共查询到19条相似文献,搜索用时 134 毫秒
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对具有阳离子和两性特征的新型表面活性剂椰油酰胺丙基PG-二甲基氯化铵/椰油酰胺丙基PG-二甲基氯化铵磷酸酯/椰油酰胺丙基羟基磺基甜菜碱与月桂醇聚醚硫酸酯钠复配体系的抑菌、增稠、发泡、耐寒、耐热性能和毒理学等进行测定,并与月桂醇聚醚硫酸酯钠、椰油酰胺丙基甜菜碱和椰油酰胺DEA的复配体系进行对比。结果表明,椰油酰胺丙基PG-二甲基氯化铵/椰油酰胺丙基PG-二甲基氯化铵磷酸酯/椰油酰胺丙基羟基磺基甜菜碱复配表面活性剂与阴离子表面活性剂复配时较其他常用表面活性剂表现出较佳的抑菌、增稠及稳泡性,刺激性低,在洗沐和洗涤剂中表现出更好的应用价值。 相似文献
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以全氟丁基磺酰氟与N,N’-二甲基-1,3-丙二胺为原料制备得到全氟丁基磺酰胺,然后分别与己基磺酰氯和辛基磺酰氯反应得到带烷基支链的全氟丁基磺酰胺,最后将两中间产物与过氧化氢氧化得N’-3-(二甲基)-丙基-(N-全氟丁基磺酰基-N-烷基磺酰基)-亚胺氧化物。通过MS和1H NMR等方法对产物进行了表征,表面张力等性能测试表明,产物具有较好的表面活性,可以作为全氟辛基磺酰胺类表面活性剂的替代品。 相似文献
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脂肪酰胺丙基甲基氧化胺的合成及性能 总被引:2,自引:0,他引:2
本文合成了一系列脂肪酰胺丙基二甲基氧化胺,测试了产物的一些表面物理化学性能将之与传统长链烷基氧化胺对照。结果表明,该类产品的去污力、泡沫力、润湿力及表面张力均接近或略优于烷基基氧化胺,但在HP〈6时用于含AES的香、浴波体系,其增稠性显著优于烷基氧化胺,泡沫性能亦优于烷基氧化胺。 相似文献
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以油酸酰胺丙基二甲基叔胺、3-氯-2-羟基丙磺酸钠和1,4-二溴丁烷为原料,通过两步反应合成了一种磺酸基甜菜碱双子表面活性剂(B18-4-18),通过傅里叶变换红外光谱仪和核磁共振波谱仪对产物结构进行表征,用表面张力仪测定不同浓度下油酸酰胺羟丙基甜菜碱(B18)和甜菜碱双子表面活性剂(B18-4-18)的表面张力,得出表面张力曲线,并用实验室定制的携液量装置分别测定了两种表面活性剂在清水、矿化水中和凝析油中的携液率。结果表明:合成的化合物与预期目标产物一致;在25℃时,B18临界胶束浓度(CMC)为6.1×10-6mol/L,γCMC=34.27 m N/m;B18-4-18的CMC为5.0×10-6mol/L,γCMC=31.67 m N/m;B18和B18-4-18在清水中的携液率分别可达87%、92%,在15万矿化水中的最高携液率分别可达82%、84%,在质量分数10%凝析油溶液中的最高携液率可以达到74%、78%。 相似文献
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以油酸酰胺丙基叔胺,3-氯-2-羟基丙磺酸钠和1,4-二溴丁烷为原料,通过两步反应合成出了一种甜菜碱双子表面活性剂,通过傅立叶变换红外光谱仪和核磁共振仪对合成产物进行了结构表征,用表面张力仪测定不同浓度下油酸酰胺羟丙基甜菜碱(B18)和甜菜碱双子表面活性剂(B18-4-18)的表面张力,得出表面张力曲线,并用实验室定制的携液量装置分别测定了两种表面活性剂在清水中,矿化水中和凝析油中的携液率。实验证明:合成的化合物与预期合成物质一致,在25℃时,B18临界胶束浓度cmc=3.5914?0-6mol/L,相应的表面张力"γ" _cmc=36.2155mN/m,B18-4-18的临界胶束浓度cmc=3.3986?0-6 mol/L,相应的表面张力"γ" _cmc=34.6464mN/m;B18和B18-4-18在清水中的携液率可以达到87%,92%,在15万矿化水中的最高携液率可以达到82%,84%。在10%凝析油中的最高携液率可以达到64%,67%。 相似文献
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针对所研究的甜菜碱乳状液运用了宏观脱水率和微观显微镜观察的方法,并通过粘度计测定了乳状液的粘度,对A(烷基二甲基磺丙基甜菜碱)和B(烷基二甲基羟丙基磺基甜菜碱)两个系列甜菜碱的乳化性能进行了研究。结果表明,AB两个系列甜菜碱的乳化性能都随长烷基链碳原子数的增加先逐渐增强,当A系列长烷基链碳原子数达到14,B系列长烷基链碳原子数达到16,乳化性最好,继续增加长烷基链碳原子数,乳化性能减弱。AB两个系列的甜菜碱都随着浓度的增加乳化性能逐渐增强。随着甜菜碱长烷基链碳原子数的增加,B系列乳化性能好于A系列 相似文献
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以辛酸、N,N-二(3-氨丙基)-甲胺和1,3-丙烷磺内酯为主要原料,通过两步反应设计了一种新型双酰胺型磺基甜菜碱表面活性剂。采用红外光谱、质谱、核磁等方法确证产物结构,并对双八酰胺磺基甜菜碱的表面化学眭能、应用性能进行了研究。结果表明,该产品具有较高的表面活性,25±0.2℃时临界胶束浓度cmc为1.02×10^-3mol·L^-1,1cmc为30.13mN·m^-1,且具有良好的润湿洼、抗硬水性以及钙皂分散性。 相似文献
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Jiayue Lu Wanfen Pu Wei He Binyang Zou Bowen Li Rui Liu 《Journal of surfactants and detergents》2023,26(4):459-475
