共查询到20条相似文献,搜索用时 109 毫秒
1.
陈亚宾 《化学工业与工程技术》1998,19(1):45-47
介绍了NCT-10型硫回收催化剂和NCT-11型有机硫水解催化剂的主要性能、活性测试,以及工业使用情况。结果表明:这两种催化剂活性好、强度高,性能达到国外同类产品的先进水平。 相似文献
2.
3.
4.
本以苯乙烯/二乙烯苯为主要原料,经聚合、物理结构稳定化、基团化、磺化、活性基团稳定化技术路线,合成了DNW型耐温树脂催化剂。通过静态/动态热稳定性等温测试等手段与国外同类树脂催化剂进行了对比,结果表明DNW型耐温树脂催化剂活性和热稳定性均达到或超过了国外同类树脂催化剂水平,表现出良好的耐温树脂催化剂活性和热稳定性均达到或超过了国外同类树脂催化剂水平,表现出良好的耐高温稳定性和反应活性,该仙化剂应 相似文献
5.
6.
7.
以微晶纤维素(MCC)为原料制备了碳基磺酸化固体酸催化剂,用该磺化碳固体酸MCC进行糖化水解,考察其催化水解微晶纤维素的最优条件及碳化温度对催化剂催化活性的影响,并对其重复使用性及再生进行了研究。结果表明,反应温度180℃、反应时间6 h、催化剂用量0.15 g为最佳反应条件,最高糖产率为68.71%;400℃为最佳碳化温度。催化剂重复使用后,由于表面磺酸基团的脱落其活性有所下降,可以通过再磺化得到恢复。 相似文献
8.
9.
10.
11.
12.
13.
14.
选用双金属催化剂,合成了窄分布的高相对分子质量烯丙醇聚醚,并采用两步法封端工艺,得到了封端率超过90%的高相对分子质量封端聚醚。在铂系催化体系下,所得封端聚醚与低含氢硅油进行加成反应,制备了软质泡沫用匀泡剂,并对其结构及发泡稳定性进行了初步评价,结果表明该匀泡剂的结构与发泡性能均与国外产品接近。 相似文献
15.
选择Cu为助剂,采用微乳法分别优选具有较好稳定性的Cu和Pd微乳液体系,并将Cu和Pd依次负载于Al_2O_3载体上,经干燥、活化和还原制备了Pd-Cu/Al_2O_3催化剂。采用原位IR、CO化学吸附和HRTEM等对催化剂进行表征,结果表明,与常规溶液负载法制备的Pd-Ag/Al_2O_3催化剂相比,采用微乳法降低了催化剂表面酸性,提高了活性组分Pd分散度,Pd粒径分布更为均匀。在750 mL加氢反应器中,采用C_2后加氢原料对催化剂性能进行评价,结果表明,与常规溶液负载法相比,微乳法制备的催化剂在反应温度低4℃条件下,乙炔转化率相当,选择性高9.9个百分点,绿油生成量较低。微乳法制备Pd-Cu双金属催化剂具有良好的工业应用前景。 相似文献
16.
17.
采用共沉淀法制备Cu-Zn-Al-Mg甲醇合成催化剂,并用XRD、N_2低温吸附、H_2-TPR、SEM、TG-DTG等手段对催化剂进行表征,着重考察焙烧温度对催化剂结构与性能的影响。结果表明,随着焙烧温度的增加,铜锌间的相互作用增强,有利于催化反应进行;但过高的焙烧温度又会导致催化剂中CuO晶粒过大,不利于铜的分散。350℃下焙烧4 h得到的催化剂活性最好; 300℃下适当延长焙烧时间得到的催化剂无法达到相同性能水平。 相似文献
18.
