Research on the microstructure,fatigue and corrosion behavior of permanent mold and die cast aluminum alloy

Permanent mold (PM) and high pressure die cast (HPDC) AlMg5Si2Mn are employed to investigate the microstructure, fatigue strength and corrosion resistance. Results indicated that the mechanical properties (R_m, R_0.2 and δ) of HPDC specimens (314 MPa, 189 MPa and 7.3%) are significantly better than those of PM specimens (160 MPa, 111 MPa and 2.5%) due to the finer grain size and less cast defects. Fatigue cracks of PM samples dominantly initiated from shrinkage pores and obscure fatigue striations are observed in crack growth region. Corrosion and pitting potentials of PM and HPDC AlMg5Si2Mn alloy are around −1250 mV, −760 mV and −1220 mV, −690 mV respectively. Numerous pits are observed around the grain boundaries because the corrosion potential of Mg₂Si is more anodic than that of α-Al matrix. In addition, the superior corrosion resistance of HPDC samples can be attributed to the fine grain size and the high boundary density which improved the formation of oxide layer on the surface and prevented further corrosion.     

Short cracks initiated in Al 6013-T6 with the focused ion beam (FIB)-technology

The fatigue crack growth behaviour of short corner cracks in the Aluminium alloy Al 6013-T6 was investigated. The aim was to determine the crack growth rates of small corner cracks at a stress ratio of R = 0.1, R = 0.7 and R = 0.8 and to find a possible way to predict these crack growth rates from fatigue crack growth curves determined for long cracks. Corner cracks were introduced into short crack specimens, similar to M(T) – specimens, at one side of a hole (Ø = 4.8 mm) by cyclic compression (R = 20). The precracks were smaller than 100 μm (notch + precrack). A completely new method was used to cut very small notches (10–50 μm) into the specimens with a focussed ion beam. The results of the fatigue crack growth tests with short corner cracks were compared with the long fatigue crack growth test data. The short cracks grew at ΔK-values below the threshold for long cracks at the same stress ratio. They also grew faster than long cracks at the same ΔK-values and the same stress ratios. A model was created on the basis of constant K_max-tests with long cracks that gives a good and conservative estimation of the short crack growth rates.     

Effects of strength level and loading frequency on very-high-cycle fatigue behavior for a bearing steel

Rotating bending (52.5 Hz) and ultrasonic (20 kHz) fatigue tests were performed on the specimens of a bearing steel, which were quenched and tempered at 150 °C, 300 °C, 450 °C and 600 °C, respectively, to investigate the influence of strength level and loading frequency on the fatigue behavior in very-high-cycle regime. Influences on fatigue resistance of materials, characteristics of S–N curves and transition of crack initiation site were discussed. The specimens with higher strength showed interior fracture mode in very-high-cycle regime and with slight frequency effect, otherwise cracks all initiate from the surface and the fatigue strength was much higher under ultrasonic cycling.     

Mechanical and wear behavior of alloyed gray cast iron in the quenched and tempered and austempered conditions

Three groups of hypereutectic cast irons alloyed with Cu, Ni and microalloying additive like Ti and Nb were examined for its hardness and wear resistance in the austempered (360 °C/3 h) and quenched and tempered conditions at varying tempering temperatures. It is observed that the cast irons in the quenched and tempered condition showed good wear resistance and moderate hardness at 400 °C. This was comparable with the wear resistance in austempered condition. The study also showed that in quenched and tempered condition, increasing Cu content in cast irons improved its wear resistance moderately while increasing Ni content has decreased its wear resistance. The presence of strong carbide formers (Nb, Ti) did not give significant improvement in wear resistance in quenched and tempered condition. Even in austempered alloys, higher Cu content increases its wear resistance and higher Ni content decreases their wear resistance. The austempered alloys showed ausferritic microstructure with 20% austenite phase which enhances wear resistance through transformation induced plasticity effect. On the other hand, the quenched and tempered alloys showed good wear resistance at 400 °C due to fine tempered carbides in the matrix.     

