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1.
自蔓延高温还原合成法制备TiB2陶瓷粉末   总被引:7,自引:0,他引:7  
采用自蔓延高温合成法(SHS)以B2O3,TiO2,Mg为原料,制备TiB2陶瓷粉料。研究了B2O3-TiO2-Mg(摩尔比为1:1:5)合成系统在加热过程中的物理化学变化规律和TiB2粉末的显微结构特征。结果表明:加热过程中合成系统有预反应,它是由于少量B2O3原造成的;掺加稀释剂对合成材料的显微结构有较的影响并进而影响MgO的化学清洗,微观分析表明,与元素合成的TiB2相比,SHS还原合成的T  相似文献   

2.
本文以FeSO4、7H2O和Na2CO3为原料,制备晶形、粒度、轴比等满足高性能磁粉要求的均匀纺锤形α-FeOOH粒子,研究考察了碱比、〔Fe^2+〕起始浓度、温度、搅拌转速、气量等工艺参数对合成均匀纺锤形α-FeOH粒子的影响规律,并制备出长轴为0.2 ̄0.3μm、轴比为4:1的、大小均匀、分散性好、无枝叉的纺锤形α-FeOOH粒子。  相似文献   

3.
纺锤形γ—Fe2O3微小颗粒的形成   总被引:1,自引:0,他引:1  
用FeSO4和Na2CO3为原料制备纺锤形γ-FeOOH微小颗粒,用透射电镜和X射线衍射观察到纺锤形γ-FeOOH微小颗粒的形成是丝状晶粒的聚集和生长的过程。研究了反应液的PH值和反应时反应气体压缩空气的流量变化对γ-FeOOH微小颗粒形貌的影响,观察了由这种γ-FeOOH制成的γ-FeOOH制成的γ-Fe2O3的形貌,提出提高其磁性能的途径。  相似文献   

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用FeSO_4和Na_2CO_3为原料制备纺锤形α-FeOOH微小颗粒,用透射电镜和X射线衍射视察到纺锤形α-FeOOH微小颗粒的形成是丝状晶粒的聚集和生长的过程,研究反应液的pH值和反应时压缩空气的流量变化对α-FeOOH微小颗粒形貌的影响,观察了由这种α-FEOOH制成的γ-Fe_2O_3的形貌,提出提高其磁性能的途径。  相似文献   

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本文研究了竹红菌素HA,HB以及13-SO3Na-DDHA在DMF-H2O(体积分数ψ=1)混合体系中的电化学氧化还原性质,结果表明,它们都为两步单电子还原过程,反应机理为:油 HA,HB:HA(HB)+e+H^+-HA(HBH)+e-HAH,水溶性13-SO3Na-DDHA:(第一步)13-SO3Na-DDHA+e-13-SO3NaDDHA,(质子化)13-SO3Na-DDHA+H^+-13-S  相似文献   

6.
中温烧结PSBN系统铁电陶瓷结构和性能的研究   总被引:2,自引:1,他引:1  
本文研究了中温烧结PbO-SrO-BaO-Nb2O5(PSBN)系统铁电陶瓷介电性能,通过XRD分析确定了在主晶相为具有钨青铜结构的Pb0.7Ba0.3Nb2O6(PBN)Ba0.27Sr0.75Nb2O5.78(BSN);分析了添加剂MnCO3,TiO2,Fe2O3,(MgCO3)4.Mg(OH)2.5H2O对PSBN系统铁电陶瓷介电性能的影响,由于这些添加剂的作用使该系统铁电陶瓷介电系数提高,  相似文献   

7.
纺锤形α—FeOOH粒子制备   总被引:3,自引:0,他引:3  
本文通过液相法利用FeSO4和Na2CO3为原料制备纺锤形α-FeOOH超细粒子,考查反应温度、浓度和碱比等工艺配方以及加料方式、通气量及搅拌转速等宏观工程因素对最终α-FeOOH粒子形貌的影响,成功地制备出大小为0.2μm左右,轴比3-4,均匀,无枝杈的纺锤形α-FeOOH粒子。  相似文献   

8.
作为除草剂的苯并噻吩化合物的制备WO9909923(BASF)文中介绍了2,3-二氢-4-氯-2-甲基苯并噻吩-7-基)-(13-二甲基-5-羟基-1H-吡唑-4-基)甲酮化合物的制备方法。该化合物以2000g/hm2用量进行芽前处理对茄属植物(Solanum)具有很高的活性。COQR5R3R4R2R1SOn2-苯甲酰环已烷-13-二酮化合物作为除草剂WO9910327(BASF)文中介绍了式中化合物的制备方法及其除草活性。MeMeOOCOONNSO2Me杂环取代的4-苯甲酰吡唑化合物作为除…  相似文献   

9.
制备均匀分散铁红微粉的新方法   总被引:1,自引:0,他引:1  
马子川  魏雨 《精细化工》1998,15(4):45-47
以FeSO4为原料,采用两步法液相氧化工艺制备了均匀α-Fe2O3微粉,研究了反应悬 浮液中Fe(Ⅱ)浓度及初PH值对γ-FeOOH相转化的影响。结果表明,FeⅡ浓度及PH值对γFeOOH-α-Fe2O3相转化时间有很大影响。在PH值近中性时,少量的Fe(Ⅱ)离子对相转化具有显著的催化作用,因而缩短了反应周期。通过改变生长与成核两阶段消耗FeSo4的比值,可方便地人为控制αFe2O3的粒度。  相似文献   

