共查询到17条相似文献,搜索用时 125 毫秒
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絮凝法处理中药制药废水的试验研究 总被引:24,自引:2,他引:24
本文系统地研究了中药制药废水絮凝处理方法及其机理,所选絮凝剂有聚合氯化铝(PAC)、聚合硫酸铁(PFS)、以及自制聚合硅酸硫酸铁(PFSS)等,研究内容包括:最佳投药量、pH值影响、温度影响以及与有机阳离子高分子絮凝剂配合使用效果等。研究结果表明:PFS较PAC有更好的絮凝效果;PFSS更适合该类废水的治理,所用絮凝剂都存在一最佳投药量:PAC、PFS为80-100mg/L,液体PFSS为1.0mL/L。有机阳离子高分子絮凝剂对PFS、PAC可增强絮凝处理效果,而对PFSS则效果不明显;水温在20-40℃时对絮凝效果影响不大;pH值是影响絮凝效果的重要因素,如用纯碱或石灰调至碱性范围,可以提高处理效果。 相似文献
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季铵型阳离子淀粉絮凝剂的微波干法合成、结构表征及应用研究 总被引:7,自引:0,他引:7
以3-氯-2-羟丙基三甲基氯化铵为阳离子醚化剂,天然淀粉为原料,微波干法合成具有絮凝、杀菌等功能季铵型阳离子淀粉絮凝剂。研究了各种因素对合成的影响,确定了最佳反应条件。结果表明:在阳离子醚化剂与淀粉摩尔比0.35,NaOn与阳离子醚化剂摩尔比1.2,微波功率184W,辐射时间5min时,产物相对粘度为3.18(0.5%)左右,阳离子取代度为0.31。所得产品与无机絮凝剂PAC复配后具有较好的絮凝及杀菌效果。 相似文献
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研究了废弃钻屑进行絮凝处理的方法及其作用机理,利用絮凝剂处理废弃钻井液,分离出废液中多余固相,所选絮凝剂为聚合氯化铝(PAC)、聚合硫酸铁(PFS)、聚乙烯亚胺(PEI)等。研究了最佳质量浓度、pH值、温度及与有机阳离子高分子絮凝剂(CPAM)复配使用效果来考察上述絮凝剂的絮凝能力。实验结果表明,三种絮凝剂均存在其最佳质量浓度,其中PAC与PFS为80~100 mg/L,PEI为70 mg/L;pH将对絮凝效果产生重要影响,其中在碱性范围内将极大提升絮凝效果;当温度在20~40℃范围内对絮凝效果无明显影响;当三种絮凝剂与有机阳离子高分子各自进行复配时对其絮凝能力有着不同程度的增强,其中PEI与有机阳离子高分子絮凝剂复配时絮凝效果要优于其他两种。 相似文献
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利用钛白副产物FeSO4.7H2O、Na2HPO4研制出一种新型复合絮凝剂聚磷硫酸铁(PPFS),研究了该絮凝剂对高岭土模拟水样的絮凝性能及pH值对絮凝效果的影响,并与聚合硫酸铁(PFS)及聚合氯化铝(PAC)比较。结果表明:PPFS的絮凝效果和絮体沉降性能均比PFS、PAC好,且在pH为6 ̄10时絮凝效果最佳。此外,将PPFS用于处理城市生活污水,PPFS除浊的优化用量为4.8 mg/L,而PFS﹑PAC优化用量为6.4 mg/L;CODCr的去除率可分别高达91.4%﹑88.4%﹑86.5%;在pH值为7 ̄9的条件下,PPFS对城市生活污水的浊度和CODCr的去除具有良好效果。 相似文献
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新型复合絮凝剂深度处理焦化废水的效果研究 总被引:3,自引:1,他引:2
对比研究了PAC、PFS和PFAC、新型复合絮凝剂深度处理钢铁厂焦化废水絮凝效果.结果表明新型复合絮凝剂不仅用量最小,而且其除COD、浊度等的效果均好于其他絮凝剂,同时对其絮凝机理进行了初步探讨. 相似文献
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Starch is a known carbohydrate in which, regardless of its origin, two polysaccharides are found namely amylose and amylopectin. By insertion of a cationic moiety to the backbone of starch, a modified cationic starch can be developed which can be used as flocculant. Various grades of cationic starches were developed to optimize the best performing flocculant. The base polysaccharide, starch and the best performing cationic starch i.e., Cat St3 (which have been confirmed from flocculation characteristics and intrinsic viscosity measurement) have been characterized by various characterization techniques such as determination of molecular weight, elemental analysis, FTIR spectroscopy, intrinsic viscosity measurement, thermal analysis, etc. From the characterization, it could be concluded that there was a substantial incorporation of cationic moiety onto the backbone of starch. The flocculation efficacy of these cationized starches was compared with each other and with some of the commercial flocculants available in national and international market in manganese ore suspensions. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
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新型高效复合絮凝剂PFCNS的制备与性能研究 总被引:17,自引:3,他引:14
