满足不同需求的水热电联产系统的模型和设计简

In order to improve the energy efficiency, reduce the CO2 emission and decrease the cost, a cogenera- tion system for desalination water, heat and power production was studied in this paper. The superstructure of the cogeneration system consisted of a coal-based thermal power plant （TPP）, a multi-stage flash desalination （MSF） module and reverse osmosis desalination （RO） module. For different demands of water, heat and power production, the corresponding optimal production structure was different. After reasonable simplification, the process model ot each unit was built. The economical model, including the unit investment, and operation and maintenance cost, was presented. By solving this non-linear programming （NLP） model, whose objective is to minimize the annual cost, an optimal cogeneration system can be obtained. Compared to separate production systems, the optimal system can reduce 16.1%-21.7% of the total annual cost. showing this design method was effective.     

Renewable energy desalination plants for the Greek islands—technical and economic considerations

For the majority of the Greek islands, water resources are quite restricted, limiting the economic development of the local societies. To face increased potable water requirements, more than 2,500,000 m of clean water is transferred annually to these islands at a cost approaching the value of 7 /m³ On the other hand, the final cost of the locally produced water from renewable energy sources (RES) based desalination plants is expected to be quite lower than this value. The main purpose of the present study is to examine the economic viability of several representative desalination plant configurations based on the available renewable energy sources using an integrated cost-benefit analysis. In the proposed analysis all the cost parameters of the problem are taken into consideration, including the capital cost of the desalination plant, the annual maintenance and operation cost, the energy consumption cost, the local economy annual capital cost index and the corresponding inflation rate. The calculation results obtained definitely support the utilization of RES-based desalination plants as the most promising and sustainable method to satisfy the fresh, potable water demands of the small- to medium-sized Greek islands at a minimal cost, without disregarding the considerable environmental and macro-economic benefits.     

考虑不同水质输入的水电联产优化设计

结合已有的反渗透/多级闪蒸混产系统和发电-多级闪蒸联产系统,设计了一个新的包括热力发电系统、反渗透海水淡化系统和多级闪蒸海水淡化系统的水电联产超结构,对以不同盐度苦咸水、海水为原水的水电联产系统进行了优化设计,通过求解系统以年费用最小为目标函数的非线性数学模型,得到不同盐度下联产系统优化的生产结构. 结果表明,在低盐度(≤25000 mg/L)下采用冷凝式发电和一级反渗透产水,高盐度下采用抽汽冷凝式发电和热膜混合产水,可降低联产系统的年费用,获得较低成本的淡化水. 在本工作所定的生产规模下,优化联产方案的年费用可降低23%~36%.     

船用海水淡化装置的产水水质特性及经济性分析

船用海水淡化装置是远洋船泊的必备设备之一,对产水水质特性及经济性进行研究具有重要的意义。本文设计搭建了一套板式蒸馏造水机性能测试平台,对系统产水pH和电导率随真空度变化规律以及进料水盐度和真空度对产水溶解性固体总量（TDS）的影响进行了研究,同时建立淡水成本数学模型探讨真空度和进料水流量引起的淡水产量变化对造水成本的影响,并进一步分析了油价、水价和渔船航行距离对淡水成本的敏感性问题。结果表明：真空度一定的情况下,进料水盐度升高,系统产水的TDS增大;真空度变化对系统产水pH影响不大,而对系统产水电导率、TDS和淡化水成本影响较大,且随着真空度的升高呈减小趋势。进料水流量为150L/h时,系统产水率最优造水成本最低,造水成本差价对油价的敏感性最高并且造水成本始终低于渔船运输淡水成本。     

热膜耦合海水淡化系统的优化设计

采用混合节点和分配节点的概念,建立了多级闪蒸(MSF)和反渗透(RO)海水淡化集成系统的超结构模型,以年度总费用最小为目标,引入产水比的概念,并将该参数作为集成系统的一个优化变量,采用改进的遗传算法进行求解,获得了集成系统的最优结构及相应的操作条件。实例结果表明:集成海水淡化系统的淡水成本比独立运行的RO和MSF低,产水比为0.45时集成系统的费用最小,流程结构为MSF-RO。     