10.
金鑫 《磁记录材料》1995,13(4):11-12,10
在用碱法制备α-FeOOH,进而合成γ-Fe2O3磁粉的过程中,经常加入Zn^2+离子以改善磁粉粒的针形,但因Zn^2+离子的电荷少于Fe^3+离子,因而能使α-FeOOH晶体产生缺陷,最终影响磁粉的性能,本文通过在制备α-FeOOH过程中掺入杂质Mn^2+的方法,探讨消除α-FeOOH晶体缺陷,提高其表观密度,改善磁粉性能。  相似文献   

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Despite its industrial importance, the subject of freeze-thaw (F/T) stability of latex coatings has not been studied extensively. There is also a lack of fundamental understanding about the process and the mechanisms through which a coating becomes destabilized. High pressure (2100 bar) freezing fixes the state of water-suspended particles of polymer binder and inorganic pigments without the growth of ice crystals during freezing that produce artifacts in direct imaging scanning electron microscopy (SEM) of fracture surfaces of frozen coatings. We show that by incorporating copolymerizable functional monomers, it is possible to achieve F/T stability in polymer latexes and in low-VOC paints, as judged by the microstructures revealed by the cryogenic SEM technique. Particle coalescence as well as pigment segregation in F/T unstable systems are visualized. In order to achieve F/T stability in paints, latex particles must not flocculate and should provide protection to inorganic pigment and extender particles. Because of the unique capabilities of the cryogenic SEM, we are able to separate the effects of freezing and thawing, and study the influence of the rate of freezing and thawing on F/T stability. Destabilization can be caused by either freezing or thawing. A slow freezing process is more detrimental to F/T stability than a fast freezing process; the latter actually preserves suspension stability during freezing. Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004 in Chicago, IL. Tied for first place in The John A. Gordon Best Paper Competition.  相似文献   

13.
In 2002–2004, we examined the flight responses of 49 species of native and exotic bark and ambrosia beetles (Coleoptera: Scolytidae and Platypodidae) to traps baited with ethanol and/or (−)-α-pinene in the southeastern US. Eight field trials were conducted in mature pine stands in Alabama, Florida, Georgia, North Carolina, and South Carolina. Funnel traps baited with ethanol lures (release rate, about 0.6 g/day at 25–28°C) were attractive to ten species of ambrosia beetles (Ambrosiodmus tachygraphus, Anisandrus sayi, Dryoxylon onoharaensum, Monarthrum mali, Xyleborinus saxesenii, Xyleborus affinis, Xyleborus ferrugineus, Xylosandrus compactus, Xylosandrus crassiusculus, and Xylosandrus germanus) and two species of bark beetles (Cryptocarenus heveae and Hypothenemus sp.). Traps baited with (−)-α-pinene lures (release rate, 2–6 g/day at 25–28°C) were attractive to five bark beetle species (Dendroctonus terebrans, Hylastes porculus, Hylastes salebrosus, Hylastes tenuis, and Ips grandicollis) and one platypodid ambrosia beetle species (Myoplatypus flavicornis). Ethanol enhanced responses of some species (Xyleborus pubescens, H. porculus, H. salebrosus, H. tenuis, and Pityophthorus cariniceps) to traps baited with (−)-α-pinene in some locations. (−)-α-Pinene interrupted the response of some ambrosia beetle species to traps baited with ethanol, but only the response of D. onoharaensum was interrupted consistently at most locations. Of 23 species of ambrosia beetles captured in our field trials, nine were exotic and accounted for 70–97% of total catches of ambrosia beetles. Our results provide support for the continued use of separate traps baited with ethanol alone and ethanol with (−)-α-pinene to detect and monitor common bark and ambrosia beetles from the southeastern region of the US.  相似文献   

14.
Vismiones and ferruginins, representatives of a new class of lypophilic anthranoids from the genusVismia were found to inhibit feeding in larvae of species ofSpodoptera, Heliothis, and inLocusta migratoria.  相似文献   

15.
A highly moisture-proof polysilsesquioxane coating was obtained from a new bis-silylated precursor, which was synthesized from 3-aminopropyltriethoxysilane (APTES) and m-xylylene diisocyanate (m-XDI) in tetrahydrofuran (THF) and verified by 1H MAS NMR. For direct comparison purposes, an SiO2 coating was also prepared by the Stöber method using tetraethoxysilane (TEOS) as the reactant. Interestingly, the coating obtained from the polysilsesquioxane sol exhibited a much higher moisture resistance capability than its counterpart, which was attributed to its more compact feature between nanoparticles as characterized by N2 absorption experiment and transmission electron microscopy (TEM). Furthermore, its high transparency of about 92% showed potential for application in the protection of optical crystals.  相似文献   

16.
Glycidyl carbamate chemistry combines the excellent properties of polyurethanes with the crosslinking chemistry of epoxy resins. Glycidyl carbamate functional oligomers were synthesized by the reaction of polyfunctional isocyanate oligomers and glycidol. The oligomers were formulated into coatings with several amine functional crosslinkers at varying stoichiometric ratios and cured at different temperatures. Properties such as solvent resistance, hardness, and impact resistance were dependent on the composition and cure conditions. Most coatings had an excellent combination of properties. Studies were carried out to determine the kinetics of the curing reaction of the glycidyl carbamate functional oligomers with multifunctional and model amines. Detailed kinetic analysis of the curing reactions was also undertaken. The results indicated that the glycidyl carbamate functional group is more reactive than a glycidyl ether group. Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, on October 27–29, 2004, in Chicago, IL.  相似文献   

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