Fatigue crack propagation damaging micromechanisms in ductile cast irons

Ductile iron discovery in 1948 gave a new lease on life to the cast iron family. In fact, these cast irons are characterized both by a high castability and by high toughness values, combining cast irons and steel good properties. Ductile cast irons are also characterized by high fatigue crack propagation resistance, although this property is still not widely investigated.In the present work, three different ferritic–pearlitic ductile cast irons, characterized by different ferrite/pearlite volume fractions, and an austempered ductile cast iron were considered. Their fatigue crack propagation resistance was investigated in air by means of fatigue crack propagation tests according to ASTM E647 standard, considering three different stress ratios (R = K_min/K_max = 0.1; 0.5; 0.75). Crack paths were investigated by means of a crack path profile analysis performed with an optical microscope. Crack surfaces were extensively analysed by means of a scanning electron microscope both considering a traditional procedure and performing a quantitative analysis of 3D reconstructed surfaces, mainly focusing graphite nodules debonding.     

Characterization of fracture behavior of a Ti alloyed supermartensitic 12%Cr stainless steel using Charpy instrumented impact tests

In this work, the toughness of a Ti-alloyed supermartensitic stainless steel with 12%Cr was evaluated by instrumented Charpy impact tests at − 46 °C. The material was heat treated by quenching and tempering at 500 °C or 650 °C. The temper embrittlement phenomena was detected in the specimen tempered at 500 °C, while the specimens as quenched and quenched and tempered at 650 °C presented a ductile fracture with high impact energy values. The predominance of cleavage fracture instead of intergranular cracks suggests that the temper embrittlement was caused by fine and disperse precipitation observed in the specimen tempered at 500 °C. The dynamic initiation fracture toughness (J_Id) was calculated from the force versus deflection curves using three different methods suggested in the literature to obtain the initiation energy.     

Crack closure and fatigue crack growth near threshold of a metastable austenitic stainless steel

In this paper R-ratio effects on fatigue crack growth near threshold region of a metastable austenitic stainless steel (MASS) in two different conditions, i.e. annealed and cold rolled, is investigated. The authors present two approaches to correlate FCGR data for R = 0.1, 0.3, 0.5, 0.7 and K_max = 23 MPa√m using a two-parameters approach (ΔK, K_max and α in Kujawski’s model) and crack closure model (using Elber’s K_op and in Donald’s ACRn2 approaches). The K_op and ACRn2 were experimentally measured on a single edge tension specimens. The K_op measurements were performed using a modified method and based on ASTM standards. While the two driving force approaches correlate data well in the Paris region, they fail to correlate them in the threshold region. However, this correlation can be improved in the threshold region when a different α value from the Paris region is used. The authors indicated that two different mechanisms operate; one in the Paris region and another in the near threshold. Hence, they proposed to combine the two-parameter and crack closure approaches where ΔK is replaced by ΔK_eff (estimated by a new method proposed in this paper), which is shown to correlate the FCGR data for different stress ratios for annealed steel. The correlation for cold rolled condition shows improvement with the new approach but is not as good as for the annealed one. The author further suggests to modify K_max in the two-parameter approach.     

Effects of Si addition on microstructure and mechanical properties of Mg–8Gd–4Y–Nd–Zr alloy

Effects of Si addition (1.0 wt.%) on microstructure and mechanical properties of Mg–8Gd–4Y–Nd–Zr alloy have been investigated using scanning electron microscopy (SEM) equipped with energy dispersive spectrum (EDS), X-ray diffraction (XRD), hardness measurements and tensile testing. The results indicated that the addition of Si led to the formation of Mg₂Si and (RE + Si)-rich particles, which enhanced the Young’s modulus of the alloy by 7 GPa while decreased the yield strength and ultimate strength by 10 MPa and 31 MPa, respectively. The tensile properties of the Mg–8Gd–4Y–Nd–Zr–Si alloy are as follows: Young’s modulus E = 51 GPa, yield strength σ_0.2 = 347 MPa, ultimate strength σ_b = 392 MPa and elongation δ = 2.7%. The increase in Young’s modulus was attributed to the formation of particles with high Young’s modulus, while the decrease in strength was ascribed to the decrease in volume fraction of metastable β′ precipitates caused by the consumption of rare earth atoms due to the formation of the rare earth containing particles.     