Hydrophilic hollow fiber membranes for water desalination by the pervaporation method

Hydrophilic ion-exchange membranes based on sulfonated polyethylene hollow fibers were manufactured, and their suitability for a water pervaporation process was studied for possible application in water desalination systems. The effects of the following parameters on the average water flux were determined: membrane properties (diameter (0.4–1.8 mm) and wall thickness (0.05–0.18 mm)); charge density (0.6–1.2 meq g⁻¹); and operating conditions (brine inlet temperature (30–68°C), air sweep velocity (0–6 m s⁻¹), and salt concentration in the feed brine (0–3 M)). A water flux of 0.8–3.3 kg m⁻² h⁻¹ was obtained using this type of hollow fiber with an inlet brine temperature of 25–65°C. It was found that, for our application, the optimal specifications for the ion-exchange hollow fibers were an outside diameter of 1.2 mm, a wall thickness of 0.1 mm, and an ion-charge density of about 1.0 meq g⁻¹. This information is required as basic data for the design of a prototype water desalination system based on a pervaporation system that uses this type of ion-exchange hollow fiber membrane.     

考虑水需求的水电联产海水淡化系统的优化设计

水电联产不仅能缓解淡水资源不足的问题,而且可有效降低能耗和淡化成本。建立了水电联产系统数学模型,将优化设计描述为一个混合整数非线性规划(MINLP)问题,并采用混合编码的遗传算法进行求解,结果表明,以水定电模式下水电联产系统最优操作模式为发电、多级闪蒸(MSF)和反渗透(RO)三者的集成,且MSF和RO的产水比存在最优值,发电采用背压式蒸汽轮机。随着淡水需求量的增加,联产系统的淡水成本逐渐降低,MSF与RO的产水比呈现出逐渐降低的趋势。     

Integrating hybrid systems with existing thermal desalinationplants

In Gulf countries, most power plants are co-generation power desalting plants (CPDP) that generate electric energy and also produce fresh water through the desalination of seawater. This paper provides detailed technical and economical analyses to evaluate a new generation of dual purpose technology that includes the integration of reverse osmosis (RO) processes with existing thermal desalination processes and power generation (triple hybrid system) at Layyah plant, Sharjah, UAE. Hybridization of sweater reverse osmosis (SWRO) and the multi-stage flash (MSF) technology was considered to improve the performance of latter and reduce the cost of the produced water. Moreover, “idle” power in winter (seasonal surplus of unused power) was mainly utilized by RO to further reduce the cost of the hybrid system for six months of the year. Spinning reserve was also used to further reduce the cost of the proposed hybrid system. Integration ofthe three processes of MSF, MED, and RO desalination technologies could be made at different levels through which the resulting of water cost will depend on the selected configuration and the cost of materials of construction, equipment, membrane, energy, etc. Thus, the capital and annual operating costs were calculated for all potential alternatives for various plant capacities. It was found that for all plant capacities, integrated hybrid systems resulted in most cost effective solution. For example, at a capacity of 50 MIGD, the present worth of the cost was calculated to be 588.7, 443.2, and 380 million US$ for MSF, MED, and hybrid RO systems, respectively.     

Waste water recycling by ion exchange: II. Partial desalination

Recycling of waste water by ion exchange was studied on a bench scale. Secondary municipal effluent, which had undergone lime flocculation, served as a feed for the ion-exchange system. Partial desalination was achieved by allowing part of the feed to bypass the strong acid cation exchanger. The salt concentration was decreased from 15 meq/l (750 ppm as CaCO₃) to 7–10 meq/l (350–500 ppm as CaCO₃) and the organic matter, from 70–100 mg/l COD (chemical oxygen demand) to about 25 mg/l. The leakage of organic matter in the partial desalination mode was somewhat higher than that found in complete desalination. The resins were found to be highly resistant to an attack of organic matter over a period of one year. Three possible resin arrangements were investigated, and a cost analysis for one of them is presented. Since inexpensive chemicals, such as H₂SO₄, and Ca(OH)₂, can be used for regeneration the system provides an economical method for recycling waste water for industry and agriculture.     

