Fe—Mn—Si形状记忆合金中元素对材料耐蚀性的影响

研究了Ｆｅ－Ｍｎ－Ｓｉ形状记忆合金中元素对材料耐腐蚀性能及形状记忆性能的影响。结果表明：在Ｆｅ－Ｍｎ－Ｓｉ合金中，随着Ｍｎ，Ｓｉ含量的增加，其耐腐蚀性能略有提高，但Ｍｎ含量过高会导致合金形状记忆性能下降。而在Ｆｅ－Ｍｎ－Ｓｉ合金中加入适量的Ｃｒ，可明显提高该合金的耐腐蚀性能，并使之具有良好的形状记忆性能。     

形变对Fe—30Mn—6Si基合金形状记忆效应的影响及其机理研究

本文用膨胀法比较了Ｆｅ－３０Ｍｎ－６Ｓｉ合金在拉伸应变下纵向（沿拉伸方向）和横向（垂直拉伸方向）恢复率的不同；研究了预应变对纵向恢复量，恢复率以及Ａｓ，Ａｆ的影响；还用一个大应变量下的样品在Ａｓ和Ａｆ范围内的不同区间进行了加热和冷却循环试验，得到了一些很有意义的信息。用正电子湮灭方法研究了Ｆｅ－３０Ｍｎ－６Ｓｉ，Ｆ３－３０Ｍｎ－６Ｓｉ－５Ｃｒ合金时效和非时效样品位伸预应变量对合金中的缺陷量，缺陷密     

Fe－Mn－Si形状记忆合金中元素对材料耐蚀性的影响

研究了Ｆｅ－Ｍｎ－Ｓｉ形状记忆合金中元素对材料耐腐蚀性能及形状记忆性能的影响。结果表明：在Ｆｅ－Ｍｎ－Ｓｉ合金中，随着Ｍｎ、Ｓｉ含量的增加，其耐腐蚀性能略有提高，但Ｍｎ含量过高会导致合金形状记忆性能下降。而在Ｆｅ－Ｍｎ－Ｓｉ合金中加入适量的Ｃｒ，可明显提高该合金的耐腐蚀性能，并使之具有良好的形状记忆性能。     

Fe—Mn—Si—Cr合金经热拉—退火后的脆性

采用金相、Ｘ射线衍射和电探针等方法，对经热拉并退火后的Ｆｅ－２８Ｍｎ－６Ｓｉ－５Ｃｒ（％）形状记忆合金出现的严重脆性进行了分析。     

多晶Fe—28Mn—4Si合金组织和形状记忆效应

以光学显微镜和透射电镜观察了Ｆｅ－２８Ｍｎ－４Ｓｉ合金的组织结构，并以弯曲法测定合金的形状记忆效应（ＳＭＥ）的大小，分析了多晶Ｆｅ－２８Ｍｎ－４Ｓｉ合金的组织结构及其与ＳＭＥ的关系，合金在室温下存在大量的层错和ε马氏体，ε马氏体这间及其与层错间呈现严重的交叉，以弯曲法测定了合金在Ｍｓ点以下和以上的ＳＭＥ，Ｍｓ以上无预存ε马氏体状态时所测得的ＳＭＥ远大于Ｍｓ以下有预存ε马氏体状态的ＳＭＥ，表明预存ε     

机械球磨法制备纳米晶Fe73.5Cu1Nb3Si13.5B95的结构研究

对Ｆｅ７３．５Ｃｕ１ｎｂ３Ｓｉ１３．５Ｂ９成分的母合金进行了机械球磨，并对不同时间的球磨样品进行了Ｘ射线衍射（ＸＲＤ）和Ｍｏｓｓｂａｕｅｒ谱（ＭＳ）的测量，结果表明样品难以完全非晶化，形成了无序的αＦｅ－Ｓｉ固溶体的纳米晶，晶粒尺寸在５ｎｍ左右，同时共存一部分富集Ｎｂ，Ｂ元素的界面非晶相。在各种球磨条件下对αＦｅ－Ｓｉ固溶体中的Ｓｉ含量进行了计算。     

