Ti_(32.8)Zr_(30.2)Ni_(5.3)Cu_9Be_(22.7)合金熔体与Ti_(61.5)Zr_(36.4)Cu_(2.1)合金间的润湿行为

用座滴法研究了Ti_(32.8)Zr_(30.2)Ni_(5.3)Cu_9Be_(22.7)合金熔滴与Ti_(61.5)Zr_(36.4)Cu_(2.1)基片在连续升温和不同温度下保温30min的润湿行为,结果表明二者具有良好的润湿性。润湿温度影响着熔滴熔体的结构,进而造成了不同温度区间内Ti_(32.8)Zr_(30.2)Ni_(5.3)Cu_9Be_(22.7)合金在Ti_(61.5)Zr_(36.4)Cu_(2.1)基片上润湿行为的差异。在连续升温过程中,由于熔体结构发生变化,熔滴铺展分为一次铺展和二次铺展两个过程。在750~850℃保温时,润湿动力学曲线分为快速减小和稳态两个阶段,润湿过程大约在7min左右完成。700℃下受到熔滴熔体结构的影响,保温过程中熔滴不继续铺展。     

Strain rate response of a Zr-based composite fabricated by Bridgman solidification

Zr_(58.5)Ti_(14.3)Nb_(5.2)Cu_(6.1)Ni_(4.9)Be_(11.0) bulk metallic glass matrix composites,containingβ-Zr dendrites,were fabricated by Bridgman solidification at the withdrawal velocity of 1.0 mm/s through a temperature gradient of～45 K/mm.Subjected to the increasing compressive strain rates,the monotonic increasing and decreasing were obtained for the maximum strength and the fracture strain,respectively.The results show that high strain rate may induce the insufficient time for the interaction between s...     

高压下LiAlGeO4晶体压致非晶化研究-研究生论坛

本文在高压下利用金刚石压砧同步辐射X射线衍射装置和高压激光拉曼装置研究了高压下LiAlGeO4的压致非晶化过程,压力分别达到29.7GPa和20.3GPa。实验在高压下首次利用同步辐射和拉曼光谱观察到了LiAlGeO4的非晶化现象,在常温条件下,当压力达到11.9GPa时样品开始出现无序化现象,在14.5GPa高压下达到了完全非晶化,拉曼数据也显示了LiAlGeO4在15GPa之前已经发生完全非晶化,当压力释放后样品依旧处于非晶状态,这表明LiAlGeO4样品高压下的非晶化是不可逆的。文中给出了样品的弹性模量和格林艾森常数。     

轧制塑性变形对Zr_（65）Al_（7.5）Cu_（12.5）Ni_（10）Ag_5非晶合金力学性能的影响

采用维氏显微硬度仪、扫描电子显微镜对铸态、轧制态Zr_（65）Al_（7.5）Cu_（12.5）Ni_（10）Ag_5非晶合金的硬度及剪切带形貌进行了研究,并对轧制变形量与合金的力学性能之间的关系进行了分析。结果发现,在室温轧制条件下,该合金最大变形量达到了95%;铸态试样的半圆形剪切带规律、平滑,随着轧制变形量的增加剪切带形貌变得越来越混乱,合金的硬度总体呈下降趋势。     

高温高压下(Mg,Fe)SiO3钙钛矿的相稳定性

在冲击波物理实验测量高温高压下(Mg,Fe)SiO₃钙钛矿的声速结果的基础之上，发现了在70～85 GPa压力范围内发生了声速的“软化”现象.利用沃尔什热力学-冲击压缩线方法和Mie Grüneisen物态方程等熵线方法计算了声速测量实验中的冲击温度，并计算了冲击压缩下70～85 GPa压力范围内的相变边界，然后用电子自旋相变的自由能变化估算了这个压力范围内的相变边界，发现两种方法计算得到的相变边界相同，从而证实这种声速“软化”现象是由(Mg,Fe)SiO₃钙钛矿的晶格畸变引起的，没有发生(Mg,Fe)SiO₃钙钛矿向氧化物(Mg,Fe)O+SiO₂的分解相变.     