刘明 《化学工业与工程技术》2008,29(2):7-10
对气相苯加氢制环己烷的Pt/Al2O3苯加氢催化剂进行了研究,考察了催化剂的制备方法、Al2O3载体的物性及竞争吸附剂的种类等对催化剂性能的影响,按优化条件制备了Pt/Al2O3苯加氢催化剂。参考工厂苯加氢制环己烷工艺条件,采用加压原粒度活性评价装置,测试了该催化剂的活性和选择性。评价结果表明,该催化剂的主要性能达到了国外同类型催化剂的水平。 相似文献
19.
Sang Joon Seo 《Electrochimica acta》2006,52(4):1676-1682
Cr-modified Pt/C catalysts were prepared by the chemical vapour deposition (CVD) of Cr on Pt/C, and their performance as a cathode of phosphoric acid fuel cell (PAFC) was compared with the case of catalysts containing Cr added by impregnation (IMP).The catalyst prepared by CVD showed a higher activity for oxygen reduction reaction (ORR) than one prepared by IMP. There was an optimum amount of Cr that yielded the maximum mass activity of the catalyst because the gain in the intrinsic activity due to the promotional effect of Cr was counterbalanced by the loss of exposed Pt surface area as a result of the Cr introduction. Nevertheless, the activity increase at the optimum amount of Cr was greater for the CVD catalyst than for the IMP catalyst. Also, the optimum amount of Cr to yield the maximum activity was smaller for the former catalyst [Cr/Pt]CVD = 0.6, than for the latter, [Cr/Pt]IMP = 1.0.The enhancement of the Pt catalyst activity by Cr addition is attributed to two factors: changes in the surface Pt-Pt spacing and the electronic modification of the Pt surface. The formation of a Pt-Cr alloy, as confirmed by X-ray diffraction, decreased the lattice parameter of Pt, which was beneficial to the catalyst activity for ORR. X-ray photoelectron spectroscopy results showed that the binding energies of Pt electrons were shifted to higher energies due to Cr modification. Accordingly, the electron density of Pt was lowered and the Pt-O bond became weak on the Cr-modified catalysts, which was also beneficial to the catalyst activity for ORR.The promotion of oxygen reduction on Cr-modified catalysts was confirmed by measuring the cyclic voltammograms of the catalysts. All the above changes were made more effectively for catalysts prepared by CVD than for those prepared by IMP because the former method allowed Cr to interact more closely with the Pt surface than the latter, which was demonstrated by the characterization of catalysts in this study. 相似文献
20.
J. Georgieva E. Valova I. Mintsouli S. Sotiropoulos S. Armyanov A. Kakaroglou A. Hubin O. Steenhaut J. Dille 《Journal of Applied Electrochemistry》2014,44(2):215-224
Bimetallic Pt–Cu carbon-supported catalysts (Pt(Cu)/C) were prepared by electroless deposition of Cu on a high surface area carbon powder support, followed by its partial exchange for Pt; the latter was achieved by a galvanic replacement process involving treatment of the Cu/C precursor with a chloroplatinate solution. X-ray diffraction characterization of the Pt(Cu)/C material showed the formation of Pt-rich Pt–Cu alloys. X-ray photoelectron spectroscopy revealed that the outer layers are mainly composed of Pt and residual Cu oxides, while metallic Cu is recessed into the core of the particles. Repetitive cyclic voltammetry in deaerated acid solutions in the potential range between hydrogen and oxygen evolution resulted in steady-state characteristics similar to those of pure Pt, indicating the removal of residual Cu compounds from the surface (due to electrochemical treatment) and the formation of a compact Pt outer shell. The electrocatalytic activity of the thus prepared Pt(Cu)/C material toward methanol oxidation was compared to that of a commercial Pt/C catalyst as well as of similar Pt(Cu)/C catalysts formed by simple Cu chemical reduction. The Pt(Cu)/C catalyst prepared using Cu electroless plating showed more pronounced intrinsic catalytic activity toward methanol oxidation than its counterparts and a similar mass activity when compared to the commercial catalyst. The observed trends were interpreted by interplay between mere surface area effects and modification of Pt electrocatalytic performance in the presence of Cu, both with respect to methanol oxidation and poisonous CO removal. 相似文献