形变对Fe－30Mn－6Si基合金形状记忆效应的影响及其机理研究

本文用膨胀法比较了Ｆｅ－３０Ｍｎ－６Ｓｉ合金在拉伸应变下纵向（沿拉伸方向）和横向（垂直拉伸方向）恢复率的不同；研究了预应变对纵向恢复量，恢复率以及Ａ_ｓ，Ａ_ｆ的影响；还用一个大应变量下的样品在Ａ_ｓ和Ａ_ｆ范围内的不同温度区间进行了加热和冷却循环试验，得到了一些很有意义的信息。用正电子湮灭方法研究了Ｆｅ－３０ＭＤ－６Ｓｉ，Ｆｅ－３０Ｍｎ－６Ｓｉ－５Ｃｒ合金时效和非时效样品拉伸预应变量对合金中缺陷量，缺陷密度，γ→ε相变量等的影响。     

Fe—Mn—Si—Cr—Ni形状记忆合金超弹性的研究

用拉伸实验研究了Ｆｅ－１５．２Ｍｎ－６Ｓｉ－８．３Ｃｒ－７Ｎｉ、Ｆｅ－１６Ｍｎ－５Ｓｉ－９Ｃｒ－４Ｎｉ和３１７Ｌ不锈钢的应力应谜面工线。结果表明,铁基形状记忆合金存在显著的超弹必     

Fe—40La及其含Mn或Ti合金的Mossbauer谱

用Ｍｏｓｓｂａｕｅｒ谱研究了Ｂ２结构金属间化合物Ｆｅ－４０Ａｌ及其加Ｍｎ或Ｔｉ量分别为１，５，１０ａｔ．－％的合金，在室温下，Ｆｅ－４０Ａｌ及其合金的Ｍｏｓｓｂａｕｅｒ谱均接近单峰谱线，Ｆｅ原子无明显磁矩。对加入第三组元的Ｆｅ－４０Ａｌ合金的Ｍｏｓｓｂａｕｅｒ谱用最小二乘法拟合为两条洛仑兹曲线之和，认为Ｍｎ原子既占据Ｆ原子位置，也占据Ａｌ原子位置；而Ｔｉ原子优先占据了Ｆｅ原子位置，超过５ａｔ．－％     

Ti—Fe二元系在机械合金化过程中的结构转变及纳米晶TiFe储氢合金的制备

研究了Ｔｉ－Ｆｅ和Ｔｉ－Ｆｅ－Ｍｎ纳米晶储氢合金的机械合金化制备，用Ｘ－ｒａｙ衍射分析了Ｔｉ－Ｆｅ和Ｔｉ－Ｆｅ－Ｍｎ在高能球磨的机械合金化过程中的结构变化及获得的ＦｅＴｉ相的晶粒尺寸。此外，还考察了球磨条件包括气氛、球磨机转速等对球磨过程中结构变化的影响。研究结果表明：采用适当的球磨参数并辅以后续热处理，可以制备出不同晶粒尺寸的纳米晶储氢合金，在本研究中获得的ＦｅＴｉ合金的最小平均晶粒尺寸可达１３ｎｍ。     

Work hardening in Fe–Mn binary alloys

The work hardening rate (WHR) of Fe–Mn binary alloys with Mn content in the range 0.42–1.21 (wt.%) has been investigated in tensile tests at different temperatures. The results show that the WHR depends on temperature and Mn content. We have concluded that the experimental results are in agreement with the model that the change of dislocation density with strain is considered to be a result of the storage and annihilation of dislocations.     

54Mn in Fe for ultralow temperature thermometry

Experimental investigations into the accuracy of nuclear orientation thermometry are reported.⁵⁴Mn in iron, a primary thermometer useful from 2–40 mK, gives consistent thermometry using both scintillation (3×3 in.-NaI) and solid-state (40-cc-Ge) detectors.⁶⁰Co-in-iron temperatures are consistent with the⁵⁴Mn temperatures above 10 mK, but are about 10% higher at 4 mK.¹²⁵Sb in iron registers a temperature that is perhaps 2 or 3% lower over the 4–15 mK region. Some of the techniques required for the utilization of this type of thermometry are discussed.Work performed under the auspices of the U.S. Atomic Energy Commission.     

Physikalische Eigenschaften von CuNi 10 Fe 1 Mn und CuNi 30 Mn 1 Fe unter besonderer Berücksichtigung des Ausscheidungsverhaltens

Influence of Precipitation Process on the Physical Properties of the Cu? Ni-Alloys CuNi 10 Fe 1 Mn and CuNi 30 Mn 1 Fe The following physical properties were measured on six heats of CuNi 10 Fe 1 Mn and seven heats of CuNi 30 Mn 1 Fe: density, Young's modulus, Poisson's ratio, thermal expansion, specific heat capacity, electrical resistivity, thermal conductivity, thermal diffusivity, thermoelectric voltage, saturation magnetization and magnetic permeability. In addition the variation of the values within different heats and different specimens were evaluated. The influence of precipitates varied depending on thermal treatment. The measurement of electrical resistivity and the magnetic properties are useful to evaluate the thermal treatment of CuNi 10 Fe 1 Mn especially after rapid cooling.     

