after impact (CAI) and PIF were small in PW CFRP laminates. Conversely, PIF properties of water-absorbed MA CFRP laminates drastically decreased than that of dry ones. CAI strength was not affected by water absorption. PIF performance of dry MA CFRP was fairly higher than that of the others. From the precise observation, some evidences of interfacial deterioration caused by water absorption were confirmed in both PW and MA CFRP laminates.     

Enhancement of mechanical performance of epoxy/carbon fiber laminate composites using single-walled carbon nanotubes

Carbon nanotubes (CNT) in their various forms have great potential for use in the development of multifunctional multiscale laminated composites due to their unique geometry and properties. Recent advancements in the development of CNT hierarchical composites have mostly focused on multi-walled carbon nanotubes (MWCNT). In this work, single-walled carbon nanotubes (SWCNT) were used to develop nano-modified carbon fiber/epoxy laminates. A functionalization technique based on reduced SWCNT was employed to improve dispersion and epoxy resin-nanotube interaction. A commercial prepregging unit was then used to impregnate unidirectional carbon fiber tape with a modified epoxy system containing 0.1 wt% functionalized SWCNT. Impact and compression-after-impact (CAI) tests, Mode I interlaminar fracture toughness and Mode II interlaminar fracture toughness tests were performed on laminates with and without SWCNT. It was found that incorporation of 0.1 wt% of SWCNT resulted in a 5% reduction of the area of impact damage, a 3.5% increase in CAI strength, a 13% increase in Mode I fracture toughness, and 28% increase in Mode II interlaminar fracture toughness. A comparison between the results of this work and literature results on MWCNT-modified laminated composites suggests that SWCNT, at similar loadings, are more effective in enhancing the mechanical performance of traditional laminated composites.     

Fatigue damage behaviors of carbon fiber-reinforced epoxy composites containing nanoclay

The effects of nanoclay inclusion on cyclic fatigue behavior and residual properties of carbon fiber-reinforced composites (CFRPs) after fatigue have been studied. The tension–tension cyclic fatigue tests are conducted at various load levels to establish the S-N curve. The residual strength and modulus are measured at different stages of fatigue cycles. The scanning electron microscopy (SEM) and scanning acoustic microscopy (SAM) are employed to characterize the underlying fatigue damage mechanisms and progressive damage growth. The incorporation of nanoclay into CFRP composites not only improves the mechanical properties of the composite in static loading, but also the fatigue life for a given cyclic load level and the residual mechanical properties after a given period of cyclic fatigue. The corresponding fatigue damage area is significantly reduced due to nanoclay. Nanoclay serves to suppress and delay delamination damage growth and eventual failure by improving the fiber/matrix interfacial bond and through the formation of nanoclay-induced dimples.     

Interconnected multi-walled carbon nanotubes reinforced polymer-matrix composites

A modified method for interconnecting multi-walled carbon nanotubes (MWCNTs) was put forward. And interconnected MWCNTs by reaction of acyl chloride and amino groups were obtained. Scanning electron microscopy shows that hetero-junctions of MWCNTs with different morphologies were formed. Then specimens of pristine MWCNTs, chemically functionalized MWCNTs and interconnected MWCNTs reinforced epoxy resin composites were fabricated by cast moulding. Tensile properties and fracture surfaces of the specimens were investigated. The results show that, compared with pristine MWCNTs and chemically functionalized MWCNTs, the chemically interconnected MWCNTs improved the fracture strain and therefore the toughness of the composites significantly.     

Compressive behavior of concrete cylinders confined by narrow strips of CFRP with spacing

Application of carbon fiber-reinforced polymer (CFRP) is one of the effective strengthening methods for structural members such as reinforced concrete columns and beams. However, air voids and debonds between CFRP and concrete due to poor workmanship may degrade the structural performance otherwise expected by the strengthening. In order to minimize such debonds and ease the installation, the authors propose to wrap compressive concrete members with narrow strips of CFRP laminates with spacing. This paper focuses on an experimental study to investigate the effectiveness of applying the narrow strips of CFRP laminates. In this study, 60 concrete cylinders wrapped with CFRP strips having different spacings and widths are tested under compression load. The effects of several key parameters such as spacing, spliced length, number of layers, and section area of the CFRP laminates are investigated. In addition, stress–strain curves of pre-damaged specimens wrapped with CFRP laminates are also focused. Based on the experimental results, constitutive models of concrete confined by narrow strips of CFRP laminates are proposed.     