Ta元素对Ni_(68.6)Cr_(8.7)Nb_((3-x))P_(16.5)B_(3.2)Ta_x非晶合金性能的影响

利用XRD、DSC、电化学工作站和SEM方法研究了不同含量的微量元素Ta的添加对Ni_(68.6)Cr_(8.7)Nb_((3-x))P_(16.5)B_(3.2)Ta_x(x=0、0.1、0.3、0.5、0.7、1,at%)合金的非晶形成能力、热稳定性和耐腐蚀性能的影响。研究表明,当x=0.5时,直径为1.5mm的Ni_(68.6)Cr_(8.7)Nb_(2.5)P_(16.5)B_(3.2)Ta_(0.5)合金棒为完全非晶结构,而x为其他值时,则有晶态相析出;适量Ta元素的添加提高了该Ni基非晶合金体系的热稳定性能,当x=0.5时合金的热稳定性能最好,之后热稳定性能开始下降;在1mol/L H_2SO_4溶液环境下,随Ta元素含量的增加,Ni基非晶薄带的耐腐蚀性逐渐增强,当x=0.5时非晶薄带的耐腐蚀性能最强。     

Ce-Al-Ni非晶合金制备及非晶形成能力研究

采用熔体旋淬法制备了Ce75Al25-xNix(x=4,8,16)和Ce68Al17Ni15,Ce73Al15Ni12非晶合金薄带,用X射线衍射(XRD)法表征了合金薄带的相结构,用差示扫描量热法(DSC)测量了合金薄带连续加热过程相变规律,研究了Ce-Al-Ni合金的非晶形成能力与合金成分及相应的非晶形成能力参数(ΔTx,Trg,γ,δ,β,ω)之间的关系.研究结果表明:当Ce的含量一定时,随着合金中Ni原子百分数的增加,合金的非晶形成能力降低;研究还发现Ce-Al-Ni体系具有非常特殊的非晶形成规律,计算评估的用来预测具有强的非晶形成能力的合金成分参数(ΔTx,Trg,γ,δ,β,ω)不能用来表征Ce-Al-Ni合金的非晶形成能力;根据非晶形成能力参数计算的预测具有强的非晶形成能力的合金成分,实验研究不能观察到更好的非晶形成能力.     

Fe对Zr55Al10Ni5Cu30非晶形成能力及力学性能的影响

为了进一步提高锆基大块非晶合金的玻璃形成能力及力学性能,采用铜模吹铸法制备了（Zr0.55Al10Ni0.05Cu0.30）100-xFex（X=1,5,10）系列合金,通过X射线衍射（XRD）、差示扫描量热法（DSC）以及压缩实验和SEM进行材料分析。研究表明：微量Fe有助于改善非晶合金在压缩变形时剪切带内的应力分布,提高材料的综合性能,当Fe添加量为1％时,塑性应变εp达到5．9％,强度达到1．89GPa,同时,随着Fe添加量的增加,过冷温度区间ΔTx减小,热稳定性减小,非晶形成能力降低。     

TM-Gd合金系非晶形成能力的热力学研究(Ⅰ)

在Co-Gd二元系合金体系的热力学优化评估的基础之上,应用CALPHAD(CALculation of PHAse Diagram)技术,研究此二元非晶合金的玻璃形成能力。本文分析了700 K、800 K时Co-Gd合金中各元素含量对非晶形成能力的影响,预测了非晶形成的最优成分,计算过冷液相中的结晶相形成驱动力。通过与部分实验和非晶共晶点准则的比较可见,本文所做的热力学分析对此二元合金的非晶制备具有一定的理论指导意义。     

微量Ta对Cu-Zr-Al合金玻璃形成能力及力学性能的影响

含Ta颗粒的非晶复合材料除具有高强度、高硬度等非晶材料的特性外,塑性也显著提高,比单一的非晶态材料更加具有工程应用价值.文中采用铜模吸铸法制备出直径为3mm的(Cu47Zr47A16)100-xTax(x=0,1,2,3,4,5)块体非晶合金.采用X射线衍射对合金的组织结构进行了分析.通过差示扫描量热法研究了微量Ta对Cu-Zr-Al块体非晶合金玻璃形成能力的影响.对合金进行了压缩测试,并通过扫描电子显微镜观察了断口形貌.实验结果表明:微量Ta的加入能提升Cu-Zr-Al合金的玻璃形成能力及其热稳定性,当加入量为3at.%时效果最为明显.Ta含量达到5at.%时,合金的玻璃形成能力显著恶化.溶入微量Ta使Cu-Zr-Al非晶的断裂强度显著上升,(Cu47Zr47A16)97Ta3的抗压强度达到2 149MPa.Ta对Cu-Zr-Al非晶合金的塑性影响不大,(Cu47Zr47A16)100-xTa仍是典型的脆性材料.     