Fabrication of efficient pervaporation desalination membrane by reinforcement of poly(vinyl alcohol)–silica film on porous polysulfone hollow fiber

Pervaporation membrane technology is commercially successful in the dehydration of organic solvents, and the technology has potential for seawater desalination with high recovery because of its capability to treat highly saline water. But to make the technology advantageous over the other available membrane desalination technologies in terms of productivity flux without additional energy cost, the selective barrier layer is required to be extremely thin, defect‐free, hydrophilic, and selective to water. In this work, we prepared an efficient membrane by reinforcing a highly water‐permeable but continuous barrier layer of poly(vinyl alcohol)–silica (PVA‐SiO₂) hybrid material on porous polysulfone hollow fibers. The PVA‐SiO₂ in acidified and hydrated ethanol was aged at room temperature for a period to allow solvent evaporation to obtain the solution concentration desired for the reinforcement. The reinforced hollow fiber membrane with optimal PVA‐SiO₂ barrier layer thickness exhibited a performance with a flux of 20.6 L m^?2 h^?1 and 99.9% salt rejection from a saline feed of 2000 ppm NaCl at 333 K. The effects of PVA‐SiO₂, temperature, and feed salinity on the pervaporation performance of the membrane were also studied. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45718.     

并联低温多效海水淡化系统优化与分析

建立了并联流程下的低温多效蒸发海水淡化系统优化数学模型。该模型以整个系统的单位产量淡水成本最小为优化目标,以加热蒸汽温度及各效二次蒸汽温度为决策变量,并应用MATLAB及其优化工具箱对其进行了求解,同时与非优化设计情况进行了比较。结果表明:当淡水产量不变,随着效数的增加,淡水成本先减小后增大,最优效数为7效,优化淡水成本为5.51元/t;与非优化设计相比,在达到6效之前,优化设计的加热蒸汽量减小,蒸发器传热面积增大,优化设计的淡水成本小于非优化设计的淡水成本。在6效之后,二者相差不大。     

Experimental investigation of a two-stage solar humidification–dehumidification desalination process

This paper experimentally evaluates a two-stage technique to improve the humidification–dehumidification process in fresh water production from brackish water. According to modeling results of multi-stage process and on the basis of construction cost estimation, using a two-stage process is the most suitable choice that can improve important parameters such as specific energy consumption, productivity and daily production per solar collector area and thus, investment cost. A pilot plant was designed and constructed in an arid area with 80 m² solar collector area to evaluate the two-stage process. This unit was tested on cold and hot days. The effect of main parameters on fresh water production of the unit is studied. Experimental results show that two-stage HD desalination unit can increase heat recovery in condensers and hence, reduce thermal energy consumption and investment cost of the unit. Moreover, productivity can be increased by 20% compared with the single-stage unit.     

Seawater integrated desalination plant without brine discharge and powered by renewable energy systems

Environmental effects are one of the main concerns of massive desalination facilities. To reach the objective of no brine discharge the salt from seawater must be completely separated and obtained as a secondary and valuable product. If no CO₂ emission increase is desired, the power source must be a combination of renewable energy systems (RES). This paper presents an analysis of an integrated desalination scheme consisting of two sequential systems: a multi-effect distillation (MED) plant and a mechanical vapour compression (MVC) system based on evaporator equipment. The energy is obtained by several wind turbines (WT) and a thermal solar collector (TSC) field. Separation of salt and water is achieved in a coupled multi-effect distillation-mechanical vapour compression (MED+MVC) two step process. The MED stage is driven by thermal solar collectors, whereas the energy consuming mechanical compression of the vapour (MVC) is fuelled by wind-powered turbines. Interestingly, the final products of this process are dry salt and fresh water. Such a system has been designed and dimensioned for a throughput of 100 m³/h of desalted water A preliminary study of the investment, amortization and exploitation costs of a combined MED+MVC+WT+TSC installation with these dimensions has been done. The price of desalted water, after considering the profits due to the sale of salt and electricity has been estimated at 0.59 ?/m³. If the initial investment has a 35% subsidy, a final price of 0.41 ?/m³ could be ensured, which is near the price associated to conventional energy sources. An outline of the solar collector system and the technical requirements of the wind turbines in needed to meet the energy demand of the MED+MVC system are also included.     