Fe0.92Mn0.08Six半导体热电性能的研究

采用快速凝固方法制备了FeSi2基热电材料Fe0.92Mn0.08Six(x=1．9、2．0、2．1、2．3、2．5)粉末，在高真空下采用热压法制备了块状热电材料。x射线衍射分析表明，所有试样热压后均达到了相平衡，而且x=1．9和2．0的试样热压后就完成了β-FeSi2相转变，随着Si含量的增加，β相逐渐减少，α相逐渐增多。热压试样经800℃退火20h后，完全转变为β半导体相。热压退火试样的致密度为93％～98％。研究发现，弥散分布的过量Si较少时，有利于提高β-FeSi2基热电材料的性能。名义成份为Fe0.92Mn0.088Si2.1的试样在高温区的无量纲优值最大，650℃时达到0．18。但是．当Si过量较多时，试样的热导率明显增加．显著降低了试样的优值。     

Nanocrystals in Fe–P–Si–Mn Alloys

Annealing Fe–P–Si–Mn amorphous alloys is found to produce a few nanocrystalline phases, with a strength gain no higher than that in Fe–P–Si alloys. This crystallization behavior is accounted for by the formation of two metastable silicides whose growth rates during annealing are higher than those of the equilibrium phases.     

Nanoscale Crystallization in Amorphous Fe–P–Mn Alloys

Mössbauer effect measurements and physicochemical analysis demonstrate that annealing of amorphous Fe–P–Mn alloys leads to the formation of a nanocrystalline structure.     

Manganese dependence of microstructure and mechanical properties in Fe–Mn alloy

Two Fe–Mn alloys with relatively low Mn content were designed. The microstructure characteristics and resultant mechanical properties were investigated in detail by means of electron back-scattered diffraction, transmission electron microscopy and X-ray diffraction. The results show that the formation of α′-martensite is effectively suppressed and the yield strength and total elongation are significantly enhanced by increasing Mn content from 12 to 13 mass%. A great amount of α′-martensite can effectively enhance strain hardening rate, but they deteriorate ductility. The austenite grain is always divided by multiple-variant ?-martensite plate. In addition, the prior austenite grain boundaries and austenite/?-martensite interfaces can act as obstacle to suppress the growth of ?-martensite plates.     

Crystallization of (Fe,Mn)-based nanoparticles in sodium-silicate glasses

In this investigation, glasses from the system Na₂O/MnO/SiO₂/Fe₂O₃ are prepared using a conventional glass-melting technique. During annealing the glass, a nanocrystalline (Fe, Mn)-based spinel phase is precipitated. The phase composition and microstructure of the formed glass–ceramics are studied using X-ray diffraction and electron microscopy. Anomalous small-angle X-ray scattering experiment is used to gather information on the size, composition and element distribution for the precipitated (Fe, Mn)-based nanocrystals. The sizes of the formed spinel crystals, as determined by scanning electron microscopy and anomalous X-ray scattering, are in the range from 12 to 50 nm for annealing temperatures in the range from 550 to 700 °C. Annealing for a longer period of time at temperatures ≥600 °C results in the formation of a second crystalline phase, NaFe(SiO₃)₂ (aegirine). The ASAXS data show the formation of core–shell structure for the (Fe, Mn)-based crystals with core consisting mostly of iron oxide and a shell, depleted of Fe and Mn. The growth of the spinel crystals is assumed to be kinetically self-constrained.     

A general perspective of Fe–Mn–Al–C steels

During the last years, the scientific and industrial community has focused on the astonishing properties of Fe–Mn–Al–C steels. These high advanced steels allow high-density reductions about ~?18% lighter than conventional steels, high corrosion resistance, high strength (ultimate tensile strength ~?1 Gpa), and at the same time ductility above 60%. The increase in the tensile or yield strength and the ductility at the same time is almost a special feature of this kind of new steels, which makes them so interesting for many applications such as in the automotive, armor, and mining industry. The control of these properties depends on a complex relationship between the chemical composition of the steel, the test temperature, the external loads, and the processing parameters of the steel. This review has been conceived to elucidate these complex relations and gather the most important aspects of Fe–Mn–Al–C steels developed so far.