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橄榄石型磷酸铁锂是目前应用十分广泛的锂离子电池正极材料之一,具有成本低、安全性高、环境友好、循环寿命长和工作电压稳定的特点。近年来,随着CTP技术、刀片电池技术等取得的突破性进展,磷酸铁锂的商业化程度得到了大幅提高。但磷酸铁锂存在电子导电性较差和离子扩散系数低的缺陷,严重限制了锂离子电池的电化学容量,因此开展磷酸铁锂制备工艺和性能强化研究对磷酸铁锂的性能提升具有重要意义。对比了磷酸铁锂电池与其他正极材料锂离子电池的性能差异和发展现状,系统总结了磷酸铁锂正极材料制备与强化的改性方法及相关研究进展与挑战,并提出了未来的发展方向与研究思路。 相似文献
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LiFePO_4正极材料制备过程研究进展 总被引:1,自引:0,他引:1
基于磷酸铁锂正极材料的动力锂离子电池是近年来最受关注的电动汽车动力电源之一。由于原料路线差异,磷酸铁锂正极材料制备工艺有多种。本文回顾了上海交通大学在磷酸铁锂正极材料制备过程设计与研究中所取得的进展。在国家重点基础研究发展计划(国家973计划)支持下,重点研究了磷酸铁锂正极材料制备过程及其充放电倍率特性,还提出了如何改善磷酸铁锂正极材料在不同环境温度下性能的解决途径。最后,介绍了LiFePO4/C正极材料制备过程中涉及的还原过程、碳源选择和制备过程装备等过程工程特性问题。 相似文献
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《Carbon》2015
The effect of a bilayer area on the electronic response to environmental gating of a monolayer graphene Hall bar device is investigated using room temperature magnetotransport and scanning Kelvin probe microscopy measurements in a controlled environment. The device is tuned through the charge neutrality point with n–p–n-junctions formed. Scanning Kelvin probe measurements show that the work function of the monolayer graphene decreases more than that of the bilayer area however magnetotransport measurements show a larger change in carrier concentration for bilayer graphene with environmental gating. Interface scattering at the boundary between the monolayer and bilayer regions also affects device response with field-dependent suppression of the conductivity observed near the charge neutrality point. Simultaneous electronic and environmental scanning Kelvin probe measurements are used to build nano-scale maps of the work function of the device surface revealing the areas of greatest work function change with environmental gating. 相似文献
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L.I. Bhagawat V.S. Patil B.B. Kale S.H. Sonawane B.A. Bhanvase D.V. Pinjari M. Ashokkumar 《Polymer Composites》2016,37(6):1874-1880
Lithium iron phosphate (LiFePO4) nanoparticles and lithium iron phosphate/halloysite (inorganic nanotubes) (LiFePO4/INT) nanocomposites were prepared by ultrasound‐assisted synthesis in an aqueous solution of lithium hydroxide containing ammonium dihydrogen phosphate and ferrous chloride and used as cathode materials in lithium ion batteries. The performance of the cathode material was measured using cyclic voltammetry. The oxidation potential for LiFePO4 polyaniline/nanotubes/anode cell was found to be in the range of −1.12 to 1.063 V while the reduction potential for lithium iron phosphate cell was in the range of −1.03 to 1.15 V. POLYM. COMPOS., 37:1874–1880, 2016. © 2015 Society of Plastics Engineers 相似文献
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《Carbon》2013
We directly measured local surface potentials of graphene oxide and poly (sodium 4-styrenesulfonate) intercalated graphene oxide (PSSGO) films, as a function of humidity, using Kelvin probe force microscopy. Our results showed a decrease in the work function of the graphene oxide (GO) film as the humidity increased. This behavior was explained using the first-principle calculation in which water molecules stacked onto the GO film, resulting in a lower local work function and ripples of the surface potential. The ripples directly measured by Kelvin Probe Force microscopy were consistent with the calculation. While the PSSGO film did not show the ripples as the humidity increased. Our results directly showed that absorbed water molecules on the films change the local surface potential and the work function such that its performance in many applications will be affected. 相似文献
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殷宪国 《硫磷设计与粉体工程》2011,(5):5-8,10
介绍了新型锂离子电池正极材料磷酸铁锂制备与改性技术,特别介绍了我国磷酸铁锂纳米化、离子掺杂、碳包覆等改性技术和水热合成、溶胶—凝胶法等磷酸铁锂制备技术,阐明了改性技术有利于进一步改进电池电化学性能,以适应混合动力汽车与电动汽车动力电池和风能、太阳能储能设备等对锂离子电池要求。基于磷酸铁锂正极材料发展前景,提出了我国传统磷化工行业调整产品结构,对接新能源材料的发展思路。 相似文献
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在生命周期评价的基础上,本文通过对锂电正极材料五个阶段对环境的影响进行评估,提出了锂电正极材料LCA计算方法,并用该方法分析比较了磷酸铁锂和锰酸锂两种正极材料对环境的影响。结果表明:锰酸锂相对于磷酸铁锂具有更大的环境效益。该结果为市场以及锂电正极材料生产厂商选择动力电池用正极材料提供一定的参考。 相似文献
