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1.
Densification and grain growth mechanisms of Yttria-Stabilized Zirconia sintered by Spark Plasma Sintering are investigated. Sintering trajectories of four commercial submicronic powders with different average particle sizes and yttria amounts have been established and sintering regimes determined. Densification mechanisms are determined in the regime where densification is occurring without grain growth using a model derived from hot-pressing. Grain growth mechanisms are determined using the conventional power law in the regime where ceramics are fully densified. Densification occurs by grain boundary sliding accommodated by an in-series interface-reaction/lattice diffusion of cations or by an overlapping of surface diffusion and grain boundary sliding mechanisms for tetragonal stabilized zirconia and by dislocation climbing for fully stabilized zirconia. A normal grain growth occurs for each ceramic, all composed of a single phase, contrary to the two-phased ceramics obtained in literature where grain growth occurs by segregation at grain boundaries.  相似文献   

2.
结构陶瓷的摩擦磨损   总被引:7,自引:1,他引:6  
本文综述了目前国内外结构陶瓷摩擦磨损的研究现状,重点评述了外部因素(主要包括摩擦方式、环境、负载、滑动速度、温度及时间等)对陶瓷摩擦磨损的影响,内部因素(主要有硬度、强度、韧性、弹性模量、粒径、气孔率、晶界相等)与磨损量的关系及搽恋裂磨损过程的各种模型,并就目前结构陶瓷摩擦磨损研究中的一些问题和热点进行了简要的讨论。  相似文献   

3.
We show that the application of a modest dc electrical field, about 4 V/cm, can significantly reduce grain growth in yttria-stabilized polycrystalline zirconia. These measurements were made by annealing samples, for 10 h at 1300°C, with and without an electrical field. The finding adds a new dimension to the role of applied electrical fields in sintering and superplasticity, phenomena that are critical to the net-shape processing of ceramics. Grain-growth retardation will considerably enhance the rates of sintering and superplasticity, leading to significant energy efficiencies in the processing of ceramics.  相似文献   

4.
SiC颗粒弥散对相变增韧陶瓷高温蠕变性能的影响   总被引:11,自引:1,他引:10  
司文捷  黄勇 《硅酸盐学报》1993,21(3):208-214
  相似文献   

5.
微波烧结钛酸钡陶瓷与常规烧结钛酸钡陶瓷界面偏析研究   总被引:3,自引:0,他引:3  
采用常规9X-4-13型马弗炉和TE103型单模腔微波炉烧结钛酸钡陶瓷,并用透射电镜和能谱相结合的分析方法分别对其晶界发布进行研究。  相似文献   

6.
In this study, calcium lanthanum sulfide (CaLa2S4, CLS) ceramics with the cubic thorium phosphate structure were sintered at different temperatures by field‐assisted sintering technique (FAST). Densification behavior and grain growth kinetics were studied through densification curves and microstructural characterizations. It was determined that the densification in the 850°C‐950°C temperature range was controlled by a mixture of lattice or grain‐boundary diffusion, and grain‐boundary sliding. It was revealed that grain‐boundary diffusion was the main mechanism controlling the grain growth between 950°C and 1100°C. The infrared (IR) transmittance of the FAST‐sintered CLS ceramics was measured and observed to reach a maximum of 48.1% at 9.2 μm in ceramic sintered at 1000°C. In addition, it was observed that the hardness of the CLS ceramics first increased with increasing temperature due to densification, and then decreased due to a decrease in dislocations associated with grain growth.  相似文献   

7.
陶瓷材料的超塑性是细晶多晶陶瓷在高温下的固有属性.本文提出了陶瓷材料超塑性产生的条件、特征和变形机制.综述了国内外Al2O3陶瓷及其复合材料超塑性研究的最新进展,最后指出了今后Al2O3陶瓷材料超塑性研究发展方向.  相似文献   

8.
The elastic-plastic deformation behaviors of nano-grained and coarse-grained yttrium aluminum garnet (YAG) transparent ceramics are investigated using nanoindentation. An inverse Hall-Petch relation is observed for the nano-grained YAG ceramic and a forward Hall-Petch relation is observed for the coarse-grained YAG ceramic. In addition, the plastic work ratio as a function of applied load for the nano-grained YAG ceramic shows a different trend than that for the coarse-grained YAG ceramic. These observations suggest that the plastic deformation of the nano-grained YAG ceramic cannot be attributed to the normal dislocation mechanism and is controlled by grain boundary sliding. A generalized self-consistent model for studying the mechanical behavior of the nano-grained YAG ceramic is developed and validated by experimental results. The stress-strain relationship predicted by this model is embedded in finite element simulations which confirmed that the plastic deformation of the nano-grained YAG ceramic indeed can be attributed to grain boundary sliding.  相似文献   

9.
High-Temperature Tensile Deformation of Glass-Doped 3Y-TZP   总被引:1,自引:0,他引:1  
Amorphous grain boundary phases in 3-mol%-yttria-stabilized zirconia ceramics (3Y-TZP) were studied to determine the influence of intergranular amorphous silicate phases on tensile superplasticity at temperatures of 1300–1500°C. Controlled additions (1 wt%) of compositionally distinct barium silicate and borosilicate phases were used. The initial grain sizes of the pure, barium silicate added, and borosilicate-added samples were 0.45, 0.55, and 0.55 μm, respectively. Systems with added barium silicate and borosilicate glass both exhibited a 60% reduction in flow stress as compared with pure 3Y-TZP, with the lower-viscosity barium silicate system exhibiting a slightly greater reduction in flow stress. The higher-viscosity borosilicate glass/3Y-TZP materials exhibited the greatest elongation to failure, while the barium silicate/3Y-TZP materials had the least elongation. Yttrium was found to segregate to grain boundaries in the pure and borosilicate-containing samples, and both yttrium and barium were found to segregate to grain boundaries in the barium silicate containing samples. No silicon was observed along two-grain boundaries in any of the samples, even those containing pockets of glass. The difference in deformation behavior may be due to a combination of viscosity of the glass addition, grain boundary segregation, and grain boundary bond character.  相似文献   

10.
Nanocrystalline ceramics are expected to possess enhanced superplasticity over their microcrystalline counterparts. In this effort of producing nanocomposites of silicon nitride and silicon carbide, amorphous Si-C-N derived from pyrolysis of a polysilazane precursor was sintered with yttria as an additive. High-pressure sintering at different temperatures resulted in sintered materials ranging from amorphous to nanocrystalline. High-resolution transmission electron microscopy was conducted to characterize the development and grain-boundary features of the nanocrystalline microstructure. The results provide a preliminary understanding of the process of the formation of the nanocrystalline structure from an amorphous matrix, under the condition of high pressure and relatively low temperature. The wide variation in the thickness of grain-boundary phases observed in this material suggests a nonequilibrium state of the grain boundary, which might be related to the processing conditions.  相似文献   

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