铜合金表面热喷涂镍基合金层激光重熔后的显微组织及耐磨性能

为了满足工业领域铜合金传热、耐磨、耐腐蚀性能优异的要求,对铜合金表面先等离子喷涂NiCrFeWBC自熔合金层,再进行激光重熔.采用现代分析技术研究了重熔处理对涂层显微组织及耐磨性能的影响.结果表明:等离子喷涂NiCrFeWBC自熔合金涂层重熔后层状组织、孔洞等缺陷完全消失,激光熔覆层与铜基体为冶金结合,涂层致密、组织均匀;熔覆层由表及里依次呈等轴晶、树枝晶及胞状晶形貌,并有WC,W_2C,Ni_3B等颗粒析出;熔覆层磨损性能明显高于铜合金基体及热喷涂涂层,磨损机理为典型的磨粒磨损.     

热喷涂涂层的重熔技术

为了改善热喷涂涂层的使用性能,研究了涂层重熔技术,综述了近年来出现的各种涂层重熔处理新工艺。     

热喷涂纯铝激光重熔涂层的阻氢性能与组织

采用热喷涂及激光重熔表面改性处理技术,研究了奥氏体不锈钢表面纯铝激光重熔涂层抑制氢渗透的性能及其组织,结果表明涂层具有一定的抑制氢渗透的能力,其原因与涂层的性能和微观组织密切相关。     

热喷涂纯铝激光重熔涂层的阻氢性能与组织

采用热喷涂及激光重熔表面改性处理技术,研究了奥氏体不锈钢表面纯铝激光重熔涂层抑制氢渗透的性能及其组织,结果表明涂层具有一定的抑制氢渗透的能力,其原因与涂层的性能和微观组织密切相关。     

热喷涂层孔隙及对涂层性能影响的研究现状

孔隙是热喷涂层的一种重要结构缺陷,热喷涂层孔隙率是表征涂层致密程度的重要指标,也是评价涂层质量优劣的重要标准。孔隙率的高低直接影响涂层的服役性能,将涂层孔隙率控制在一定范围内,对提高涂层使用寿命、增强涂层的防护性能具有重要意义。总结了热喷涂层孔隙的形成机理、热喷涂层孔隙形成的影响因素、涂层孔隙率的测试方法,阐述了热喷涂层孔隙对涂层隔热性能、力学性能、腐蚀性能的影响,并展望了该领域未来的重点研究方向。     

热喷涂Ni基金属陶瓷层的重熔处理研究进展与展望

热喷涂Ni基金属陶瓷涂层具有耐磨损、耐高温和耐腐蚀等优良性能,已被广泛应用于零件的修复,但是由于涂层中的气孔、微裂纹等微观缺陷较多,结合强度较低,在恶劣的环境中适应性较差。重熔处理可以提高此类涂层界面的结合强度、耐磨性及耐蚀性能,延长其使用寿命。介绍了每种Ni基金属陶瓷热喷涂层的重熔处理方法、性能和结构组织,指出了重熔处理存在的一些问题,并给出了未来研究的展望。     

涂层

20010601 等离子喷涂Ni-Cr-B-Si及激光重熔涂层的耐磨性 ──Liang G Y. Surface & Coatings Technology, 2000,12 7(2～3):233(英文)在Al合金上等离子喷涂Ni-Cr-B-Si和Ni-Cr-B-Si+WC,用CO_2激光器重熔合金涂层, 对比研究了激光重熔涂层和等离子喷涂涂层的耐磨性,用SEM分析了磨损形貌。结果表明, 激光重熔涂层和等离子喷涂涂层均具有良好的耐磨性,激光重熔Ni-Cr-B-Si涂层耐磨性 最好,优于等离子喷涂Ni-Cr-B-Si涂层;等离子喷涂Ni-Cr-B-Si+WC涂层的耐磨性优 于等离子喷涂Ni-Cr-B-Si涂层,但激光重熔并未改变二种涂…     

Ni60优化高铝青铜SAPS—感应重熔涂层组织结构的研究

采用超音速等离子喷涂技术在45#钢基体上制备Ni60/高铝青铜梯度涂层,并进行高频感应重熔处理。通过SEM、XRD等手段分析了感应重熔前后涂层的组织结构特征、相结构变化以及界面元素扩散情况。结果表明,超音速等离子喷涂层在基体/Ni60结合面处以机械咬合为主,在Ni60/高铝青铜涂层界面处有轻微熔结特性,形成了机械结合和轻微冶金结合的混合结合方式。感应重熔后,Ni60中间层分别与基体、高铝青铜涂层进行充分的双向扩散熔合。在Ni60和基体间形成结构致密、无孔隙的冶金扩散带,元素扩散迁移后不同元素呈现梯度或均匀分布形式。在Ni60和高铝青铜涂层之间分层界面基本消失,形成了完全的一体化涂层,涂层中元素扩散呈现梯度形式。     

镁合金表面熔覆改性技术的研究进展

评述了镁合金表面熔覆改性技术的国内外发展概况,着重介绍了热喷涂、激光熔覆及热喷涂 激光重熔复合熔覆3种处理工艺和熔覆涂层材料,提出采用热喷涂 激光熔覆复合法熔覆工艺、镁合金表面熔覆非晶合金以及熔覆高熔点涂层是提高镁合金表面性能的有效方法,具有良好的应用前景.     