Fatigue strength of sharp V-notched specimens made of ductile cast iron

In the present, the high cycle fatigue strength of notched ductile cast iron is investigated. Experimental tests under axial loading, has been carried out on sharp V-notched specimens taken from heavy section casting considering nominal load ratios (R = 0). All specimens, taken from a heavy section casting, are characterized by a notch tip radius less than 0.1 mm, a notch depth of 10 mm and a notch opening angle = 90°. In order to evaluate the influence of chunky graphite morphology on fatigue life, fatigue tests were carried out also on a second set of specimens without that microstructural defect.Metallurgical analyses were performed on all the samples and some important microstructural parameters (nodule count and nodularity rating, among others) were measured and compared. It was found that a mean content of 40% of chunky graphite in the microstructure (with respect to total graphite content) does not influence significantly the fatigue strength properties of the analysed cast iron.     

Variable amplitude fatigue of high-strength cast iron alloys for automotive applications

In the automotive sector, the cumulative damage calculation method generally applied is the Palmgren–Miner-Hypothesis with its modification according to Haibach (steeper slope of the SN-line after the knee-point) as a means of also including the damage by stress amplitudes below the knee-point. This approach results in the total damage sum of the spectrum D_spec. However, the resulting question is the value of the allowable damage sum D_al for the evaluation of D_spec ⩽ D_al. The only design code that considers the assessment of cast iron components under spectrum loading is the FKM-Guideline of the Cooperative Research Association for Mechanical Engineering (FKM, Frankfurt/Germany) for designing machine components. Here, the theoretical Palmgren–Miner-damage sum D_th = 1.0 is still suggested as the allowable damage sum D_al despite the fact that this damage sum renders unsafe calculated fatigue lives in about 90% of all published results.The results obtained with component-like notched specimens of modern high-strength cast iron alloys (R_m = 650–800 MPa) such as EN-GJS-500-7, SiboDur 700-10 and MADI (Machinable Austempered Ductile Iron), which were investigated under a standard Gaussian spectrum for chassis applications and also for a fuller injection pump spectrum, suggest the allowable damage sum D_al = 0.3 for fatigue life estimations of components manufactured with these materials can be proposed; i.e. the allowable fatigue life is about one third compared to calculations with the theoretical damage sum D_th = 1.0 that is still used.     

Single crystal structure determination and infrared fluorescence of the system (K3Sr1−xNdx) (Nd1−xSr1+x) Nb10O30

The μ-pulling down technique has permitted to grow single crystal fibers, of the gross chemical formula K₃Sr₂NdNb₁₀O₃₀, having a sufficient optical quality to carry out spectroscopic studies. The crystal structure has been determined and refined to reliability factors: (i) R₁ = 0.0384 (wR₂ = 0.0665) at room temperature; (ii) R₁ = 0.0334 (wR₂ = 0.0638) at 120 K. Difference in the cationic distribution over the 15- and 12-fold sites was noticed. IR fluorescence spectra investigated under different laser excitation wavelength at 300 K and 77 K show strong emissions at 0.9 and 1.06 μm. Low temperature fluorescence behavior is compatible with Nd³⁺ ions located in both Sr²⁺ and K⁺ sites with 15- and 12-fold coordination, respectively.     

22 Cr 5 Ni duplex and 25 Cr 7 Ni superduplex stainless steel: Hydrogen influence on fatigue crack propagation resistance

Duplex stainless steels (DSS) fatigue crack propagation resistance is strongly affected by both microstructure and environment. In this work, environment influence on the fatigue crack propagation in a 22 Cr 5 Ni duplex and in a 25 Cr 7 Ni superduplex stainless steels is investigated considering three different stress ratios (R = K_min/K_max = 0.1, 0.5, 0.75). Tests are performed according to ASTM E 647 standard, both in air and under hydrogen charging conditions (0.1 M H₂SO₄ + 0.01 M KSCN aqueous solution, ?0.9 V/SCE). Crack fracture surfaces are extensively analysed by means of a scanning electron microscope. Furthermore, crack paths are investigated by means of a crack profile analysis performed through a light optical microscope. Nickel coated fracture surface sections obtained for constant ΔK values are considered in order to analyse the loading (R values) and environment influence on fatigue crack paths.     

The effect of thermal cycling in superplastic diffusion bonding of 2205 duplex stainless steel

In view of the requirement of large cold rolling deformation and bonding pressure in the conventional superplastic diffusion bonding of 2205 duplex stainless steel, a novel method of introducing thermal cycling into the process was proposed. During the thermal cycling process, due to the change of temperature, surface chemical activity of 2205 duplex stainless steel was improved, activity of atoms and grain boundaries were improved, and the recrystallized grains were refined. The shear bond strength of joint prepared in the mode of thermal cycling using specimens with the cold roll reduction of 60% was 15 MPa higher than that of conventional bonding using specimens with the cold roll reduction of 85%. Compared to the shear bond strength of 430 MPa under the specific pressure of 10 MPa after conventional bonding, shear bond strength of 623 MPa was obtained under the condition of T_max = 1000 °C, T_min = 900 °C, cycle number of heating and cooling N = 3, and specific pressure P = 5 MPa.     