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《Diamond and Related Materials》2006,15(9):1378-1382
To explore the work function of a typical amorphous-CN film containing a nitrogen concentration of 23.5 at.%, surface potential images were acquired using Kelvin probe force microscopy. Based on the Fermi level of the n-type Si and the contact potential difference between the amorphous-CN film and the n-Si substrate, the work function of the amorphous-CN film was estimated to be 5.2 ± 0.2 eV below its vacuum level. Using the surface potential depth profile for an etched amorphous-CN film, energy diagrams of the amorphous-CN/SiO2/n-Si interface were constructed based on the positional relationship of the Fermi level. These band diagrams showed that band bending occurred at the amorphous-CN/SiO2/n-Si interface despite the Fermi level pinning effect of surface trapping due to the SiO2 insulator layer. 相似文献
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Negative electron affinity on polycrystalline diamond surface induced by lithium fluoride deposition
《Diamond and Related Materials》1999,8(10):1885-1890
Lithium fluoride (LiF) was deposited on hydrogenated and oxygenated polycrystalline diamond surfaces. Lowering of the work function induced by the dipole effect of LiF was clearly observed using UV photoemission spectroscopy and Kelvin probe. The decrease of the work function was sufficiently large so that negative electron affinity was induced. This shows that the LiF overlayer on diamond acts as an effective dipole layer to lower the surface work function of the diamond film. 相似文献
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Lithium Ion Diffusion Mechanism in Lithium Lanthanum Titanate Solid‐State Electrolytes from Atomistic Simulations 下载免费PDF全文
Perovskite‐structured lithium lanthanum titanate (LLT, La2/3–xLi3xTiO3, 0 < x < 0.16) is a promising solid electrolyte with high lithium ion conductivity and a good model system to understand lithium ion diffusion behaviors in solids. Molecular dynamics (MD) and related atomistic computer simulations were used to study the diffusion behavior and diffusion mechanism as a function of composition in LLT solid‐state electrolytes. The effect of defect concentration on the structure and lithium ion diffusion behaviors in LLT was systematically studied using MD simulations and molecular static calculations with the goal to obtain fundamental understanding of the diffusion mechanism of lithium ions in these materials. The simulation results show that there exists an optimal vacancy concentration at around x = 0.067 at which lithium ions have the highest diffusion coefficient and the lowest diffusion energy barrier. The lowest energy barrier from dynamics simulations was found to be around 0.22 eV, which compared favorably with 0.19 eV from static nudged elastic band calculations. It was also found that lithium ions diffuse through bottleneck structures made of oxygen ions, which expand in dimension by 8%–10% when lithium ions pass through. By designing perovskite structures with larger bottleneck sizes can be a means of further improving lithium ion conductivities in these materials. 相似文献
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A kinetic study was carried out of the ionic current in the anodic barrier oxide layer on iron at the steady state in the passive potential region in acidic phosphate solutions. It is found that the ionic current follows the classical high field ion conduction equation in which the current is expressed as an exponential function of the electric field in the barrier layer. From the kinetic constants appearing in this equation and their temperature dependence, the diffusion coefficient and the activation energy for diffusion of moving ions in the layer were estimated and compared with those of high temperature diffusion in iron oxides. It is suggested that the ionic current is carried by oxygen ions than by iron ions in the barrier oxide film. 相似文献