加热功率对感应重熔涂层性能的影响

为明确重熔工艺参数对感应重熔涂层表面状态、硬度及成分的影响,优化重熔工艺参数,采用预涂和感应重熔方法以不同加热功率在20钢柱塞杆上制备Ni60重熔层,并分析了重熔层的微观形貌、硬度和成分。结果表明:感应加热功率合适(40 kW)时,工件表面平整光洁,涂层组织致密均匀,涂层表面平均硬度为758.9 HV_(1 N);感应重熔过程主要为基体中Fe元素向涂层内部扩散,而涂层中Ni、Cr元素向基体扩散较少。     

常规和纳米ZrO_2-7%Y_2O_3等离子喷涂热障层及其激光重熔后的抗热震性能

为了探讨激光重熔对等离子喷涂常规和纳米热障涂层(TBCs)的影响,采用等离子喷涂工艺在γ-TiAl合金表面制备了常规和纳米ZrO2-7%Y2O3TBCs,并对其进行激光重熔处理,研究了等离子喷涂常规TBCs、激光重熔-等离子喷涂常规TBCs、等离子喷涂纳米TBCs及激光重熔-等离子喷涂纳米TBCs 4种涂层在850℃下的抗热震性能。结果表明:4种TBCs热震失效次数依次为73,118,146,163次,相应的热震破坏形式分别为整体剥落、局部剥落、边角剥落和局部剥落;纳米结构有利于提高涂层的抗热震性能;激光重熔在一定程度上改善了等离子喷涂层的抗热震性能。     

WC基热喷涂金属陶瓷涂层的激光改性研究

本工作研究了CO2激光重熔处理对超音速火焰喷涂WC--Co和WC--NiCr涂层的组织结构和摩擦学行为的影响。结果表明：选定优化参数下,激光重熔可降低涂层气孔率,提高涂层显微硬度,涂层与基材之间实现冶金结合;干摩擦条件下,涂层经过激光重熔处理耐磨性能显著提高;但润滑条件下劣于未经重熔处理涂层,这可能与未重熔涂层含有较多的气孔,可存储润滑油较好地发挥润滑效果有关。     

Laser surface remelting of WC–12Co coating: finite element simulations and experimental analyses

A three-dimensional finite element model taking into account interfacial topography, porosity of plasma sprayed coatings, temperature dependent thermophysical parameters and phase change has been developed to simulate multipass laser remelting process. Temperature evolution, temperature gradient, melting pool shape and dimensions are simulated. The laser remelting experiments are carried out on the plasma sprayed WC–12Co coatings. The simulated results are in good agreement with the experimental measurements. After laser remelting, a denser and more homogenous coating is obtained. The microhardness of the coating is significantly enhanced owing to the dispersion strengthening, the fine grain strengthening and the solution strengthening, which is increased by three times compared with that of the plasma sprayed coatings.     

Laser Remelting of Plasma Sprayed Thermal Barrier Coatings

A CO2 continuous wave laser with defocused beam was used for remelting the surface of plasma sprayed ZrO2-8 Wt pct Y2O3 (8YSZ)/Ni22Cr10AlY thermal barrier coatings (TBCs) on GH536 superalloy substrate. Two main laser processing parameters, power and travel speed, were adopted to produce a completely remelted layer, and their effects on remelted appearance, remelting depth, density and diameter of depression, space of segment crack and remelted microstructure were evaluated. With energy of 4.0 to 8.0 J.mm(-2), an appropriate laser processing for applicable remelted layer was suggested.     

激光重熔对NiCrBSi等离子喷涂层显微结构和性能的影响

1Crl8Ni9Ti不锈钢表面的NiCrBSi等离子喷涂层存在孔洞及与基体结合差等缺陷,为此进行了激光重熔处理.采用扫描电镜和显微硬度压痕仪分别对涂层的显微结构和力学性能进行了对比研究,采用SRV试验机评价了涂层激光重熔前后的滑动摩擦磨损性能,研究了激光重熔对NiCrBSi等离子喷涂层结构和性能的影响.结果表明:经过激...     