Consideration of mean-stress effects on fatigue life of welded magnesium joints by the application of the Smith–Watson–Topper and reference radius concepts

Three types of welded joints have been assessed with regard to their fatigue strength based on the mean-stress damage parameter model according to Smith, Watson, and Topper (P_SWT) and on the reference notch radius concept. These analyses were performed with three different stress ratios, R = −1, R = 0 and R = 0.5, under axial loading. For each stress level, the corresponding Neuber-Hyperbolas, Masing-loops and their maximum stress and maximum strain values were determined in order to calculate damage parameter (P_SWT) values. For a given weld geometry, this damage parameter is able to unify the fatigue results for different R-values within at a tight scatter band and therefore to consider the mean-stress effect. The unification of the results for different weld geometries is performed by applying the reference radii r_ref = 0.05 and r_ref = 1.00 mm as suggested by the IIW-Recommendations.     

Evaluation of residual stress relaxation and its effect on fatigue strength of AISI 316L stainless steel ground surfaces: Experimental and numerical approaches

This paper is aimed at evaluating the residual stress relaxation and its effect on the fatigue strength of AISI 316L steel ground surfaces in comparison to electro-polished surfaces. An experimental evaluation was performed using 3-point and 4-point bending fatigue tests at R_σ = 0.1 on two sets of notched specimens finished by electro-polishing and grinding. The residual stress fields were measured at the notch root of specimens, before and after fatigue tests, by means of the X-ray diffraction technique. It was found a degradation of about −35% for the 4-point bending fatigue limit at 2 × 10⁶ cycles of the ground specimens in comparison to the electro-polished ones. This degradation is associated with a slight relaxation of the grinding residual stresses which remain significant tensile stresses at the stabilized state. While under the 3-point bending test, these residual stresses relax completely and provoke a noticeable increase of the fatigue limit estimated at about 50% in comparison to the 4-point bending fatigue test. The numerical evaluation of residual stress relaxation was carried out by FE analyses of the cyclic hardening behaviour of the ground layer. The isotropic and nonlinear kinematic model proposed by Chaboche was used and calibrated for the base material and the ground layer. The results show that residual stresses relax to a stabilized state characterized by elastic-shakedown response. This stabilization is occurred after the first cycle of the 4-point bending test corresponding to the higher stress concentration (K_t-4p = 1.66), while it requires many cycles under the 3-point bending test corresponding to the lower stress concentration (K_t-3p = 1.54). The incorporation of stabilized residual stress values into the Dang Van’s criterion has permitted to predict with an acceptable accuracy the fatigue limits under both bending modes.     

The investigation of crack growth in specimens with rectangular cross-sections under out-of-phase bending and torsional loading

The paper presents the fatigue test results of rectangular cross-section specimens made of 10HNAP (S355J2G1W) steel. The specimen height to width ratio was 1.5. The tests under bending with torsion were performed for the following ratios of bending to torsional moments M_aB/M_aT = 0.47, 0.94, 1.87 and the loading frequency 26.5 Hz. Nominal stresses were chosen for the equivalent stress according to the Huber-Mises hypothesis equal to 360 MPa. The tests were performed in the high cycle fatigue regime for the stress ratio R = −1 and phase shift between bending and torsion loading equal to ϕ = 0 and 90°. Crack initiation and propagation phases were observed on the specimen surface using the optical microscope (magnification 20×) with an integrated digital camera. The test results for the fatigue crack growth rate versus the stress intensity factor range for mode I and mode III have been described with the Paris equation.     