Nano-enhanced composite materials under thermal shock and environmental degradation: A durability study

Carbon nanotubes (CNTs) were incorporated at 0.5 wt% in epoxy resin using sonication at two different levels of amplitude (50% and 100% of 400 W nominal sonication power). The CNTs modified epoxy systems were used to manufacture carbon fibre reinforced laminates (CFRPs). All specimens were subjected to thermal shock and hygrothermal exposure. The presence of CNTs did not alter the water absorption profiles for the epoxy resin, but it resulted in a spectacular 40% reduction in the water uptake at equilibrium for the CFRPs. The interlaminar shear strength of the CFRPs was not significantly affected by the thermal shock cycles; however it was reduced by 50–60% after hygrothermal exposure. The addition of CNTs led to slightly lower interlaminar shear strength values in the as-manufactured state. However their presence did not accelerate the deterioration of the strength after the environmental exposure. Although the addition of CNTs did not significantly influence the thermomechanical properties of the resin, they were beneficial in the case of the CFRPs since (i) they enhanced the storage modulus and glass transition temperature and (ii) limited the deterioration of these properties after thermal shock and hygrothermal exposure. The amplitude level during sonication which determined the dispersion state and length of the CNTs had a clear effect on the durability of the studied systems.     

Mechanical properties of CFRP laminates manufactured from unidirectional prepregs using CSCNT-dispersed epoxy

This study presents the experimental results of the mechanical properties of three-phase CFRP laminates consisting of traditional carbon fibers and epoxy matrix modified using cup-stacked carbon nanotubes (CSCNTs) in comparison to those of CFRP laminates without CSCNTs. The prepreg system of carbon fibers impregnated with CSCNT-dispersed epoxy is developed, and successful fabrication of three-phase CFRP laminates is achieved using an autoclave. Basic mechanical properties of unidirectional laminates (stiffness, strength, fracture toughness, etc.) are summarized. Next, quasi-isotropic laminates are subjected to tension, compression, flexural, and compression after impact (CAI) tests. Improvement of stiffness and strength and no adverse effects on mechanical properties due to CSCNT dispersion are experimentally verified.     

复合材料层合板低速冲击损伤容限的改进方法和影响因素

依据笔者在这方面的研究和前人的工作，以及现有各种改进炭纤维增强树脂基复合材料冲击性能的方法，分析和总结了复合材料层合结构冲击损伤以及损伤容限，其中主要是冲击后压缩强度的重要影响因素，并且讨论了这些因素的作用。     

Characterization of defects in carbon fiber-reinforced plastics by inverse heat conduction analysis using transfer matrix between layers

In this study, inverse analyses of the defects in carbon fiber-reinforced plastics (CFRPs) are performed using the transfer matrix approach. The material properties used in the calculation were obtained on the basis of mixture laws for epoxy resin and carbon fibers. The accuracy of the inverse analysis was confirmed by calculations employing numerical models of CFRP plates with PAN-based and pitch-based carbon fibers containing defects. The inverse analysis was conducted based on the temperature distribution of CFRP laminates with PAN-based carbon fibers, which was obtained by infrared measurements. The analyses successfully estimated the positions of defects, and the effectiveness of the transfer matrix method for CFRPs was demonstrated through the inverse analysis.     

Quantification of flexural fatigue life and 3D damage in carbon fibre reinforced polymer laminates

Carbon fibre reinforced polymer (CFRP) laminated composites have become attractive in the application of wind turbine blade structures. The cyclic load in the blades necessitates the investigation on the flexural fatigue behaviour of CFRP laminates. In this study, the flexural fatigue life of the [+45/−45/0]_2s CFRP laminates was determined and then analysed statistically. X-ray microtomography was conducted to quantitatively characterise the 3D fatigue damage. It was found that the fatigue life data can be well represented by the two-parameter Weibull distribution; the life can be reliably predicted as a function of applied deflections by the combined Weibull and Sigmodal models. The delamination at the interfaces in the 1st ply group is the major failure mode for the flexural fatigue damage in the CFRP laminate. The calculated delamination area is larger at the interfaces adjacent to the 0 ply. The delamination propagation mechanism is primarily matrix/fibre debonding and secondarily matrix cracking.     