The synthesis of sulfobetaine surfactants and their application in tertiary oil recovery (TOR) are summarized in this paper. The synthesis of sulfobetaine surfactants was classified into three categories of single hydrophobic chain sulfobetaine surfactants, double hydrophobic chain sulfobetaine surfactants and Gemini sulfobetaine surfactants for review. Their application in TOR was classified into surfactant flooding, microemulsion flooding, surfactant/polymer (SP) flooding and foam flooding for review. The sulfonated betaine surfactants have good temperature resistance and salt tolerance, low critical micelle concentration (cmc) and surface tension corresponding to critical micelle concentration (γcmc), good foaming properties and wettability, low absorption, ultralow interfacial tension of oil/water, and excellent compatibility with other surfactants and polymers. Sulfobetaine surfactants with ethoxyl structures, hydroxyl and unsaturated bonds, and Gemini sulfobetaine surfactants will become an important direction for tertiary oil recovery because they have better interfacial activity in high-temperature (≥90°C) and high-salinity (≥104 mg/L) reservoirs. Some problems existing in the synthesis and practical application were also reviewed. 相似文献
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Cationic surfactant is a chemical substance used in hair conditioner, fabric softener and other household products. By investigating the relationship between the aquatic toxicity and the chemical structures of two types of mono alkyl cationic surfactants, alkyl trimethylammonium salts and alkyl dimethylamine salts, we have found that the C22 alkyl chain length is effective to reduce the toxicity. Besides, we have recognized that the amidopropyl functional group contributes to the enhanced biodegradability by investigating the biodegradation trend of (alkylamidopropyl)dimethylamine salt (alkyl chain length: C18). Based on these findings, we have developed mono alkyl cationic surfactant called APA-22, N-[3-(dimethylamino)propyl]docosanamide salt. APA-22 is formed by the C22 alkyl chain, amidopropyl functional group and di-methyltertiary amine group. We evaluated the aerobic and anaerobic biodegradability of APA-22 by two standard methods (OECD Test Guideline 301B and ECETOC technical document No.28) and found that this substance was degraded rapidly in both conditions. The toxicity to algae, invertebrate and fish of this substance are evaluated by using OECD Test Guideline 201, 202 and 203, respectively. All acute toxicity values are >1 mg/L, which indicates that environmental toxicity of this substance is relatively less toxic to aquatic organism. In addition, we estimated the biodegradation pathway of APA-22 and observed the complete disappearance of APA-22 and its intermediates during the test periods. Based on the environmental data provided above, we concluded that APA22 is more compatible with the aquatic environment compared to other cationic surfactants with mono long alkyl chain. 相似文献