以工业废渣和淀粉为基本原料,通过阳离子化、接枝共聚和复合三步反应,合成了一种新型高效的复合絮凝剂PFCNS,并探讨了絮凝剂用量对絮凝效果、C ODcr去除效果和透光率的影响.通过对生产废水的絮凝实验,表明PFCNS投药量少,絮凝沉降速度快,CODcr去除率高,絮凝效果优于聚合硫酸铁和聚合氯化铝. 相似文献
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天然高分子改性阳离子型絮凝剂的开发与应用 总被引:28,自引:3,他引:25
天然高分子改性絮凝剂具有无毒,可生物降解,价廉等优点,近年来得到了国内外学者的广泛重视和开发应用。作者对用于废水处理的改性阳离子淀粉衍生物,本质素省生物,甲壳素衍生物以及兼具有絮凝作用的植物胶改性多功能水处理剂的研究进展进行了简要的评述。 相似文献
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Flocculation behavior of cationic pea starch prepared by the graft copolymerization of acrylamide for wastewater treatment 下载免费PDF全文
Yongqiang Zou Shanshan Li Yuqi Wang Chenxi Yuan Weijian Yuan Lan Zheng Xiaolong Han 《应用聚合物科学杂志》2016,133(37)
To improve the flocculation efficiency of coal mine wastewater treatment, we synthesized a cationic flocculant by grafting acrylamide (AM) onto pea starch, and we performed the characterization with elemental analysis, Fourier transform infrared spectrometry, scanning electron microscopy, thermogravimetric analysis, and NMR. The effects of the synthesis conditions were also investigated, and the optimal synthesis parameters of the cationic flocculant were obtained. The mass ratio between pea starch and AM was 0.5 with a reaction temperature of 65 °C. The dosages of ceric ammonium nitrate and 3‐chloro‐2‐hydroxypropyl‐trimethylammonium chloride were 0.02 and 0.11 mol/L, respectively. Application experiments for wastewater treatment were carried out consequently, and the optimal dosage of cationic pea starch was 40 mg/L within the pH range 6–8. Compared with other traditional flocculation products, the cationic pea starch showed the best flocculation behavior for coal mine wastewater. Therefore, the cationic pea‐starch‐grafted AM may be applicable as a novel flocculant in wastewater treatment and has already demonstrated outstanding features. It is bound to replace other traditional flocculants in the future. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43922. 相似文献
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The hydrophobically associating cationic fluorinated polyacrylamide (CFPAM), modified with fluorinated acrylate, 2-(perfluorooctyl)ethyl
acrylate (FEA), has been newly synthesized, by free radical micellar copolymerization in aqueous solution. The solution properties
of these polymers were investigated in details in this study. In addition, the flocculation of CFPAM was also evaluated. The
results showed that there were strong hydrophobic associations in the CFPAM aqueous solution. The addition of NaCl resulted
in an increase of solution viscosity, which indicated the good salt-resistant performance of CFPAM. The polymers also exhibited
excellent property of temperature and shearing tolerance. Furthermore, the polymer showed high surface activity. At the same
time, its flocculation properties were evaluated with kaolin suspensions using a standard jar test. All the results demonstrated
the superiority of the cationic fluorinated polyacrylamide as a flocculant. 相似文献