Piezoresistivity of unidirectional carbon/epoxy composites for multiaxial loading

The applied strain of carbon fibre reinforced plastics (CFRPs) is measurable by their electrical resistance changes. For damage monitoring of laminated CFRPs, piezoresistivity strongly affects the measured electrical resistance change through residual strain relief attributable to delamination cracks. Although several studies of CFRP laminates’ piezoresistivity have been published, this study uses single-ply CFRP for specific piezoresistivity measurements in four directions. A review of the theory of in-plane piezoresistivity reveals orthotropic properties of CFRP piezoresistivity. In the present study, piezoresistivity of multiaxial loading is derived, and the unsymmetrical piezoresistivity matrix is calculated using the measured piezoresistivity here. Effects of multiaxial loading in a misaligned unidirectional laminate are also discussed here. The misaligned laminate causes large shrink in the transverse direction during tensile tests; poor electrical contacts at electrodes increases the electric current in the transverse direction; these two effects cause decrease of electrical resistance for the poor electrical contact specimen with large fibre misalignment.     

Fatigue behavior of RC T-beams strengthened in shear with EB CFRP L-shaped laminates

The use of externally bonded carbon fiber-reinforced polymer (EB-CFRP) to strengthen deficient reinforced concrete (RC) beams has gained in popularity and has become a viable and cost-effective method. Fatigue behavior of RC beams strengthened with FRP is a complex issue due to the multiple variables that affect it (applied load range, frequency, number of cycles). Very few research studies have been conducted in shear under cyclic loading. The use of prefabricated CFRP L-shaped laminates (plates) for strengthening RC beams under static loading has proven to be technically feasible and very efficient. This study aimed to examine the fatigue performance of RC T-beams strengthened in shear for increased service load using prefabricated CFRP L-shaped laminates. The investigation involved six laboratory tests performed on full-size 4520 mm-long T-beams. The specimens were subjected to fatigue loading up to six million load cycles at a rate of 3 Hz. Two categories of specimens (unstrengthened and strengthened) and three different transverse-steel reinforcement ratios (Series S0, S1, and S3) were considered. Test results were compared with the upper fatigue limits specified by codes and standards. The specimens that did not fail in fatigue were then subjected to static loading up to failure. The test results confirmed the feasibility of using CFRP L-shaped laminates to extend the service life of RC T-beams subjected to fatigue loading. The overall response was characterized by an accelerated rate of damage accumulation during the early cycles, followed by a stable phase in which the rate slowed significantly. In addition, the strains in the stirrups decreased after the specimens were strengthened with CFRP, despite the higher applied fatigue loading. Moreover, the addition of L-shaped laminates enhanced the shear capacity of the specimens and changed the failure mode from brittle to ductile under static loading. Finally, the presence of transverse steel in strengthened beams resulted in a substantially reduced gain in shear resistance due to CFRP, confirming the existence of an interaction between the transverse steel and the CFRP.     

静电植绒法处理多壁碳纳米管改性玻纤织物/环氧树脂复合材料的制备及力学性能

为提高玻纤增强环氧树脂复合材料的力学性能,采用静电植绒法将多壁碳纳米管(MWCNTs)附着在玻纤织物表面,得到改性的玻纤织物。利用一种低黏度的环氧树脂和所制得的改性织物,采用真空辅助成型工艺(VARI)制备了MWCNTs改性格玻纤织物/环氧树脂复合材料层合板,表征了层合板的力学性能。对进行力学实验后的MWCNTs改性玻纤织物/环氧树脂复合材料试样断口进行了SEM和OPM观察。结果显示:与未添加MWCNTs的玻纤织物/环氧树脂复合材料层合板相比,添加了MWCNTs的层合板的拉伸强度降低了10.24%,弯曲强度降低了13.90%,压缩强度降低了17.33%,拉伸模量和弯曲模量分别提高了19.38%和16.04%,压缩模量提高了13%;MWCNTs与玻纤织物之间的结合较弱,在拉伸作用下,存在明显的脱粘和分层;将改性玻纤织物在200℃下热压处理2h后,制备的MWCNTs改性玻纤织物/环氧树脂复合材料层合板的力学性能均有所提高,热压处理后树脂与玻纤织物之间的界面结合得到改善。