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选用羧酸类溶剂,采用固相法合成了孔雀石绿-硼酸系列可逆热致变色材料.考察了孔雀石绿和硼酸的配比、羧酸类溶剂的种类与用量对其热变色性能的影响并探讨了材料的变色机理.结果表明,孔雀石绿-硼酸体系的最佳配比(质量比)为1∶100,最佳溶剂为丙二酸,且m(孔雀石绿)∶m(硼酸)∶m(丙二酸)=1∶100∶10时,颜料变色敏锐,色彩鲜艳,变色温度降低到65 ℃,复色时间为25 s,可逆性好.DSC检测颜料的热变色过程发现,样品在58~72 ℃之间出现一个强的吸热峰.复配物体系的变色机理可归结为分子间的电子得失机理. 相似文献
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Fe3+/TiO2光催化剂降解孔雀绿染料的研究 总被引:10,自引:0,他引:10
采用快速溶胶法制备纳米TiO2光催化剂,用Fe^3 对其掺杂改性,并进行了催化剂的X-射线衍射分析(XPd3),傅立叶红外光谱分析(FT-IR),BET比表面积的表征,用于光催化降解水中孔雀绿染料的研究.研究了不同催化剂的光催化活性,确定了光催化剂的用量.结果发现60W紫外光辐射80min,孔雀绿可以彻底降解;可见光下,光催化剂对孔雀绿降解120h,其转化率为98%,COD的去除率为75.3%。可见光下孔雀绿的脱色率和COD的变化不一致,并对其产生的原因和孔雀绿的光催化降解机理作了探讨。孔雀绿的光催化降解符合一级动力学反应规律,反应速率常数随催化剂的用量增加而增大,但增大幅度逐渐减小。 相似文献
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Poly(malachite green) film: Electrosynthesis, characterization, and sensor application 总被引:1,自引:0,他引:1
Poly(malachite green) films were synthesized electrochemically on the glassy carbon electrode in the potentiodynamic mode. The characterization and growth mechanism of as-prepared films were studied with FT-IR spectroscopy, UV-vis spectroscopy, cyclic voltammetry, chronocoulometry, and electrochemical impedance spectroscopy. Charge transfer and ion transport of poly(malachite green) films were investigated in the aqueous solutions with different types of supporting electrolytes. The poly(malachite green) film coated glassy carbon electrode showed catalytic ability towards ascorbic acid and dopamine. The difference of the anodic peak potential of ascorbic acid on the poly(malachite green) film modified electrode from that of dopamine was 180 mV. Based on their voltammetric responses, the poly(malachite green) film coated glassy carbon electrode was utilized as an electrochemical sensor for the content determination of ascorbic acid and dopamine simultaneously and separately in pharmaceutical and injections. 相似文献
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《分离科学与技术》2012,47(17):2689-2699
Cinnamomum camphora sawdust (CCS) was employed as a cheap and effective biosorbent to remove basic dye from aqueous solutions. The biosorbent was characterized by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR). Adsorption experiments were carried out in a batch system as a function of initial pH, adsorbent dose and particle size, ionic strength, initial dye concentration, and reaction temperature. The selected basic dye (malachite green) adsorption onto CCS significantly depended on these factors. By comparative kinetic analysis, the rate of sorption was conformed with good correlation to pseudo-second-order kinetics. Equilibrium data were fitted well by Langmuir isotherm with the maximum adsorption capacity of 155.0 mg/g at the temperature of 318 K and pH 7.0 ± 0.1. Thermodynamic parameters proved that malachite green dye biosorption process was spontaneous and endothermic within the investigated temperature range. The mechanism of adsorption was also studied. It was found that the adsorption of malachite green onto CCS was mainly governed by film diffusion. The electrostatic attractions and ionic interactions between malachite green dye and CCS might be responsible for the adsorption process. The comparative investigation suggested that the sawdust could be considered as a potential adsorbent for malachite green dye removal from wastewater. 相似文献
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In this study, a new type of flexible polyurethane foam containing p-tert-butyl thiacalix[4]arene (TC4A) macrocycle was synthesized. TC4A macrocycle was incorporated into polyurethane foam as a part of crosslinking agent as well as glycerol. Structural, morphological, thermal and mechanical properties of this prepared foam were studied and compared with a polyurethane foam based on only glycerol as crosslinking agent, by Fourier transform infrared (FTIR), Scanning electron microscopy (SEM), Thermal gravimetric analysis (TGA), and dynamic mechanical thermal analysis (DMTA). The effect of introduction of TC4A crosslinker on cream time, rise time, apparent density, and water absorbency of the PU foams was evaluated. Moreover, it was shown that new TC4A-based polyurethane foam (TC-PUF) can be a high performance adsorbent for removal of malachite green from aqueous media using batch adsorption technique. The adsorption results indicated that TC-PUF has a high adsorption capacity of 58.82 mg/g for malachite green due to the presence of TC4A macrocycles in the structure of polyurethane foam. The kinetics of adsorption of malachite green was also investigated using the pseudo-first-order and pseudo-second-order kinetic models. The results of kinetic studies showed that the adsorption of malachite green onto TC-PUF followed pseudo-second-order kinetic model. 相似文献
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《分离科学与技术》2012,47(14):2076-2085
The potential usage of almond shell (P. dulcis), which is an agricultural waste product, in the removal of malachite green from aqueous solutions was evaluated with respect to various experimental parameters including contact time, initial malachite green concentration, temperature, adsorbent concentration, etc. The adsorption kinetics of malachite green fitted well the pseudo-second-order kinetic model. The monolayer adsorption capacity of almond shell was found to be 29.0 mg g?1. The adsorption of malachite green onto almond shell increased with raising the temperature. From the experimental results, almond shell could be employed as a low cost and easily available adsorbent for removal of malachite green in wastewater treatment process. 相似文献
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采用微波辐射-活性炭吸附催化法,研究其处理孔雀石绿染料废水的可行性及其影响处理过程的因素和规律。结果表明:微波辐射-吸附催化法对孔雀石绿染料废水具有较好的处理效果,当孔雀石绿染料废水的质量浓度为250 mg/L,活性炭的投加量为36 g/L,辐射电压为165 V,辐射时间为20 min时,脱色率可达83%;增加活性炭用量、处理时间和染料废水浓度均能提高微波-吸附催化法处理孔雀石绿染料废水的脱色率;微波辐射可加快活性炭吸附催化孔雀石绿的速率,具有加速孔雀石绿裂解和氧化速率的作用。 相似文献
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