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A new method for the preparation of new heterocyclic amine surfactants based on sulfobetaines is proposed. Interfacial activities of the surfactants obtained in aqueous solution were studied by surface tension measurements. The critical micelle concentration, surface excess concentration, minimum area per surfactant molecule, and standard Gibbs energy of adsorption were determined. The adsorption properties of these compounds depend significantly on the alkyl chain length. Alkyl chain length also affects biological properties of the new surfactants, determining the minimum inhibitory concentration and size of inhibited growth zone. The compounds have high antimicrobial activity. 相似文献
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Synthesis and Interfacial Activity of Novel Heterogemini Sulfobetaines in Aqueous Solution 下载免费PDF全文
Dobrawa Kwaśniewska Katarzyna Staszak Daria Wieczorek Ryszard Zieliński 《Journal of surfactants and detergents》2015,18(3):477-486
Three new heterogemini sulfobetaines and their chloride salts were synthesised. The interfacial activities of the obtained chlorides in aqueous solution were studied by equilibrium and dynamic surface tension measurements. The critical micelle concentration, surface excess concentration, minimum area per surfactant molecule and standard Gibbs energy of adsorption as well as micelle lifetime and diffusion coefficient were determined. The adsorption properties and micelle lifetime of these compounds significantly depend on the length of alkyl chain. The critical micelle concentration decreases with increasing chain length of the compounds considered. The values of the diffusion coefficient of N‐alkyl‐N‐methyl‐N‐(3‐sulfopropyl)‐6‐(N‐alkyl‐N‐methylamino)hexylammonium chloride tend to decrease as the concentration is increased. 相似文献
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通过原料的季铵化合成油酸酰胺羟丙基甜菜碱(S18),S18与二卤代烷反应,得到的Gemini表面活性剂(S18-18)。S18-18用红外光谱(FT-IR)和核磁共振氢谱(1H NMR)进行了表征。在25℃下研究了不同质量浓度的S18-18的表面张力。其临界胶束浓度(CMC)为5.0×10-6 mol/L,表面张力(γcmc)为31.67 mN/m。测定了S18-18的携液率,在清水、250000 mg/L矿化水、质量分数为30%凝析油溶液和质量分数为30%甲醇溶液中,S18-18的携液率分别为90%、76%、63%和79%,数据表明,矿化度、甲醇、凝析油对S18-18的泡沫携液性能影响很小。对比S18与S18-18的携液性能,S18-18的携液性能优于S18。比较3种不同类型表面活性剂与S18-18的液体携带性能,S18-18具有更好的携液性能和泡沫性能。 相似文献
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为了改善储层的非均质性差异,有效提高碳酸盐储层的酸化解堵效果,以长链烷基二甲基叔胺、3-氯-2-羟基丙烷磺酸钠和1,4-二溴丁烷为原料,通过两步反应合成了一系列磺基甜菜碱双子表面活性剂(2C n -SGS,其中n为疏水链中碳原子数,n=12,14,16,18)自转向酸主剂。以2C16-SGS为例,采用FTIR对中间产物(C16-SGS)及2C16-SGS的结构进行表征。通过表面张力法测定2C n -SGS的表面活性,结果表明,2C n -SGS具有良好的表面活性,随着疏水链的增长,2C n -SGS的CMC和表面张力均减小,且胶束化能力增强。可用于黏弹性表面活性剂自转向酸酸化技术,具有良好的转向分流能力,优选配方为4% 2C16-SGS+20%盐酸+20%Ca2+,而且高黏胶束遇煤油等烃类能够自动破胶降黏,易返排对地层无伤害。 相似文献