Applicability of flashing desalination technique for small scale needs using a novel integrated system coupled with nanofluid-based solar collector

The present study introduces an attempt for the application of flash desalination technique for small scale needs. An integrated system uses a flashing desalination technique coupled with nano-fluid-based solar collector as a heat source has been made to investigate both the effect of different operating modes and that of the variation of functioning parameters and weather conditions on the fresh water production. The flashing unit is performed by similar construction design technique of commercial multi-stage flashing (MSF) plant. The thermal properties of working fluid in the solar collector have been improved by using different concentrated nano-particles. Cu nano-particle is used in the modeling to determine the proper nano-fluid volume fraction that gives higher fresh water productivity. An economic analysis was conducted, since it affects the final cost of produced water, to determine the cost of fresh water production. Although a system may be technically very efficient, it may not be economical. The effect of different feed water and inlet cooling water temperatures on the system performance was studied. The mathematical model is developed to calculate the productivity of the system under different operating conditions. The proposed system gives a reasonable production of fresh water up to 7.7 l/m²/day under the operation conditions. Based on the cost of energy in Egypt, the estimated cost of the generated potable water was 11.68 US$/m³. The efficiency of the system is measured by the gained output ratio (GOR) with day time. The gained output ratio (GOR) of the system reaches 1.058. The current study showed that the solar water heater collecting area is considered a significant factor for reducing the water production cost. Also, the produced water costs decrease with increasing the collecting area of the solar water heater. The volume fractions of nano-particle in solar collector working fluid have a significant impact on increasing the fresh water production and decreasing cost.     

Green analogs of polybutadienes from carbon dioxide and epoxy-based feedstocks

Polybutadiene has widespread use as a commodity as well as a specialty polymer, but currently, it is prepared from non-renewable feedstocks. Herein, we report the synthesis of rubbery unsaturated polycarbonates (RUPCs) as green alternatives for polybutadiene. We prepared two RUPCs (respectively, denoted as RUPC1 and RUPC2) via the copolymerization of carbon dioxide (CO₂) and a mixture of saturated and unsaturated long-chain epoxides using a Co(III) catalyst. The RUPCs were reacted with a styrene monomer via free-radical polymerization to prepare RUPC-graft-Polystyrene. All of the prepared polymers were characterized by ¹H nuclear magnetic resonance spectroscopy and gel permeation chromatography. For RUPC, the number average molecular weight (M_n) increased by three-fold after the grafting reaction. Differential scanning calorimetry analysis confirmed that the glass transition temperature (T_g) of the RUPCs were low (~ −40°C) and approached those of polybutadienes. After polystyrene chains had been grafted onto the RUPC backbone, the T_g increased to 81°C. These green RUPCs have the potential to replace non-renewable polybutadiene in some applications such as high impact materials.     

Exergetic,economic and environmental analyses and multi-objective optimization of an SOFC-gas turbine hybrid cycle coupled with an MSF desalination system

The present study presents thermodynamic, economic and environmental (emissions cost) modeling of a solid oxide fuel cell–gas turbine (SOFC–GT) hybrid system integrated with a multi stage flash (MSF) desalination unit. A heuristic optimization method, namely, multi-objective genetic algorithm (MOGA) is employed afterwards to obtain the optimal design parameters of the plant. The exergetic efficiency and the total cost rate of the system are considered as the objective functions of the optimization procedure; where, the total cost rate of the system (including the cost rate of environmental impact) is minimized while the exergetic efficiency is maximized. Applying the optimization method, a set of optimal solutions is achieved and the final selected optimal design leads to an exergetic efficiency of 46.7%, and a total cost of 3.76 million USD/year. The payback time of the selected design is also determined to be about 9 years. Although the determined value for the payback period seems to be relatively high for the proposed plant (due to the high capital cost of the SOFC system), this integrated technology is expected to be promising in the near future as the capital costs of SOFCs are decreasing and their operational lifetimes are increasing.     