Laser welding of Zr41Ti14Cu12Ni10Be23 bulk metallic glass and zirconium metal

The laser bonding technology between the Zr41 Ti14 Cu12 Ni10 Be23 bulk metallic glass and zirconium metal was investigated under welding parameters of 1.3 kW and 7 m/min. The welded bead, microstructure, and micro-hardness of the welded joint were examined by Keyence, transmission electron microscopy, scanning electron microscopy, and Vickers hardness, respectively. The experimental results showed that the Zr41 Ti14 Cu12 Ni10 Be2 bulk metallic glass and zirconium metal were successfully bonded together. The Zr41 Ti14 Cu12 Ni10 Be2 in the base material zone maintained amorphous structure, and the welding fusion zone kept the hardness as high as as-received BMG. Therefore, the laser welding technology can be used to achieve successful bonding of bulk metallic glasses and crystallization metal.     

Tensile and compression properties of Zr-based bulk amorphous alloy at different temperatures

Since the discovery of the Au-Si metallic amorphous alloy ribbon in 1960 by Duwez and co-workers[1] by rapid quenching, rapid developments have been obtained on the preparation of the amorphous alloy with the rapid quenching technique. However, from 1960 to 1989, the amorphous alloy could be only produced into forms of ribbon, flake, wire and powder due to the limitation of the cooling rate (>105 K/s). In the late 1980s, the Inoue group at Tohoku University in Sendai, Japan, investigated th…     

Si3N4-doped Zr50Al15Ni10Cu25 glassy alloy by mechanical alloying and sintering process

Zr₅₀Al₁₅Ni₁₀Cu₂₅ amorphous powder was synthesized by mechanical alloying. The effect of Si₃N₄ addition on the crystallization behavior of the alloy during sintering process was studied. Thermal stability of the powders was performed by differential scanning calorimetry (DSC). The phase and microstructure of the powders and bulk specimens sintered were determined by X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The results show that, introducing 0.05% (mass fraction) Si₃N₄ can enhance the crystallization activation energy of the Zr₅₀Al₁₅Ni₁₀Cu₂₅ amorphous powders, which indicates that Si₃N₄ addition has hindrance effect on forming crystals from Zr₅₀Al₁₅Ni₁₀Cu₂₅ amorphous powder. However, 0.10% Si₃N₄ results in the decrease of the crystallization activation energy, which makes its crystallization process easy to occur.     

Effects of Ta addition on the microstructure and mechanical properties of Ti40Zr25Ni8Cu9Be18 amorphous alloy

The effects of Ta addition on the microstructure and mechanical properties of Ti₄₀Zr₂₅Ni₈Cu₉Be₁₈ bulk amorphous alloy were investigated by using X-ray diffraction (XRD), transmission electron microscopy (TEM), scan electron microscopy (SEM) and compressive testing. As a result, the addition of Ta (0-8at%) prompted the successive precipitation of quasicrystalline phase, CuTi₂ phase and bcc β-Ti solid solution. Additionally, the addition of less Ta content (3at%-5at%) led to the formation of amorphous matrix/nanoquasicrystal/CuTi₂ complex phase structure; and nanoquasicrystals, as reinforcement precipitates, improved the fracture strength of Ti-Zr-Ni-Cu-Be-Ta alloys, which led to the high compressive fracture strength 1856 MPa of Ta5 alloy. With increasing Ta content (5at%-8at%), although the ductile dendritic β-Ti solid solution was precipitated, the strength and plasticity decreased to a great extent resulting from the growth of quasicrystalline phase and CuTi₂ phase.     