TiAl合金表面激光重熔热障涂层组织及抗高温氧化性能

为了进一步提高TiAl合金表面等离子喷涂ZrO2-7%(质量分数)Y203热障陶瓷涂层的性能,采用激光重熔工艺对涂层进行处理,研究了激光重熔对涂层微观组织和抗高温氧化性能的影响.用扫描电镜(SEM)分析了涂层形貌和微观结构,同时对其抗高温(850℃)氧化性能进行了考察.结果表明,等离子喷涂热障陶瓷涂层呈典型的层状堆积特征,有一定的孔隙且分布有微裂纹;经过激光重熔处理后,陶瓷涂层片层状组织得以消失,致密性提高,获得了基本没有裂纹等缺陷的重熔层;整个重熔层包括界面没有明显特征的平面晶和上部沿热流方向生长的柱状晶组织.等离子喷涂热障涂层具有较好的抗高温氧化性能,经过激光重熔后可进一步提高其抗高温氧化能力.     

Laser Remelting of Plasma Sprayed NiCrA1Y and NiCrAlY-A12O3 Coatings

Two types of plasma sprayed coatings (NiCrAIY and NiCrAIY-AI2O3) were remelted by a 5 kW cw CO2 laser. With increasing laser power and decreasing traverse speed in the ranges of 200～700 W and 5～30 mm/s respectively, the melted track grew in width and depth. In the optimum range of laser parameters, a homogeneous remelted layer without voids, cavities, unmelted particles and microcracks was formed. On the surface of remelted layers, AI2O3 and YAIO3 were detected.As a result of isothermal oxidation tests, weight gains of laser remelted coatings were obviously lower than that only plasma sprayed, especially laser remelted NiCrAIY-AI2O3 coatings. The effects of laser remelting and incorporation of Al2O3 second phase in NiCrAIY matrix on high temperature oxidation resistance were discussed.     

Laser remelting of plasma sprayed NiCrAlY and NiCrAlY-Al2O3 coatings

Two types of plasma sprayed coatings (NiCrAlY and NiCrAlY-Al2O3) were remelted by a 5 kW cw CO2 laser. With increasing laser power and decreasing traverse speed in the ranges of 200 similar to 700 W and 5 similar to 30 mm/s respectively, the melted track grew in width and depth. In the optimum range of laser parameters, a homogeneous remelted layer without voids, cavities, unmelted particles and microcracks was formed. On the surface of remelted layers, Al2O3 and YAlO3 were detected. As a result of isothermal oxidation tests, weight gains of laser remelted coatings were obviously lower than that only plasma sprayed, especially laser remelted NiCrAlY-Al2O3 coatings. The effects of laser remelting and incorporation of Al2O3 second phase in NiCrAlY matrix on high temperature oxidation resistance were discussed.     

Mechanical properties of thermally sprayed Fe based coatings

Abstract

An additional coating against wear or corrosion on component parts is required for many applications. These coatings protect the substrate material against external influences, thus increasing the economic lifetime of the component. Coating processes such as build-up welding and thermal spraying are well established and commonly used. The thermal spray process, in particular, permits deposition of metals, ceramics, or cermets materials to produce near net shape coatings on complex surface geometries. However, commonly used coating materials suffer from high raw material costs, thus decreasing the cost effectiveness of the coating process. Fe based materials are low priced and possess noteworthy mechanical properties; they thus provide the possibility of substituting the expensive Ni and Co based materials commonly used for thermal spray processes. In this work, 2 mm thick high velocity oxyfuel sprayed Fe based coatings in the as sprayed and thermally sprayed and hot isostatic pressed condition were investigated with respect to their mechanical and wear properties. Additionally, the fracture surface was investigated by scanning electron microscopy to characterise the fracture behaviour. It could be demonstrated that the substrate and the heat treatment have the greatest impact on the shear strength of thermally sprayed cold work tool steel. It is shown that the substrate materials as well as the heat treatment are promoting diffusion processes across the interface between the coating and the substrate. Hence, a material integrated bond is formed. The microstructures of the thermally sprayed coatings become more important regarding the mechanisms of failure of the four point bending tests. The material strength is influenced by quenching and tempering and the specimen deflection is influenced by diffusion reactions induced by hot isostatic pressing treatment. The thermally sprayed coatings in the as sprayed condition feature the highest wear resistance due to their hardness.     

FORMATION OF YBaCu-O SYSTEM SUPERCONDUCTOR BY THERMAL SPRAYING

The YBaCu-O and Bi(Pb)SrCaCu-0 system superconductor coatings by thermal spraying are described. YBaCu-O system superconductor coatings are sprayed by using perovskite type and non-perovskite type powders. As sprayed coatings are not superconducting and there is no perovskite structure even when perovskite type powders are used, but they become superconducting after heat treatment in air. An electrochemical method was also employed, to obtain a high quality superconductor applying an electric field treatment. Bi(Pb)SrCsiCu-0 system superconductor coatings are sprayed by changing the starting composition. As-sprayed coatings were not superconducting, but they become superconducting after heat treatment in air like the YBaCu-O system. The Tc of the sprayed coatings using (Bi_1-xPb_x)₅Sr₃Ca₂Cu₃-O powders is higher than the Tc of sprayed coatings using (Bi_1-xPb_x) ₂Sr₂Ca₂Cu₃-O powders.