Distillation vs. membrane filtration: overview of process evolutions in seawater desalination

The worldwide need for fresh water requires more and more plants for the treatment of non-conventional water sources. During the last decades, seawater has become an important source of fresh water in many arid regions. The traditional desalination processes [reverse osmosis (RO), multi stage flash (MSF), multi effect distillation (MED), electrodialysis (ED)] have evoluated to reliable and established processes; current research focuses on process improvements in view of a lower cost and a more environmentally friendly operation. This paper provides an overview of recent process improvements in seawater desalination using RO, MSF, MED and ED. Important topics that are discussed include the use of alternative energy sources (wind energy, solar energy, nuclear energy) for RO or distillation processes, and the impact of the different desalination process on the environment; the implementation of hybrid processes in seawater desalination; pretreatment of desalination plants by pressure driven membrane processes (microfiltration, ultrafiltration and nanofiltration) compared to chemical pretreatment; new materials to prevent corrosion in distillation processes; and the prevention of fouling in reverse osmosis units. These improvements contribute to the cost effectiveness of the desalination process, and ensure a sustainable production of drinking water on long terms in regions with limited reserves of fresh water.     

A small solar desalination plant for the production of drinking water in remote arid areas of southern Algeria

The common methods of desalination salt water for production of fresh water by distillation, reverse osmosis and electrodialysis are intensive energy techniques. However, in remote arid areas, the desalination needs not exceed a few cubic meters per day. This decentralised demand favours local water production by developing other desalination processes, especially those using renewable or recovered energy (solar, geothermal, etc.). Solar desalination process is one of these methods used to resolve the scarcity of fresh water. Several reviews have been published by different authors. Small production systems as solar stills can be used if fresh water demand is low and the land is available at low cost. To supply the population of remote arid lands of South Algeria with drinkable water, solar distillation of brackish waters is recommended. It satisfies some of theses demands. Solar stills are used to produce fresh water from brackish water by directly utilising sunshine. These stills represent the best technical solution to supply remote villages or settlements in South Algeria with fresh water without depending on high-tech and skills. The production capacity indicates a possible daily production of far more than 15 l/m²d. Therefore, the still has a place in the upper range of known comparable products with regards to production output. This depends on the material used and the price of the solar stills and their accessories. The best working temperature solves most problems. Small, modular high-performance stills with features like the possibility of decentralised use, less maintenance and robust construction can help to reduce fresh water scarcity. The recent development of stills based on new concepts and heat recovery has been successful. The technical optimization is still in process today, it aims to improvement of the efficiency of these distillers. In our research work, a plant for brackish water distillation by directly sunshine and heat recovery was constructed and investigated experimentally and theoretically in South Algeria. This study aims the improvement of the performance of this solar distillation plant, conducted under the actual insulation, for brackish underground geothermal water desalination.     

海水淡化与水源热泵联合系统性能与成本研究

提出了低温多效海水淡化装置与水源热泵联合系统技术,建立了联合系统数学模型,并利用MATLAB编制程序进行了求解,分析了末效二次蒸汽温度对联合系统热力性能与成本的影响,并且与低温多效海水淡化系统进行了成本比较。计算结果表明:在文章的计算范围内,随着末效二次蒸汽温度的升高,加热蒸汽量减少,蒸发器总传热面积增大,驱动蒸汽量减少,供热水量减少,综合效果是淡水成本增加。其他参数相同的情况下,与低温多效海水淡化系统相比,联合系统的淡水成本节省11.68%。     

Performance prediction of hydraulic energy recovery (HER) device with novel mechanics for small-scale SWRO desalination system

The biggest proportion of the cost of desalted water is the energy consumption, especially for small-scale SWRO desalination system. In order to decrease the cost of desalted water, the energy recovery device is preferred to be considered in small-scale SWRO desalination system. However, the investigation of energy recovery device for small-scale SWRO system is scarce. Until now the design of energy recovery device has not been based on the results of the mathematical simulation but almost on experimental and empirical knowledge, and there are few detailed reports about the optimal design of energy recovery device for small-scale SWRO desalination system in previous articles. In the current paper, a hydraulic energy recovery (HER) device with novel mechanics is introduced, the detailed simulation results of the HER device and specific energy consumption of small-scale SWRO system equipped with the HER device are presented. The simulated results are very useful for optimal design of the HER device and its coupling SWRO desalination system.