Cooling Rate Dependence of Structural Order and Energy Landscape in Zr55Cu35Al10 Glass

论冷却速率对Zr55Cu35Al10合金结构和能量的影响

赵静锋,谢祥续,陈锋,狄凯龙,周雪峰*

（常熟理工学院 材料工程学院,江苏 常熟 215500）

中文说明：

经典分子动力学模拟被广泛应用于非晶合金的快速冷却过程研究。然而,模拟冷却速率比实验冷却速率高几个数量级。本文以Zr55Cu35Al10合金为例,发现在略低于玻璃转变温度的温度下加入等温退火,延长等温退火时间可有效降低冷却速率。用这种方法获得的非晶样品具有显著的能量稳定性和更有序的中短程序结构。

关键词：经典分子动力学模拟,冷却速率,等温退火,能量稳定性,短程有序,中程有序

     

Bulk glass formation in ternary Cu-Zr-Ti system

The formation of bulk metallic glasses (BMGs) in ternary Cu-Zr-Ti system was investigated by a copper mold casting method. The nature of the amorphous phase was verified by X-ray diffraction (XRD) and differential scanning calorimetry (DSC). It was demonstrated that the BMGs could be formed in a broad composition range in this system. Cu₅₀Zr_42.5Ti_7.5, Cu₆₀Zr_27.5Ti_12.5, CU₆₀Zr₃₀Ti₁₀, and Cu₆₀Zr_32.5Ti_7.5 alloys exhibit strong glass-forming ability (GFA), and fully glassy rods of 5 mm in diameter can be obtained. In the center region of the ternary diagram, however, the GFA of the alloys was degraded due to the presence of Laves phase. The degradation of the GFA results from easy nucleation of the Laves phase in the undercooled liquid.     

Determination of Grüneisen EOS of MSN Alloy Steel Under High Pressure

30CrMnSiNi2A(MSN)alloysteelperformsquiteimportantfunctionsnotonlyinavigationandarmor piercingprojectilebutinmachineryandmetallurgybecauseofitshighhardness ,highintensity ,highdensityandfavorabledynamicmechanical perfor mance .Highperformance 30CrMnSiNi2Aalloysteelhasbeenusedinarmor piercingprojectileinforeigncountriesrecently .Itmakesthearmor piercingpro jectilecapabilitybeimproveddistinctly[1] .ResearchontheperformanceofMSNalloysteelwasstartedsolatethatsatisfactoryconclusionshaven’tbee…     

Stability of titanium-aluminium nitride (Ti<Subscript>2</Subscript>AlN) at high pressure and high temperatures

The stability of Ti2AlN at high pressure of 5 GPa and different temperatures of 700-1 600 ℃ was investigated using X-ray diffraction (XRD),scanning electron microscopy (SEM) equipped with an energy dispersive spectrometer (EDS).Ti2AlN was found to be stable at temperatures as high as 1 400 ℃under 5 GPa for 20 min,and was proved that it held better structure stability than Ti2AlC under 5 GPa through comparative experiments of Ti2AlN and Ti2AlC (representative compounds of M2AX phases (211 phase)).The reaction process at high pressure had some difference from that at ambient pressure/vacuum,and Ti2AlN directly decomposed to TiN and TiAl at 5 GPa and 1 500 ℃ for 20 min.Moreover,the mechanism of phase segregation was discussed.In addition,the behavior of Ti2AlN contacting with Zr at high pressure and high temperature (HPHT) was also studied.     

Equation of state of Zr41 Ti14 Cu12.5 Ni10 Be22.5 bulk metallic glass

The knowledge of the equation of state （EOS） and the compressibility of a solid are of central importance for the understanding of the behavior and the application of a condensed matter. The compression behavior of Zr41Ti14Cu12.5Ni10Be22. 5 bulk metallic glass （BMG） is investigated at room temperature up to 24 GPa using in-situ high pressure energy dispersive X-ray diffraction with synchrotron radiation. A model of basic cell volume has been established and the equation of state of BMG is determined by the calculation of radial distribution function. The experimental results indicate that the BMG contains a large amount of vacancy-like free volume. Low pressure （ below 7 GPa） induces the collapse of the free volume to some extent and structure relaxation in the BMG.     

Modeling and simulation of JWL equation of state for reactive Al/PTFE mixture

An analytical method is presented to fit parameters of Jones-Wilkins-Lee (JWL) equation of state (EOS) for the chemical process of aluminum-polytetrafluoroethylene ( Al/PTFE ) mixture.Subroutine codes ...