Effects of processing parameters on microstructure and mechanical properties of squeeze-cast Mg–12Zn–4Al–0.5Ca alloy

In this paper, a new magnesium alloy Mg–12Zn–4Al–0.5Ca (ZAX12405) was prepared by squeeze casting. The effects of processing parameters including applied pressure, pouring temperature and dwell time on the microstructure and mechanical properties of squeeze-cast ZAX12405 alloy were investigated. It was found that squeeze-cast ZAX12405 alloy exhibited finer microstructure and much better mechanical properties than gravity casting alloy. Increasing the applied pressure led to significant cast densification and a certain extent of grain refinement in the microstructure, along with obvious promotion in mechanical properties. Lowering the pouring temperature refined the microstructure of ZAX12405 alloy, but deteriorated the cast densification, resulting in that the mechanical properties firstly increased and then decreased. Increasing the dwell time promoted cast densification and mechanical properties just before the solidification process ended. A combination of highest applied pressure (120 MPa), medium pouring temperature (650 °C) and dwell time (30 s) brought the highest mechanical properties, under which the ultimate tensile strength (UTS), yield strength (YS) and elongation to failure (E_f) of the alloy reached 211 MPa, 113 MPa and 5.2% at room temperature. Comparing with the gravity casting ZAX12405 alloy, the UTS and E_f increased 40% and 300%, respectively. For squeeze-cast Mg–12Zn–4Al–0.5Ca alloy, cast densification was considered more important than microstructure refinement for the promotion of mechanical properties.     

Influence of casting defect and SDAS on the multiaxial fatigue behaviour of A356-T6 alloy including mean stress effect

The effect of mean stress on the multiaxial High Cycle Fatigue (HCF) behaviour of cast A356-T6 alloy containing natural and artificial defects with varying Secondary Dendrite Arming Spacing (SDAS) has been investigated experimentally. Tension, torsion and combined tension–torsion fatigue tests have been performed for two loading ratios: R_σ = 0 and R_σ = −1. A Scanning Electron Microscopy (SEM) was used to perform fractographic analysis of the fracture surfaces to characterise the defect causing failure. In order to gauge the effect of mean stress and defects, the results are reported with standard Kitagawa and Haigh diagrams. A surface response method has been employed to characterise the influence of defect size and SDAS on the fatigue limit. Relationships and correlations describing the observed behaviour have been incorporated in the Defect Stress Gradient (DSG) criterion with the goal of determining the influence of defects on the fatigue limit through a stress gradient approach.Results clearly show that: (i) the mean stress has a detrimental effect on the fatigue limit. This effect is a function of the loading, which is most pronounced under tension, less under combined tension–torsion, and least pronounced under torsion conditions; (ii) in the absence of defects, the SDAS controls the fatigue limit of cast A356, this effect is much more important under torsion loading; (iii) the DSG criterion is improved by the mean of a parameter describing the microstructure effect through the SDAS.     

Fatigue strength improvement factors for high strength steel welded joints treated by high frequency mechanical impact

Numerous studies have observed that the fatigue strength of improved welds increases with material yield strength. This paper provides a comprehensive evaluation of published data for high frequency mechanical impact treated welds. In total, 228 experimental results for three weld geometries subject to R = 0.1 axial loading have been reviewed. A design recommendation including one fatigue class increase in strength (about 12.5%) for every 200 MPa increase in static yield strength is proposed and are shown to be conservative with respect to all available data. Special cautions are given for high R-ratio or variable amplitude fatigue and potential alternate failure locations.     

Very high cycle fatigue of nitrided 18Ni maraging steel sheet

Thin sheets of nitrided 18Ni maraging steel are tested under cyclic tension (load ratio R = 0.1) in the very high cycle fatigue (VHCF) regime. The ultrasonic fatigue testing method with a cycling frequency of about 20 kHz has been further developed for these experiments. Sheet specimens with 0.35 mm thickness are mounted on a carrier specimen, they are pre-stressed and are forced to vibrate jointly. Between 10⁷ and 10⁹ cycles, fatigue cracks are initiated exclusively at internal TiN inclusions. The areas of the crack initiating inclusions projected perpendicular to the applied tensile stress are evaluated. The square root of inclusion areas, (area_INC)^1/2 lies between 2.5 μm and 5.3 μm. Considering inclusions as cracks, their stress intensity range is between ΔK_INC = 1.3 MPa m^1/2 and 2.4 MPa m^1/2. The sizes of crack initiating inclusions influence fatigue lifetimes. This is considered in a crack propagation model and by presenting lifetimes versus the stress amplitudes multiplied by (area_INC)^1/12. A mean lifetime of 10⁹ cycles is found at a stress amplitude of 22% of the tensile strength, which is comparable to other high strength steels tested under cyclic tension.